• Tertiary alcohol do not undergo oxidation * The order of reactivity of halogenoalkanes is R-I > R-Br>R-Cl>R-F * The order of reactivity

ctivity of halogenoalkanes is Tertiary > secondary >primary

No reaction silver mirror red brown ppt, Cu2O

CO2/Alde
hyde/Ket
polym
ones [Ag(NH3)2]+Tollen’s Alkali, Cu2+Fehling’s [Ag(NH3)2]+Tollen’s (oxi) Alkali, Cu2+Fehling’s(oxidation)
Diol ers

Hydroxy alkane
Yellow ppt HCN nitrile
Cold&dil hot & conc 2,4-DNPH nucleophilic addition
ketones Aldehydes

H+/KMnO4/K2Cr2O7 H+/KMnO4/K2Cr2O7 Redu/H2/LiALH4 H+/KMnO4/K2Cr2O7 H+/KMnO4/K2Cr2O7 Redu/H2/LiALH4

Cracking /Al2O3/SiO2 H+/H2O/electrophilic addition secondary primary

Alkanes Alkene Alcohol Carboxylic acid

H2/Ni/Pt /150C0 concH2SO4/reflux/heat

Primary:SN2/sec:SN1/SN2Ter:SN1 H+/heat H2O/H+

X2/HX/Electrophilic addition KOH(aq)/ Reflux /heat esters

Heat/ Reflux/Nacl+H2SO4/

PCl3/PCl5/SOCl2/p+I2 NH3 Heat/ Reflux/Nacl+H2SO4/

X2/UV/free radicle substitution KOH(alc) nucleophilic substitution PCl3/PCl5/SOCl2/p+I2

H2O

H2O/H+/heat reflux

Acyle NH3/Nucleophilic sub Amide+

Amines Halogeno HCl
Alkane chloride
NH3 /nucleophilic subs alkane HCN/Nucleophilic substitution
nitrile
(Compounds containing CH3-CO- can undergo iodoform reactiob in which , they form yellow ppt of CHI3(Iodoform) when reacted with Alkali(ex:NaOH) and Iodine) By:MR.Syed