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Heat and Mass Transfer MEE 421
Heat and Mass Transfer MEE 421
CHAPTER ONE
INTRODUCTION
Heat and work are two forms of energy that can cross the boundary of a
closed system and both are subjects of engineering thermodynamics, which is a
prerequisite course to heat transfer. A thermodynamics analysis is concerned with
the amount of heat transfer as a system undergoes a process from one equilibrium
state to another. The science that deals with the determination of the rates of such
energy transfer is the heat transfer.
Heat is a transient energy (energy that is transferred between two systems
or between a system and its surrounding) under the driving force of a temperature
difference just as the voltage difference is the driving force for electric current flow
and pressure difference the driving force for fluid flow. Heat as a form of energy
cannot be accumulated; it is always being transferred from one medium of higher
temperature to the other of lesser temperature. Without temperature difference,
there cannot be any heat transfer.
The temperature of a body is a measure of the amount of thermal energy
content of the body. It is a relative measure of how hot or cold a substance is and
can be used to predict the direction of heat transfer. The symbol for temperature is
T. The common scales for measuring temperature are the Fahrenheit, Rankine,
Celsius, and Kelvin temperature scales. When two bodies at different temperatures
are brought together, heat flows from the hotter body to the colder body. In absence
of any change of phase like melting or solidification, the temperature of the hotter
body decreases while that of the colder body increases until the two bodies attain
equal temperature. An isolated hot body transfers its heat to the surrounding until
it attains a thermal equilibrium with the surrounding. The heat flow rate cannot be
computed without knowing the temperature distribution.
A process during which there is no heat transfer is called an adiabatic
process. Adiabatic comes from a Greek word adiabatos, which means not to be
passed. There two ways a process can be adiabatic
1. Either the system is well insulated so that only a negligible amount of heat
can pass through the boundary
2. Both the system and the surroundings are at the same temperature and therefore
there is no driving force (temperature difference) for heat transfer.
2
The symbol for heat is Q. Common units for measuring heat are the British
Thermal Unit (Btu) in the English system of units, the calorie and, kiloJoules (kJ)
in the SI system (International System of Units).
. Work is an energy interaction that is not caused by a temperature difference
between a system and its surroundings. It is simply energy transfer associated with
any force acting through a distance. There are two requirements for a work
interaction between a system and its surrounding. There must be a force acting on
the boundary and the boundary must move. We have various types of work:
1. Electrical work. Electrons in a wire move under the effect of electromotive
forces, doing work. When N coulombs of electrical charge move through a
potential difference V, the electrical work done is
We= VN
When expressed in rate form. (I = N/t)
W = VI (Watt)
2. Mechanical work
Work W, = The product of Force, F and displaced distance, s.
Mechanical work can take the form of shaft work, spring work, work done on
elastic solid bars, work associated with the stretching of a liquid film, work done to
raise or accelerate a body
Shaft work: Energy transmission with a rotating shaft is very common in
engineering
Power transmitted is Work done per unit time = T = 2N T Watts
Spring work: When a force F is applied to a spring, the length of the spring changes
by dx
W = F dx
For linear elastic springs, F = kx
W = ½k (x22-x12) kJ
The work done to raise a body (or move a car uphill at a constant velocity) is the
work that needs to be done per unit time to raise the elevation of the car. This is
equal to change in the potential energy of the car per unit time (mgVvertical).
The average power required to accelerate a car to a specified velocity is simply the
change in the kinetic energy of the car in addition to the power required to overcome
friction, rolling resistance and other irreversibilities.
that possess higher kinetic energy impart their energy to other molecules of lesser
kinetic energy in succession. Conduction can take place in solids, liquids or gases.
In solids, conduction is due to a combination of vibrations of the molecules in a
lattice and the energy transport by free electrons. This explains the reason why
metals have higher heat conduction ability than other conductive solids.
Conduction cuts across the boundary of a solid into another body that makes contact
with it. In liquid and gases, conduction is due to the collisions and diffusion of the
molecules during their random motion. Conduction in liquids and solid dielectrics
is by means of elastic waves.
The rate of heat conduction through a medium depends on the geometry of
the medium, its thickness and the material of the medium, as well as the temperature
difference across the medium. The conduction law is generally based on
experimental observations made by Biot and named after Fourier. The Fourier law
governs conduction heat transfer and it states that the rate of heat flow by
conduction through a layer in a given direction is proportional to the temperature
difference across the layer and the area normal to the direction of heat flow.
Mathematically,
𝑇1 −𝑇2 ∆𝑇
Qcond = kA = -kA∆𝑥 (Watt)
∆𝑥
𝑑𝑇
𝑄𝑥 = −𝑘𝐴 𝑑𝑥 T
𝑇2− 𝑇1
𝑄𝑥 = −𝑘𝐴 ∆𝑥
𝑇1− 𝑇2
𝑄𝑥 = 𝑘𝐴 ∆𝑥
T1 T(x)
T2
x
Figure 1
For this situation, T1 > T2 hence (T2 – T1) is a negative quantity. The
negative cancels the negative sign in the equation to give a positive Q x in the
positive x direction.
The heat flow rate per unit area is called the heat flux i.e.
qx = Qx/ A W/m2 ____________________________(2)
From the definition of Fourier’s law (eqn 1), some terms arise that required
more explanatory notes. These terms are: temperature field, temperature gradient &
thermal conductivity.
TEMPERATURE FIELD
Conduction in solids is generally accompanied by variations of temperature both
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in time and space. Analytical investigation of heat conduction amounts to study of the
space-time variation of temperature i.e. to determine the temperature field T as a function
of space coordinates and time. This is expressed mathematically as.
T = f (x, y, z, t,)
𝑑𝑇
≠0 --------------------------------------------------4
𝑑𝑡
This is the temperature of a particular location in space being studied at any given
time t. This kind of temperature field is called transient state temperature field because of
its dependence on time. The other kind is of a steady state i.e. it is a function of the space
coordinates only
T = f (x, y, z) ____________________________________________ 5
𝑑𝑇
=0
𝑑𝑡
TEMPERATURE GRADIENT
The temperature gradient is a vector normal to the isothermal surface and is
positive in the direction of increasing temperature. The isothermal surface of a body is the
locus of points of identical temperature, in a temperature field. The temperature in a body
varies only in directions crossing isothermal surface. The greatest temperature difference
per unit length is observed in the direction normal to the isothermal surface. Temperature
gradient is the temperature derivative along the normal n i.e.
dT
Grad T = ----- ______________________________6
dn
The component of grad T in x, y and z axes are:
dT
grad T)x = ----- ______________________________7
dx
dT
grad T)y = ----- ______________________________8
dy
dT
grad T)z = ----- ______________________________9
dz
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General observations & comments on the table of thermal conductivities of materials are:
(1) Solid is a better conduction of heat than a liquid while a liquid is a better conductor than a
gas. For example, Mercury can exist in three phases at different temperature. At about –
193oC it is a solid with thermal conductivity of 48.44 W/m oC. It is a liquid at 0oC with
thermal conductivity of 8.21 W/m oC and finally on a gas at 200oC its thermal conductivity
is reported to be 0.034W/m oC. The difference is due to change in molecular structure as
the substance change from one phase to another. Molecules of solid are closely packed
while that of liquid gases are loose packed in varying degree.
2 Crystalline structure of some solids like quartz and metals enhance a higher
thermal conductivity than an a morphine solid such as glass. The crystalline structure
provides an additional heat transfer as a result of a vibratory motion of the crystal lattice as
a vibratory motion of the crystal decreasing temperature. Any imperfection in the lattice
structure decrease the conductivity of the substance.
3 Metals have greater conductivities than do nonmetals. Besides the mechanism of
molecular communication and lattice vibration through which heat energy is transferred in
crystalline solids, metals have an added advantage of free electrons that drift in the
direction of the decreasing temperature on account of these free electrons in pure metal
their high thermal and electrical conductivities are enhanced. Thermal conductivity in case
of pure metals is the highest. It decreases with increase in impurity. Also, the thermal
conductivity of most metals decreases with the increase in temperature (aluminium and
uranium being the exceptions)
4 Alloy metals have lesser thermal conductivity than pure metals. Thermal conductivity of
alloys increases with increase in temperature
1.3.2 Thermal conductivity of solid substances
(a) Pure metals and metal alloys
Electrons are the principal agent of heat transfer in metals. They are also responsible for
electrical current transmission in metals. Both thermal & electric conductivities are
proportional to each other. Some of the factors are chemical composition, atomic structure,
phase changes, grown size, temperature, pressure and deformation of all these, only
temperature effect is usually accounted for.
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from liquid metals, water has the highest value of thermal conductivity of any liquid. It increases
with temperature and rises to a maximum at about 130oC and falls with increasing temperature.
The thermal conductivity of liquid metals are significantly greater than that of other liquid
substances. K for liquids range between 0.07 to 0.7 W/m oC.
2.3.3 Thermal conductivity of gases
Heat transfer by conduction in gases at ordinary pressure and temperature occurs
through the transport of the kinetic energy of molecular motion arising from the random movement
and collision of the gas molecules. The thermal conductivity of gases is determined by the relation
that follows.
K = 1/9 V LCv ________________10
Where
V = mean travel velocity of gas molecules
L = mean the path of gas molecules during the internal between collisions
Cv = specific heat of gas at constant volume
= gas density
Thermal conductivity of gases does not depend on the pressure exerted except at
very low and very high pressures. As pressure increases gas density increases to the same extent
while it diminishes in inverse proportion, and the product L remain constant. The mean travel
velocity V of gas molecule and the specific heat of gases increase with temperature increase.
V = (3RmT)/M _________________11
Where
Rm = Universal gas constant = 8314.2 J/Kmol.K
M = Molecular weight of gas.
T = absolute temp, K.
This explains why the thermal conductivity of gases increases with temperature
increase. The range of K for gases is from 0.006 to 0.6 W/mo C
Thermal Resistance
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By analogy, heat transfer may be compared with the flow of current in an electrical resistance. As
the flow of electric current, I, is directly proportional to potential difference, dV, so also heat flow,
Q, is directly proportional to temperature difference, dT
By Ohm’s law,
𝑑𝑉
𝐼= 𝑅
𝑑𝑇
By analogy, heat flow equation (Fourier law) may be written as:𝑄 = 𝑑𝑥
𝑘𝐴
The reciprocal of Rth)cond is called thermal conductance. The rule for combining electrical
resistance in series and parallel equally applied for thermal resistance.
Q
1 2
𝑑𝑥
𝑅𝑡ℎ = 𝑘𝐴
dT
Q = - KA
dx
T2 – T1 -50
= -KA ---------- = -(70) (2) -----
t 0.05
= 140000W
16
= 140KW
Example 2
The inside and outside surfaces of a window glass are at 20oC and –5oC respectively. If
the glass is 76 cm by 15.3 cm in size and 1.5cm thick, with a thermal conductivity of 0.78 W/moC,
determine the heat loss through the glass over a period of 2 hours.
Solution
t = 1.5m
k = 0.78 W/moC
T1 = 20oc, T2 = -5oc
A = 76 x 15.3 cm2
Fourier law
Q = -KA dT/t
= -(0.78 (0.76 x 0.153) x (-5 – (20)
0.015
= 151.16 W
The heat loss through the window glass over a period of 2 hours becomes
Heat loss = Qx t
= 0.1512 x 2 = 0.302 KW.h
Example 3
The heat flux through a 10cm thick layer of loosely packed rock root for a term difference
of 100oc is 75 W/m2. What is the thermal conductivity of the packed rock root?
Solution
Given t = 10cm
t = 100oc
q = 75 W/m2
Required To find K?
From Fourier Law
q = K T/ t
k = q t / T
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= (75 x 0.1)/100
= 0.075 W/m .oc
Exercise 1
1 If 3 kW is conducted through a section of insulating material 1.6m2 in
cross-section and 2.5cm thick and the thermal conductivity may be taken
as 0.2 W/m.oC, find the temperature difference across the material?
2 A temperature difference of 86 oC is impressed across a fiber glass layer of
15cm thickness. The thermal conductivity of the fiber glass is 0.035
W/moC. Compute the heat transferred through the material per hour per
unit area.
3 The heat flow through a 4cm thick corkboard for a temperature difference of 100 oC across
the surface is 0.1 kW/m2. What is the thermal conductivity of the corkboard?
4 The temperature of the hot surface of 5cm thick insulating material of
(k= 0.026 W/m oC) is maintained at 500oc. If the heat flux across the material is 20W/m2,
what is the temperature of the cold surface?
5 The roof of an electrically heated home is 6 m long, 8 m wide, and 0.25 m thick, and is made
of a flat layer of concrete whose thermal conductivity is k = 0.8 W/m oC. The temperatures of
the inner and the outer surfaces of the roof one night are measured to be 15 oC and 4oC
6. A plane wall (thermal conductivity = 10.2W/moC) of 100mm thickness and area
3m2 has steady surface temperature of 170oC and 100oC, determine
1. the rate of heat flow across the plane wall
2. the temperature gradient in the flow direction
1.3.2 Convection
Convection is a mechanism of heat transfer initiated when temperature difference exist
between a fluid and a solid boundary. Heat is transferred by convection as a portion of the
fluid moves and mixes with another. The actual process of heat transfer from one fluid
particle to another is one of conduction but the transport of energy from one point in space
to another is by the motion of the fluid itself. This motion can be induced by density
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gradient created by temperature difference which exist in the fluid and externally by
mechanical means e.g. by a fan, pump etc. The former process of heat transfer is called
free or natural convection and the latter process is the forced convection. The circulation
of water molecules in a heated container is an example of free convection. The flow of
fluid within the tubes of heat exchanger with the aid of pump as it occurs in car radiator is
an example of forced convection.
Heat transfer process that involve change of phase of a fluid are also considered to
be convection because of the fluid motion induced during the process, such as the rise of
vapour bubbles during boiling or the fall of the liquid droplets during condensation.
Convection heat transfer is more difficult to analyses than conduction because it is
a combined problem of heat and fluid flow. The rate of heat transfer is influenced by all
the fluid properties that can affect both heat and fluid flow such as velocity, thermal
conductivity, viscosity, density and thermal expansion. The basic laws of heat conduction
must be coupled with those of fluid motion in order to describe the process of heat
convection mathematically. These include the equation of motion, energy equation,
continuity flow equation and Fourier’s law of conduction. The resulting system of
differential equations can only be solved numerically with the aid of computer simulation.
In engineering application, Newton’s law of cooling is used to simplify the flow of
heat from a hot body into a cold fluid. The law states mathematically thus:
q = h (Ts– Tf) --------------------------------------13
Where q = heat flux W/m2
h = heat transfer coefficient W/m2. OC
Ts = Temperature of hot body
Tf = Temperature of a cold fluid
And if the heat flux is from fluid to the wall, the above is written thus:
q = h (Tf – Ts)
The value of h depends on some many factors such as:
1 Flow type – whether laminar or turbulent
2 Temperature difference
3 Mechanism of heat transfer – natural or forced
4 Geometry of the body
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Fluid flow Tf
Q Ts > Tf
Ts
Q
Ts Tf
1
𝑅𝑡ℎ = ℎ𝐴
𝑇𝑠 − 𝑇𝑓
𝑄=
1
ℎ𝐴
1
The denominator, ℎ𝐴 𝑖𝑠 𝑐𝑎𝑙𝑙𝑒𝑑 𝑐𝑜𝑛𝑣𝑒𝑐𝑡𝑖𝑜𝑛 𝑡ℎ𝑒𝑟𝑚𝑎𝑙 𝑟𝑒𝑠𝑖𝑠𝑡𝑎𝑛𝑐𝑒 Rth/conv to heat flow.
Comparing Fourier law of equation 1 and the Newton’s law of cooling equation 13 at the wall, i.e.
at y = 0, we shall have
𝑑𝑇
ℎ(𝑇𝑠 − 𝑇𝑓 ) = −𝑘
𝑑𝑦
𝑘 𝑑𝑇
ℎ = − (𝑇 −𝑇
𝑠 𝑓 ) 𝑑𝑦
This equation relates heat transfer coefficient, h, with thermal conductivity and the temperature
gradient at the surface. This is used in the experimental determination of h.
Example 1
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Water at 20oC flows over a flat plate at 80oC and if the heat transfer coefficient is 200W/m2
O
C, determine the heat flow per square meter of the plate.
Solution
q = h (Tp – Tf)
Tp = Temperature of plate = 80 oC
Tf = Temperature of water = 20 oC
h = 200 W/m2 oC
q = 200 (80 – 20)
= 200 x 60
= 12000 W/ m2 = 12 kW/m2
Example 2
Determine the rate of heat flow to the cold air which flow at 10oC over a tube of 6m length
and 2cm OD. The surface of the tube is maintained at 100oC and the heat transfer
coefficient between this outside surface of the tube and the cold air is 100 W/m2 oC
Solution
Tf = 10oC
Tr = 100oC
h = 100 W/m2. oC
dia = 0.02m
L = 6m.
Example 3:
A 2 m long, 0.3 cm diameter electrical wire extends across a room at 15oC, as shown in the
figure below. Heat is generated in the wire as a result of resistance heating, and the surface
temperature of the wire is measured to be 152oC in steady operation. Also, the voltage drop and
electric current through the wire are measured to be 60V and 1.5A, respectively. Determine the
convection heat transfer coefficient for heat transfer between the outer surface of the wire and the
air in the room. Assuming heat transfer by radiation is negligible.
Solution
A steady operating state exists when the temperature reading do not change with time.
At this point, the rate of heat loss from the wire equals the rate of heat generation in the wire as a
result of resistance heating.
Q = h A (Ts -Tf) = 90 W
90 90
ℎ= =
𝐴(𝑇𝑠− 𝑇𝑓 ) (0.01885)(152 − 15)
h = 34.9 W/m2 oC
Exercises 2
1 A 50cm diameter pipeline carries hot oil at 30oC and is exposed to a
surrounding temperature of –10oC. A special kind of powder insulation of
5cm thick surrounds the pipe and has a thermal conductivity of 7m W/moC the convection
heat transfer coefficient on the outside of the pipe is 12W/m2.oC. Estimate the energy loss
from the pipe per meter of length.
2 A 25cm vertical wall with a surface temperature maintained at 50oC is suspended
in atmospheric air at 25oC. Determine the heat flow rate by free convection from the wall
to the air.
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3 Cold air at 0oC is forced to flow over a flat plate maintained at 30oC. The mean
heat transfer coefficient is 50W/m2.oC. Find the heat flow rate from the plate to
the air permit area
1.4. 3 Thermal Radiation
Radiation is the energy emitted by matter in the form of electromagnetic
waves (or photons) as a result of the changes in the electronic configuration of the atoms or
molecules. Heat can be transferred by radiation in a vacuum without any material carrier or
intervening medium. The process of heat transfer by the means of electromagnetic waves emitted
at the surface of a body, which has been thermally excited because of their temperature, is called
thermal radiation. The rate of heat transfer through this mechanism depends only on the
temperature and on the optical properties of the heated body which convert its internal energy into
radiation energy. Thermal radiation differs from other forms of electromagnetic radiation such as
x-rays, gamma rays, microwaves, radio waves, and television waves because they are not related
to temperature.
All matters-solid, liquids and gases at temperatures above absolute zero emit,
absorb, or transmit thermal radiation at varying degrees. The emitted radiation, when strikes
another body may be absorbed, transmitted or reflected partly in a ratio that depends on the nature
of the body. The heat of the sun is the most obvious example of thermal radiation.
In the analysis of thermal radiation the engineering concern is to know the total
quantities of radiation energy emitted and absorbed by matter at various temperatures. The basic
laws used in the estimation of these quantities of radiation energy are: Stefan-Boltzmann,
Kirchhoff’s and Wien’s laws.
The radiation energy leaving a body through its surfaces actually originates from
the interior of the body. And when incident on another body, it penetrates into the interior of the
body where it is absorbed. Bodies like metals, wood, stone, rocks and paper that do not allow
thermal radiation to be transmitted through them are opaque objects. For these objects, radiation
is considered to be a surface phenomenon. Those that permit transmission of thermal radiation are
called semi-transparent bodies e.g. a sheet of glass. Generally the propagation of thermal radiation
in a medium is weakened as a result of absorption. This weakening effect is not found in a vacuum.
Therefore, a vacuum is considered completely transparent to radiation.
According to Stefan – Boltzmann law, the maximum rate of radiation that can be
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1
𝑅𝑡ℎ =
𝐴𝑠 (𝑇𝑠 + 𝑇𝑓 )(𝑇𝑠2 +𝑇𝑓2 )
𝑇𝑠 −𝑇𝑓
Q= 𝑅𝑡ℎ
Emissivity has a value which range from 0 to 1. It is a measure of how close a surface approximates
a blackbody which has = 1. A blackbody is a perfect emitter. For a non-blackbody surface,
<1.
An radiation flux (qi) incident on a blackbody is absorbed completely i.e.
qi = qa
where qa - radiation absorbed.
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A blackbody is a perfect absorber with absorptivity = 1. The situation is different for a non-
blackbody, only a fraction of the incident radiation is absorbed. This depends on the absorptivity
of the body
qa = qi
Note: = for a real, non-blackbody.
Both and of a surface depend on the temperature and the wavelength of the radiation.
According of Kirchoff’s law of radiation, the emissivity and the absorptivity of a surface
at a given temperature and wavelength are equal. For opaque surfaces, the portion of incident
radiation not absorbed by the surface is reflected back. The difference between the rates of
radiation emitted by the surface and the radiation absorbed is the net radiation heat transfer.
Note: Radiation is usually significant relative to conduction or natural convection but negligible
relative to forced convection especially when the surfaces involved have low emissivities.
Wien’s law states that the wavelength 𝜆𝑚 corresponding to the maximum energy is
inversely proportional to the absolute temperature T of the hot body. That is the product of
wavelength and temperature is a constant.
𝜆𝑚 𝑇 = 𝑐𝑜𝑛𝑠𝑡𝑎𝑛𝑡
Example 6
A hot surface at a temperature of 400k has an emissivity of 0.8. Calculate the radiation
flux emitted by the surface.
Solution
q = T4
= 0.8
T = 400k, T4 = (400)4 k4
= 5.6697 x 10 –8 W/m2.k4
q = 1.161 kW/m2
Example 7
A radiation flux of 1000W/m2 is incident upon a surface that absorbs 80 percent of the
incident radiation. Calculate the amount of radiation energy absorbed by a 4 m2 area of the surface
over a period of 2 hour.
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Solution
qi = 1000 W/m2
= 0.8
qa = qi = 800 W/m2
Qa = A qa = 4 x 800 = 3200 W
Qa= 3.2 KW
For over a period of 2 hours,
Qa = 6.4 KW h.
Exercises 3
1 A blackbody at 30oc is heated to 80oC. Calculate the increase in its emissive power.
2 A solar radiation flux at 700W/M2 is absorbed in a metal plate which is perfectly
insulated coefficient on the plate is 11 W/m2 oC and the ambient air temperature is
30oC. Calculate the temperature of the plate under equilibrium conditions.
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