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    CH 12

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    Zeel Shah

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    © All Rights Reserved
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    14, Calculate the potential ofthe following cal ala temperature of 208 K. Mg/Mg2+(0.13m) || Cl (0.001M) | Cie | pt E*Mg+2/Mg-= -2.36v E°CLICI =1.36 v 15. Derive the formula for the rate constant and haltlfe fora first-order process. 16. Write the reactions of KMnO4 in acidic medium with (i) Fe** (ii) CO, SO, ion. 117. Write the difference between operation of SN and SN2 process. 18. Explain dehydration of alcohol. 419, Wile the cross aldol process of ethanol and propanal and waite the IUPAC names ofthe products obtained. 20, Write the stepwise processes for the preparation of orange azacolor from banzenamide, 21. Explain that he boling point of an amine compound having the same carbon number is higher than that ofa halogen compound while that ofan alochol compauind is lower. Section : C The following question no. Answer any 4 questions from 22 to 27 as required. (Each question carries 4 marks.) [16] 22. 0.6mlL of acetic acid (CH,COOH) having a density of 1.08 g mL-tlis dissolved in 1 L of water. The deceleration at its vertex is 0.0205 °C. So for that consider Vanthoff factor and'dissociation constant of acid. [kf = 1.86 K kg mol’] [Molecular mass of acid = 60 g mol-"] jgm 23, Explain the chemistry of ferrous salts and write down its prevention 24, The lime required for 10% completion ofa first-order process at 298 k is the same as the time required for 25% completion of the same process at 308 k. Calculate k and Ea at 318K if the _ value of A is 4 x 100 S" 25. K [Cr({I:O), (C202)2] *31120 Syndication Sambhan Nien Question 4th So. (0 We the IUPAC name ofthe compound (ii) State the index and magnetic field value of the metal. (spin based only) (i) Assen 0 6 wn Sit ng face crenata (iv) State the number of its spatial coefficient8. 26. Write the bromination; nitration, alkylation and acylation processes of anisole. 27, Wte the only equation forthe formation of benzaldehyde fom each ofthe folowing compounds (i) Benzoyl chloride (ii) Benzonitrile (ii) Toluene (iv) Benzene 12 Gujarat Board of Secondary and Higher Secondary Education, Gandhinagar Class-12 (Science Stream) Chemistry (052) ‘Annual Examination PART - B Time : 2 hrs Total Marks : 50 Instructions: (1) Part B of his question paper consists of thre sections A,B and Cn otal (2) _Allsections are compulsory. General options are provided in each section. (3) Thenumeral tothe right of a section indicates its marks, (4) Write a new section on a new page. (2) We te sosues oe esbons inorder (6) Maintain legible satin (7) Students will be able,to use simple calculators and log tables where necessary. Te, or Section : A > ® The folowing question no. Answer any 8 questions from 1 to 12 in shor. 3. [16] Cats each sin - 1 sara pecnice tte peeingcsmagmneimscinavess yf) 2 mang hela anther a Ss 3. An aqueous solution of Cuci:is colored while an aqueous solution of Cu. is coleress. Why? set 4.The second ionization enthapy of chromium is higher than the second nizatin enthalpy of manganese Give a reason, 5. Drawthe geometrical constants of {CotNH), (NO oO © Explain the nature of bonding in metal carbon ~~ 1. Give he transformation: benzyl alcoho rom toluene @ 8. Explain wurz fitting procedure with example. 8 Wie the equation forthe formation of phenol by cumin method 10. Write the reactions of cyclopentane carbaldehyde with () phMgBrtH+ and (i) NHsNHCONHE. 11. Explain the presence of ~CHO group in glucose by process equation, 42. Differentiate : globular and fibrous proteins Section: B © Tre Totoving question no. Wie the answer to any 6 questions rm 18102. (Esch question cares Smarts) [18] 13, Derive a formula for finding the molecular mass of the salute based on Raoul’ law fora soluton formed by dissolving ‘a non-volatile solute in a volatile solvent, ste 45. Choose the correct statement for the given combination. (A) Ring-1 is more active than ring-2 for electron-loving displacement. {) On bromination in the presence of anhydrous AICI the Br group wil atach tothe para position in ring 2. (C) CO. Group +1 shows effect and NH- group shows -R effect. (D) Both have ringlike reactivity in an electron loving displacement process. 48. By which method can the diference between aniline and benzyl amine be distinguished? (A) CHCI3/KOH (8) NaNO, + HCL (CQ) C,H,80,C1 (D) CHicOCI Sa 47, What is the number of chiral carbon atoms in one molecule of glucose? (A) 4 ®) 5 ©.3 ©) 6 48, Which amino acid does not have a primary amino group? (A) Proline (B) Glycine (C) Alanine (p) Giutamic’acid 49. Which odd eyclic base is not present in DNA? (A) Adenine (B) Guanine (C) Uracil (D) Thymine 50, Glucose does not react with which ofthe following reactions? ® ~ “ ne (© (@)NaHsos = ©) -NH,OH —(D) (CH.CO), Q = & & ® =) . > 2% O ? © ° % e 10 40, Which ofthe following is the result ofthe process shown incorrectly? we j=) 41. Which ofthe following compounds does nt give a cannizer process? o (a) Bt Miny A WV, ® Mey, Le Oey © ©) ® Sey icy ‘Al EDUCATION 42. Which substance is useful inthe productiprf nylon 6, -CHACER a p (A) Malonie acid (8) Succinic acids (C) Glutaric acid ()Adipicacia | 43. Select the correct option based on the given property. (A) C.H.NH, <(CaHts), NH < (CHa), N (Vayuskh3pabhan ming prastha) (B) (CH,), NH > C,H.NH, > C,H,OH (Gcserrilg) (C)CH3NH2 <\C,H.NH, <(C:H2);NH (H:O mother solubility) (0) p= nitro aniline < p- toluidine < aniline (predominance of basicity in water) “4 Which compound gives carbyl amine test.1. gives, the dyer (A) p-Methyl benzyl amine (B) N-methyl ethanamine (C) N-ethyl-N-methy! ethanamine (D) NN dimethyl amino base 34. Which diazonium salt is insoluble in water? (A) OH.NiCI- (B) C.H.NHSO; (© CgtNzBF, ©) OHNBe 36, Which of the following is associated with maximum stabilization energy? 36. Which of the following ions is not electron loving? (A) CHS @ ¢xo, thank You 37. What is the maximum stable yield for the following process? (D) CH.COo CH, —CH-CH—CH,—™.(2) CH3 . CHS BH CH=CH CH3-C-CH2-CH3 a CH3 Br (3) i a CH3 © a = + gd " S ey Sectieaece + cH3-c-CHe-cHa S Os CH2Br S be 2 se ¢ pe 2”, _ the most stable product of dehydration for the process -CH2-OH H? (A) (yee @B) poy © <_y os ©) Con, 39. What will be the number of phenolic isomers having the atomic formula CHO? A) 4 ®) 5 O6 ©) 3 25, Select the correct hybridization for the transition metal ion or molecule, (A) Kx[Ni(CN)> SP3 (B) [Ni(NH,)}*> d2sp? (© [Fe(Co),]— sp’ ) [Fe(CN),[P >sP'a? 28. Which complex compound is colourless? (A) K,cro, @) [za(nH,), J” (C) [Fe(CN)]” () K,[Mno,] 27. Which ofthe following processes does not show cleavage of C-O bond of alcohol? (A) ROH+PCI, (B) ROH+SOCI: (© ROH+HCI . ROH +.Na 28. Which hydroxyl group in the {a#Wing compound shows.the most reactivity with sodium ww Z Ay. ye a “ ll jou’ ev cal 29, Which functional groups are present in vanillin? o| @ (A) -COOH, -CHO, -OH (B) -OH, -CH3, -COOH & (©) -cilo, -c1, -coou (D) -CHO, -OH, -OCH3 8 50. Tho reduce of ho condensation proces beeen berzalehyde and acstophenone have the namie stra and tarde see An (A) 24 and 6 (B)27and8 © (C)27and6 ~—(D) 24 and 8 31, Jones's reaction ch. u @) Kcro/H ®) God, © Cr0,+HS0, Gandhi, ©) KMn0,/H,s0, 32. Which substance is used as a food preservative? (A) CH,COONa (B) C,H,ONa (©) HCOONa ©) C,H,COOH 33. Which process does not form a primary amine? (A) CH,CONH, Yr > ®) cH,cons, — 0°04, (C) CH3NC — uaa (D)CH:CN 5 49. Number of spatial isomers of [Cr(Ox), Chl]. a (A) 5 @) 2 © 3 (D) 4 20. Which isomer of CrCi3.6HLO is dark green and precipitates one mole of silver chloride when treated with a solution of excess AgNO? (a) [Cr(H,0), Jel, ce [Cr(H,0), CI]CLH.O (©) [Cr(H,0), Cl, Cl-2H,0 ww, (£t(H.0)}, C1, ]-3H,0 21. Choose the correct option for the given diagram. harrodlamaredape\ efeaawerts (C) AHL (D) eouganow. oO 22, veh ie tho coro order of megnati cao? O, sy (A) Cr3+ < Mn+ < Fe3t (B) Cut > 2n2t> cS %. _ What product of Mn is obtained by heating KMnO,, at 513K? me (C) T+ ‘So what wil bs the order of process with respect to.NO? er (A) 3 2 ol 1. Saroj Yo. 17. Which of the folowing GomBhation fs mat BASIC 2012 (A) La(oH)3. ®) smOH; (© TmOH), (0) Lu(OH)3 418, Which ofthe folowing is @ Wikkinson stimulant? (A) [(PAP), RiCT] (© [(PA,P), RCI, ] @) [(Ph,P), Ret] @) [(Ph,),P RaCr] Gujarat Board of Secondary and Higher Secondary Education, Gandhinagar Class-12 (Science Stream) Chemistry (052) ‘Annual Examination Time: 3 hrs Sample Question Paper Total Marks : 100 PART - A Time: 1 hour Total Marks : 50, Insucions_: (1) Part of his question paper contains 50 questions of muliple chole type. All questions are compulsory is wirat rate? 2) Queton ran Bit S FE OANd aA caries 1 mark (3) Carctuty siody each question and write the answer in the OMR sheet by selecting the correct option (4) In the separate OMR sheet given to you which is given (A) © (B) O (C) 0 (D) © against the question number. The circle on the option ofthe correct answer to that question should be filed witha bal pen. (5) Rough work is to be done in this question paper only. (6) Question Paper Set No. given at the top right side of the question paper. should be written in the space provided in the OMR sheet. (7) Students will be able to use simple calculators and logtables where necessary. 1. The vapor pressure of a solution is 75mm Hg. which contains one mole of volatile component A (P +100 mm Hig) and three "of volatile component & (P = 60 mm Hg). So for such a solution < (A) shows cubic deviation from Raout's law! g XL (B) shows a decrease in boiling point. =a spar hgyen digo te a sorta pA iSO eather nn (0) Allthe above statements are correct. Gandhinagar (A) C6H6 + C6HSCH3 ., i> ii (Oili

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