Scribd Logo
Upload

Welcome to Scribd!

  • CP Líquidos Yaws

    Uploaded by

    PAULINA CASTRUITA GARCIA
    16 views27 pages

    Original Title

    cp líquidos Yaws

    Copyright

    © © All Rights Reserved

    Available Formats

    PDF or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    Report this Document

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd
    Flag for inappropriate content
    Download as pdf
    16 views27 pages

    CP Líquidos Yaws

    Uploaded by

    PAULINA CASTRUITA GARCIA

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd
    Flag for inappropriate content
    Download as pdf
    of 27
    Chapter 3 HEAT CAPACITY OF LIQUID Carl L. Yaws, Xiaoyan Lin, Li Bu, Sachin Njhawan, Deepa R. Balundgi, and Saumya Tripathi Lamar University, Beaumont, Texas ABSTRACT Results for heat capacity of liquid as a function of temperature are presented for major organic and inorganic chemicals. The results cover a wide temperature range and include many compound types. The agreement between correlation and data is quite good. INTRODUCTION Thermodynamic properties such as liquid heat capacity are important in the engineering design of chemical processes. In liquid-phase chemical reactions, the liquid heat capacity is required to determine the energy (heat) necessary to bring the liquid chemical reactants up to reaction temperature. Additional uses include heat exchanger and energy balance design calculations. In this article, correlation results for liquid heat capacity are provided in an easy-to-use tabular format that is especially applicable for rapid engineering use with the personal computer or hand calculator. HEAT CAPACITY CORRELATION The correlation for heat capacity of liquid is a series expansion in temperature: Cp=A+BT+CT?+DT? (3-1) where C, = heat capacity of liquid, joule/(mol K) A, B, C, and D = regression coefficients for chemical compound T = temperature, K The results for heat capacity of liquid are given in Tables 3-1 and 3-2. In preparing the compilation, a literature search was conducted to identify data source publications for organics (1-43) and inorganics (1- 104). Both experimental values for the property under consideration and parameter values for estimation of the property are included in the source publications. The publications were screened for appropriate data The compilation resulting from the screening is based on both experimental data and estimated values. For organic compounds, most of the estimates were based on group contribution (Cheuh-Swanson, 29), corresponding states (Lee-Kesler, 29) and boiling point methods (Yaws and co-workers). The relation of (heat capacity)(density")=constant was utilized to extend both experimental data and estimates. Values of n ranged from 1/2 to 1. Experimental data and estimates were then regressed to provide the same equation for all compounds. For inorganic compounds, many of the estimates are based on the JANAF tables (57-59), Bureau of Mines bulletins (60-63), and group contribution methods. The relation of (heat capacity)(density")=constant was utilized to extend both experimental data and estimates. Very limited experimental data for liquid heat capacity are available at temperatures in the region of the melting point temperature. Data in the boiling-critical point temperature interval are also very scarce. Thus, the values in the region of the melting point and in the boiling-critical point temperature interval should be considered rough approximations. The values in the intermediate region (above melting and below boiling point) are more accurate. ‘A comparison of correlation and actual data for liquid heat capacity is shown in Fig. 3-1 for a representative chemical. The graph discloses good agreement of correlation and data. EXAMPLES The correlation results maybe used for prediction and calculation of heat capacity and additional thermodynamic properties. Examples are given below. Example 1 Estimate the liquid heat capacity of pentane (C5H12) at 298.15 K. Substitution of the coefficients from the table and temperature into the equation for heat capacity yields Cp = 80,641 + 6.2195E-01*298.15 — 2.2682E-03°298.15? + 3.7423E-06"298.15° Cp = 163.64 joule/(mol k) Example 2 Calculate the energy required to heat liquid toluene (C7H8) from 300 to 500 K. 56 HEAT CAPACITY OF LIQUID From thermodynamics, the change in enthalpy, AH, at constant pressure is AH=JCp aT =[(A+BT+CT?+DT)aT T; AH=AT+(B2)T?+ (Cia) T?+ (014) TH] y ‘Substitution of the coefficients from the table and the temperature limits into the equation yields ‘4H = (83.703) (500 - 300) + (5.1686E-01/2) (500? - 300) — (1.491 0E-03/3) (500° - 300°) + (1.9725E-06/4) (500* - 300") ‘AH = 36,200 joule/mol Portions of this material appeared in Hydrocarbon Processing, 70, 73 (December, 1991) and Chem. Eng., 99, 130 (April, 1992). These portions are reprinted by special permission. REFERENCES ~ ORGANIC COMPOUNDS 1-36. See REFERENCES - ORGANIC COMPOUNDS in Chapter 2, HEAT CAPACITY OF GAS 37. Altunin, V. V., V. Z. Geller, E. K. Petrov, D.C. Rasskazov, and G. A. Spiridonov, THERMOPHYSICAL PROPERTIES OF FREONS, Methane Series, Part 1, Hemisphere Publishing Corporation, New York, NY (1987). 38. Altunin, V. V., V. Z. Geller, E. A. Kremenevskaya, |. I. Perelshtein, and E. K. Petrov, THERMOPHYSICAL PROPERTIES OF FREONS, Methane Series, Part 2, Hemisphere Publishing Corporation, New York, NY (1987). 39. Wilhoit, R. C. and B. J. Zwolinski, PHYSICAL AND THERMODYNAMIC PROPERTIES OF ALIPHATIC ALCOHOLS, American Chemical Society, American Institute of Physics, National Bureau of Standards, New York, NW (1973). 40. Yaws, C. L. and others, Hydrocarbon Processing, 70, 73 (December, 1991). 44. Yaws, C. L. and others, Chem. Eng., 99, 130 (April, 1992), 42. Yaws, C. L., HANDBOOK OF THERMODYNAMIC DIAGRAMS, Vols. 1, 2, 3, and 4, Gulf Publishing Co., Houston, TX (1996). 43. Yaws, C. L., HANDBOOK OF CHEMICAL COMPOUND DATA FOR PROCESS SAFETY, Gulf Publishing Co., Houston, TX (1997). REFERENCES - INORGANIC COMPOUNDS 1-64. See REFERENCES - INORGANIC COMPOUNDS in Chapter 2 HEAT CAPACITY OF GAS 65. Lyon, R. N., ed., LIQUID-METALS HANDBOOK, 2nd ed., Atomic Energy Commission, Washington, DC (1954). 66. Janz, G. J. and C. B. Allen, PHYSICAL PROPERTIES DATA COMPILATIONS RELEVANT TO ENERGY STORAGE. ||, MOLTEN ‘SALTS: DATA ON SINGLE AND MULTICOMPONENT SALT SYSTEMS, Nat. Bur.Stand., Molten Salts Data Center, Troy, NY (April 1979). 67. Fink, J. K., TABLES OF THERMODYNAMIC PROPERTIES OF SODIUM, Argonne National Lab., ANL-CEN-RSD-82-4, Chemical Engineering Division, Argonne, IL (June, 1982). 68. Mills, K. C., THERMODYNAMIC DATA FOR INORGANIC SULPHIDES, SELENIDES AND TELLURIDES, Butterworths, London, England (1974), 69. Tarakad, R. R. and R. P. Danner, AIChE J. 23(6), 944 (1977) and 23(5), 685, (1977) 70. Chueh, C. F. and A. C. Swanson, Chem. Eng. Prog. 69(7), 83 (1973). 71. Giauque, W. F. and T. M. Powell, J. Amer. Chern. Soc. 61, 1970 (1939). 72. Davis, C. M., Jr., J. Chem. Phys, 45(7), 2461 (1966). 73. Hu, J.,.D. White, and H. L. Johnston, J. Amer. Chem. Soc., 15, 5642 (1953). 74. Smith, T. O. and B. M. Fabuss, Wright Air Development Center, Technical Report 59-327 (1962). 5, Grosh, J. and M. S. Jhon, Proc. Nat. Acad. Sci. 54, 1004 (1965). 76. Hu, J. H. and D. White, J. Amer. Chem. Soc. 75, 1232 (1953). Giauque, W. F. and R. Wieke, J. Amer. Chem. Soc., 51, 1441 (1929). Forsythe, W. R. and W. F. Giauque, J. Amer. chem. Soc., 64, 48 (1948). Evans, W. H. and R. Jacobson, J. Res. Nat. Bur. Stand., 55, 83 (1955). Douglas, T. B. and A. F. Ball, J. Amer. Chem. Soc. 74, 2472 (1952). Douglas, T. B. and L. F. Epstein, J. Amer. Chem. Soc., 77, 2144 (1955). Haar, L. and J. S. Gallagher, J. Phys. Chem. Ref. Data, 7(3), 635 (1978). Giauque, W. F. and J. O. Clayton, J. Amer. Chem. Soc., 55, 4875 (1933). Wiebe, R. and M. J. Brevoort, J. Amer. Chem. Soc., 51, 622 (1930), ‘Scott, D. W. and G. D. Oliver, J. Amer. Chem. Soc., 74, 2293 (1949). 5. Giaugue, W. F. and J... Kemp, J. Chem. Phys., 8, 40 (1938). McCarty, R. D. and L. A. Weber, Nat. Bur. of Stand, Tech. Note 384, Washington DC (1971). 3. Giauque W. F. and H. L. Johnston, J. Amer. Chem. Soc., 51, 2300 (1929). 89. Jenkins, A. C. and F. S. Dipaolo, J. Chem. Phys., 25(2), 296 (1956) 90. Lee, B. I. and M. G. Kesler, AICHE J., 21(3), 510 (1975). 91. Ott, J.B. and W. F. Giauque, J. Amer. Chem. Soc., 82, 1308 (1960). 92. McDonald, R. A., J. Chem. Eng, Data, 12, 115 (1967). 93. Majer, V., V. Svoboda, and M. Lencka, J. Chem. Thermo., 17, 365 (1985). 94, Sherman, R. H. and W. F. Giauque, J. Amer. Chem. Soc., 77, 2154 (1955). a BISRLSRLS3S 57 HEAT CAPACITY OF LIQUID 96. Clarke, J. T., E. B. Rifkin, and H. L. Johnston, J. Amer. Chem. Soc., 75, 781 (1953). 96. Jhon, J. S., J. Grosh, and H. Eyring, J. Phys. Chem.,71(7), 2533 (1967). 97. Pace E. L. and M. A. Reno, J. Chem. Phys., 48(3), 1231 (1968). 98. Pace, E. L. and M. A. Reno, J. Chem. Phys., 48(3), 1231 (1968). 99. Clayton, J. O. and W. F. Giauque, J. Amer. Chem. Soc., 54, 2610 (1932). 100. Kalscheu, R., Z. Phys. Chem., B40, 273 (1938). 101. Kemp, J. D. and W. F. Giauque, J. Amer. Chem. Soc., 59, 79 (1937). 102. Void, R. D., J. Amer. Chem. Soc., 59, 1515 (1937). 103. Weissler, A., J. Amer. Chem. Soc. 71, 1272 (1949) 104, Pace, E. L. and J. S. Mosser, J. Chem. Phys., 19(1), 154 (1963). 58 Heat Capacity of Liquid, joule/(mol K) 300 HEAT CAPACITY OF LIQUID Figure 3-1 Heat Capacity of Liquid C7H8 TOLUENE 250 2004 150+~ 100- Temperature, C = data 59 —— equation Table 3-1 HEAT CAPACITY OF LIQUID - ORGANIC COMPOUNDS: Cp=A+BT+CT?+DT* (Gp -joule(mol K), T - K) NO FORMULA NAME x = t [Twn TwAX 16, @25C 1 [oBrcira 'BROMOCHLORODIFLUOROMETHANE B6842_| 427i9E0T | 17626609 | SATOSEDS [115 | 368) 127.81 [2 [eercis ~~ BROMOTRICHLOROMETHANE 32205 [7.162601 | <1 8205.09 | 2.08606.00 | 259545 | 12005, 3 [CBs ~~ BROMOTRIFLUOROMETHANE Suess | sourato1 | owes | seso.00 tor | “sas ~4_[CBraF2” | DIBROMODIFLUOROMETHANE” e014" 5.48976-01 | -1.99976-03 | 2.9706E-06 | 164 428.94 5 [GOS | CHLOROTRIFLUOROMETHANE arora | ssarreai | asveaeas _ e02eat-os 99 | ae 6 ‘CYANOGEN CHLORIDE. 7130070 | 20318«100_|"-6.61506-03 | 7,70536.06 268404” 04.08, T [DICHLORODIFLUOROME THANE 53.463 | 46919601 | 20770603 42098E-06 | 116 | 346) 121.07 @ [PHOSGENE 53075 | 452096-01_1.99006-09 | 2a2s7E-00 | wet «10 | 11203 | 8 "TRICHLOROFLUOROMETHANE _ "29.120 | 3.0976E-01 47195606" 163] 424 (CARBON TETRACHLORIDE - e671 | 999636-01 | -2e76ee-03 | “3042sc06 | 251601 | 1007? | [CARBONYL FLUORIDE -33.419 | 1.9984E+00_-1.0973E-02 | 1.9136E-05 163. 267 ‘CARBON TETRAFLUORIDE 7] 2ss05 [9 woere-01 | -7.07316-03 | 2. re186-05 81 205] —— TRIBROOMET? 23676 | 7.16606-01 | -169%46-05 | 1.63146.00 202 | 608! ta9.94 [CHLOROOIFLUOROMETHANE 44.503 477a7e-01_-22107€-05 | 45708606 147992 | 11160 | DICHLOROFLUOROMETHANE 51.597 | 4.1564E-01 | -1.5739E-03 | 2.7008E-06 439 406 407.20 [CHLOROFORM 28.296_| 65897E.01_-2.0359E-03 | 2-s00r€-06 | 2111 4831 11249 “TRIFLUOROMETHANE 19.42 | 8448201 | 4071603} 106076.05 119 | 209 | _— HTRIIQDOMETHANE touese | -0.15006-02 | 1ass0eo4 | —— ser) sat | THYDROGEN CYANIDE 7123.185 | 1.7769E+00 | -$.9083€-03 | 69120606 | 261 TISOTHIOCYANIC-ACID _——— — a |BROMOCHLOROMETHANE 48.459 | 3.8479E-01 | -1.1676E-03 | 1.5606E-06 186 DIBROMOMETHANE 38730 | 48154601 | “19991603 | 15440-08222 [CHLOROFLUOROMETHANE 95.915 3.60286.02 | 2esste04 | —— [144 [DICHLOROMETHANE "38.961 | 48008E-01 | -1.6226E-03 | 250096-06_| 179 (DIFLUOROMETHANE — 21136 rosaae-o1 [3.33576-05 | 6.47576.06 138 (DIODOMETHANE 49.597 555006-01 | ~1.25006-05 | 1.1654E-06 | 200, [FORMALDEHYDE - —_ — wel FFORMIC ACO “6110_| B7zH9E.0F | -2oe05E-OS | 2aasiE eons METHYL BROMIDE —— 25042 | 49612601 | -17627E-03 | 259036-08 "181 { METHYL CHLORIDE | 11.381 | 6.2328€-01 | -24353€-03 | 3.83336.06 [176 METHYL TRICHLOROSILANE [seai6 [ 88604E-01_| -2.85836-03 | 3.84086-08 | 196 T ct METHYL FLUORIDE ~ 382 | 8.352601 | -+4.40876.03 | 9.17086-08 | 132 t [33 cH IMETHYL IODIDE 24202 | 454596-01_-145656-05 | 187926-06 | “aoe” 475] at 34 /CHSNO FORMAMIDE 38,786 | 5.1948E-01 | 1.14226-05 | 1.04806-06 | 277 | 684 | 116.12 ‘35. [CHSNO2 ___[NITROMETHANE 10.892 | 7.0067E-01 | -1.95256.03 | 21677606 266 | 529 104.22 295. CHaNO2 ——[METHYL-NITRITE —— —— a 37 (CHONOS | METHYL-NITRATE — SS 38 [cH IMETHANE - [Gore | 4.t0e2ee00 | -ee7296-03 | ai670606 92 | 172 39 CH«CI2Si__/ METHYL DIGHLOROSLANE @5,1906n6306-01 | -23767E-03 | as007E-06 | 194435 40__(CHAC METHANOL. _ [40.162 | 3.10466-01 | -1.02016-03 | 1.45906.06 | 176 | 461 “41 [CHAOGS____[METHANESULFONIC ACID — — —a— crs METHYL MERCAPTAN ~Wea7o | 370596-04 —-i35656-08_ | 320056.06 | 161 (CHSCISI [METHYL CHLOROSILANE - 198963 | G6 0103E-01 | -20067609 | «02016-0840 (CHEN METHYLAMINE 13565 | s0036€-01 | -s.4516.03 | 52706-06181 1 [METHYL SLANE 36.550” | 4.67206-01 | -2.94486.03 | 4.96686.06 117 ‘TETRANITROMETHANE 280.326 | 4.0096E+00 | -1.13046-02 | 1.19686.05 208 [CARBON MONOXIDE ~ig.ai2 | 26072E+00 | 20070602 | 12745608 68 [CARBONYL SULFIDE {“ats0s —|"s.ee8e-01 [1.752760 | 33206-08195 | 941] [CARBON DIOXIDE — 390.956 |"6.2700E+00 | -2.32796.02 | 9.ss60605 | 210 (CARBON DISULFIDE - 2.565601 | -7.2098E.04 | 1.0446-08 | 163 | 487 | [BROMOTRIFLUOROETHYLENE 4.4074E+00 | -5.1867E-03 | 7.4525E-06 ‘201 ~/1.2.01BROMOTE TRAFLUOROETHANE, 785496-01 | -2.75946.09 | 4,17416.00 164 ‘CHLOROTRIFLUOROETHYLENE_ 1649426-01 | -29048E-03 | 59780E-06 | 116. ‘CHLOROPENTAFLUOROETHANE ‘LB274E+00 | -8.04526.03 || 1.36696.05 175 [85 [Gaciaré 1. 2-DICHLOROTETRAFLUOROE THANE 17.100 | 02104604 | -3.17586-09 "49217E05 | 100) [56 \caciors|1.1,2-TRIGHLOROTRIFLUOROETHANE 25.900 | 1.94886+00 | -6.28246-09 608) 29) «30 ‘s7_[c2cla TETRACHLOROETHYLENE. '51.760_| 6S700E-01 | -1.6916E-03 | 1.86626-06 | 252 568 58 C2CMFS 1.4,2.2-TETRACHLORODIFLUOROETHANE s122.474 | 2.30326+00 | -6.5504E-03 | 6.6997E.06 300 | 496 '59[C2CMO _TRICHLOROACETYL CHLORIDE Teese | 650006-01 | -190206-03 | 2.92596.00 201601 {@0__/C2C}6 —HEXACHLOROE THANE ——— —— on ——aie——t 1 /C2F4_|TETRAFLUOROETHYLENE “2266 | 182646000 | -7.0070E-09 | 16018605 | 143) 276 | [22 [core IHEXAFLUOROETHANE: 762.628 | 38978E+00 | -1.0409602 | 3.5409E.05 | 173264 @3_(CoHBICIFS [HALOTHANE = [siete e77iteo1 | -2760s6-09 | a0os1e-06 "201 | 400 4 (GaHCF2 __ 2.CHLORO-1,{DFLVOROETHYLENE 49350 | 60574601 | -2.55016.09 | 47271E08 | 136 360 (65. CHC | TRICHLOROETHYLENE -AT250E-01 | -1.40956-03 189536-06 | 100514 168_(G2HO30 _[DICHLOROACETYL CHLORIDE ~iemse.03 | 231106-05 7 /C2HC80_ ITRICHLOROACETALDEHYDE ~2.26956-03 | 2.7747E-06 | ‘68 [C2HCIs__|PENTACHLOROETHANE “2.00816-03 | 2.19956-08 | "es [czvra I TRIFLUOROETHENE “24508.04 70 |C2HF302 [TRIFLUORGACETIC ACID “75.827 | 2.0868E+00 | -6.4086E.03 | 7.5280E.06_| 71_[CoHFS IPENTAFLUOROETHANE 1.9633E+00 | -8.92296-03 | 1.55126-05 | 72 \C2H2 [ACETYLENE L — — [ [73 icahomea——|1.1.22-TETRABROMOETHANE 420056-01 | B.81006-04 | 7.87066-07 74 [o2H2c2 1. 1-DICHLOROETHYLENE = “ADS50E-01 | -142506-03 2 2741.06, 75_(G2H2ci2_¢s-12-D/CHLOROETHYLENE 591006-01 | -18704E-05 | 752006-06 | 194 474 “76 |C2H2ci2 lirans-1,2-DICHLOROETHYLENE 8.7604E-01 | -2.7731E-03 | 3.4932E-06 224 487 [77 [c2Haci2O__|CHLOROACETYL CHLORIDE '9.6906E.01 | -2.74156.09 | 9.04596.06 | 252 | 823, “78_|c2H2c720__[DICHLOROACETALDEHYDE. 8.0754E-01 | -2:3963E-03 | 2:9026E-06. 224 500 Table 3-1 HEAT CAPACITY OF LIQUID - ORGANIC COMPOUNDS (continued) Cp=A+BT+CT+DT® (Cp -joule/(mol K), T - K) NO FORMULA WANE x 5 € DTN | TWAX [6-@25 9 [G2H9Gi202 —[BIGHLOROAGETIC AGIO ori Taratew zeae | aanerEss [awe [eit ‘var2 '80_C2H2GISF___|1.1,1-TRICHLOROFLUOROETHANE 36.523 | 7.140201 | -2.1347E03 | 27158606 | 201 | 509 | 15142 ‘81_[G2H2G4 ——11,1,1..TETRACHLOROETHANE. 74301 | S6404E-01 | -1.54612603 | 1.85626-06 | 204 | 662, 15463 2 [C2H2CM __1,1.22-TETRACHLOROETHANE 62651 | 67404E01 | -1.7561E-03 | 1.95626-08 250. | 68115939 183 [C2H2F2 —|1.7-DIFLUOROETHYLENE “1271 | 102856100 | -55247E-0S_| 1. 1867E-05 130 T ‘8% _(GaH2F2 __|cis-1.2-DF LUOROETHENE 79.304 | -2.22406-02 | 25980604 — | 108 {85_[Gaii2F2 ___rans-12-DIFLUOROETHENE esos | -272406-02 | 25306604 | ——- 109 08 [CoHars 1.1.1 2-TETRAFLUOROETHANE “14.015 | 1.4906E+00 | 6.07206-08 | S966 173 7 C220 KETENE ‘35905 | 435736.01 | -199606.03 | 4030%6-08 | 123, ‘88 (C2ii204 | OXALIC ACID ——- ~ a 98 |c2HsBr \VINYL BROMIDE 50.988 | 3.824E-01 | -1.4003E-03 2.3630E-06 136 [426 | 103.13 90 Ca#sci [VINYL CHLORIDE 45366 | 2.87026-01 | -1.1535E-03 | 2.16366-06 | 120 369 | 0601 91 (COHSGF2 ___1-CHLORO-1,1-DiFLUOROETHANE 40,999 | 7.30506.01 | 30172603 | 53495608 | 143] 369 | 13237 22 [C2H9GIO [ACETYL CHLORIDE ‘443276-01 | -1.48856-03 | 2.23626-06 | 161 | 457 | 11502 85 |C2HSGIO | CHLOROACETALDEHYDE 71.80836.05 | 23175606 | 201 | 600 | 115.19 4 (C2HSGIO2__[CHLOROACETIC ACID 356] 14722E+00 | -33749E-03 | 29610606 | 304 | 617 —— 95 [C2HSCIO2 | METHYL CHLOROFORWATE. 47266 | 7:35996-01 | -232616.03 | a.0867E06 | 201 | 473_| 96 |C2H9GI3____|1.1,1-TRICHLOROETHANE 11.142 1L0501E+00_| -3.08206.05 | ss0es6.06 | 244491 S7_|C2HSG:s 1.1 2-TRICHLOROETHANE 34.934 | 850546-01 | -2.39066-03 | 2.64556-06 | 236 | 542 98 [C2HoF [VINYL FLUORIDE 37.095 | 5.7390E-01 | -2.9404€-03 | 6.50206-06 | 114) 295 99 _(C2HIFS 1.4.1-TRIFLUOROETHANE ~2805| 1.3367E+00 | -6.17206.03 | 1.08626.05 | 163 (c2HaN "ACETONITRILE 206 | s.s4006-01 | -2.08706-05 230 (C2HGNO [METHYL ISOGYANATE ~45:350_ | 1.1206€+00 | -3.46396-03 257 icon ETHYLENE 25597 | 67076E-01 | -3.36206-03 | 8.4120E-06 | 105 (C2462 [1 1-DIBROMOETHANE. 60555 | S1074E01 | -15765603 | 16277608 211 [can5r2 1 2-01BROMOETHANE— “16.067 |~9.10296-01|~-2.00966.05 | 1.9054E-06 | 204 (Cauca —_[1,1-DICHLOROETHANE 57325 | S60WE-01 | -1.8196E-03 | 256176-06 | 177 (C242 '12-DICHLOROETHANE 26310__| 7 75556-01 | 22271603 | 2.61096-06 | 236 (C2H4GI20 __"BIS(CHLOROMETHYLJETHER 31958 | 80721E01 | -22061E-05 | 24674606 | 295 (Cana? IFLUOROETHANE 18.899_| 7.1043€-01 | -3.0751€-03 | 5.2308E-06 | 157 [caHar2 1 2-D1FLUOROE THANE 2349 | 938776-01 | 37379603 444596-08 | 201 icant 1.2-DIODOETHANE 796.357 | -9.30836-02 | 2.14016 04 — [czHao [ACETALDEHYDE 45056 | 448536-01 | -teso7e-03 | 2.7000E-06 | 151 (G20 [ETHYLENE OXIDE 35.720 | 429006-01 | -1.54736-03 | 24070E-06 [C2408 THIOACETIC-ACID wee ae ee (C202 ACETIC ACIO — tase | ioo71e+00 | -2e8216-05 | 20276606 (Gze02 METHYL FORMATE 42381 | 6.70646-01 | -1.9727E-03 | 2.09486-06 (Galas | THIACYCLOPROPANE 81.206 | -8.17176-02 | a7077E-O4 | —— | 168 (C2H56r_—_[BROMOETHANE 803 0340e-01 -130866-03 | 20088e-08 | 158 (c2Hsci ETHYL CHLORIDE 160.180 | 34553601 -1.20636.03 | 2 19696-06198 | 414 105.00, (C2HECIO_[2-CHLOROETHANOL 58.464 | 420026-01_ | -1.24826-03 | 1.52636-06 207 | 527_116.14 (cane ETHYL FLUORIDE a7zi_| 55316601 24970603 | 481606-05 | 131 | 338 117.88 (czHsi [ETHYL IODIDE ‘8413 | 97300601 | -1.14056-09 | 1.65166-08 163) 505 | 111.06, (CaHsN ETHYLENEIMINE 40410 | 52635601 | -16704E-03 | 2.18506-08 | 196 483 107.36 [C2HENO__[ACETAMIDE 42231 | 1.191100 | -2s794e-03 | 197286-06 | 955 685 | —— (C2HENO | N-METHYLF ORMAMIDE 35271_| 622016.01_| -14573E-03 | 140596-08 | 270) 649 | 12060 (C2isNO2__[NITROETHANE 70396 | 5.6739E-01_| -16579E-05 | 214086.06 | 18553414899 (C2vsNOS | ETHYL-NITRAY = a —— (CzH6 [ETHANE 38532 | A7008E-0T | 280208 | BeswTEOS | of as | (C2H6AIGI__[DIMETHYLALUMINUM CHLORIDE ‘waot | 9.26716-01 | -248286.09 26078606) 755587 14160_| (6260 [DIMETHYL ETHER - “48074 | §62256-01 | -230156-03 44614E-05 | 15936012136, (C260. [ETHANOL 9342 | 26360601 | -121646-03 | 1.803006 | 160 | 465 | 107.40 ‘a1 [C2H6OS [DIMETHYL SULFOXIDE. 27.879 | 7.86286.01 | -177626.03 | 1.6546E-08 | 293) 653._| 14827 "a2 [C2602 ETHYLENE GLYCOL 75878 | 64162E01 | -1.6493E-03 | 1.6937E-05 433 [C2H604S [DIMETHYL SULFATE (85.080 | 6.4496E-01 | -1.4269E-03 1.4557E-06 | 194 [CaH6S [DIMETHYL SULFIDE [50.108 | 5.55036-01 | -1.86166-03 | 269106-06 | 176 453, 135. |C2H6S [ETHYL MERCAPTAN 2st 3.44196-01_| -1.49006-03 | 205806-08 128 448 196 [624682 [DIMETHYL DISULFIDE 76236 | 497956-01 | -130156-03 1.77626-06 | 169 137 |GaHIN [DIMETHYLAMINE [ "36962 | @ser7e.01 | 3.se4se.03 | 539906-05 | 162 TETHYLAMINE [rs 764 874-01 | 3. 11086-0581 4.4673€.06 | 103 att (MONOETHANOLAMINE zat [ S12t8e-08 | 3.07146-06 sr) [ETHYLENEDIAMINE -4.01726-05 | 40670606 705534 [DIMETHYL SILANE ‘S1509E.01 | -24542E.03 | 472506-08 | 128 | 362 (CYANOGEN ‘38145E+00_ | -130976-02 | 16021605 | 248 | 360 [HEXAFLUOROPROPYLENE 7 ‘B5516E-01 | 3.9961E03 62659606 | 118 | 351 | HEXAFLUOROACE TONE 1.7703E+00 | 8.12886-08 | 1474E-05 | 152 | 321 ‘OGTAFLUOROPROPANE 12101E+00 | 5.96726-03 | 12066605 | 126 | 311 [MALONONTTRILE 1.035400 | -230026-03 | 2.1470E-06 | 308 | 644 | [PROPARGYL CHLORIDE. '5.8350E.01 | -17967.03 | 234696-06 | 201487 [ACRYLONITRILE S.064EOt | 1.962503 | 24956E-06 | 101482 ‘OXAZOLE, 4247601 | .25316.09 | 162206-08 | 201 | 409 (METHYLAGETVLENE Teasie-0t | -$.16686.03 | 6.19756-06 | 171) 962 [PROPADIENE “485996-01 | 207166-03 | se4n4e06 | 138 | 354 '23.DICHLOROPROPENE ‘55282601 | 16272603 | 2.106E-08 | 193] 519 [ACROLEIN _ SO1G9E.01 | 19935603 | 260606-06 165 | 455 'PROPARGYL ALCOHOL 43633 | a26s0E-01 | -2s747e-0s | 2ezsse-o6 | 222 | 52 [ACRYLIC ACID 10242 | 1.2106E+00 | -3.11606-03 | 3.14096-06 | 208 | 554 ‘bet PROPIOLACTONE. 45,746 | 5.26096-01 | -1.3096E-03 | 197266-06 241) 617 Table 3-1 HEAT CAPACITY OF LIQUID - ORGANIC COMPOUNDS (continued) Cp=A+BT+CT+DT? (Cp -Joulel(mol K), T=) NO[_FORMULA TAME ay = © o TwIN_| TWAX | @25C “67 CSH4G2___|VNYLFORMATE B20 | OS2ET | SOVIETS aiTeES [701 | 448 | 489 168 [C3H403 [ETHYLENE CARBONATE 36.594 | 7.71046-01 | -4.62206-03 | 13975068 | att | 711) — 189 [C3H403__ PYRUVIC ACID "5.206 | 9.58846-01 | -245146-03 | 25979606 | 708 671 | 19845 160_|C3HBGr [SBROMO-1-PROPENE 413.650 _| 7.906060 4.1077E0¢ | — | 155 | 3739735 161_|G3HSCl__'2.CHLOROPROPENE — 64.195 | 407596-01 | -14075E45 | 24659606 | 137 | 430 | 12087 | 162 [caHsct 'CHLOROPROPENE e2ari_| sseo0e-o1 12005603 | 197016-06 | 140 | 463 | 11283 | 163” G3H5CIO_|alpna-EPICHLOROHYDRIN 1412-01 | -157636-03 | 1.90876.06 | 217 | si | 133.04 ‘64 |C3HSCIO2 | METHYL CHLOROACETATE 9.8044E-01 | 26059509 | 80209E-06 242) 640) 162 465. [C3HsCIO2 [ETHYL GHLOROFORMATE ~ 40786E+00 | 3.5908603 | «69556-08199. 165 [C3HSCis __[12.3-TRICHLOROPROPANE 9.33696-01 | 23606603 | 24895E-05 | 259 167 [c3Hs1 [31000-1-PROPENE — 02sse-01 | 4si72E04 | —— 175 168. |C3H5N PROPIONITRILE SO7O1E-01 1550703 2073106 | 181 (CaHNO ACRYLAMIDE ‘.057E+00 | -232216.03 | 1.8296E-08 | 959 (GsHsNO__ HYORACRYLONITRICE = @50446.01 | -1.6508E-08 | 1.76496-08 228 | [¢sHsNO—|LACTONTTR 4002601 | -19408E-03 2. 19556-05 | 294 (C3hSNGO9__NITROGLYCERINE — — — cH 'CYCLOPROPANE = SoiwBEDI | Tiowoeas | S7eue-08 | a7 | 868 9242 [cane PROPYLENE - 34512601 | -169156-03 38755-0569 328 | 1180_| (G3H6B2 [1.2 DIBROMOPROPANE ~102e2e-or | 37eseeos | —— | 219 | 44s) 10008 (CaHECI2 1, -DICHLOROPROPANE 6.914601 | -207206-03 | 265936-08 | 201 | 604 159.16. \C3H6Ci2 1. 2.DICHLOROPROPANE 50261601 | -15107E-03 | 20567E-06 | 174515 | 145.81 (Gahsci2 | 13-DICHLOROPROPANE, A47O1E01 | -1.20506-03 | 1.69336-06 175 543| 149.59 (csHeG2 _|22-DICHLOROPROPANE ~2oszie-o1 | e0esseo6 | —— | 240) 372 | 12688 1.2 DIODOPROPANE — 6 -145656.01 | 4.2127E.04 | — | 264) 590 | 19049 [ACETONE = ~ [Vezeszeo1-2oveteos | 29603605179 4s7 | 127.59 — ALLY ALCOHOL '436726.01 | 14019609 | 2.12596-06 | 145 | 49114267 [METHYL ViNvL ETHER 6.476E-01 | -234516-03 | 3.69266-06 | 162 | s03 | 12931 1-PROPIONALOEHYDE 81621€-01 | -2.73606-03 | 3.76676-06 | 194 | 46 | 129.26. 2. PROPYLENE OXIDE 515496-01 | ~,00206-03 | 2.77956-06 | 162 | 4m | 12042 ~HS-PROPYLENE OXIDE > [[e.xee6e-o1 | -tertreas | 26t02€06 | 201_| 468 | 107-38 ~TETHYL FORMATE — 8.1051E-01 | 26471603 | S6081E-06 195) 458 149.98 ~~ METHYL ACETATE ‘63751E-01 | -2.1308E-05 | 3.056960 | 176 | 456 | 13099 PROPIONIC ACID ‘94514E.01 -255696.05 | 27644606 | 753 | Sud | 15044 'SMERCAPTOPROPI 2179E+00-2.72206-05 | 25743606 | 252 | 656) 20260 —SWacticaco = — —— ~~ TMETHOXYACETIC ACID ‘Goa7evo0 | 2826-05 | Zo077E06 | 72/622 | 19082 [TRIOKANE 196576100 -407616.05 | 4.48906.06 | 936 | su) — = ~ M11626-01 | 41249604] — 201 | ane | 19282 \Gai7er a 49718601 | -157086-05 | 22562606164 | 490) 19024 cane "2.BROMOPROPANE 74056E-01 | 23106605 | 32525608 | 185” 479, 14224 ‘csH7ct ISOPROPYL CHLORIDE ‘B2262E-01 | -10174E-03 | 287306.08 | 157 | 440 | 19371 (caH7cr ‘PROPYL CHLORIDE 45271601 | -1.5406E.09 | 24002600") 151 | 459) 12029 (CaHTe “-FLUOROPROPANE ~199196-02 | 22365604 —— | 115) 900) 101.44 (Cahir "2FLUOROPROPANE _— “33616602 | 26170604) —— | at) ae) (caHrt ISOPROPYL IODIDE — ssz4E-01 | -140666-08 | To6é7EoS | tea | 520 | 13608 ican ‘PROPYL IODIDE 43776601 | -1.2686.03 | 1,7051E.09_ 173 | 5x4) 19508 CCoHTN/ALLYLAMINE 8590 0+ | -230036.05 |” 3.1803E.06 | 186 | 45514640 CoH 'PROPYLENEIMINE 9.195261 | 25116603 | 34264606 | 230 476” ‘2851 SHINO [NN-DIMETHYLFORMAMIDE 0708-01 -4.61636.03 | 1.560606 214 | 58215024 (COHTNO__/N-METHYLACETAMIDE a7erseot | ‘15209608 902] 646 | — (CoHTNO2___/-NITROPROPANE S.17506.01 19047605 170) 545 | 16588 CaHTNO2_/2NITROPROPANE 6.068601 '2.29206-06 (C3HTNOS | PROPYL-NITRATE — —— IC3H7NOs [ISOPROPYL NITRATE Tt io (Cake [PROPANE —_ woe | azeste-0i | -15977e-03 a65a96.05 (CaHeO|'SOPROPANOL T2525 7'sss96.01 | 2.63006.05 3 64086.06 | [est90 ‘METHYL ETHYL ETHER [Tsa7s0” 7o1ase0r | -26587€.03 | 431666-08 ‘caH60 ‘-PROPANOL 7 40224601 “13082603 19677606 (CsH802__2.METHOXYETHANOL [7.12586-01 | -2.15046-08 | 2.82606-08 METHYLAL 71.690 69490E-01 | -239746.03 | 9.63506-06 12-PROPYLENE GLYCOL ite i¢ 6 72036. 01 | 1776-03 2.19036-08 #.3-PROPYLENE GLYCOL 79.062 _|1.1436E+00_-29055E-03 | 3.08206-06 ~[etyceRoL ‘5007.01 | ~1.9745E.03 | 1.0606.08 ‘1 PROPYLMERCAPTAN — “45417EOt | -1.48506.03 | 2.16006-08 ~ ISOPROPYL MERCAPTAN “436886.01 | -14514-05 | 2.26606.08 ETHYLMETHYL-SULFIDE ai21s76.01 | 56450e04 | —— sro 14480| ‘-PROPYLAMINE. 9703601”) -3.27286.03 | W51S5E08 101) 71698 ISOPROPYLAMINE 8710601 | 3.071609 | 4.60406) 179| 425” 160.10 "TRIMETHYLAMINE 3020.01 -263886.05 "4.505.068 | 1571390] 195.78 ~~ FrAMING-2-PROPANOL 1.2623E+00 | 3.37226-05 | 3s905e.06 | 276 | 553) 16288 '-AMINO-1-PROPANOL 1.3660£+00 | -3.3987E-03 | 3.35436-08 | 205 | 584 | 204.25 METHYLETHANOLAMINE Tos | 1.47216+00 | -302926-03 | 3.12046.08 | 270 | sar) 104.11 [TRIMETHYL PHOSPHATE — — — ff Z00_[C3H10N2 __[1.2-PROPANEDIAMINE. 728.000 |436696+00 | Sasoae-oo | A3ss7e08 | He | sie | 20508 zo1_[C3Hi0Si | TRIMETHYL SILANE [e962 | 67557601 | -200646.034.69606.06_| 196 | 90915569 | za2 [cacus |TETRACHLOROTHIOPHENE — | ee [233 [cacis HEXACHLORO-13-BUTADIENE 6750 | SR06KE-O1 A160) | 1a0NNEOS 259) a7 | 4B 74 754 (CAFO [OGTAFLUORO-BUTENE. 49574 | 032596-01 -35078E.09 | 659236.08 139953115358 Table 3-1 HEAT CAPACITY OF LIQUID - ORGANIC COMPOUNDS (continued) Cp=A+BT+OT+DT? (Cp -joute/(mol K), T -K) NO] FORMULA TAME x 5 € B TWIN TWAX | ©, @256 735 (Caro ‘OGTAFLUOROCYCLOBUTANE "Bre4a4_| GOGBTEOO | -TROGSETE |_25EVSEOE | 24360 | 2a7Ae 736_ CAF 10 (DECAFLUOROBUTANE 74.634 | 1.56026+00 | 67549603 171656-05 | 146 | 348 | 26196 zat cavia BUTADIVNE(BIACETYLENE}) = — _—-—— 738_CAH208___MALEIG ANHYDRIDE - {osesE+00 | 2azaae-03 | 20s1ee-08 | 327 798 awa \VINYLAGETYLENE B8876E-01 | -3.1484E-03 4.43146-06 | 201 240_[CAH«N2 | SUCCINONTTRILE LISSTE+OO | -2.45396.03 20499606 | 332 241_[CaHaO [FURAN 6S2016-01 | -2.2726E-03 | 3.1164E-06 | 109 242 [CaH602 __|DIKETENE 9.9002E.01 -25652E-032690%E-06 | 268 243 [C4H803 | SUCCINIC ANHYDRIDE 113452E+00 | -261406-05 | 1.94086-06 | 394 | 244 [GaHao4_[FUMARIC ACID “105826101 | -1.87296-02 | 1.0941605 | 561 245_[C4H4O#___|MALEIC ACID ‘22616+00 | -4.56%6E-03 | 3.39966-06 | 404 246 [Canes "THIOPHENE G7e7IE-01 | -1.90746-03 | 22160608 736 7247_[CaH5CI (CHLOROPRENE “42596E.01 | -14073E03 | 21060608 144 748_|CAHEN \rans-CROTONITRILE 73162601 | -20987E-03 | 2.4768E-08 | 223 249 _|CAHSN ‘is-CROTONITRILE 7 ‘6004E-01 | -20035E-03 | 2.53266-08 | 202 250 _(CaHeN (METHACRYLONITRILE 1.1226E+00 | -3.29666.08 | 3.65926.00 206 251_|CaHSN PYRROLE 6.44596-01 | -16782E.03 | 17807E.05 | 251 252_[CAHEN \VINYLACETONITRILE 53062601 | 15720603 | 20380606 | 187 7253__|CAHENO2 [METHYL GYANOACETATE S7717E-01 | -230026-03 | 24111606 | 261 254 (Cate (CYCLOBUTENE -24826E-02 | 172616-06 | —— | 165 255 (Cave 1:2.BUTADIENE S0078E-01 | 19600608 | S4071E-08 | 136 | 256 [cate 1 3-BUTADIENE, — 7.S206E-01 | -2.84266-03 | 4.60366-08 | 165 257 (Cane DIMETHYLACETYLENE E 1.2684E+00_| 4.11116-03 | 60352E-06 | 242 | 258_|oaHe [ETHYLACETYLENE 55.668 | 624966-01 | -2.30636-03 | 47476-06148) 250 |CaH6Gi2 [1 S-DICHLORO-rane-2BUTENE. 87309 | 60354601 | -1.6636E.03 | 20265E-08 | 201 260_CAHEGI2 [1 4-DIGHLORO-dis 2-BUTENE (65982 7 7047E-01_ -20300-03 | 22964E-06 | 226 251 CAHEGI2 __|1.4;DICHLORO-rane-2-BUTENE 15006 | 1.117460 | -261986-03 | 26433E-06 | 275 7262_|CAHBCI2___|34-DICHLORO-1-BUTENE 2876 | TSS69E-01 | -2.14966-03_ | 260356-06 | 213 263 |CaHi60 'vans-CROTONALDEHYDE 52946 | 7.276601 21630603 27646-08198 284 |C4H6O '2.5-DIHYDROFURAN, 45,309 | 6.32716-01 | -1.95016-03 | 2.63496-06 | 201 285 _[caH60 DDIVINYL ETHER 46544 | 6896E1 | -24756E.03 37562606 | 173 266_[CAHEO (METHACROLEIN 42511 | 686S0E.01 | -21861E03 29238606 193 267 |CAH6O2__[2-BUTYNE-1 4-010. 32.149 | 1.6408+00 | -8.71996-03 | 3.26626-06 | 332 7268 |C4H602_|gamma-BUTYROLACTONE, 73.028 | 434806-01 | -1.01886-08 1.052706 231 269_[C4HEO2_[els-CROTONIC ACIO 7.425 | 1.4354E+00 | 357116-03 | 3.49636.08 700 [270 |c4H602 |rans-CROTONIC ACID —_ “HTBOTT | 2O711E+00 | 4.7646E-03 | 4.1639E-08 346 27i_|C4H602 | METHACRYLIC ACID 7.089 | 12862E+00 | -3.21956-05__3.16236-06 269 772_|G#Hi602 METHYL ACRYLATE 54.109 | 60309E-01 | -251496-03 | 31656-05197 7273_|C4H602 VINYL ACETATE 63.910 7.06s6E01 | -276376.03 | 3.1788E-08 | 181 7274_|CAHE03 "ACETIC ANHYDRIDE Test 8e67sE-01 | -265¢E03 | 33501605 | 201 275_|caHe04 [SUCCINICACID. “#16851 8.5096E+00 | -661606-05 | 44507606 | 462 276_|C4H605 _[DIGLYCOLIC ACID 207.030 | 2.58336+00 | ~4.89366.03 | 3467108 | 422 277 |[Gati605 _|MALIC ACID “2811 | 25006+00 | -4.9347E-03 | 3.67236-06 | 404 278_|CAH6O8 [TARTARIC ACID “512873| 44067Ew00 | -7.8667E-03 | 5.1216E-06 | 480 273_[CAHTN In-BUTYRONITRILE 24.111 | S04s0E-o1 | -1514E-03 | 210126-06 | 162 | 524 | 15572 7280_|C4HTN ISOBUTYRONTTRILE 51808 | 7.8610E-01 | -23406e-03 | 296876-06 | 203 781_[Geki7NO_ [ACETONE CYANOHYORIN | sseea | 1.3576e+00 | -s.4seze-03 | s.6r606-05 | 254 7282 |CAHTNO |. METHAGRYLAMIDE [80.764 |"1.71106+00 | -3.54056.09 | 2.7746E-06 "| 965 | 253 [CAHTNO |: METHOXYPROPIONTTRILE ‘63084 | 7.03846-01 | -1.90876-05 | 22168606 | 211 784_|CAHTNO_[2-PYRROLIONE 52.256 | 7.8791€-01 | -1.6538E-03 14659-06299 285 |CaHe ‘VBUTENE 14597 | 33434601 | -139146-03 | 30241606 | 09 708_[CaH6 (Gs-2-BUTENE ‘50899 | 50376E-01 | -19765E-03 | 3.50366-06 | 135 2a7_| CAH. "eans-2-BUTENE “6.162 | 79739601 | -30674E.05 | «9196.06 | 169 7288 |C4H_____CYCLOBUTANE 40687 | 83104601 1809103 | 27874E-08 185 7 789_|CAH ISOBUTENE srt | seastear | 41773608194 720 _[caHe82 —|1.2-DIBROMOBUTANE 461.110 | -9.19636-02 =| 200 a1 [Cae [2.3-1BROMOBUTANE tear [1.19616-013.85696.04 | 00, 232. |CaHeCi2 | 14-DICHLOROBUTANE, 64966 | B36516.01-2.19026-03 | 24084608 | 297 723_|CaHE2 12:DI]ODOBUTANE [194.119 | -te0s7E-01 | 486006-04 | — | 280 ‘4_|CaH6O InBUTYRALOEHYDE (64.383 | 7-25666-01 | -2:3548-05_| 830656-068 | 178 795 _C4H80 ISOBUTYRALDEHYDE 31.228 | 1.10206+00 | -3.86016-03 | 4.66626-06 | 209 7296_[C4HEO 1: 2EPOXYBUTANE 197.205 | S8742E-01 12008603 | 21365E-08 | 126 737_[CAHEO METHYL ETHYL KETONE 61406 | 75324E-01 | -23814E-03_| 322406-06 | 107 7298 CaH80 ETHYL VINYL ETHER. 65:135_| 649486-01 | -2.29716-03 | 560266-06 | 158 7299 _[c4H80 "TETRAHYDROFURAN 163303 | 40257E-0" | -1.26006.03 | 1.62756-08 | 166 900. |CAHEO2 cls 2-BUTENE-1 4-D10L 33870 | 45014E+00_-a6176e-03 | 360226-08 | 205: ‘301_|C4H602 —__[wans-2-BUTENE-1.4-010L [437117115000 | -4.0527E-03_ | 379396-06 | 301, 502 |C4H802 _|ISOBUTYRIC ACID 162425 | 8.1702E-01 | -2.24636-03 | 25743606 | 278 305 [CaHeo2 __[-BUTYRIC ACID 28210 | 1.1040E+00_-2.85296-03 | 2.95286-06 | 268 306 [CAHeO2 _1,4.DIOKANE 20728 | 1.2813E+00_-3.4796E-03 | 3.54086-06 | 706 305_[caHe02 ETHYL ACETATE 162832 | 840s7e-01 26088603 | sceate-os [191 308 _|C4H602 [METHYL PROPIONATE [72707 |e 2008-01 -261196-03 | 35561606 | 167 | 307_[Gewa02 PROPYL FORMATE “743i | 68672601 | -2.19696-03 | 30196E-06 | 161 308 [canoes —_[SULFOLANE 74500 | 5.59396-01_-1.1027E-05 | 9.3860€-07 | 902 309 [canes "TETRAHYDROTHIOPHENE ‘91345 | S.1960E-01 | -B6978E-06 | 11074606 | 178 310_[C4HSBr '-BROMOBUTANE ‘86013 | 465696-01 | -1:39526-03 | 1.9586-06 | 162 311 [GaHe6r ®-BROMOBUTANE [0s 227” |~4.s615e-01 | -1.40086-03 | 1.96586-06 | 162 312 [CaHSCI 1-BUTYL CHLORIDE, 06.225 | 51021601 -16387E-03 | 2.46006-06 | 15% 63 Table 3-1 HEAT CAPACITY OF LIQUID - ORGANIC COMPOUNDS (continued) CpeA+BT+CT+DT (Cp - Joule/(mol K), T - K) NO_[ FORMULA TAME [-- 5 € 3 TIN | TMAX | 6-@25C ~_ See BUTYL CHLORIDE _ D056 ATOOEDT | -15052E03 25017608 | 143] 469 | 150.19 “Jler-BUTVL CHLORIDE S28. 720 | 1. 4906E+00 | 4.50456.09 | 544206-08 | 249 | 456 | 159.90 1ODO-2-METHYLPROPANE [2728 | -t68a7e-01 | 5.23606-00 | 296409 199.08 [PYRROLIDINE (se715 | ressse-o1 | 22572603 27400606 | 216) 512 | 15036 INN-DMETHYLACETAMOE 43.946 89037E-01 | -22645E-03 2.3578E-06 254) 8821 170.59 IMORPHOLINE. 72401 | 1.087500 | -28725E-03 | 2.9705E-06 | 271 | 656 | 173.02 ~ | PNITROBUTANE —s we ——— — 2-NITROBUTANE _—— wal — TTn-BUTANE szars| Sa01se-01 | 29500608 | 4zzs7e-08 | 198 | 83) ome | ISOBUTANE Ti7o1_| 4e4726-01 | -2.05196-03 | 4.0654E-06 | 115 | 967 t41.6¢ [PIPERAZINE “182418_| 27211E+00 | -6.1900603 | 5.17366-06 | 380 | 574) — ‘BUTANOL — ‘eaar? | Se628e-01 | -17208-03 | 227806-06 | 185 | 607 | 160.12 ‘see BUTANOL — [s6.037_|"sesce-o1 | -tasee-0s | 26676e-06 | 169) 402 | 172.16 [len BUTANOL “308.418. |4.4868E+00 | -1.29686-02 | 1.364205 300] 486 | — [DIETHYL ETHER, 75.939 1.7335E-01 | -2.7936E-03443836.06 158420) 17681 (METHYL-PROPYLETHER [iaaa0s[-tesote-o1 | 7747aE04 [ —— | 158 ox] 16440 METHYL ISOPROPYL ETHER 94.709 | 4eoaze-o1 | -17158-03 | 29676608 129 | 418 "| 150,70 ISOBUTANOL 96.150 | 49462601 | -15601E-05 | 22031606 | 166 | 493| 169.33 oI {25062_|"7e2eee-01 | -203616-03_| 24560606 | 197/679 | 20642 ~[1a-BUTANEDIOL — 10308 | 15972E+00_| -3.86286-05 | 3.70726-06 "23-BUTANEDIOL 1022 | 1.60596+00 | -4.1757E-03 | 4.264106. [tBUTVL HYOROPEROXIDE 718.694 1.1762E+00 | -3.20106-03 | 3:37226-06 12-DIMETHOXYETHANE 45.096 | 1-1083€+00 | -2.3900E-03 | 4.26056-06 —T[RIETHORYETHANOL ([Tetes2 | 9 s006e.01 "| -2.77966.09 3 52036-06 DDIETHYLENE GLYCOL 126618 | 85587E-01 | -1.9468E-03 1.87256-06 | 336 ceii10048 [DIETHYL SULFATE _ — — — — 338. [CAHI0S__-BUTYL MERCAPTAN, 9315 | 622646-01 | -157636-03 | 225896-06 7 340_[CAH0S ISOBUTYL MERCAPTAN [415036 | 3.60536-01 | 1.15006-03 | 1.8046E-06 | 341 [CaH105___|sec BUTYL MERCAPTAN_______04.316_| «4004-01 | -1 30946-03 | 2.192606. [42 |CAHIOS tat. SUTYL MERCAPTAN [5206 "1.90006 +00 | -5.75406-03_| 6.31446-06 [43 [Gei105 DIETHYL SULFIDE 99.432 | 58704E-01 | -1.81236-03 | 252176.06 344 [Cati0S __ISOPROPYL_METHYL SULFIDE, 150,769 13087601 | 57976606 | —— 388 |" a45_[caHi105 __ IMETHYL-PROPYL-SULFIOE 159.495 | -1.20826-01 | 5799260 | —— 399 346 |CaH10S2 [DIETHYL DISULFIDE 125.723 | 6.29436-01 -14155E-03 | 1 82616-06 576 347_[CAHTIN —_[n-BUTYLAMINE 32.672 _[1.47386+00 | 3.613703 | 4.4206E-06 a9 348 [CAHN ISOBUTYLAMINE 71304 | 854ae-o1 | -2.94236-03 | 4.01086-06 482 ue [CAHN [s06-BUTYLAMINE 181998 | 69550601 | -25225E-03 | 3.353266 463 | 7178 350_[CAHTIN_ ltt SUTYLAMINE — 43.328 | 1.2643€+00_| ~4.24006-09 | 6.6876E-06 436 | 19409 (HIN [DIETHYLAMINE 2800 | 14016E+00 | -4.52716-03 | S.7611€-06 447,170.40 [GAHNNO__ [OIMETHYLETHANOLAMINE 74876 | 1.0965E+00 | -3.19606-03 | 3.90696-08 | 215 | 515) 721.16 (C4H11NO2__[DIETHANOLAMINE 703 |~1.0821€+00-2.48606.05 | 2.2497E.06 | 902) 64 — (cant1No2 44i.0it_| 7.29646-01 | -181106-03 | 20710608 | —201_| 628 | 259.17 ~[G4Ht12N20__ [N-AMINOETHYL ETHANOLAMINE 151694 | 7.7974E-01 | -1.9967E-03 | 2.20526-06 | 201/629 | 270.10 (caii12S|____|TETRAMETHYLSILANE 155.176 | 1.1892E+00 | -425126-03 | 6.5006E-05 | 175) 405 | 195.17 [CaH1aNS —_[DIETHYLENE TRIAMINE 91.990 | 026306-01 | -207296-03 | 2.2506E-06 | 2356068 | 213.67 (CSCS HEXACHLOROCYCLOPENTADIENE S7164 | S0776E-01 | -1.1391E-03 | 1.0504E-06 | 265 [671 | 11567 (CsH4G2____|FURFURAL ~ [65792 | 7.07556-01 | -1a0826-03 | 1.963006 | 238 | 501 | 16003 (CSHEN PYRIDINE. 37.450 69497E-01 | -1.8749E-03 | 2.11686-06 (C56 GYCLOPENTADIENE 43.542 | 58709601 | 19261603 | 26761E-06 ‘csH6 [2METHYL1-BUTENES-YNE 61.157] 857826-01 | -19126E-03 | 2.9378E.06 | ‘VPENTENES-YNE — SF ate2[esrteeo1 | 2976603 | a9677e-06 [[EPENTENE-4-YNE 36297 | 82047601 26040603 | 36127608 | TGLUTARONITRILE 70.15 | 7.1706E-01 -1.5840-03_ 1 1.56006-06_| 245! 704 |FURFURYL ALCOHOL 72363 | 9340001 | 24272603 | 25437E-06 | 260 | 669 ‘GLUTARIC ANHYDRIDE “41.100 | 9.55496-01_-1.9004E-03 | 15471E-06_| 329 | 754 TCITRACONIC ACID =18.090_|16511E+00 | -3.2561E-03 | 253346-06 | 957 _| 748 (csH604__—_|ITACONIC AIO - 278206 | 2.9906E+00 | -6.4439E-03 | 8.7600E-06 | 440 | 739 (csH6S. [2METHYLTHIOPHENE 141557 | “1248601 46171604 —— | ait | 416 [esH6s | SMETHYLTHIOPHENE [D10361_[ -120056-01 | 44s76e-04 | —— | 205 | ave (CHIN INMETHYLPYRROLE 41.210 | 78258E-01_-2.1667E-03 | 75563606 | 718 | 540 (CsHTNO2 [ETHYL CYANOACETATE 1.0887E+00_-27196E-03 | 26166-06252 | 611, (cst (CYCLOPENTENE S4830601 1.104003 | 191096-06 | 139 | «56 (GsHe——~*ISOPRENE 45089-01 | -1.6168€-03 | 27736-06128 | 436 (GsHe ‘|S METHYL-42-BUTADIENE ‘68966601 | 24259603 | 3.70016-06 | 161] «at icsHe "2METHYL-13-BUTADIENE ~107ese-01 | 65526604 | —— 128 | 387 A2PENTADIENE 440156-01 | -155166-03 | 759026-06 [137 | 480 {cis PENTADIENE —Tass08E-01 16164609 | 26740E-06 199) 440 [rans-1 3-PENTADIENE Te0vieor | 25039603 | s6547e-06 | 167 | 450 1a-PENTADIENE 57753601 21090603 | s6sete-o6 | 128 | 431 ~[23:PENTADIENE 5 7996E-01 | 20270E-03 | 4.18636-06 149 | 447 | 18807 [-PENTYNE: 84209601 -3.2005E-03 | §02546-06 | 160 | 439] 160.56 2-PENTYNE 1.40606-01 | 6.6609E-04 | —— | 165” | 359 | 17409 SMETHYLTSUNYNE "35.285 | 1.07686+00 | 3240-03 | 66180606 | 184 | 417] 16530 _| SSPIROPENTANE —— [167 | 9429287 PENTAERY THRITOL TETRANITRATE == ————— (CYCLOPENTANONE Seno | Gas7eEo; ieoete-os | 2116108 | mms, 563 16416 METHYL ISOPROPENYL KETONE 41822 | 66400E-01 | -259506-05 | a1410E06 | 221 | 609 | 158.17 [ACETYLACETONE 49.793 1.457E+00-3.11916-03 | 3.40796-06 | 261_| 5421 204.46 Table 3-1 HEAT CAPACITY OF LIQUID - ORGANIC COMPOUNDS (continued) Cp=A+BT+CT+DT? {Cp - Joule/(mol K), T - K) NO FORMUTA TAME & a € a THIN | TWA | C, @250 ‘or [O5H802____|ALLYLACETATE = Tiase_| SHusEOT | ETIEGS | AADAGEGE soa ttre? | '392_[CsH802 [ETHYL ACRYLATE 68535 | 9.13126-01 | -27675E.03 | 3.543%E-06 498) 18667 ‘383 CSHBO2 METHYL METHACRYLATE. 42.265 | 1.0787E+00 | -3.1551E-03 | 3.7759E-06 sos | 183.58 {304 [058802 | VINYL PROPIONATE 64.575 | a76406-01 | -2.60326.05 | 3.751606 aot | 17918 395 [¢8H803____ [21YOROXYETHYL ACRYLATE | "¥12.540_|7.76906-01 | -2.00026-03_2.2917E-06 22689 396_(C5H803__[LEVULINIC ACID 41.840 | 14153E+00 | -3.1901E-03 | 2.85846-06 — 397 [CSHBO3 [METHYL ACETOACETATE. 427.450 | .1044E-01 | -1.3704E-03 | 1.6570E-06 20068 398_|CsH9O4 | GLUTARIC ACID 10.226 | 172656000 | -0.4237E-032.63246.-06 — 399. |CSHON \VALERONITRILE 100.491 | 6.2946E-01 | -1.8110E-09 | 2.36366-08 veo 400 [CSHONO [n-BUTYL ISOCYANATE_ 24.441 | 1.1425E+00 | -3.3850E-03 | 4.3637E-06_ 180.06 “401 |CSHONO_|N-METHYL2-PYRROLIGONE 10.326 | 63604E-01 | -1.49516-03 | 1.501706 7727 1402 [GsHONO4 —_|L-GLUTAMIC ACIO ——— — —- — 405 [C5H10 (CYCLOPENTANE: 49.998 |" 3004E-07 | “i 7606E-03_| 2.50596-08 11978 404 05H 2METHYL-+1-BUTENE Tr452_| 5767-01 | 2.147303 | 365556-06 | 197 | 419 | 15802 405 _[csH0 ‘2METHYL2.BUTENE 74305 | 86364E-01 | -2.1986603 | 35676606 | 140 | 426 | 15262 406 [esHi0 [SMETHYL-1-UTENE ‘0005 | 39777601 | -15462E09 | 290006-08 106 | 405 | 15042 407_[esi10 “-PENTENE [e192 |~4.21086-01 | -1.50036.05 | 2.970006 | 109 | 418 | 159.18 408_[esH0 cis-2-PENTENE 0445 | 494006-01 | -151996-03 | 32037E-05 | 125 | 428) 151.67 409 (CsHt0 ‘vans-2-PENTENE 81528 | 52108E-01 | -19000e-03 | 372136-08 | 1m | 428 | 15337 410_[CSH10B72 _|28-DIBROMO-2-METHYLBUTANE [te0.60% | -170096-01 | 4soqzeo« | —— | 289 | «74 | 16867 “411” (C5HI0C2_1.5-DICHLOROPENTANE 109.966 |7.14126-01 | -1.8637E-03 | 2.165206 “412. [CSHI00___| METHYL ISOPROPYL. KETONE 83.052 | 7.14196-01_ | -2.19626-03 | 2.9759E-06 “419 (CSHI00__|2.PENTANONE —— — — “414_[CSH100_ [DIETHYL KETONE [aezr | i2aa2e+00 | S7a49E-05__ a3016E-08 415 _|C5H100 \VALERALDEHYDE 97.499 6.5995E-01 | -2.0349E-03 | 27202606 | “416 [C5H1002 |e-BUTYL FORMATE 94.203) 7.30406-01 2.904706 “17_C5H1002 [ETHYL PROPIONATE - ["ros20 97543601 3.80Z36.06 “s16_[GsH1002 ISOBUTYL FORMATE 104038) 621876-01 3.4864E.06 “419. [GsH1002 ISOPROPYL ACETATE T0800 | 9.861801 30555603 3,990TE-06 420__C5H1002 _|n-PROPYL ACETATE [Terse1 | 7e20seor | 24341603 3.32676-08 421 [C8H1002 | METHYL n-BUTYRATE 90.082 | B64sie-or | -265086.03 | 351646-06 [422 [cs1002 _[2METHYLBUTYRICACID 09.104 | 74atte-o1 | -19804e-03 | 2.3727E-06 423 |¢st1002 __|ISOVALERIC ACIO 81.045 | 1.11146+00 | -290046.09 | 9.1566-06 1424 |CsH1002 | VALERIC ACID _——— Ta976_ | 86720E-01 | -227096.03 | 2.47 66-06 425_|C5H1002 ___TETRAHYDROFURFURYL ALCOHOL 715.40 | 6.17026-01 | -1.38756-03 | 1.65176-06 128 |¢sH10025 —|3-METHYL SULFOLANE 10.366 | 7.26636-01 | -1.4981E-03 | 1.36636-06 421 |C5H1003 DIETHYL CARBONATE 195.855 | 1.16596+00_| -23274E-03 | 3.90066-06 1425 |[GsH1003 ETHYL LACTATE 48.239 | 21823E+00- | -5.08526.03 | 6.65036.08 423 |GsH108 | THAGYCLOHEXANE jeaat? | -2ac7oE-o1 | 59160604 —— 1430__[CsHi0S [CYCLOPENTANETHIOL 143.203._| -7.26096.02 | 36400608 — 4S1_[CSHTBr | -BROMOPENTANE 3.414 | 11607601 | 47706606 | — 462 |GSHTIGl _|1-CHLOROPENTANE 99732 | 6340901 | -19117E03 | 260226-08 433_[CSHTICl___|1-CHLORO-S- METHYLBUTANE wratt | 11249601 | 4947606 | —— 404 [CSHI1Cl__[2-CHLORO-2.METHYLBUTANE 179.68 14760601 | 53859604 | —— 495_(CSHTIN_NMETHYLPYRROLIONE TaA63_| 61054601 -1770E.09_| 25900E-08 496_[CsH1IN__[PIPERIOINE 11977 | 1.261200 | -3750E-03 | 3.7200€-06 437 |CSH1INO tot. BUTYLFORMAMIDE 20.654 | 1.2624E100 | -2.9800E-03 | 2.8965E-06. 436 (OsHt2 ISOPENTANE 1474 | 44952601” -1.69506.09 | 9.19426-08 | 430 [osHt2 'NEOPENTANE 106.316 | 3.244100 | -1.09106-02 1.34206-05. “a0 lesHt2 [pPENTANE, 0.641 | 6 21966-01 | -226826-03 | s7azse-06 | 144 | «za | 16364 “W4t_(CSH120___2.2.01METHYL--PROPANOL "200.652 | S.8455E00 _-4.0176E-02 | 96S7IE-06 | 328495 | — ‘42 _|G5H120 [tet PENTYL-ALCOHOL, 739.683 | 25063601 | S6073E-4 — | 328418 M43 [CSH120_ 2. METHYL-#-BUTANOL, 109.661 66256E-01 | -264226-03 | 334156-06 201 | 509 | 22668. “i44_[C5H120 [2 METHYL-2-BUTANOL [c-sest3 [22919600 | -659556.09 7.2005E-08 | 265.) 401 | “445_CSH120___S METHYL-1-BUTANOL [Tss's90 | 4.00226-01-143676-05 20586-06157 | 622 {446_(CSH120 |S METHYL-2-BUTANOL. ‘esaio | eesi7eor | -26982e-03 | 321006-06 201 | 51720252 “W47_(CSH120 | -PENTANOL 105.748 | 7.46236-01 | -2.16946-09 2.7316E-06 | 197 | 528 | 207.70 “48 |CsH120___ [2 PENTANOL —— 93.720 | ‘1.1S7OE+00 | -34487E-03 444see-05 | 201 | 497 | 243.98 (csH120_[S-PENTANOL '87.761_| 42602600 | -S8016-03 49160606 205 | 492 | 25251 _| (GsH120 METHYL soc BUTYL ETHER 49.275 | 1.15826+00 | 36163603 | 5.1616E-05 | 201 | 448 | 192.16 (G5H120 METHYL ter- BUTYL ETHER ware | 76502601 | 26192603 | s91716-08 | 166 | 447 | 165.06 (csH120 (METHYL ISOBUTYL ETHER 49604 | 1.1435E+00 | 37712603 | 6.1067E-06 | 201 | 447 | 190.88 [CsH120__ ETHYL PROPYL ETHER 502666 | 7.0110E-01 | -24096E-03 | 3.67526-06 | 147 | 450 | 199.04 [Gsi1202 _|ETHYLENE GLYCOL MONOPROPYL ETHER 99.5 | 72670601 | -219716-03 | 2803906 | 164 | 526 | 20052 | (csH1202_|NEOPENTYL GLYCOL “508 209 | 5.1925E+00 | -1.1404E-02"| 9.15206.06_| 401) 679 — [cst1202_|1.5PENTANEDIOL ‘67470 | 1.0849E+00 26042603 | 2.76436-06 | 268 | 606 | 22526 [CsH1203__[242-METHOXYETHOXYJETHANOL {36.608 |"e673te-01 | -26028E-03 | 3.2670E-06 | 108 | 567 | 780.22 | (CsH1204 | PENTAERYTHRITOL Ti420.747 | 9.5192E+00 | -1.6660E-02 | 1.034%6-05 625) 702) — (CsH12s__[mPENTYL MERCAPTAN 94716 | 7597001 | 21472603 | 2esese-o6 | 198 | 598 | 20169 (CSHi2S | BUTYLMETHYL-SULFIDE. “97240 | -1.47@0E-01 | 62060604 — | 176 | aay | 199.73 (GsH'128___[ETHYL-PROPYL-SULFIDE “90919 | -1.24056.01 | 69700604 [157 | 4221970 _| (CsH128 (2 METHYL-2-BUTANETHIOL [795.372 |-=1.20066-01 | 6.55466.04 470402 | 17895 463 [CSHION_[n-PENTYLAMINE. ©0963 | 1.15536+00 | -345306-03 421166-08 | 219 | 500 | 20046 464 CSHTONOZ__/METHYL DIETHANOLAMINE 105.51 [4.386400 | -334s0e-03 | a

    You might also like