MINISTRY OF EDUCATION, BOTSWANA in collaboration with UNIVERSITY OF CAMBRIDGE LOCAL EXAMINATIONS SYNDICATE. Botswana General Certificate of Secondary Education CANDIDATE NAME NUMBER NUMBER CENTRE | | | CANDIDATE ‘== CHEMISTRY 0570/03 Paper3 October/November 2007 1 hour 15 minutes Candidates answer on the Question Paper. No Additional Materials are required. READ THESE INSTRUCTIONS FIRST Write your Centre number, candidate number and name in the spaces provided at the top of this page. Do not use staples, paper clips, highlighters, glue or correction fluid. Answer all questions. Write your answers in the spaces provided on the question paper. Show your working for any calculations. ‘The number of marks is given in brackets [ ] at the end of each question or part question. A copy of the Periodic Table is printed on page 12. | For Examiner’s Use 1 a This document consists of 10 printed pages and 2 blank pages. sp (sMicaw) TA4016/2 ; BEC 2007 [ur1 2 Lead(Il) bromide, PbBr,, is electrolysed using inert electrodes as shown. heat (a) What happens to the brightness of the bulb when heating is stopped? Give a reason for your answer. oo [3] {b) Suggest another substance that can be used instead of lead(I!) bromide to cause the flow of current. (c) 0.414g of lead was deposited at the cathode when a current of 2.5A was passed. (i) Calculate the number of moles in 0.414g of lead. a] (ii) Calculate the total charge in Faradays required to liberate 0.414g of lead at the cathode. (2) (iil) Use your answer to (¢){i) to calculate the amount of charge in coulombs. [1 Faraday = 96500 coulombs} m1‘ fat 7 | Examiners (iv) Calculate the time taken, in seconds, to liberate the 0.414 of lead if the current is 25h. 2] [Total: 10] Sulphur trioxide, $O,, is produced from sulphur dioxide, SO,, as shown by the reaction equation. 280,(g) + O,(g) == 280,(9) (a) (i) The reaction is reversible. What is meant by a reversible reaction? (1) If the pressure at equilibrium is increased, will the yield of sulphur trioxide, SO,, increase, decrease or stay the same? Give a reason for your answer. 3] (b) State two conditions necessary for the production of sulphur trioxide, SO,, from sulphur dioxide, SO,, and oxygen, O,, in the Contact process. 1 2 [2] (c) Describe how sulphur trioxide, SO,, is converted into sulphuric acid, H,SO,, in the Contact process. (d)_ Give two uses of sulphur dioxide, SO,, other than for the production of sulphuric acid by the Contact process. (2) [Total: 10]3 4 ‘The diagram shows how ethanol was prepared from water and sugar solution. sugar, water and Universal Indicator yeast (a) Name the process by which ethanol is produced from water and sugar solution. (b) The gas produced is bubbled through water containing Universal Indicator. (i) Name the gas produced (ii) What colour change is observed as the gas is bubbled through the Universal Indicator solution? to 2] (c) A student suggested bolling the sugar water and yeast solution so that the reaction can be faster. Explain why the solution should not be boiled. ao) (d) (i) Describe how the ethanol can be separated from the mixture after the reaction is complete. [1] (ii) When using the method named in (d)(i), describe how you would know that all the ethanol has been separated. 1 (e) The ethanol is heated with potassium dichromate(V!) to form an organic compound. Name the organic compound formed. Give the structural formula of the organic compound named in (e)(). (1 Total: 9] ” For exeninors Use5 4 The equation shows the reaction of one mole of methane with two moles of oxygen, OHA(9) + 20,{4) ——» 00,(q) + 2,019) The bond energies are given in the table. (@) () Calculate the total energy needed to break all the bonds in the reactants, total energy = +. kJ/mol (2] (i Calculate the total energy needed to form al the bonds in the products. total energy kJ/mol (2) (ili) Calculate the total energy change for the reaction, total energy change =... kJ/mol [2] (lv) State whether the reaction is exothermic oF endothermic. [1] for the reaction of (b) Draw a labelled energy level diagram, including activation energy, ‘methane and oxygen, Far 4 | (otal: 41] “BEC 2007 os70/0/0/N/075 6 ‘The diagram shows how an experiment was set up. x z Zz KD cI cotton wool soaked cotton wool soaked in in hydrogen sulphur dioxide solution sulphide solution The solutions release hydrogen sulphide gas, H,S, and sulphur dioxide gas, SO,, respectively. The two gases react to form a yellow powder. The equation for the reaction is, HSC) +. we SO3() ——> vee S() + HOC) (a) Balance the equation and write the state symbols for alll the substances. (2) (b) (i) Calculate the relative molecular mass of hydrogen sulphide, H,S. [4,:H, 1:8, 32] a] (ii) Calculate the relative molecular mass of sulphur dioxide, SO,. [A,:S, 32; 0, 16] (iii) At which point, X, ¥ or Z, will the yellow powder be formed? Explain your answer. (c) Name the process being demonstrated by this experiment. (@) Explain what would happen if the experiment was repeated at a slightly lower temperature, 2] Total: 9] |exaninatsrs te z Examiner's (b) A student attempted to prepare potassium chloride crystals from the mixture of 20cm? potassium hydroxide and 35cm® hydrochloric acid. Small amounts of charcoal were added to the mixture and then removed. (i) Explain the purpose of adding charcoal. (I) How was the charcoal removed? (c) The solution was heated to dryness. { (i) What is the colour of the solid which remained? (d) Give one application of acid-base reactions in daily life. © BEC 2005 osvomvonvos TTurn over6 The diagram shows a simple cell. copper electrode —| zinc electrode |— dilute sulphuric acid (2) (i) Describe how the cell produces an electric current. (2) (ii) Which electrode is the cathode? ti) (iil) Write the equation for the reaction taking place at the zinc electrode. (1)9 (b) The experiment was repeated with different metals replacing the zinc electrode. The voltage across the electrodes was measured. The results are shown in the table. electrode which replaced | voltage (V) the zine rod nickel 0.59 copper 0.00 zine eo tin 0.50 lead 0.47 (Using the voltages of the metals, place the metals in order of their reactivity, starting with the most reactive. most reactive least reactive .... (2) (ii) Calculate the voltage obtained if the copper electrode was replaced with lead and the zinc electrode replaced with tin, vay For Examiners Use10 The diagram shows the electrolytic cell used for the extraction of aluminium from molten alumina. waste gases anode cathode —— molten alumina (a) (I) What are the electrodes made from? (b) (co) : 1] (ii) Name the ore of aluminium from which alumina is extracted on . tt (iii) Write the chemical formula of alumina. oranonnssnsenn ~O) Give one use of aluminium and state the property upon which this use depends. Mises sees property a The molten alumina is electrolysed for 2 hours using a current of 250 amps. (i) Write the equation for the formation of aluminium metal from the aluminium ion, Ast, eee a) (il) Calculate the quantity of electric charge used. (2) (ii) Calculate the number of moles of electrons used. [1 Faraday = 96 500 C} [2] (iv) Calculate the mass of aluminium produced. (2) Exannors Use