1. Homogeneous mixture of two or more than (A) 0.025 × 1023 (B) 1.505 × 1022
two components is called (C) 15 × 1022 (D) 2.5 × 1023
(A) solute (B) solvent 12. How many grams of NaOH are present in
(C) both (A) & (B) (D) solution 250 mL of 0.5 M NaOH solution ?
2. Which of the following is an example of (A) 7.32 g (B) 3.8 g
gaseous solution ? (C) 5 g (D) 0.5 g
(A) Camphor in nitrogen gas 13. 250 mL of sodium carbonate solution
(B) Solution of hydrogen in palladium contains 2.65 g of Na2CO3. If 10 mL of this
(C) Chloroform mixed with nitrogen gas solution is diluted to 500 mL, the
(D) Both (A) and (C) concentration of the diluted acid will be
3. In amalgam of mercury with sodium, (A) 0.01 M (B) 0.001 M
solvent is (C) 0.05 M (D) 0.002 M
(A) mercury (B) sodium 14. The density of a solution prepared by
(C) amalgam (D) none of these dissolving 120 g of urea (mol. mass = 60 u)
4 What is the mass percentage of carbon in 1000 g of water is 1.15 g/mL. The
tetrachloride if 22 g of benzene is dissolved molarity of this solution is
in 122 g of carbon tetrachloride ? (A) 1.78 M (B) 1.02 M
(A) 84.72% (B) 15.28% (C) 2.05 M (D) 0.50 M
(C) 50% (D) 44% 15. What will be the molality of a solution of
5. What is the mole fraction of glucose in 10% glucose in water which is 10% w/W ?
w/W glucose solution ? (A) 0.01 m (B) 0.617 m
(A) 0.01 (B) 0.02 (C) 0.668 m (D) 1.623 m
(C) 0.03 (D) 0.04 16. The molality of 648 g of pure water is
6. A solution is obtained by mixing 200 g of (A) 36 m (B) 55.5 m
30% and 300 g of 20% solution by weight. (C) 3.6 m (D) 5.55 m
What is the percentage of solute in the final 17. What is the mass of urea required for
solution ? making 2.5 kg of 0.25 molal aqueous
(A) 50% (B) 28% solution ?
(C) 64% (D) 24% (A) 37 g (B) 25 g
7. When 1.04 g of BaCl2 is present in 105 g of (C) 125 g (D) 27.5 g
solution the concentration of solution is 18. Concentration terms like mass percentage,
(A) 0.104 ppm (B) 10.4 ppm ppm, mole fraction and molality do not
(C) 0.0104 ppm (D) 104 pm depend on temperature. However, molarity
8. What will be the mole fraction of ethanol in is a function of temperature because
a sample of spirit containing 85% ethanol by (A) volume depends on temperature and
mass ? molarity involves volume
(A) 0.69 (B) 0.82 (B) molarity involves non-volatile solute
(C) 0.85 (D) 0.60 while all other terms involve volatile solute
9. What is the molarity of a solution containing (C) number of moles of solute change with
10 g of NaOH in 500 mL of solution ? change in temperature
(A) 0.25 mol L–1 (B) 0.75 mol L–1 (D) molarity is used for polar solvents only
(C) 0.5 mol L–1 (D) 1.25 mol L–1 19. Express the terms representing the following
10. What will be the molarity of 30 mL of 0.5 M formulae
H2SO4 solution diluted to 500 mL ? No. of moles of solute
(A) 0.3 M (B) 0.03 M (i)  (W)
Volume of solution in litres
(C) 3 M (D) 0.103 M
+ No. of moles of solute
11. How many Na ions are present in 100 mL (ii)  (X)
of 0.25 M of NaCl solution ? Mass of solvent in kg

   



 No. of moles of component pressure of the gas in vapour phase (p) is
(iii)  (Y) proportional to the mole fraction of the gas
Moles in the solution
(x) in the solution’. For different gases the
Mass of component
(iv)  (Z) correct statement about Henry’s constant is
Mass of solution (A) higher the value of KH at a given
W X Y Z pressure, higher is the solubility of the gas
(A) Molality Molarity Mass fraction Mole fraction (B) higher the value of KH at a given
(B) Molarity Molality Mass fraction Mole fraction
(C) Molarity Molality Mole fraction Mass fraction pressure, lower is the solubility of the gas
(D) Molality Molarity Mole fraction Mass fraction (C) KH is not a function of nature of gas
20. Solubility of a substance is its maximum (D) KH value for all gases is same at a given
amount that can be dissolved in a specified pressure
amount of solvent. It depends upon 25. The value of Henry’s law constant for some
(i) nature of solute gases at 293 K is given below. Arrange the
(ii) nature of solvent gases in the increasing order of their
(iii) temperature solubility.
(iv) pressure He : 144.97 kbar, H2 : 69.16 kbar,
(A) Only (i), (ii) and (iii) N2 : 76.48 kbar, O2 : 34.86 kbar
(B) Only (i), (iii) and (iv) (A) He < N2 < H2 < O2
(C) Only (i) and (iv) (B) O2 < H2 < N2 < He
(D) Only (i), (ii), (iii) and (iv) (C) H2 < N2 < O2 < He
21. During dissolution when solute is added to (D) H2 < O2 < N2 < H2
the solvent, some solute particles separate 26. H2S is a toxic gas used in qualitative
out from the solution as a result of analysis. If solubility of H2S in water at STP
crystallization. At the stage of equilibrium, is 0.195 m, what is the value of KH ?
the concentration of solute in the solution at (A) 0.0263 bar (B) 69.16 bar
given temperature and pressure (C) 192 bar (D) 282 bar
(A) increases (B) decreases 27. Henry’s law constant for molality of
(C) remains constant (D) keeps changing methane in benzene at 298 K is 4.27 × 105
22. Consider the two figures given below. mm Hg. The mole fraction of methane in
benzene at 298 K under 760 mm Hg is
(A) 1.78 × 10–3 (B) 17.43
(C) 0.114 (D) 2.814
28. When a gas is bubbled through water at 298
K, a very dilute solution of gas is obtained.
Henry’s law constant for the gas is 100 kbar.
If gas exerts a pressure of 1 bar, the number
Which of the following statements regarding of moles of gas dissolved in 1 litre of water
the experiment is true ? is
(A) The solubility of a gas in liquid in (A) 0.555 (B) 55.55 × 10–5
–3
beaker (i) is greater than that in beaker (ii) (C) 55.55 × 10 (D) 5.55 × 10–5
(B) The solubility of a gas in beaker (i) is 29. How much oxygen is dissolved in 100 mL
less than that in beaker (ii) water at 298 K if partial pressure of oxygen
(C) The solubility of a gas is equal in both is 0.5 atm and KH = 1.4 × 10–3 mol/L/atm ?
beakers (A) 22.4 mg (B) 22.4 g
(D) The solubility of a gas remains (C) 2.24 g (D) 2.24 mg
unaffected by change in weights. 30. At high altitudes the partial pressure of
23. The law which indicates the relationship oxygen is less than that at the ground level.
between solubility of a gas in liquid and This leads to
pressure is ….. (A) low concentrations of oxygen in the
(A) Raoult’s law blood and tissues
(B) Henry’s law (B) high concentrations of oxygen in the
(C) lowering of vapour pressure blood and tissues
(D) van’t Hoff law (C) release of dissolved gases and formation
24. According to Henry’s law ‘the partial of bubbles of nitrogen in the blood
   


 (D) thickening of blood and tissues
31. Partial pressure of a solution component is
directly proportional to its mole fraction.
This is known as
(A) Henry’s law (B) Raoult’s law
(C) Distribution law (D) Ostwald’s
dilution law
32. 3 moles of P and 2 moles of Q are mixed,
what will be their total vapour pressure in
the solution if their partial vapour pressures
are 80 and 60 torr respectively ?
(A) 80 torr (B) 140 torr
(C) 72 torr (D) 70 torr
33.
X, Y and Z in the above graph are
(A) X = p1 + p2, Y = 1, Z = 0
(B) X = p1 + p2, Y = 0, Z = 1
(C) X = p1 × p2, Y = 0, Z = 1
(D) X = p1 – p2, Y = 1, Z = 0
34. Among the following substances the lowest
vapour pressure is exerted by
(A) water (B) alcohol
(C) ether (D) mercury
35. In three beakers labelled as (A), (B) and (C),
100 mL of water, 100 mL of 1 M solution of
glucose in water and 100 mL of 0.5 M
solution of glucose in water are taken
respectively and kept at same temperature
Which of the following statements is correct
? (A) Acetone + Aniline
(A) Vapour pressure in all the three beakers
is same
(B) Vapour pressure of beaker B is highest
(C) Vapour pressure of beaker C is highest
(D) Vapour pressure of beaker B is lower
than that of C and vapour pressure of beaker
C is lower than that of A
36. The given graph shows the vapour pressure
temperature curves for some liquids.
   


Liquids A, B, C and D respectively are
(A) diethyl ether, acetone, ethyl alcohol,
water
(B) acetone, ethyl alcohol, diethyl ether,
water
(C) water, ethyl alcohol, acetone, diethyl
ether
(D) ethyl alcohol, acetone, diethyl ether,
water
37. For an ideal solution with pA > pB, which of
the following is true ?
(A) (xA)liquid = (xA)vapour
(B) (xA)liquid > (xA)vapour
(C) (xA)liquid < (xA)vapour
(D) (xA)liquid and (xA)vapour do not bear any
relationship with each other
38. What are the conditions for an ideal solution
which obeys Raoult’s law over the entire
range of concentration ?
(A)  mix H  0,  mix V  0, PTotal  pA x A
pB x B
(B)  mix H 
ve,  mix V  0, PTotal  pA x A
pB x B
(C)  mix H  0,  mix V 
ve, PTotal  pA x A
pB x B
(D)  mix H  0,  mix V  0, PTotal  pB x B
39. Intermolecular forces between n-hexane and
n-heptane are nearly same as between
hexane and heptanes individually. When
these two are mixed, which of the following
is not true about the solution formed ?
(A) It obeys Raoult’s law, i.e., pA = xApA°
and pB = xBpB°
(B) Hmixing is zero
(C) Vmixing is zero
(D) It forms minimum boiling azeotrope
40. Which of the following solutions shows
positive deviation from Raoult’s law ?
(B) Acetone + Ethanol
(C) Water + Nitric acid
(D) Chloroform + Benzene
41. Which of the following solutions is an
example of negative deviation from Raoult’s
law ?
(A) Acetone + Ethanol
(B) Carbon tetrachloride + Chloroform
(C) Acetone + Chloroform
 (D) Water + Ethanol stronger than A – B interactions
42. Study the figures given below and mark the (B) A – A and B – B interactions are weaker
correct statement. than A – B interactions
(C) A – A, B – B and A – B interactions are
equal
(D) The liquids form separate layers and are
immiscible
46. Match the column I with column II and
mark the appropriate choice.
Column I Column II
(A) Hmix = 0, Vmix = 0 (i) Non-ideal solution
(B) Hmix 0, Vmix 0 (ii) Positive deviation
(A) (i) Nitric acid + Water, (ii) Acetone (C) Hmix < 0, Vmix < 0 (iii) Ideal solution
+ Ethyl alcohol (D) Hmix > 0, Vmix > 0 (iv) Negative deviation
(B) (i) Water + Ethyl alcohol, (ii)
(A) (A)  (i), (B)  (iii), (C)  (ii), (D)  (iv)
Acetone + Benzene
(B) (A)  (iii), (B)  (i), (C)  (iv), (D)  (ii)
(C) (i) Acetone + Ethyl alcohol, (ii)
Acetone + Chloroform (C) (A)  (ii), (B)  (iii), (C)  (iv), (D)  (i)
(D) (i) Benzene + Chloroform, (ii) (D) (A)  (iii), (B)  (ii), (C)  (i), (D)  (iv)
Acetone + Chloroform 47. Fill in the blanks with appropriate words.
43. When acetone and chloroform are mixed Azeotropic mixture boil without change in
together, hydrogen bonds are formed their _____. Azeotropic mixtures exist in
between them. Which of the following solutions showing ______ or ______
statements is correct about the solution made deviations. _____ solutions do not form
by mixing acetone and chloroform ? azeotropes.
(A) On mixing acetone and chloroform will (A) colour, positive, negative, non-ideal
form an ideal solution (B) properties, positive, negative, ideal
(B) On mixing acetone and chloroform (C) boiling point, positive, negative, non-
positive deviation is shown since the vapour ideal
pressure increases (D) composition, positive, negative, ideal
(C) On mixing acetone and chloroform 48. The system that forms maximum boiling
negative deviation is shown since there is azeotrope is
decrease in vapour pressure (A) acetone – chloroform
(D) At a specific composition acetone and (B) ethanol – acetone
chloroform will form minimum boiling (C) n-hexane – n-heptane
azeotrope (D) carbon disulphide – acetone
44. Few mixtures formed by mixing two 49. Two liquids HNO3(A) and water (B) form a
components are given. Which of the maximum boiling azeotrope when mixed in
following binary mixtures will have same the ratio of 68% and 32% respectively. It
composition in liquid and vapour phase ? means
(i) Ethanol + Chloroform (A) A – B interactions are stronger than A –
(ii) Nitric acid + Water A and B – B interactions
(iii) Benzene + Toluene (B) A – B interactions are weaker than A –
(iv) Ethyl chloride + Ethyl bromide A and B – B interactions
(A) (i) and (iii) (B) (i) and (ii) (C) vapour pressure of solution is more than
(C) (i), (ii) and (iii) (D) (iii) and (iv) the pure components
45. When acetone and chloroform are mixed (D) vapour pressure of solution is less since
together, which of the following only one component vaporizes
observations is correct ? 50. Which of the following azeotropes is not
Cl correctly matched ?
H3C
(A) HNO3 (68%) + H2O (32%) : Maximum
C O + Cl C H boiling azeotrope, boiling point = 393.5 K
H3C (B) H2O (43%) + HI (57%) : Minimum
Cl
(B)
boiling azeotrope, boiling point = 290 K
(A)
(C) C2H5OH (95.5%) + H2O (4.5%) :
(A) A – A and B – B interactions are
   


 Minimum boiling azeotrope, boiling point = boiling point
351.15 K (C) PQ is the curve for solvent, XY is the
(D) Chloroform (93.2%) + C2H5OH (6.8%) : curve for solution and T is molal elevation
Minimum boiling azeotrope, boiling point = in boiling point
332.3 K (D) PQ is the curve for solvent, XY is the
51. Match the column I with column II and curve for solution and T is elevation in
mark the appropriate choice. boiling point
Column I Column II 56. A solution containing 12.5 g of non-
(A) Ethyl alcohol (i) p = p°x electrolyte substance in 185 g of water
+ water shows boiling point elevation of 0.80 K.
(B) Benzene + (ii) Effect of pressure on Calculate the molar mass of the substance.
Toluene gas solutions
(Kb = 0.52 K kg mol–1)
(C) Henry’s law (iii) Ideal solution
(A) 53.06 g mol–1 (B) 25.3 g mol–1
(D) Raoult’s law (iv) Azeotropic mixture –1
(C) 16.08 g mol (D) 43.92 g mol–1
(A) (A)  (i), (B)  (ii), (C)  (iii), (D)  (iv) 57. If 1 g of solute (molar mass = 50 g mol–1) is
(B) (A)  (i), (B)  (iii), (C)  (ii), (D)  (iv) dissolved in 50 g of solvent and the
(C) (A)  (iv), (B)  (iii), (C)  (ii), (D)  (i) elevation in boiling point is 1 K. The molar
(D) (A)  (iii), (B)  (ii), (C)  (i), (D)  (iv) boiling constant of the solvent is
52. The relative lowering in vapour pressure is (A) 2 (B) 3
proportional to the ratio of number of (C) 2.5 (D) 5
(A) solute molecules to solvent molecules 58. In the given graph, pq, qr and st represent
(B) solvent molecules to solute molecules
(C) solute molecules to the total number of
molecules in solution
(D) solvent molecules to the total number of
molecules in solution
53. Vapour pressure of a pure liquid X is 2 atm
at 300 K. It is lowered to 1 atm on
dissolving 1 g of Y in 20 g of liquid X. If
molar mass of X is 200, what is the molar
mass of Y ? (A) pq  liquid state of solution, qr  solid
(A) 20 (B) 50 state of solution, st  liquid state of solvent
(C) 100 (D) 200 (B) pq  liquid state of solvent, qr  solid
54. An aqueous solution of 2% non-volatile state of solvent, st  liquid state of solution
solute exerts a pressure of 1.004 bar at the (C) pq  liquid state of solvent, qr  solid
normal boiling point of the solvent. What is
state of solution, st  liquid state of
the molecular mass of the solute ?
solution
(A) 23.4 g mol–1 (B) 41.35 g mol–1
(D) pq  solid state of solvent, qr  liquid
(C) 10 g mol–1 (D) 20.8 g mol–1
55. In the graph plotted between vapour state of solvent, st  solid state of solution
pressure (V.P.) and temperature (T) 59. 2 g of sugar is added to one litre of water to
give sugar solution. What is the effect of
addition of sugar on the boiling point and
freezing point of water ?
(A) Both boiling point and freezing point
increase
(B) Both boiling point and freezing point
decrease
(C) Boiling point increases and freezing
(A) PQ is the curve for solvent, XY is the point decreases
curve of solution and T is depression in (D) Boiling point decreases and freezing
freezing point point increases
(B) PQ is the curve for solution, XY is the 60. Sprinkling of salt helps in the snow covered
curve for solvent and T is elevation in roads in hills. The phenomenon involved in

   



 the process is
(A) lowering in vapour pressure of snow
(B) depression in freezing point of snow
(C) increase in freezing point of snow
(D) melting of ice due to increase in
temperature by putting salt
61. Equimolal solutions in the same solvent
have
(A) same elevation in boiling point and
same depression in freezing point
(B) different elevation in boiling point and
different depression in freezing point
(C) same elevation in boiling point but
different depression in freezing point
(D) same depression in freezing point but
different elevation in boiling point.
62. A 5% solution (w/W) of cane sugar (molar
mass = 342 mol–1) has freezing point 271 K.
What will be the freezing point of 5%
glucose (molar mass = 18 g mol–1) in water
if freezing point of pure water is 273.15 K ?
(A) 273.07 K (B) 269.07 K
(C) 273.15 K (D) 260.09 K
63. What weight of glycerol should be added to
600 g of water in order to lower its freezing
point by 10° C ?
(Kf = 1.86°C m–1)
(A) 496 g (B) 297 g
(C) 310 g (D) 426 g
64. If semipermeable membrane is placed
between the solvent and solution as shown in
the given figure then
(A) the solvent molecules will flow through
the membrane from solution to pure solvent
(B) the solvent molecules will flow
continuously till the equilibrium is attained
(C) the flow of the solvent from its side to
solution side across a semipermeable
membrane can be stopped if some extra
pressure (called osmotic pressure) is applied
on the solution
(D) both (B) and (C)
65. Study the following figure showing osmosis
and mark the correct statement.
   


(A) The external pressure applied on the
solution to stop osmosis is called osmotic
pressure
(B) The external pressure applied on the
solvent to stop osmosis is called osmotic
pressure
(C) The hydrostatic pressure built up on
solvent which just stops osmosis is osmotic
pressure
(D) Pressure developed by solvent while
solution flows through semipermeable
membrane
66. Relative lowering of vapour pressure,
osmotic pressure of a solution and elevation
in boiling points are ____(p)____ properties.
Osmosis is the passage of ____(q)____
through a semipermeable membrane from a
solution of ____(r)____ towards a solution
of ____(s)____. Osmotic pressure is
equivalent to mechanical pressure which
must be applied on ____(t)____ to prevent
osmosis.
In the above paragraph p, q, r, s and t
respectively are
(A) colligative, solution, higher
concentration, lower concentration, solution
(B) colligative, solvent, higher
concentration, lower concentration, solution
(C) colligative, solution, lower
concentration, higher concentration, solvent
(D) colligative, solvent, lower concentration,
higher concentration, solution
67. The osmotic pressure of a solution can be
increased by
(A) increasing the volume
(B) increasing the number of solute
molecules
(C) decreasing the temperature
(D) removing semipermeable membrane
68. People taking lot of salt experience puffiness
or swelling of the body due to
(A) water retention in tissue cells and
intercellular spaces because of osmosis
(B) water loss from the cells through skin
tissues
(C) capillary action of water through skin
pores
 (D) excessive thirst and drinking more water (A) 30.96 (B) 34.36
69. The preservation of meat by salting and of (C) 68.72 (D) 48.25
fruits by adding sugar protects them from 76. Osmotic pressure of a solution containing 2
bacterial action because g dissolved protein per 300 cm3 of solution
(A) bacteria die of eating sugar or salt is 20 mm of Hg at 27°C. The molecular
(B) due to osmosis bacteria lose water on mass of protein is
salted meat or candied fruit and die (A) 6239.6 g mol–1 (B) 12315.5 g mol–1
(C) due to osmosis bacteria gain water on (C) 3692.1 g mol–1 (D) 7368.4 g mol–1
salted meat or candied fruit and die 77. A solution is made by dissolving 20 g of a
(D) bacteria get stuck to the salt and sugar substance in 500 mL of water. Its osmotic
layers and die pressure was found to be 600 mm of Hg at
70. Sea water is desalinated to get fresh water 15°C. Find the molecular weight of the
by which of the following methods ? substance.
(A) When pressure more than osmotic (A) 1198 (B) 500
pressure is applied pure water is squeezed (C) 1200 (D) 1000
out of sea water by reverse osmosis 78. Which of the following statements is not
(B) When excess pressure is applied on sea correct ?
water pure water moves in by osmosis (A) 5% aqueous solutions of NaCl and KCl
(C) Water moves out from a sea water due to are said to be isomolar
osmosis (B) 1 M sucrose solution and 1 M glucose
(D) Salt is precipitated from sea water when solution are isotonic
kept undisturbed for sometime (C) Molecular mass of acetic acid and
71. A 5% solution of cane sugar (Mol. wt. = benzoic acid is higher than normal mass in
342) is isotonic with 1% solution of cryoscopic methods
substance X. The molecular weight X is Tb K b
(A) 171.2 (B) 68.4 (D) For the same solution,  .
Tf K f
(C) 34.2 (D) 136.2
79. Grapes placed in three beakers X, Y and Z
72. Which of the following statements is correct
containing different types of solutions are
about diffusion and osmosis ?
shown in figures.
(i) In osmosis, a semipermeable membrane
is used while diffusion is without membrane
(ii) In osmosis, movement of molecules
occurs in one direction while in diffusion,
movement occurs in all directions.
(iii)In osmosis, only the solvent moves
while in diffusion both solute and solvent
move If beaker X contains water, Y and Z contain
(A) Only (i) and (ii) (B) Only (i) (A) Y-hypotonic solution, Z-hypertonic
(C) Only (ii) and (iii) (D) (i), (ii) and (iii) solution
73. 10% solution of urea is isotonic with 6% (B) Y-hypertonic solution, Z-hypotonic
solution of a non-volatile solute X. What is solution
the molecular mass of solute X ? (C) Y and Z-isotonic solutions
(A) 6 g mol–1 (B) 60 g mol–1 (D) Y and Z-hypotonic solutions
–1
(C) 36 g mol (D) 32 g mol–1 80. A plant cell shrinks when it is kept in a
74. A solution containing 10.2 g glycerine per (A) hypotonic solution
litre is isotonic with a 2% solution of (B) hypertonic solution
glucose. What is the molecular mass of (C) isotonic solution
glycerine ? (D) pure water
(A) 91.8 g (B) 1198 g 81. Which of the following statements is correct
(C) 83.9 g (D) 890.3 g ?
75. What will be the osmotic pressure in pascals (A) A saturated solution will remain
exerted by a solution prepared by dissolving saturated at all temperatures.
1.0 g of polymer of molar mass 150,000 in (B) A plant cell swells when placed in
500 ml of water at 37°C ? hypertonic solution
   


 (C) The depression in freezing point is (C) i
Number of molecules actually present
directly proportional to molality of the Number of molecules exp ected to be present
solution (D) i
Total number of particles taken before association / dissociation
(D) Lowering in vapour pressure is a Number of particles after association / dissociation

colligative property 87. Which of the following relations is not

82. For carrying reverse osmosis for correctly matched with the formula ?
desalination of water the material used for i 1
(A) In case of association,  
making semipermeable membrane is 1
1
(A) potassium nitrate n
(B) parchment membrane i 1
(C) cellulose acetate (B) In case of dissociation,  
n
1
(D) cell membrane (C) Relative lowering of vapour pressure
83. Which of the following is not an industrial
p  p nB
or biological importance of osmosis ?  A  A i
(A) Movement of water from soil into plant pA nA
nB
roots and upper portion of plant (D) Elevation in boiling point,
(B) Salting of meat to prevent bacterial WB 1000
action Tb  K b
M B WA
(C) Reverse osmosis for desalination of sea
88. Which of the following will have same
water
value of van’t Hoff factor as that of
(D) Filling of ink in a fountain pen
K4[Fe(CN)6] ?
84. Match the column I with column II and
(A) Al2(SO4)3 (B) AlCl3
mark the appropriate choice.
(C) Al(NO3)3 (D) Al(OH)3
Column I Column II
89. Arrange the following aqueous solutions in
(A) Kb (i) K b W2 1000
the order of their increasing boiling points.
Tb W1 (i) 10–4 M NaCl (ii) 10–4 M Urea
–3
(B) M2 (ii) W2 1000 (iii) 10 M MgCl2 (iv) 10–2 M NaCl
M 2 W1 (A) (i) < (ii) < (iv) < (iii)
(B) (ii) < (i) = (iii) < (iv)
(C)  (iii) RTb2 (C) (ii) < (i) < (iii) < (iv)
1000 L V (D) (iv) < (iii) < (i) = (ii)
(D) m (iv) Tb dRT 90. Which of the following has the highest
freezing point ?
1000 K b
(A) 1 m NaCl solution
(A) (A)  (i), (B)  (iii), (C)  (ii), (D)  (iv) (B) 1 m KCl solution
(B) (A)  (iv), (B)  (ii), (C)  (i), (D)  (iii) (C) 1 m AlCl3 solution
(C) (A)  (ii), (B)  (iv), (C)  (iii), (D)  (i) (D) 1 m C6H12O6 solution
(D) (A)  (iii), (B)  (i), (C)  (iv), (D)  (ii) 91. If  is the degree of dissociation of Na2SO4,
85. Why is the molecular mass determined by the van’t Hoff’s factor (i) used for
measuring colligative property in case of calculating the molecular mass is
some solutes is abnormal ? (A) 1 +  (B) 1 – 
(A) Due to association or dissociation of (C) 1 + 2 (D) 1 – 2
solute molecules 92. For which of the following solutes the van’t
(B) Due to insolubility of solute molecules Hoff factor is not greater than one ?
(C) Due to decomposition of solute (A) NaNO3 (B) BaCl2
molecules (C) K4[Fe(CN)6] (D) NH2CONH2
(D) Due to large size of solute molecules 93. What will be the degree of dissociation of
86. Which of the following representations of 0.1 M Mg(NO3)2 solution if van’t Hoff
i(van’t Hoff factor) is not correct ? factor is 2.74 ?
(A) i
Observed colligative property (A) 75% (B) 87%
Expected colligative property
(C) 100% (D) 92%
(B) i
Normal molecular mass
94. Which of the following will have the highest
Observed molecular mass
freezing point at one atmosphere ?

   



 (A) 0.1 M NaCl solution (C) 2.834 g (D) 1.820 g
(B) 0.1 M sugar solution 98. The van’t Hoff factor of 0.005 M aqueous
(C) 0.1 M BaCl2 solution solution of KCl is 1.95. The degree of
(D) 0.1 M FeCl3 solution ionization of KCl is
95. A solute X when dissolved in a solvent (A) 0.95 (B) 0.97
associates to form a pentamer. The value of (C) 0.94 (D) 0.96
van’t Hoff factor (i) for the solute will be 99. The elevation in boiling point of a solution
(A) 0.5 (B) 5 of 9.43 g of MgCl2 in 1 kg of water is (Kb =
(C) 0.2 (D) 0.1 0.52 K kg mol–1, Molar mass of MgCl2 =
96. What will be the freezing point of a 0.5 m 94.3 g mol–1)
KCl solution ? The molal freezing point (A) 0.156 (B) 0.52
constant of water is 1.86°C m–1. (C) 0.17 (D) 0.94
(A) –1.86°C (B) –0.372°C 100. 0.001 molal solution of Pt(NH3)4Cl4 in water
(C) –3.2°C (D) 0°C had a freezing point depression of 0.0054°C.
97. What amount of CaCl2 (i = 2.47) is If Kf for water is 1.80, the correct formula of
dissolved in 2 litres of water so that its the compound is
osmotic pressure is 0.5 atm at 27°C ? (A) [Pt(NH3)4Cl3]Cl (B) [Pt(NH3)4Cl4]
(A) 3.42 g (B) 9.24 g (C) [Pt(NH3)4Cl2]Cl2 (D) [Pt(NH3)4Cl]Cl3

ANSWER KEY
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
D D B A A D B A C B B C D C B
16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
B A A C D C B B B A D A B D A
31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
B C B D D A C A D B C C C B B
46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
B D A A B C C A B D D C B C B
61 62 63 64 65 66 67 68 69 70 71 72 73 74 75
A B B D A D B A B A B D C A B
76 77 78 79 80 81 82 83 84 85 86 87 88 89 90
A A A A B C C D D A D B A C D
91 92 93 94 95 96 97 98 99 100
C D B B C A D A A C