ORGANIC CHEMISTRY

(JEE-ADVANCED)

TOPIC : IUPAC DPP-1

Single Correct :
1. In which of the following side chain (acyclic chain) is the main chain ?

(A) (B)

(C) (D)

2. The correct IUPAC name of is :

(A) 1-Cyclopentyl-1, 1-dimethylbutane (B) 2-Cyclopentyl-2-methylpentane

(C) 2-Methyl-2-cyclopropylpentane (D) 1, 1-Dimethyl-1-cyclopentylbutane

OH

3. Give IUPAC Name

O
(A) 5-Hydroxy cyclohex-3-en-1-one (B) 3-Hydroxy cyclohex-5-en-1-one
(C) 8-Hydroxy cyclohex-3-en-1-one (D) 7-Hydroxy cyclohex-5-en-1-one

NO2

4.

OCH3
Write IUPAC name of following compound
(A) 4–Methoxy–6–Nitro cyclohexene
(B) (B) 5–Methoxy–3–Nitro cyclohexene
(C) 3–Nitro–1–Methoxy cyclohex–4–ene
(D) 3–Nitro–5–Methoxy cyclohexene

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5. CH2 — CH2 –– CH2
| |
COOH COOH
(A) Pentane-1, 5-dioic acid (B) Pentane-1, 5-dicarboxylic acid
(C) Propane-1, 3-dioic acid (D) None of these

6.
(A) But-2-ene-1, 4-dicarboxylic acid (B) But-2-ene-1, 4-dioic acid
(C) Ethene dicarboxylic acid (D) Ethene dioic acid

CH3
|
7. CH2 = C — COOCH3

(A) Methyl-2-methylprop-1-en-3-oate (B) 2-Methoxycarbonylpropene

(C) 2-Methoxycarbonylprop-2-ene (D) Methyl-2-methylprop-2-enoate

8. The IUPAC name of the compound is :

(A) 5-Bromo-3-hydroxybenzenecarbaldehyde
(B) 3-Bromo-5-formylphenol
(C) 3-Bromo-5-hydroxybenzenecarbaldehyde
(D) 1-Bromo-3-formyl-5-hydroxybenzene

9. is named as -

(A) 4-Chloro-2-methyl anisole (B) 2-Chloro-4-methyl anisole

(C) 3-Chloro-1-methyl anisole (D) 1-Chloro-3-methyl anisole

10. Which one of the following structures has the IUPAC name
3-ethynyl-2-hydroxy-4-methylhex-3-en-5-ynoic acid?
OH

HO2C
(A) CO2H (B)
OH
OH OH

(C) CO2H (D) CO2H

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One or more than one correct :
11. The IUPAC name(s) of the following compound is(are)

H3C Cl

(A) 1-chloro-4-methylbenzene (B) 4-chlorotoluene

(C) 4-methylchlorobenzene (D) 1-methyl-4-chlorobenzene

Paragraph :
COOH
O
H
N O
N
⊕
Me2N N N
Me H
12. How many different type of functional groups are present in given compound.
(A) 6 (B) 5 (C) 4 (D) 3

13. Degree of unsaturation of this compound is

(A) 10 (B) 9 (C) 8 (D) 7

14. Number of 2° nitrogens present in given compound are

(A) 2 (B) 3 (C) 4 (D) 5

Subjective Type :
Calculate DBE value -
CN

15.
||
O

16.

17. COOH
COOH

18.

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 Compound IUPAC name

19.

20.

Et
21.

Cl

22.
Br

ANSWER KEY

1. (C) 2. (B) 3. (A) 4. (B) 5. (A)

6. (B) 7. (D) 8. (C) 9. (-) 10. (D)

11. (AB) 12. (A) 13. (D) 14. (A) 15. (6)

16. (4) 17. (4) 18. (10) 19. 2, 6-dimethyl octane

20. 2, 2-dimethyl pentane 21. Ethylcyclohexene

22. 1-Bromo-2-chlorocyclobutene

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