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PINNAACLE CLASSES

26. Decreasing order of stability of and 32. The outer orbitals of in ethene molecule can
be considered to be hybridized to give three
is
equivalents orbitals. The total number
(a)
ofsigma and pi bonds in ethene
(b) molecule is

(c)
(a) 3 sigma and 2 pi bonds
(d)
(b) 4 sigma and 1 pi bonds

27. Which of the following pairs of ions are (c) 5 sigma and 1 pi bonds
isoelectronic and isostructural?
(d) 1 sigma and 2 pi bonds.
(a) (b)
33. In which of the following ionization processes
(c) (d) the bond energy increases and the magnetic
behaviour changes from paramagnetic to
28. The correct bond order in the following diamagnetic.
species is
(a) (b)
(a) (b)
(c) (d)
(c) (d)
34. Bond order of 1.5 is shown by
29. Which of the following options represents the
correct bond order? (a) (b)

(c) (d)
(a) (b)

(c) (d) 35. The name of complex ion, is


(a)hexacyanitoferrate (III) ion
30. Maximum bond angle at nitrogen is present in (b)tricyanoferrate (III) ion
which of the following? (c)hexacyanidoferrate (III) ion
(d)hexacyanoiron (III) ion. (2015)
(a) (b)

(c) (d) 36. The sum of coordination number and oxidation


number of the metal in the complex
31. The pair of species that has the same bond (where is
order in the following is ethylenediamine) is
(a) 6 (b) 7
(a) CO, (b) NO, (c) 8 (d) 9 (2015)
(c) (d)
37. Cobalt (III) chloride forms several octahedral
complexes with ammonia. Which ofthe following
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PINNAACLE CLASSES

will not give test for chloride ions with silver


(d) (2002)
nitrate at ?.
42. Coordination number of¿ in is
(a)
(a) 3 (b) 6
(b) (c) 4 (d) 2 (2001)
(c)
(d) (2015, Cancelled) 43. IUPAC name of is
(a)Triamminebromochloronitroplatinum (IV) chloride
(b)Triamminebromonitrochloroplatinum (IV) chloride
38. An excess of is added to 100 of a 0.01 (c)Triamminechlorobromonitroplatinum (IV) chloride
solution of dichlorotetraaqua‐ chromium (III) (d)Triamminenitrochlorobromoplatinum (1V) chloride
chloride. The number of moles of (1998)
precipitated would be
(a) 0.003 (b) 0.01 44. Theformulaofdichlorobis(urea)copper(II) is
(c) 0.001 (d) 0.002(NEET2013)
(a)

39. The correct IUPAC name for is (b)


(a)chlorodifluoridoethylenediaminechromium (III) (c)
chloride
(b)difluoridobis (ethylene diamine)chromium (III) (d) (1997)
chloride
(c)difluorobis‐(ethylene diamine) chromium (III) 45. The I.U.P.A.C. name of K 3 [ Ir (C 2 O4 )3 ] is
chloride (a) Potassium tri oxalato iridium (III)
(d)chlorodifluoridobis (ethylene diamine) chromium (b) Potassium tri oxalato iridate (III)
(III)(KarnatakaNEET2013) (c) Potassium tris (oxalato) iridium (III)
(d) Potassium tris (oxalato) iridate (III)

40. The complexes and 46. Total number of moles of AgCl precipitated on
addition of excess of AgNO3 to one mole each of
are the examples of which the following complexes [Co(NH3)4Cl2]Cl,
type of isomerism?. [Ni(H2O)6]Cl2, [Pt(NH3)2Cl2] and [Pd(NH3)4]Cl2 is
(a) Linkage isomerism
(b) Ionization isomerism 47. The spin only magnetic moment of [Mn(H2O)6]2
complexes is_______BM. (Nearest integer)
(c) Coordination isomerism
(d) Geometrical isomerism (2011) 48. The number of resonating structures exist for the azide ion,
N 3– are ……………

41. when reacts with forms ,


49. The sum of number of sigma and pi bonds formed
which is insoluble in water. It is soluble in excess
between two carbon atoms in CaC2 are:
of , due to formation of the following
complex 50. The dipole moment of HBr is 1.6 x 10-30 Coloumb-

(a) metre and inter-atomic spacing is 1 . The % ionic


character of HBr is
(b)
(c)

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