PINNAACLE CLASSES

46. Consider the following species: , CN, NO 52. Maximum bond angle at nitrogen is present in
and CN. Which one of these will have the which of the following?
highest bond order?
(a) (b)
(a) NO (b)
(c) (d)
(c) (d) CN

53. Which of the following molecules has the

47. Which one of the following pairs of species
maximum dipole moment?
have the same bond order?
(a) (b)
(a) (b) CN, CO
(c) (d)
(c) (d) CO, NO

54. Dipole‐induced dipole interactions are present

in which of the following pairs
48. Decreasing order of stability of and
(a) HC1 and He atoms
is
(b) and He atoms
(a) (c) and alcohol

(b) (d) and

(c) 55. The pair of species that has the same bond
(d) order in the following is

(a) CO, (b) NO,

49. Which of the following pairs of ions are
isoelectronic and isostructural? (c) (d)

(a) (b)
56. The outer orbitals of in ethene molecule can
(c) (d) be considered to be hybridized to give three

50. The correct bond order in the following equivalents orbitals. The total number
species is
ofsigma and pi bonds in ethene
(a) (b) molecule is

(c) (d)
(a) 3 sigma and 2 pi bonds

51. Which of the following options represents the (b) 4 sigma and 1 pi bonds
correct bond order?
(c) 5 sigma and 1 pi bonds
(a) (b) (d) 1 sigma and 2 pi bonds.
(c) (d)
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 PINNAACLE CLASSES

57. In which of the following ionization processes 63. Cobalt (III) chloride forms several octahedral
the bond energy increases and the magnetic complexes with ammonia. Which ofthe following
behaviour changes from paramagnetic to will not give test for chloride ions with silver
diamagnetic. nitrate at ?.
(a)
(a) (b)
(b)
(c) (d)
(c)
58. Bond order of 1.5 is shown by (d) (2015, Cancelled)

(a) (b)
64. An excess of is added to 100 of a 0.01
(c) (d) solution of dichlorotetraaqua‐ chromium (III)
chloride. The number of moles of
59. Four diatomic species are listed below. precipitated would be
Identify the correct order in which the bond (a) 0.003 (b) 0.01
order is increasing in them (c) 0.001 (d) 0.002(NEET2013)

(a) NO
65. The correct IUPAC name for is
(b) (a)chlorodifluoridoethylenediaminechromium (III)
chloride
(c) (b)difluoridobis (ethylene diamine)chromium (III)
(d) chloride
(c)difluorobis‐(ethylene diamine) chromium (III)
60. Which of the following has the minimum bond chloride
length? (d)chlorodifluoridobis (ethylene diamine) chromium
(III)(KarnatakaNEET2013)
(a) (b)

(c) (d) 66. The complexes and

are the examples of which

61. The name of complex ion,
(a)hexacyanitoferrate (III) ion
(b)tricyanoferrate (III) ion
(c)hexacyanidoferrate (III) ion
(d)hexacyanoiron (III) ion. (2015)
is type of isomerism?.
(a) Linkage isomerism
(b) Ionization isomerism
(c) Coordination isomerism
(d) Geometrical isomerism (2011)

62. The sum of coordination number and oxidation

67. exhibits
number of the metal in the complex
(a)linkage isomerism, geometrical isomerism and
(where is optical isomerism
ethylenediamine) is (b)linkage isomerism, ionization isomerism and optical
(a) 6 (b) 7 isomerism
(c) 8 (d) 9 (2015) (c)linkage isomerism, ionization isomerism and
geometrical isomerism
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 PINNAACLE CLASSES

(d)ionization isomerism, geometrical isomerism and

(a)
optical isomerism.(2006)
(b)
68. The hypothetical complex chlorodiaquatriammine (c)
cobalt(III) chloride can be represented as
(d) (1994)
(a) 74. How many ions are produced in aqueous solution of
[Co( H 2 O )6 ] Cl 2
(b)
(a) 2 (b) 3
(c) (c) 4 (d) 6

(d) (2002)
75. IUPAC name of [ ] is
3 3Pt ( NH ) (Br )( NO )Cl Cl
2

(a) Triamminechlorobromonitroplatinum (IV)

69. when reacts with forms , chloride
which is insoluble in water. It is soluble in excess
(b) Triamminebromonitrochloroplatinum (IV)
of , due to formation of the following
chloride
complex
(c) Triamminebromochloronitroplatinum (IV)
(a) chloride
(d) Triamminenitrochlorobromoplatinum (IV)
(b)
chloride
(c)
76. Oxidation state of nitrogen is incorrectly given for
(d) (2002) Compound Oxidation state

70. Coordination number of¿ in is (a)

[Co( NH 3 )5 Cl ]Cl 2
0
(a) 3 (b) 6 NH 2 OH −1
(b)
(c) 4 (d) 2 (2001)
( N 2 H 5 )2 SO4 +2
(c)
Mg 3 N 2 −3
71. IUPAC name of is (d)
(a)Triamminebromochloronitroplatinum (IV) chloride
77. The IUPAC name of the complex [ (
(b)Triamminebromonitrochloroplatinum (IV) chloride Pt NH 3 ) 2 Cl 2 ]
is
(c)Triamminechlorobromonitroplatinum (IV) chloride (a) Platinum (II) diammino dichloride
(d)Triamminenitrochlorobromoplatinum (1V) chloride (b) Diammino dichloro platinate (IV)
(1998) (c) Bis (ammino) dichloro platinum (IV)
(d) Dichloro diammine platinum (II)
72. Theformulaofdichlorobis(urea)copper(II) is
78. The formula of sodium nitroprusside is
(a)
Na 4 [ Fe (CN )5 NOS ] Na2 [ Fe ( CN )5 NO ]
(a) (b)
(b) NaFe [ Fe (CN )6 ] Na2 [ Fe ( CN )6 NO 2 ]
(c) (d)
(c)
[ Pt (NH 3 )4 Cl 2 ] [ PtCl 4 ]
(d) (1997) 79. The correct name of is
(a) Tetraammine dichloro platinum (iv) tetrachloro platinate (ii)
(b) Dichloro tetra ammine platinium (iv) tetrachloro
73. Which of the following ligands is expected to be platinate (ii)
bidentate?.

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 PINNAACLE CLASSES

(c) Tetrachloro platinum (ii) tetraammine platinate 87. In the coordination compound, K 4 [ Ni(CN ) 4 ] oxidation
(iv) state of nickel is
(d) Tetrachloro platinum (ii) dichloro tetraammine (a) −1 (b) 0
platinate (iv) (c) +1 (d) +2

80. Correct formula of potassium ferrocyanide is 88. Which of the following is wrong statement
K 4 [ Fe ( CN )6 ] K 2 [ Fe ( CN )6 ] H 2 O
(a) (b) (a) Ni(CO ) 4 has oxidation number + 4 for Ni
K 3 [ Fe ( CN )6 ]
(c) (d) None of these (b) Ni(CO ) 4 has zero oxidation number for Ni
(c) Ni is metal
(d) CO is gas
81. The IUPAC name of [ ( 3 )3
Co NH ( NO 2 )3 ]
is
(a) Trinitrotriammine cobalt (III)
(b) Trinitrotriammine cobalt (II) 89. The I.U.P.A.C. name of K 3 [ Ir (C 2 O4 )3 ] is
(a) Potassium tri oxalato iridium (III)
(c) Trinitrotriammine cobalt (III) ion
(b) Potassium tri oxalato iridate (III)
(d) Trinitritriammine cobaltate (III)
(c) Potassium tris (oxalato) iridium (III)
(d) Potassium tris (oxalato) iridate (III)
The IUPAC name of [ 4]
Ni (CO )
82. is
(a) Tetra carbonyl nickel (II)
[ Ag(CN )2 ]−
(b) Tetra carbonyl nickel (0) 90. The charge on complex is
(c) Tetra carbonyl nickelate (II) (a) −1 (b) +1
(d) Tetra carbonyl nickelate (0) (c) +2 (d) +3

83. The correct nomenclature for Fe 4 [ Fe(CN )6 ]3 is

(a) Ferroso-ferric cyanide
(b) Ferric-ferrous hexacyanate
(c) Iron (III) hexacyanoferrate (II)
(d) Hexacynoferrate (III-II)

The IUPAC name of compound 3 [

Na Co( ONO)6 ]
84. will be
(a) Hexanitritocobalt (III) sodium
(b) Sodium cobalt nitrite
(c) Sodium hexanitrocobaltate (III)
(d) Sodium hexanitritocobaltate (III)

[ Pt (C2 H 4 )Cl 3 ]−
85. The oxidation number of Pt in is
(a) + 1 (b) + 2
(c) + 3 (d) + 4

86. The oxidation state of cobalt in the complex compound

[ Co ( NH 3 )6 ] Cl 3 is
(a) + 3 (b) + 6
(c) + 5 (d) + 2

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