Test ID : 401

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.CUMULATIVE TEST - 32.

Std : XI (CBSE) Max. Marks: 480
Test Date : 11.03.2024 CHEMISTRY Time : 2 Hrs.
Note :
For every correct answer four marks will be awarded. For every wrong answer one mark
will be reduced. For unanswered questions zero mark.
Choose the correct answer : 30 x 4 = 120
o
1. If the atomic radius of Li is XA then radius of 5. If the uncertainty in its position and velocity
Be atom of same orbit. are equal then the uncertainty in the
3X o 4X o momentum is
1) A 2) A
4 3 1 mh 1 h
1) 2)
X X 2 π 2 π
3) A o 4) A o
4 3 1 h
st o
2. If the radius of 1 orbit of H is XA then its
3) 4) both (2) and (3)
2 mπ
th
debroglie wavelength in its 4 orbit.
6. Incorrect electronic arrangement in K L M N
1) 2πXAo 2) 8π XAo shells
o o
3) 10π XA 4) 12π XA 1) 2, 8, 2 2) 2, 8, 12, 2
3. Percentage of maximum probability of finding 3) 2, 8, 13, 1 4) 2, 8, 18, 1
an electron around the nucleus of an atom 7. The d-orbital having zero nodal plane
1) 80% 2) 95%
1) d x 2 − y2 2) dxy
3) 100% 4) 40%
4. The impossible set of all four quantum 3) dzx 4) dz2
numbers 8. For the Balmer series in the sepectrum of H
n l m s 1 1
atom, υ = R H  2 − 2  , the correct statement
1  n1 n 2 
1) 4 3 –3 −
2 among I to IV are
1 I) As wavelength decreases the liner in the
2) 4 2 –1 +
2 series coverage
1 II) The integer n1 is equal to 2
3) 4 2 0 +
2 III) The lines of longest wavelength
1 corresponds to n2 = 3
4) 4 1 –3 –
2 IV) The ionization energy of hydrogen can be
calculated from wave number of these lines
 2 Test ID : 401
1) I, II, IV 2) I, II, III 3) An anti bonding σ orbital
3) I, II, IV 4) II, III, IV 4) An anti bonding π orbital
9. Consider the ground state of Cr atom (X = 24) 15. Bond length of HF is 9.17 x 10–11 m. Dipole
the number of electrons with 1 = 1 and 2 are moment of HF is 6.104 x 10–30 Cm. The
respectively percentage of ionic character in HF will be
1) 16 and 4 2) 12 and 5 (electronic charge = 1.6 x 10–19 C)
3) 12 and 4 4) 16 and 5 1) 61.0% 2) 38.0%
10. The electrons are more likely to be 3) 35.5% 4) 41.5%
16. The structure of PCl5 in solid state is
1) Tetrahedral [PCl4]+ and octahedral [PCl6]–
2) Square planar [PCl4]– and octahedral [PCl6]–
3) Square pyramidal
4) Trigonal bipyramidal
17. The group of molecule have identical shape
1) in the region of a and c 1) PCl5, IF5, XeO2F2
2) a and b 2) BF3, PCl3, XeO3
3) only a to a 3) SF4, XeF4, CCl4
4) only a to c 4) ClF3, XeOF2, XeF3+
11. Strongest ionic bond 18. Maximum number of 90o angles between bond
pair – bond pair of electron is observed in
1) CsF 2) KF
1) dsp2 2) sp3d
3) NaF 4) LiF
3) dsp3 4) sp3d2
12. Which of the following has strongest
H-bonding? 19. Number of planar atom in IF7
1) O – H ---- F 2) O – H ---- H 1) 7 2) 5
3) F – H ---- F 4) O – H ---- O 3) 6 4) 4
13. Which of the following species is not 20. Lattice energy of ionic compounds depends
paramagnetic? upon
1) NO 2) CO 1) charge on the ion and size of the ion
3) O2 4) B2 2) packing of ions only
14. Which of the following but describes the 3) size of the ion only
diagram of molecular orbital? 4) charge on the ion only
21. If 50% dissociation of HI then the value of Kc
1) 1 2) 0.5
3) 0.75 4) 0.25
22. If Kc for the reaction 2A + B ⇌ C + D is 10

1) A bonding π orbital then calculate ∆Go at 298K

2) A non bonding orbital 1) +5.7 kJ 2) –5.7058 kJ
 3 Test ID : 401
3) 0.57 kJ 4) –0.57 kJ 4) A-II, B-I, C-IV, D-III
23. If some amount of CO gas added to 28. Statement – I : The Qc for the reaction
PCl5(g) ⇌ PCl3(g) + Cl2(g) then the equilibrium [SO3 ]2
2SO2(g) + O2(g) ⇌ 2SO3(g) is Qc =
[SO 2 ]2 [O 2 ]
shifted towards.
1) backward Statement – II : When Qc < Kc the reaction is
2) forward not at equilibrium and it will be fast in the
backward reaction.
3) no change
1) Both Statement-I and II are true
4) cannot be predicted
2) Both Statement-I and II are false
24. The active mass of 5.6lit of N2 gas at STP
3) Statement-I is true and Statement-II is false
0.5 0.25
1) 2) 4) Statement-I is false and Statement-II is true
5.6 5.6
+3 −
0.75 0.25 29. Fe(aq) + SCN (aq) ⇌ [Fe(SCN)]2 +
3) 4) Deep Re d
5.6 11.2
1 Deep red colour intensity increases when
25. If the conc. of [OH–] decreases times then
4 1) Oxalic acid is added
conc. of Fe+3 has to change as per the reaction 2) Addition of HgCl2
+3 −
Fe(OH)3(s) ⇌ Fe (aq ) + 3(OH )(aq) 3) Addition of potassium thio cyanate
4) Both (1) and (2)
1) 16 2) 32
1
3) 128 4) 64 30. Assertion (A) : SO2(g) + O2(g) ⇌ SO3(g) +
2
26. 3 O2(g) ⇌ 2O3(g) at 298K, Kc is 3 x 10–59. If heat forward reaction is favoured at very high
the concentration of O2 at equilibrium is temperature.
0.040M, then concentration of O3 in M is Reason (R) : The reaction is exothermic
–63 31
1) 1.9 x 10 2) 2.4 x 10 1) Both (A) and (R) are true and the (R) is a
21
3) 1.2 x 10 4) 4.3 x 10–32 correct explanation of the (A)
27. Match the following 2) Both (A) and (R) are true but (R) is not a
List – I List – II correct explanation of the (A)
A) Kp > Q I) Non-spontaneous 3) (A) is true but the (R) is false
B) ∆Go < RT log Q II) Equilibrium 4) (A) is false and (R) is true
C) Kp = Q III) Spontaneous
endothermic
D) T > ∆H IV) Spontaneous
1) A-I, B-II, C-III, D-IV
2) A-III, B-IV, C-II, D-I
3) A-IV, B-I, C-II, D-III
*** All The Best ***