Test ID : 401

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XI (CBSE) CUMULATIVE TEST - 32 (CHEMISTRY – ANSWER KEY) - 11.03.24
Note :
For every correct answer four marks will be awarded. For every wrong answer one mark
will be reduced. For unanswered questions zero mark.
Choose the correct answer : 30 x 4 = 120
4X o 1 mh
1. 2) A 5. 1)
3 2 π
Solution : Solution :
o
Z XA 3 h h
r∝ rLi = = ------ (1) ∆X.∆P = ⇒ ∆x. m∆V =
n2 12
1 4π 4π
4 XA o Given ∆X = ∆V
rBe = ------ (2)
3 h
∴ ∆V m∆V = ⇒ multiply m on both sides
4 4π
(2) rBe rBe
= = =1 m ∆V.m∆V =
ph
⇒ (m∆V)2 =
mh
(1) XA o XA o 3 4π 4π
1 1
mh
r 4 4X o ⇒ (∆P) 2 =
⇒ Be o = ⇒ rBe = A 4π
XA 3 3
1 mh
2. 2) 8π XAo ⇒ ∆P =
2 π
Solution :
6. 2) 2, 8, 12, 2
2πr = nλ ⇒ 2π x 0.529 Ao x n2 = nλ
Solution :
⇒ λ ∝ 2πr1 (of H atom)
(2, 8, 2) = 1s22s22p63s2,
Given r1 of H = XA ⇒ λ = 2π r1 x n1
o
(2, 8, 12, 2) = 1s22s22p63s23p63d44s2
o
⇒ λ = 2π XA ------ (1) (2, 8, 13, 1) = 1s22s22p6, 3s23p63d54s1
4th orbit λt = 2πr1 x n4 = 2π XAo x 4 (2, 8, 18, 1) = 1s22s22p6, 3s23p63d104s1
r ⇒ λ4 = 8πXAo 7. 4) dz2
3. 2) 95% Solution :
Solution : In case of dz2 all lobes are present like a donut
Fact NCERT ring around the nucleus on the X – Y plane
1 and a single dumbbell on Z-axis
4. 4) 4 1 –3 –
2 8. 2) I, II, III
Solution : Solution :
1 In the balmer series of H-atom the transition
Always n > l l≥|m| s= ±
2 takes place from the higher orbital to n = 2.
 2 Test ID : 401
∴ the longest λ corresponds to n1= 2 and n2 = 3 % ionic character =
As the wave length decreases, the lines in the µ obs 6.104 x10−30
x100 = = 41.5%
series converges. Hence, statement I, II, III are µ cal 14.672 x10 −30 x100
correct 16. 1) Tetrahedral [PCl4]+ and octahedral [PCl6]–
9. 2) 12 and 5 Solution :
Solution : 2PCl5(s) → [PCl4]+ + [PCl6]–
2 2 6 2 6 1 5
1s 2s 2p 3s 3p 4s 3d Tetrahedral octahedral
l = 1 means p subshell = 12 electrons 17. 4) ClF3, XeOF2, XeF3+
l = 2 means d subshell = 5 electrons Solution :
10. 1) in the region of a and c ClF3 sp3d –| shape
Solution : XeOF2 sp3d –| shape
Probability of finding are electron will have XeF3+ sp3d –| shape
maximum value at both a and c and at b zero
18. 4) sp3d2
probability
Solution :
11. 4) LiF
Solution :
| Z+ || Z− |
Ionic strength = 1.44 x
(r+ + r− ) 2
12. 3) F – H ---- F
Solution :
sp3d2 has 12(90o)
Greater the E.N difference, stronger is the
H-bond 19. 3) 6

13. 2) CO Solution :
F
Solution :
NO → 1 unpaired electron in π* F F

CO → all paired electron KK I F

σ2s 2 π2p 2x = π2p 2y σ2p 2z σ * 2p 22 F F

14. 4) An anti bonding π orbital F

Solution : 20. 1) charge on the ion and size of the ion

If one lone +ve and other one –ve indicate out Solution :
of phase and anti bonding molecular orbital Lattice energy depends upon charge on ions as
15. 4) 41.5% well as size of the ion

Solution : 21. 4) 0.25

Solution :
µcal = δ x l = 1.6 x 10–19 x 9.17 x 10–11
= 14.672 x 10–30
2HI ⇌ H2 + I2
 3 Test ID : 401
Initial moles 2 0 0 ⇒ [Fe ]* = 64 [Fe ]
+3 +3

Eq. moles 2–2∝ ∝ ∝ 26. 4) 4.3 x 10–32

moles dissociated Solution :
% dissociation = x100
initial moles 3O2(g) ⇌ 2O3(g)
2
50 = x100 [O3 ]2
2 Kc = ⇒ [O3 ]2 = K c [O 2 ]3
[O 2 ]3
∝x∝ 0.5 x 0.5 0.5 x 0.5
Kc = = = ⇒ [O3]2 = 3 x 10–59 x (0.04)3 = 1.9 x 10–64
(2 − 2 ∝) 2
(2 − 2 x 0.5) 2
(2 − 1)2
Kc = 0.25 [O3] = 19 x10−64 = 4.38 x 10–32 M
22. 2) –5.7058 kJ 27. 3) A-IV, B-I, C-II, D-III
Solution : Solution :
∆G = –2.303 x 8.314 x 298 log 10
o
Kp > Q rate of forward reaction > rate of
= –5705.85 J = –5.7058 kJ backward reaction
23. 2) forward ∆Go < RT logc θ, ∆Go is +ve non spontaneous
Solution : Kp = Q, equilibrium
CO + Cl2 → COCl2 T∆S < ∆H, ∆Go will be –ve only when
As per Lechatelier principle, if conc. of ∆H = +ve
products decrease reaction favours forward 28. 3) Statement-I is true and Statement-II is false
0.25 Solution :
24. 2)
5.6 When Qc < Kc, the reaction will be fast in
Solution : forward reaction
Active mass = molarity 29. 3) Addition of potassium thio cyanate
5.6 1 1 0.25 Solution :
= x = =
22.4 56 22.4 5.6 If SCN– is added conc. of SCN– increases
25. 4) 64 intensity also increases.
Solution : 30. 4) (A) is false and (R) is true
Fe(OH)3 ⇌ Fe+3 + 3OH– Solution :
1
Kc = [Fe+3] [OH–]3 SO2(g) + O2(g) ⇌ SO3(g) + heat is an
3
2
1 1 * 1 
Given [OH–] = K c =  Fe +3   OH  exothermic reactions, As per Lechatelier
4  4  principle forward reaction is favoured at low
Kc = K1c temperature and inoderate temperature
3
1
[Fe ] [OH ] = [Fe ]   [OH − ]3
+3 – 3 +5

4
1
[Fe+3] = x[Fe +3 ]*
64