Test ID : 401

,
E- mail : gpccnamakkal@gmail.com Website : www.gpccnamakkal.com

.CUMULATIVE TEST - 32.

Std : XI (CBSE) Max. Marks: 480
Test Date : 11.03.2024 CHEMISTRY Time : 2 Hrs.
Note :
For every correct answer four marks will be awarded. For every wrong answer one mark
will be reduced. For unanswered questions zero mark.
Choose the correct answer : 30 x 4 = 120
+2 o
1. If the atomic radius of Li is XA then radius 5. If the uncertainty in its position and velocity
+3
of Be atom of same orbit. are equal then the uncertainty in the
3X o 4X o momentum is
1) A 2) A
4 3 1 mh 1 h
1) 2)
X X 2 π 2 π
3) A o 4) A o
4 3 1 h
st o
2. If the radius of 1 orbit of H is XA then its
3) 4) both (2) and (3)
2 mπ
th
de-Broglie wavelength in its 4 orbit.
6. Incorrect electronic arrangement in K L M N
1) 2πXAo 2) 8π XAo shells
o o
3) 10π XA 4) 12π XA 1) 2, 8, 2 2) 2, 8, 12, 2
3. Percentage of maximum probability of finding 3) 2, 8, 13, 1 4) 2, 8, 18, 1
an electron around the nucleus of an atom 7. The d-orbital having zero nodal plane
1) 80% 2) 95%
1) d x 2 − y2 2) dxy
3) 100% 4) 40%
4. The impossible set of all four quantum 3) dzx 4) dz2
numbers 8. For the Balmer series in the sepectrum of H
n l m s 1 1
atom, υ = R H  2 − 2  , the correct statement
1  n1 n 2 
1) 4 3 –3 −
2 among I to IV are
1 I) Balmer series is found in visible region
2) 4 2 –1 +
2 II) The integer n1 is equal to 2
1 III) The line of longest wavelength corresponds
3) 4 2 0 +
2 to n2 = 3
1 IV) The ionization energy of hydrogen can be
4) 4 1 –3 –
2 calculated from wave number of these lines
1) I, II, IV 2) I, II, III
 2 Test ID : 401
3) I, II 4) II, III, IV 3) An anti bonding σ orbital
9. Consider the ground state of Cr atom (X = 24) 4) An anti bonding π orbital
the number of electrons with l = 1 and 2 are 15. Bond length of HF is 9.17 x 10–11 m. Dipole
respectively moment of HF is 6.104 x 10–30 Cm. The
1) 16 and 4 2) 12 and 5 percentage of ionic character in HF will be
3) 12 and 4 4) 16 and 5 (electronic charge = 1.6 x 10–19 C)
10. The electrons are more likely to be 1) 61.0% 2) 38.0%
3) 35.5% 4) 41.5%
16. The structure of PCl5 in solid state is
1) Tetrahedral [PCl4]+ and octahedral [PCl6]–
2) Square planar [PCl4]– and octahedral [PCl6]–
3) Square pyramidal
4) Trigonal bipyramidal
1) in the region of a and c 17. The group of molecule is have identical shape
2) a and b 1) PCl5, IF5, XeO2F2
3) only a to a 2) BF3, PCl3, XeO3
4) only a to c 3) SF4, XeF4, CCl4
11. Strongest ionic bond is in 4) ClF3, XeOF2, XeF3+
1) CsF 2) KF 18. Maximum number of 90o angles between bond
pair – bond pair of electrons is observed in
3) NaF 4) LiF
1) dsp2 2) sp3d
12. Which of the following has strongest
H-bonding? 3) dsp3 4) sp3d2
1) O – H ---- F 2) O – H ---- H 19. Maximum number of planar atoms in IF7
3) F – H ---- F 4) O – H ---- O 1) 7 2) 5

13. Which of the following species is not 3) 6 4) 4

paramagnetic? 20. Lattice energy of ionic compounds depends
1) NO 2) CO upon
3) O2 4) B2 1) charge on the ion and size of the ion

14. Which of the following but describes the 2) packing of ions only
diagram of molecular orbital? 3) size of the ion only
4) charge on the ion only
21. If 50% dissociation of HI then the value of Kc
1) 1 2) 0.5
3) 0.75 4) 0.25
22. If Kc for the reaction 2A + B ⇌ C + D is 10
1) A bonding π orbital
2) A non bonding orbital then calculate ∆Go at 298K
1) +5.7 kJ 2) –5.7058 kJ
 3 Test ID : 401
3) 0.57 kJ 4) –0.57 kJ Statement – II : When Qc < Kc the reaction is
23. If some amount of CO gas added to not at equilibrium and it will be fast in the
backward reaction.
PCl5(g) ⇌ PCl3(g) + Cl2(g) then the equilibrium
1) Both Statement-I and II are true
shifted towards.
2) Both Statement-I and II are false
1) backward
3) Statement-I is true and Statement-II is false
2) forward
4) Statement-I is false and Statement-II is true
3) no change
+3
4) cannot be predicted
29. Fe(aq) + SCN −(aq) ⇌ [Fe(SCN)]2 +
Deep Re d
24. The active mass of 5.6lit of N2 gas at STP
Deep red colour intensity increases when
0.5 0.25
1) 2) 1) Oxalic acid is added
5.6 5.6
2) Addition of HgCl2
0.75 0.25
3) 4) 3) Addition of potassium thio cyanate
5.6 11.2
4) Both (1) and (2)
1
25. If the conc. of [OH–] decreases times then 1
4 30. Assertion (A) : SO2(g) +O2(g) ⇌SO3(g) + heat
conc. of Fe+3 has to change as per the reaction 2
+3 − forward reaction is favoured at very high
Fe(OH)3(s) ⇌ Fe(aq ) + 3(OH ) (aq)
temperature.
1) 16 2) 32 Reason (R) : The reaction is exothermic
3) 128 4) 64 1) Both (A) and (R) are true and the (R) is a
–59
26. 3 O2(g) ⇌ 2O3(g) at 298K, Kc is 3 x 10 . If correct explanation of the (A)
the concentration of O2 at equilibrium is 2) Both (A) and (R) are true but (R) is not a
0.040M, then concentration of O3 in M is correct explanation of the (A)
1) 1.9 x 10–63 2) 2.4 x 1031 3) (A) is true but the (R) is false
3) 1.2 x 1021 4) 4.3 x 10–32 4) (A) is false and (R) is true

27. N2(g) + 3H(g) ⇌ 2NH3(g) ; ∆H = –46.1 kJ mol–1

relation between Kp and Kc for the above
reaction.
1) Kp < Kc 2) Kc > Kp
2
3) Kc = Kp(RT) 4) All of these
28. Statement – I : The Qc for the reaction
[SO3 ]2
2SO2(g) + O2(g) ⇌ 2SO3(g) is Qc =
[SO 2 ]2 [O 2 ]

*** All The Best ***