REVISION SERIES Coordination Compounds

[ ]
Y
primary valency
-----

Co
Yellow teamy valuy
cole

[i]
-
..... I
Tempco a

[ -Ins]
Me
HN
Guenvious
"*
 Theory for
Valence Bond co-ordination no 6 -
:

strength of
donation
of
eis
.

C-donors >N-donors] O-donor > Galide-donor

.

Ein , 20) Nz en) Co o > Fict ,

Bre
, ,

(strong ligands (weak

ligand (
[16] i is
field ligand
# a weak .

26 +
(Ar/3 do ,
45

26iet -(Arl 306

39 us 4P 4d

4411 + 1 + 19 XX xx(xx) xXxxx)))

hybridization =
spd
octahedral
shape -

=)
magnetic no unpaireds
moment u BM n =

u = +) Bin :
BM
-

paramagnetic nature
in .

high spin complex (outer abitat complex

.
Fansference: It is
chiftinga
the transfer elec as
of an

when higher
from lower
energy energy
level
in a
compound
complex is called certain conditions

are
satisfied transference
.

① electron be
Only transferred.
one can

should be there
of strong fieldigand
2 Presence

There should be
possibility of formation of
inner orbital
3

complex .
 pairing energy
P-
-
* Q
only pairing
Do > P then
G
- will occur
.

② so < P- will not

If pairing
then occur
 Tetrahedral
CFT
for complexes

i
⑪ In tetrahedral
field the
ligands
- are
approaching
in between the

Thereforewhich
those d-orbitals
.
axis

the metal in between

of axis
are
-------> Y
the will
get repelled
& more
.

dxy dyz dax

11 t2

-
&
&

+ 0 4 DE.

At
-

I 1 1
W
. . . --------
&

-
0 6
.

DE

T C

dry2 daz

because
- of of ligands
At = Do no

- = became
of
direction
.
* in
compounds'
Colours

Reasons
for colour

I d-d transitions

②
Ligand
to metal
charge transfer (LMCT)
③ (delocalization
of charge) Colour inda
Resonance

④ Polarization

F-centress metal
⑤ excers
defect
⑥ Homo-LUMO transition -

① d-d transitions :
The transition
abitals to lower
d-e-from higher
. When the
datitals
energy energy
transition occurs or
e-jumps froma higher level to lowes

energyin visiblecorrespondingly
level it will emit some

some
light of
some
wavelength region
.
↑

has absorbed the

If compound
VRI a
R -

light .
I
it will emit the
-
- O
B &

en
colour
wheel
-
Y G -
red
light
I
AY CASE is
wavelength a a of
willhe
more the absorbed

higher
radiation & will be the emitted
radiation .

② do
LMCT :
complexes having configuration
:

Fo
Mut 30 Pink
purple colour is
= -
o

due to 02-mn e-hamfer

.

or
Y +7 Y
:
.
-
Mr Td
& :

offe j2
+6

⑪ KcCrg07 LiCT
-orange
-

+6

Cros - LMCT - blu

④ Colours due to
polarization :
+1 & +1
10
4d
- Age AgBr AgI
white Pale yellow
Bright yellow
In 1010
⑤
-

#centres
> TnD
zuO-
A
&
O
(In 20)
1+

white

&
yellow
a
(metalexus
P6O - 96O
Yellow Red
-
-

⑥ Homo Lumo transition

alogen
in
-

Reddish Brown
↳ fz-colourles
-

Bone
UrT yellow
greenish violet
-
 sphere
↳ Co-ordination Isomerism :-
- M
The have both
cationic
compoundsshowwhich
this
type
1 anionic

isomerium
part as
complex of
by exchange of the legands 61w them .

+3 +3 + 3 :

(Cr((N) 6]

T
[Co(Ns)s]

C
- , ,

#
[Co(NH3) CN] (Cr(CNS NA3]
~

3 +3 +3

(812N) 6] (Cr(NH3)s]
-

#
III

(CrCNH31s] (Co(IN) o]

⑤ co-ordination :
position isomerism
It occurs when
have central metal
ligands different positions wot the two
.

ions in a
polynuclear complex .

MH2-cr(R20n]
[WNH3(yCo -O
-
(son)a

(N13))
M12 <
(son)
&20)
- (H20s
(NHbly Co cr a

-02/
 0
o --
-
o
-20 -
LO

co /
- -
o co

(Mn ,(CO) 10) A = 7X2 + 2x10 =

34
B =
(18XU) - A

34 2
= 18X2 - =

of E
no Bonds =
= 1

CO CO

a 1 I ,
co

OC Mn-Mn
-
Co
-

Lo koco

(RUU(Ph3P)s]
catalyst
wilkinson's
↓ o

hydrogenati
↓ on of
alkenes

the chain
of
double bond at the end
is
hy drogenated but
-
double bond in centres all

affected
not . H2

- x