Which of the following values is an index of mean molecular weight of fatty acid in the

triglycerides?
The lower this value, the larger the locular weighr of fatty acid in the triglycerides.
A. Reichert-Meissl no.
B. Polenske number
C. lodine number
D. saponification no.
C. anhydrous ammonia
Which chemical fertilizer for nitrogen would have the highest %N?
A. ammonium sulfate
B. calcium nitrate
D. Urea
Essay. Answer the following concisely,
1. Outline the analysis of crude protein by providing the major steps and necessary reagents.
Make sure to represent each step with a balanced chemical equation where applicable. (15
points). Compare and contrast the three volumetric method of fat determination milk. (9 points)
3. Compare and contrast Polenske, Reichert-Meissl and Kirschner numbers then outline their
analysis in a given oil sample. Give the equation that will be used to calculate each parameter.
(15 points)4. Outline the analysis of the free fatty acid in copra. Set up the equation for its
calculation from its raw data.(5 points)
Problem solving. Solve the following by showing all necessary solutions, Make sure to express
final
Answer to correct number of significant figures.
1. Calculate the percent total solid and percent ash in a milk sample given the following
data:
Weight of dish
Weigh of dish + milk sample
Weight of dish + dried milk samples
106.52 g61 187.16g 109.46 9
Weigh of dish + ash
107.96 9
2. A solution of lactic acid was standardized by titration with 0.ozUU M NaOH.
a. If 4.36 mL of the NaOH solution is required to completely neutralize 15.42 ml of the lactic
acid
solution. What is the molarity of the lactic acid?
b. If 25.0 mL of the milk sample requires 19.63 mL of 0.0200 M NaOH to reach the
phenolphthalein
endpoint, what is the % lactic acid in the milk sample?
2. A sample of oil weighing 2.0050 g was refluxed with 40.05 mL of 0.5005 N KOH. The
excess KOH was back-
Titrated with 26.00 mL of 0.4085 N HCl using phenolphthalein indicator. Calculate the
saponification
Number of the oil.
4. A 0.8121 g sample of a wheat flour (factor = 5.70) was analyzed by Kjeldahl method. The
ammonia formed by the addition of concentrated base after digestion with HaS0a was distilled
into 25.00 mL of 0.04977 M HzSOa. Th excess HzSO4 was then back-titrated with 3.97 mL of
0.04012 M NaOH. Calculate the percent protein.
5. A 0.643-g sample of a water-soluble fertilizer was dissolved and analyzed for nitrogen using
the Kjeldahl method. After digestion, the distilled ammonia was collected in 100 mL of 0.1334
M boric acid. This solution required 21.4 mL of 0.202 M HCI for titration to the methyl red end
point. Calculate the % N in the fertilizer.
6. Determine the iodine value of a sample of olive oil weighing 0.2100 g if 24.15 ml and 12.00
mL of 0.1100
N of sodium thiosulfate solution are required for the blank and olive oil titrations, respectively.
KI+ICL→KCl+12
2NazS203+12 → 2 Nal +NazS406
7. Menthyl acetate is a natural monoterpene which contributes to the smell and flavor of
peppermint.
Calculate the percent menthyl acetate if a 9.120 g sample of peppermint oil, refluxed with 25.00
mL of
About 0.500 N alcoholic KOH, required 21.52 mL of 0.4900 N HCI for titration. A blank sample
was
Analyzed and required 26.00 mL of the same HCI to reach the endpoint.