[7a] ~ engineerin on ea ROBLEMS SOLVED NUMERICAL P co On: 2: : // Calculate the a: tbe ven electrode couple E'yemen =~ 90) the Fe on S For redox a °C. Given, E° Bogen 2 OMY Calculate the emf of the mye setutton: five ye cen notation He (FETT = aM, z = IM ay Fe" ee, ‘ough cu] = 0.1M OS) Reduction potential | © ( ; Bhaline = Solution: iat are |. ™ a We have, Note: At first both electrodes potent BP yey = + 0.34V | convened in terms of reduction potential fad Ew #1 | Atanode (oxidation) Cu- 2° ——* cu nae 3: . es cell is form ‘At cathode (Reduction) Fett? +e" ——> Fe] x2 ~ rod in 0.N ‘Net cel reaction: Gut DF ——+ Cu" + 2Fe™ and calculat Eset = Ecatode adc) ~ Ene Ricca Be £0.77 v-034V Bw aie Solution: . At anode (ox: 7 , Ising Nernst equation, _Atcathode ( ey ZB, 208 221, [Net cell reac Brea - ag +) (Betty? =043-—" log {Cu} {Fe"*y" (Fe }° 2043-2052 og on 02? We know t ay = 0.43 +0.709 Eau =05V Cell notation, oO Cell notati © Zn cwcur U*(O.IMY/IFe** (02M), Rares amy ~ ?-Electro-Chemistry and Butter .. mple 2: / Calculate the reduction potential for the Fe'*"/Fe™ electrode when the Fe" ion concentration is half of the Fe" ion concentration at 25°C. Given, E'pqepex = +0.77V, Solution: Fe ee——+Fe* = E=+0.77V © We have, Ewa =E’an-2 veh log Q=0.77- one toe ( = 077400177 =0.78V Example 3: A cell is formed by dipping Zn-rod in 0.01 M Zn™ solution and Ni - rod in 0.5M. Ni’ solution. Write the cell notation, cell reaction and calculate the emf of the cell. EB ptn = - 0-76 V Ee =~ 0.25V Solution: At anode (oxidation) Zn - 2°» ——+ Zn" E°,=-0.76V Atccathode (reduction) _Ni‘* + 2e° ——+ Ni B= -0.25V Net cell reaction Za + Ni? ——» Zn" + Ni Ec = Ecatuae eda) ~ Epnate Redaction) =-0.25 +0.76 =051¥ We know that, using Nernst equation, _ po 0.0591 Zn") 0.0591 (0.01 Beas = Eee 9 108 ti] = O51 -—3— log 1G 5) = 0.51 + 0.0502 =0.56V Cell notation, o @ Za/Zn**(0.01M)/INi** (0.SM)/Ni