SELF ASSESSMENT TEST

Chapter 13 : Amines

Time : 1 Hour ]  [ Marks : 20

Notes :
1. All questions are compulsory.
2. Figures to the right indicate full marks.

SECTION – A

Q. 1. Multiple Choice Questions : (1 mark each)

(i) Identify ‘B’ in the following reactions :

JA J B
Na / C2H5OH NaCO2 / dil. HCl
CH3 – CN

(a) CH3 – CH2 – NH2 (b) CH3 – CH2 – NO2

+
(c) CH3 – CH2 N2 Cl – (d) CH3 – CH2 – OH [1]

(ii) Which of the following compounds contains azo linkage?

(a) Hydrazine (b) p-Hydroxyazobenzene
(c) N-Nitrosodiethylamine (d) Ethylenediamine [1]

(iii) n-propyl alcohol is obtained when HNO2 is treated with

CH3 CH3
(a) CH3 – CH2 – NH (b) CH3 – N – CH3

(c) CH3 – CH2 – CH2 – NH2 (d) (C2H5)2NH [1]

(iv) Which of the following amines is most basic in nature?

(a) 2, 4 - Dichloroaniline (b) 2, 4 - Dimethylaniline
(c) 2, 4 - Dinitroaniline (d) 2, 4 - Dibromoaniline [1]

Q. 2. Very Short Answer Questions (VSA) : (1 mark each)

(i) Write the IUPAC name of benzyl amine. [1]
(ii) Arrange the following compounds in decreasing order of basic strength
in their aqueous solutions :

NH3, C2H5NH2, (CH3)2NH, (CH3)3N [1]

SELF ASSESSMENT TEST : LEARN SERIES CHEMISTRY XII (PART – 2) (CHAPTER 13) 1
 SECTION – B

Q. 3. Short Answer Questions (SA-I) : (2 marks each)

(i) How is ethyl amine obtained from phthalimide? [2]
(ii) How will you convert the following?
(a) Phenyl acetonitrile to  -phenylethyl amine.

(b) Acetamide to ethylamine. [2]

SECTION – C

Q. 4. Short Answer Questions (SA-II) : (3 marks each)

(i) Explain Hofmann’s exhaustive alkylation. [3]



(ii) What is the action of acetyl chloride (ethanoyl chloride) on :

(1) ethylamine (ethanamine)

(2) diethylamine (N-Ethylethanamine)

(3) triethylamine? [3]

SECTION – D

Q. 5. Long Answer Question (LA) : (4 marks)

How will you prepare propan-1-amine from (1) butane nitrile (2) 1-nitropropane

(3) propanamide (4) butanamide? [4]

__________

For Model Answers – Click here - https://bit.ly/3x7sZZs

2 SELF ASSESSMENT TEST : LEARN SERIES CHEMISTRY XII (PART – 2) (CHAPTER 13)