Total No. of Questions — 21 Regd. ‘Total No, of Printed Pages ~2 No. Part - 11 CHEMISTRY, Paper-II (English Version) ‘Time : 3 Hours} « [Max. Marks : 60 Note: Read the following instructions carefully = (1) Answer all questions of Section — *A*. Answer any six questions in Section — *B? and any two questions in Section —*C”. (2) In Section ~ +A", questions from Sr. Nos, 1 to 10 are of “Very short answer type”, Each question carries two marks. Every answer may be limited to two or three sentences. Answer all these questions at one place in the same offer. 8) _ In Section ~ *B*, questions rom Sr. Nos. 11 to 18 are of “Short answer type”. Each question carries four marks. Every answer may be limited to 75 words. (4) In Section - *C?, questions from Sr. Nos. 19 to 21 are of “Long answer type”. Each question catries eight marks. Every answer may be limited to 300 words. (5), Draw labelled diagramis, wherever necessary for questions in Section — *B? and *C’. i SECTION-A 10x2=20 Note : Answer alll the questions : Define Osmotic Pressure. What are antibiotics ? Give example. Write the difterence between a soap and a synthetic detergent. State Faraday’ first law of electrolysis. Give the composition of the following alloys : (@)_ Brass (6) German Silver List out any two uses of Neon, Write the structure of XeF,, “weeps Why Zn** is diamagnetic whereas Cr" is paramagnetic ? ‘What is biodegradable polymer ? Give one example. ‘Write the names of the monomers of the following polymers : (a) Bakelite (b) Nylon-6,6 223 (Day-12) 1 P10. ewe ne 5am p a 12. 13. 14, 15. 16. 17. 19. 21. 223 (Day-12) SECTION -B 6x4=24 Note : Answer any six questions : ‘What is doping ? Explain n-type and p-type semi-conductors. Explain the purification of Sulphide ore by froth floatation method. State Raoult’s law. The vapour pressure of pure Benzene at a certain temperature is 0.850 bar. A non-volatile, non-cleetrolyte solid weighing 0.5 g when added to 39.0 g ‘of benzene (molar mass 78 g mol"), Vapour pressure of the solution, then is 0.845 bar. What is the molar mass of the solid substance ? Describe the purification of colloidal solutions by Dialysis method with a neat diagram. ‘Write the equations for reactions of chlorine with the following : (a) Cold and dilute NaOH (b) - Excess NH, (©) Ca(OH), (8) Na,S,0, Explain Werner's theory of Co-ordination compounds. ‘What are Hormones ? Give one example for each of the following : (a) Steroid hormones. = (b) Polypeptide hormones (©) Amino acid derivatives Explain the mechanism of S.2 reaction with one example. SECTION-C 2x8=16 Note : Answer any two of the following questions : (@ What are Galvanic cells ? Explain the working of Galvanic cells with one example. “ (b) Write the differences between order and molecularity of a reaction. (@ How is ammonia manufactured by Haber’s process ? Explain. (b) How does ozone react with the following : (i) Pbs (i) KI Gil) CH, (iv) NO Explain the following reactions with suitable example (@)_ Reimer-Tiemann reaction (b) Cannizaro reaction (©) Aldol condensation (@)_ Sandmeyer reaction223 GiD Total No. of Questions—21 eee OE ee Part IL CHEMISTRY Paper II (English Version) Time : 3 Hours Max. Marks : 60 Note :—Read the following instructions carefully : () Answer ALL the questions of Section A. Answer ANY SIX questions from Section B and ANY TWO questions from Section C. i) In Section A, questions from Sr. Nos. 1 to 10 are very short answer type. Each question carries TWO marks. Every answer may be limited to 2 or 8 sentences. Answer ALL these questions at one place in same order. (iii) Tn Section B, questions from Sr. Nos. 11 to 18 are of short answer type. Bach question carries FOUR marks. Every answer may be limited to 75 words. (iv) In Section C, question from Sr. Nos. 19 to 21 are-of long answer type. Each question carries EIGHT marks. Every.answer may be limited to 300 words. (©) Draw labelled diagrams wherever necessary for questions in Section B and Section C. SECTION A 10x2=20 Note :—Answer ALL questions. 1. Define osmotic pressure. 2 What are antibiotics ? Give an example. 3% What is PHBV ? How is it useful to man ? 223 (1) P.T.O.10. Note a. 12, 13. 14, 15. 16. li. 18. 223 A solution of CuSO, is electrolysed for 10 minutes with a current of 1.5 amperes. What is the mass of copper deposited at the cathode. What are food preservatives ? Give an example. What is Ziegler-Natta catalyst ? Why does NH, act as a Lewis base ? What is flux ? Give an example. Which chemical compound is formed in the brown ring test for nitrate ion ? Write the formula. What is an alloy ? Give an example. SECTION B 6x4=24 :—Answer any SIX questions. : Derive Bragg’s equation. What is catalysis ? How is catalysis classified ? Explain each type of catalysis with an example. 4 Explain the following with examples = @ — Galcination (i) Roasting. (a) Define mole fraction. (&) Calculate the molarity of a solution containing 10 g of NaOH in 500 mil of solution. How are XeF, and XeF, prepared ? Write their structures. Explain Werner's theory with example. “4 What are hormones ? Give one example for each of the following = (@® Steroid hormones (ii) Polypeptide hormones (ii) Amino acid derivatives. Explain the following reactions : (a) Wurtz-Fittig reaction (0) Friedel-Crafts reaction.SECTION C 2x8=16 Note :—Answer any TWO questions. 19. Give a detailed account of the collision theory of reaction rates of Bimolecular gaseous reaction, 20. (a) How does ozone react with the following : @ ~~ Pbs @) CH, (i) Ag i (ey) Hg. (6) How is chlorine prepared in the laboratory ? Explain the reactions of chlorine with the following : @ Cold dil. NaOH (i) Hot con. NaOH. 21. Explain the following reactions with suitable examples : (@) Williamson's synthesis } (6) Reimer-Tiemann reaction © — Carbyl amine reaction 5 (d) _ Diazotization.Total No. of Questions ~ 21 Regd. [ Total No. of Printed Pages —2 No. Part-I a7 CHEMISTRY, Paper-II i (English Version) Note: Anker al th questions 1 What is relative lowering of vapour pressure ? a ne as jon of the following alloys ; Oe @ )) Bro (e) ‘German silver Br i we 4, What happens when white phosphorus is heated with cone. NaOH coon nan ne atmosphere of CO, ? 5. How is chlorine manufactured by Deacon’s Method ? 6, Whats Misch metal? Give is composition and , ; |. b PTO. aes “a > 4 a 298. What is PDI (Poly Dispersity Index) ? 9. What are analgesics? How are they classified ? 10, What are antiseptics ? Give examples. SECTION-B 6x4=24 Note: Answer any six questions : F 1. Describe the two main types of semi-conductors and contrast ‘their conduction 2 of water at 293 K is 17.535 mmblg. Calculate the the solution a Dod Kwon 25 got Use ovens go 13. ‘Name any four enzyme catalysed reactions. 14. Explain the purification of sulphide ore by Froth Floatation Method: 15. How are XeF, and XeF, prepared ?.Give their structures, 16. ne ors. wcities bie Slow = @ TCO GICh Gi) [FCO T° Gi) (FCN) Gy) (Nic? 17. What are Hormones ? Give one example for each @ Steroid Hormones ). Polypeptide Hormones Amino Agid derivatives 18. Which compound in each of the following pairs will react faster in Sy2 reaction with OE @ — CH,Br (or) CHL Gi) (CH3),CCI (or) CHC SECTION~C (2x 8=16 Note ; “Answer any two questions 19. Give the different types of Batteries and explain the construction and working of ‘each type of battery. 20. How is ozone prepared from oxygen ? Explain its reaction with ; @ Ay @ KI Gi) He Gy) Pos” 21. Describe the following : oat = : @ Acetylation (i) Cannizato reaction - ii) Cross aldol condensation (iv) Decarboxylation 223 (Day-12) 2223 Nay ‘Total No. of Questions — 21 Regd. | | ‘Total No. of Printed Pages —2 No. | Part— It CHEMISTRY, Paper-Il (English Version) Time : 3 Hours J [ Max. Marks : 60 Note: Read the following instructions carefully : (1) Answer all questions of Section - ‘A’, Answer any six questions from Section ~ {BY and any two questions from Seetion— °C” (2) In Section ~ *A°, questions from Sr. Nos. 1 to 10 are of “Very short answer type”. Each question carries two marks. Every answer may be limited to two or three sentences, Answer all these questions at one place in the same order. (3) In Section ~ “B', questions from Sr, Nos. 11 to 18 are‘of “Short answer type" Each question carries four marks. Every answer may be limited to 75 words. (4) In Section — *C°, questions from Sr. Nos. 19 to 21 are of “Long answer type Each question carries eight marks, Every answer may be limited to 300 words, (5) Draw labelled diagrams, wherever necessary for questions in Section — *B” ‘and Section —*C”, SECTION—A 10 x2=20 Note: Answer all questions ‘What is an Ideal Solution ? Wiite the Arthenitis equation for the rate constant (K) of @ reaction, Give the composition of the following alloys : (a) Brass (b) Bronze How is XeOF, prepared ? Give its structure. Write the reactions of F, and Cl, with water. ‘Scandium is a transition element. But Zinc is not. Why ? What is PDI (Poly Dispersity Index) ? What is allosteric site ? eae 223 (Day-12) [of2} PLO.nl. 12. 13. 14. 15, 16, 17. 18. 19. 20. 21. ‘What are antacids ? Give example. ‘Write the names and structures of the monomers used for getting the following : (@) Poly Vinyl Chioride (>) Teflon SECTION -B 6x4=24 Note: Answer any six questions : Derive Bragg’s equation. Define Mole fraction. Calculate the Mole fraction of ethylene glycol (CgH,O,) in a solution containing 20% of C,H,O, by mass, ‘What is an Emulsion ? How emulsions ate classified. Give one example for each type ‘of emulsion. Explain the following : (@) Zone refining (b) Poling How is ammonia manufactured by Haber’s process ? Explain geometrical isomerism in co-ordination compounds giving suitable examples. Give the sources of the following vitamins and name the disease caused by their deficiency, @ A ) D © & @ kK Explain the Grignard reagents preparation and application with suitable example SECTION-C 2x8=16 Note: Answet any two questio1 (a) State and explain Kohlrausch’s law of independent mizration of ions. (b) What is *molecularity” of a reaction ? How is it different from the “order” ofa reaction ? Name one bimolecular and one trimolecular gaseous reactions, How is ozone prepared from oxygen ? Explain its reaction with @ CH, ) KI (@) He @) Pes (a) Describe the following : (i) Cannizaro reaction Gi) Decarboxylation (b) How do you prepare Ethyl cyanide and Ethyl isocyanide from a common alkyl halide ? 223 (Day-12) [20f2}@ 223 (ar | Total No. of Questions - 21 Regd. | Total No. of Printed Pages ~ 3 No. Part - II CHEMISTRY, Paper-II (English Version) Time : 3 Hours | (2) Answer all questions of Section ~ ‘A’. Answer any six questions from Section ~‘B’ and any two questions from Section - ‘C’. (2) In Section ~ ‘A’, questions from Sr. Nos. 1 to 10 are of “Very short answer type”. Each question carries two marks. Every answer may be limited to two or three sentences. Answer all these questions at, one place in the same order. (8) In Section ~ ‘B’, questions from Sr. Nos. 11 to 18 are of “Short answer type”. Each question carries four marks, Every answer may be limited to 75 words. (In Section + ‘C’, questions from Sr. Nos. 19 to 21 are of “Long _ answer type”. Each question carries eight marks. Every answer may be limited to 300 words. (5) Draw labelled diagrams, wherever necessary for questions in Section — ‘B' and Section ~ ‘©’. SECTION -A 10 x 2= 20 Note: Answer all questions : What are artificial sweetening agents ? Give example. What is Zeigler-Natta Catalyst ? ‘Name two most familiar antioxidants used as food additives. ae Pe Write names of the monomers used for getting the polymers (@) Bakelite (b) Glyptal 5. What are colligative properties ? Give any one, [of 4] 22310. ll. 12. 13. 15. 16. ‘Adentify the reaction order from each of the following rate constants : @) K=23x 10% mol et ) K=3x104¢s! What is the role of eryolite in the metallurgy of aluminium ? Why Zn?* is diamagnetic whereas Mn®* is paramagnetic ? Complete the following : (@) XeF,+0,F, > (b) XeF, +H,0 > Give the hybridization of sulphur in the following : @) so, ®) so, © sr, @ SF, SECTION-B 6x4=24 Note : Answer any six questions : (a) What are amino acids ? Give two examples. (>) Write any two differences between Globular and fibrous proteins. Explain the following with one &xample for each : (a) Wurtz reaction 10: () Fittig reaction Explain Werner's theory of co-ordination compounds with suitable examples. |. How does PCI; react with the following : (a) Water (>) C,H,OH (© CH,CooH @ Ag Define the following with suitable examples : (@) Anti-ferromagnetism (b) Frenkel defect State Henry's law. Calculate the mass of a non-volatile solute (molar mass 40 g mol“) which should be dissolved in 114 g of octane to reduce its vapour pressure to 80%, Rota | 223What is catalysis ? How is catalysis classified ? Give one example for each of catalysis. . Write any two ores of the following metals : (@) Aluminium () Zine (©) Tron @) Copper SECTION -C 2x8=16 Note : Answer any two questions : . Explain the following with suitable examples : (a) Conversion of alkylhalide to ether. (6) Conversion of phenol to salicylic acid. (i) (@) How do you prepare carboxylic acid and alcohols from Grignard’s reagent ? Give example. (b) What is carbylamine reaction ? Give example. . @ State Faraday's first and second laws of electrolysis. A solution of CuSO, is electrolysed for 10 minutes witha current of 1.5 amperes, What is the mass of copper deposited at the éathdde ? (i) What is molecularity of a reaction ? How is it different from the order of a reaction ? Nate one bimolecular and one trimolecular gaseous reactions. - (i) How does chlorine react with (a) acidified FeSO, ? (b) dry slaked lime ? (i) Describe the manufacture of H,S0, by contact process, [8 of 4] 223[4 of 4] 2238 223 Total No. of Questions ~ 21 Regd. Tom Nn of Printed ager. Xe sof Section — ‘A’. Answer any six questions from two questions from Section — Cr. Nos. 1 to 10 are of “Very short wo marks. Every answer may tellmiel to two or three sentences. Answer all these questions at one place in the from Sr. Nos. 11 to 18 are of “Short or type”. ruihn carte tuctligegoce opens Every answer may be limited to 75 words. (4) In Seetfon ~ ‘C’, questions from Sr. Nos. 19 to 21 are of “Long answer type”. ene ee ae Every answer may be limited to 300 (6) Draw labelled diagrams, wherever necessary for questions in Section - ‘B’ and Section —‘C’, SECTION-A Note: Answer all questions : 10x 2=20 a. ‘Wiehe Gat deta6. 8. il. i, 13. 14. 15. 16. 18. Nitrogen molecule is highly stable - Why ? Write any two uses of argon. What is Ligand ? Give an example. What are reducing sugars? Explain Fittig reaction with an example. ). What is carbylamine reaction ? SECTION -B Note : Answer any six questions : 6x4=24 Derive Brage’s equation. Vapour pressure of water at 293 K is 17.635 mm He. Calculate the vapour pressure of the solution at 293 K when 25 g of glucose is dissolved in 450 g of water. Define order of reaction and molecularity of reaction. Write the differences between them. What is adsorption ? Give any three differences between physical adsorption and chemical adsorption. How does ozone react with the following : (a) PbS 7 ) KT © CH, @ He Explain Werner's theory of coordination compounds with suitable examples. '. Write a brief note on the structure of glucose. Explain the mechanism of Nucleophilic bimolecular substitution (Sy2) reaction with one example. [2 of 4] 223SECTION - C Note : Answer any two questions : 2x8=16 19. (a) Explain the working of a galvanic cell with a neat sketch taking Daniel cell as example. (b) State and explain Kohlrausch's Law of independent migration of ions. 20. How is chlorine prepared in laboratory ? How does it react with the following os (a) Cold, Dil, NaOH (b) Hot, Cone. NaOH (©) NH,(excess) (a) NH, with excess Cl, 21. Describe the following : (a) Reimer - Tiemann reaction (b) Williamson’s Ether synthesis (©) Cross aldol condensation reaction (@ _Decarboxylation reaction [3 of 4) 223[4 of 4] 223