Total No. of Questions : 4] SEAT No.

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PA-1680 [Total No. of Pages : 2

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ENGINEERING CHEMISTRY

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(2019 Pattern) (107009)

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Time : 1 Hour] [Max. Marks : 30
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Instructions to the candidates:
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1) Neat diagrams must be drawn wherever necessary.

2) Figures to the right indicate full marks.
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3) Use of logarithmic tables slide rule, Mollier charts, electronic pocket
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calculator and steam tables is allowed.

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4) Assume Suitable data if necessary.
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5) Answer Question No. Q1 or Q2, Q3 or Q4.
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Q1) a) What is EDTA? Give its structure. Explain the process for water hardness
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determination using EDTA with reactions. [5]
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b) Explain boiler corrosion due to dissolved gases oxygen and carbon

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dioxide with reactions. [4]

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c) 100mL water consumed 5.2mL, 0.02M HCl up to phenol phthalein in

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and point and 15.8mL at methyl orange and point in titration. Find amount
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and types of alkalinity in water. [3]

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d) What are zeolites? Give reactions for : [3]

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i) Removal of Ca and Mg
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ii) Regeneration of exhausted zeolite.
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Q2) a) Define scales. Give any four causes of scale formation in boiler. [5]
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b) Explain process of reverse osmosis for separation of salts from water

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with neat labeled diagram. [4]

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c) 50mL water sample required 18mL 0.05M EDTA in a hardness

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determination experiment. Whereas 50mL of the same water after boilling

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consumed 9mL 0.05M EDTA. Calculate Total, Permanent and temporary

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Hardness of water sample. [3]

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d) A zeolite bed exhausted by softening 4000 liter of water requires 10 liters

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of 15% NaCl solution for regeneration. Calculate hardness of water. [3]

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Q3) a) Explain three stages of pH metry titration between HCl & NaOH with

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titration curve and reactions. [5]

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b) Give construction working with diagram of glass electrode. [4]

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c) Give composition of membrane of ion selective Electrode used to detect

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i) H+

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ii) F–
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iii) C1–
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d) Define : i) Equivalent conductance

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ii) Molar conductance

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iii) Cell constant
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[3]
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OR
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Q4) a) Explain conductometry Titration curve for neutralization of strong acid

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using strong base with reactions. [5]

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b) Give construction, working with neat labled diagram of calomel Electrode.

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[4]
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c) Write any two advantages of instrumental methods of analysis. Give
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stepwise process for calibration of a pH-meter. [3]

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d) What is a buffer solution? Give its types with example each. [3]
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