SOP,Organic K+®Standard SOP, Organic K+®Mid Granular SOP, Organic K+®Mini Granular SOP

SAFETY DATA SHEET

, Organic K+®Choice Granular SOP, Protassium+™ Organic Standard, Protassium+™ Organic
Mid Granular, Protassium+™ Organic Soluble Fines, Protassium+™ Organic Ag Granular,
SAFETY DATA SHEET
Protassium+™ Organic Standard Fines, Protassium+™ Organic Mini Granular, Protassium+™
Turf Granular, Protassium+™ Choice Granular, Protassium+™ Standard Fines, Protassium+™
Soluble Fines,Protassium+™ Mini Granular, Protassium+™ Greens Grade, Protassium+™ Ag
1. Product and Company Identification
Granular, Protassium+™ Mid Granular, Protassium+™ 220 GL, Protassium+™ 145 GL,
Product identifier Protassium+™
Sulfate 17 IX,
of Potash
Turf Granular SOP,
Diamond K Gypsum, Inc.
Protassium+™ 3 IX, Protassium+™ 90 IX, Protassium+™ 40 IX, Protassium+™ 17 GL,
Ag Protassium+™
Granular SOP, 40 Soluble Fines SOP, Standard
Other means of identification Protassium+™ 145 IX, GL, Protassium+™ 30 GL, SOP, Mid Granular
SOP-220, SOP-145,SOP, Mini
Granular
SOP-17IX, SOP, Choice SOP-40IX,
SOP-25IX, Granular 1720 South Redhills
SOP,Organic
SOP-90IX, SOP-145IX, Drive
K+®Ag Granular SOP, Organic
SOP-235IX, SOP-17, K+®Soluble
SOP-30, Fines
SOP,Organic K+®Standard
SOP-30P, Protassium+™ 25SOP, Organic K+®Mid
IX, Richfield,
Protassium+™ Utah Granular
3084701
IX, SOP, Organic
Protassium+™ K+®Mini
235 IX, SOP-3, Granular SOP
SOP-30IX,
,SOP-40.
Organic K+®Choice Granular SOP, Protassium+™ Organic Standard, Protassium+™ Organic
(435) 896-8870
Mid Granular, Protassium+™ Organic Soluble Fines, Protassium+™ Organic Ag Granular,
Recommended use Specialty crop nutrient, turf grass fertilizer,
Protassium+™ Organic Standard Fines,(435)
Fax: general fertilizer
896-8893
Protassium+™ uses,Mini
Organic and Granular,
specialty industrial uses.
Protassium+™
Recommended restrictions NoneGranular,
Turf known. Protassium+™ www.diamondkgypsum.com
Choice Granular, Protassium+™ Standard Fines, Protassium+™
Manufacturer Soluble Fines,Protassium+™
Great Salt Mini Granular, Protassium+™ Greens Grade, Protassium+™ Ag
Lake Minerals Corporation
Granular, Protassium+™
Product Safety: 1-800-497-7861
Mid Granular, Protassium+™ 220 GL, Protassium+™ 145 GL,
A Compass Minerals Company
Protassium+™
9900Sulfate
West 109th 17Street,
IX, Suite 100
Product Identifier: Protassium+™ of Potash
Overland Park, 3KSIX,66210
Protassium+™
US 90 IX, Protassium+™ 40 IX, Protassium+™ 17 GL,
Recommended Use: Specialty
Protassium+™ crop
145
Phone: 913-344-9200 IX,nutrient,
Protassium+™turf grass
40 GL,fertilizer,
Protassium+™ general fertilizer
30 GL, uses,
SOP-220, and
SOP-145,
SOP-17IX, SOP-25IX,
speciality SOP-40IX,
industrial uses. SOP-90IX, SOP-145IX, SOP-235IX, SOP-17, SOP-30,
CHEMTREC 1-800-424-9300
SOP-30P, Protassium+™ 25 IX, Protassium+™ 30 IX, Protassium+™ 235 IX, SOP-3, SOP-30IX,
Recommended
CANUTEC Restrictions: None Known.
1-613-996-6666
SOP-40.
Recommended use Specialty crop nutrient, turf grass fertilizer, general fertilizer uses, and specialty industrial uses.
2. Hazards Identification
Recommended restrictions None known.
Physical hazards
Manufacturer Not classified.
Great Salt Lake Minerals Corporation
Health hazards A Compass
Not Minerals Company
classified.
9900 West 109th Street, Suite 100
Environmental hazards Not classified.
Overland Park, KS 66210 US
OSHA defined hazards Phone:
Not 913-344-9200
classified.
CHEMTREC 1-800-424-9300
Label elements
CANUTEC 1-613-996-6666
Hazard symbol None.
Signal word Not available. 2. Hazards Identification
Hazard
Physical statement
hazards Not classified.
Not available.
Precautionary
Health hazards statement Not classified.
Prevention
Environmental hazards Not
Not available.
classified.
Response
OSHA defined hazards Not
Not available.
classified.
Storage Not available.
Label elements
Disposal Not available.
Hazard symbol None.
Hazard(s) not otherwise None known.
classified
Signal(HNOC)
word Not available.
Supplemental information
Hazard statement Not available.
None.
Precautionary statement 3. Composition/Information on Ingredients
Prevention Not available.
Substance
Response Not available.
ChemicalStorage
name Common name and synonyms
Not available. CAS number %
Potassium sulfate
Disposal Not available. 7778-80-5 96 - 100
Hazard(s) not otherwise None known.
classified (HNOC) 4. First Aid Measures
Supplemental
Inhalation information None.
If symptoms develop move victim to fresh air. If symptoms persist, obtain medical attention. Call a
physician if symptoms develop or persist.
3. Composition/Information on Ingredients
Skin contact Brush away excess of dry material. Flush with cool water. Wash with soap and water. Obtain
Substance medical attention if irritation persists.
Eye contact Flush with cool water. Remove contact lenses, if applicable, and continue flushing. Obtain
Chemical name Common
medical attention name and
if irritation synonyms
persists. CAS number %
Potassium sulfate
Ingestion 7778-80-5
Do not induce vomiting. Never give anything by mouth if victim is unconscious, or96is- 100
convulsing.
#-15620 Page: 1 of 7 Issue date Draft version.
Obtain medical attention.
Most important Direct contact with eyes may cause temporary 4.irritation.
First Aid Measures
symptoms/effects, acute and Exposed individuals may experience eye tearing, redness, and discomfort.
Inhalation
delayed If symptoms develop move victim to fresh air. If symptoms persist, obtain medical attention. Call a
physician if symptoms develop or persist.
Indication of immediate Symptoms may be delayed.
Skin contact Brush away excess of dry material. Flush with cool water. Wash with soap and water. Obtain
medical attention and special
medical attention if irritation persists.
treatment needed
General information If you feel unwell, seek medical advice (show the label where possible). Ensure that medical
personnel are aware of the material(s) involved, and take precautions to protect themselves. Show
#-15620 this safety data sheet to the doctor
Page: 1 of 7in attendance. Avoid contact with eyes and
Issueskin. Keep
date Draft out of
version.
Indication of immediate
medical attention and special
treatment needed
General information
Suitable extinguishing media
Unsuitable extinguishing
media
Specific hazards arising from
the chemical
Special protective equipment
and precautions for firefighters
Fire-fighting
equipment/instructions
Specific methods
Hazardous combustion
products
Explosion data
Sensitivity to mechanical
impact
Sensitivity to static
discharge
Personal precautions,
protective equipment and
emergency procedures
Methods and materials for
containment and cleaning up
Environmental precautions
Precautions for safe handling
Conditions for safe storage,
including any incompatibilities
Occupational exposure limits
Biological limit values
Exposure guidelines
Appropriate engineering
controls
#-15620
Individual protection measures, such as personal protective equipment
Eye/face protection
Symptoms may be delayed.
If you feel unwell, seek medical advice (show the label where possible). Ensure that medical
personnel are aware of the material(s) involved, and take precautions to protect themselves. Show
this safety data sheet to the doctor in attendance. Avoid contact with eyes and skin. Keep out of
reach of children.
5. Fire Fighting Measures
Treat for surrounding material.
None known.
Firefighters should wear a self-contained breathing apparatus.
Firefighters should wear full protective clothing including self contained breathing apparatus.
In the event of fire, cool tanks with water spray.
Cool containers exposed to flames with water until well after the fire is out.
May include and are not limited to: Oxides of sulfur.
Not available.
Not available.
6. Accidental Release Measures
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear a dust
mask if dust is generated above exposure limits. Do not touch damaged containers or spilled
material unless wearing appropriate protective clothing. Avoid inhalation of dust from the spilled
material. For personal protection, see section 8 of the SDS.
Before attempting clean up, refer to hazard data given above. Use broom or dry vacuum to collect
material for proper disposal without raising dust. Rinse area with water. Prevent large spills from
entering sewers or waterways. Contact emergency services and supplier for advice. For waste
disposal, see section 13 of the SDS.
Do not discharge into lakes, streams, ponds or public waters.
7. Handling and Storage
Avoid breathing dust.
Minimize dust generation and accumulation.
Provide appropriate exhaust ventilation at places where dust is formed.
In case of insufficient ventilation, wear suitable respiratory equipment.
Use good industrial hygiene practices in handling this material.
Wash thoroughly after handling.
Guard against dust accumulation of this material.
Store in a well-ventilated place.
Store in a closed container.
Store away from incompatible materials (see Section 10 of the SDS).
Keep out of reach of children.
8. Exposure Controls/Personal Protection
No exposure limits noted for ingredient(s).
No biological exposure limits noted for the ingredient(s).
This material does not have established exposure limits.
TWA PEL: No specific limits have been established for potassium sulfate (a soluble substance).
As a guideline, OSHA (United States) has established the following limits which are generally
recognized for inert or nuisance
Page: 2dust.
of 7 Particulates Not Otherwise Regulated (PNOR):
Issue 5mg/cu.m.
date Draft version.
Respirable Dust 8-Hour TWA PEL, 15mg/cu.m. Total Dust 8-Hour TWA PEL.
TWA TLV: No specific limits have been established for potassium sulfate (a soluble substance).
As a guideline, ACGIH (United States) has established the following limits which are generally
recognized for inert or nuisance dust. Particulates (insolubles) Not Otherwise Classified (PNOC):
10mg/cu.m. Inhalable Particulate 8-Hours TWA TLV, 3mg/cu.m. Respirable Particulate TWA TLV.
Wear safety glasses with side shields.
 recognized for inert or nuisance dust. Particulates (insolubles) Not Otherwise Classified (PNOC):
10mg/cu.m. Inhalable Particulate 8-Hours TWA TLV, 3mg/cu.m. Respirable Particulate TWA TLV.

Individual protection measures, such as personal protective equipment

Eye/face protection Wear safety glasses with side shields.
Skin protection
Hand protection Rubber gloves. Confirm with a reputable supplier first.
Other As required by employer code.
Respiratory protection Where exposure guideline levels may be exceeded, use an approved NIOSH respirator or
NIOSH-approved filtering facepiece.
Thermal hazards Not available.
General hygiene Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks
considerations and immediately after handling the product. When using do not eat or drink.

9. Physical and Chemical Properties

Appearance Solid.
Physical state Solid.
Form Crystals, Granular
Crystals or or Powder
Granular.
Color white to brown
Odor Odorless
Odor threshold Not available.
pH 7 (10% solution)
7 Aqueous solution is neutral
Melting point/freezing point 1952.6 °F (1067 °C)
Initial boiling point and boiling 3072.2 °F (1689 °C)
range
3072.2 °F (1689 °C)
Pour point Not available.
Specific gravity 2.66 @21°C (H2O = 1)
2.66
Partition coefficient Not available.
(n-octanol/water)
Flash point None
Evaporation rate Not available.
Flammability (solid, gas) Not applicable.
Upper/lower flammability or explosive limits
Flammability limit - lower Not applicable
(%)
Flammability limit - upper Not applicable
(%)
Explosive limit - lower (%) Not available.
Explosive limit - upper (%) Not available.
Vapor pressure < 0 kPa at 25 °C
Vapor density Not available.
Relative density Not available.
Solubility(ies) Appreciable
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Not available.
Other information
Density 2.66 g/cm3 estimated
Flash point class Flammable IB
Molecular formula
#-15620
H2-O4-S.2K Page: 3 of 7 Issue date Draft version.
K2SO4
Molecular weight 174.27
176.26 g/mol

10. Stability and Reactivity

Reactivity May react with incompatible materials.
Possibility of hazardous Hazardous polymerization does not occur.
 Molecular weight 174.27
176.26 g/mol

10. Stability and Reactivity

Reactivity
Possibility of hazardous
reactions
Chemical stability
Conditions to avoid
Incompatible materials
Hazardous decomposition
products
May react with incompatible materials.
Hazardous polymerization does not occur.
Stable under recommended storage conditions.
Avoid dispersal of dust in the air (i.e., clearing dust surfaces with compressed air).
Contact with incompatible materials.
Do not mix with other chemicals.
Magnesium. Aluminum.
May include and are not limited to: Oxides of sulfur.

11. Toxicological Information

Routes of exposure Eye, Skin contact, Inhalation, Ingestion.
Information on likely routes of exposure
Ingestion May cause stomach distress, nausea or vomiting.
Inhalation Inhalation of dusts may cause respiratory irritation.
Skin contact May be irritating to the skin.
Eye contact May be irritating to eyes. Dust in the eyes will cause irritation.
Symptoms related to the Direct contact with eyes may cause temporary irritation.
physical, chemical and Exposed individuals may experience eye tearing, redness, and discomfort.
toxicological characteristics
Information on toxicological effects
Acute toxicity
Components Species Test Results
Potassium sulfate (CAS 7778-80-5)
Acute
Dermal
LD50 Not available
Inhalation
LC50 Not available
Oral
LD50 Rat 6600 mg/kg
Skin corrosion/irritation May cause irritation.
Exposure minutes Not available.
Erythema value Not available.
Oedema value Not available.
Serious eye damage/eye Dust in the eyes will cause irritation.
irritation
Corneal opacity value Not available.
Iris lesion value Not available.
Conjunctival reddening Not available.
value
Conjunctival oedema value Not available.
Recover days Not available.
Respiratory or skin sensitization
Respiratory sensitization Not available.
Skin sensitization Not available.
Germ cell mutagenicity Non-hazardous by WHMIS/OSHA criteria.
Mutagenicity Non-hazardous by WHMIS/OSHA criteria.
Carcinogenicity Not classified or listed by IARC, NTP, OSHA and ACGIH.
Reproductive toxicity Non-hazardous by WHMIS/OSHA criteria.
Teratogenicity
#-15620 Non-hazardous by WHMIS/OSHA
Page: 4 ofcriteria.
7 Issue date Draft version.

Specific target organ toxicity - Not available.

single exposure
Reproductive toxicity Non-hazardous by WHMIS/OSHA criteria.
Teratogenicity Non-hazardous by WHMIS/OSHA criteria.
Specific target organ toxicity - Not available.
single exposure
Specific target organ toxicity - Not available.
repeated exposure
Aspiration hazard Not available.
Chronic effects Non-hazardous by WHMIS/OSHA criteria.
Further information Not available.
Name of Toxicologically Not available.
Synergistic Products

12. Ecological Information

Ecotoxicity See below
Product Species Test Results
Sulfate of Potash
Aquatic
Fish LC50 Fathead minnow (Pimephales promelas) 510 - 880 mg/l, 96 hours
Components Species Test Results
Potassium sulfate (CAS 7778-80-5)
Algae IC50 Algae 2900 mg/L, 72 Hours
Crustacea EC50 Daphnia 890 mg/L, 48 Hours
Aquatic
Fish LC50 Fathead minnow (Pimephales promelas) 510 - 880 mg/l, 96 hours
Persistence and degradability Not available.
Bioaccumulative potential Not available.
Mobility in soil Not available.
Mobility in general Not available.
Other adverse effects Not available.

13. Disposal Considerations

Disposal instructions
Local disposal regulations
Hazardous waste code
Waste from residues / unused
products
Contaminated packaging
Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Waste must be
disposed of in accordance with federal, state/provincial and local environmental control
regulations.
Dispose in accordance with all applicable regulations.
The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Dispose of in accordance with local regulations. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Empty containers should be taken to an approved waste handling site for recycling or disposal.
Since emptied containers may retain product residue, follow label warnings even after container is
emptied.

14. Transport Information

U.S. Department of Transportation (DOT)
Not regulated as dangerous goods.
Transportation of Dangerous Goods (TDG - Canada)
Not regulated as dangerous goods.

15. Regulatory Information

Canadian federal regulations
WHMIS status
US federal regulations
This product has been classified in accordance with the hazard criteria of the Controlled Products
Regulations and the SDS contains all the information required by the Controlled Products
Regulations.
Not Controlled
This product is NOT known to be a "Hazardous Chemical" as defined by the OSHA Hazard
Communication Standard, 29 CFR 1910.1200.

#-15620 Page: 5 of 7 Issue date Draft version.

 TSCA
TSCA Section
Section 12(b)
12(b) Export
Export Notification
Notification (40
(40 CFR
CFR 707,
707, Subpt.
Subpt. D)
D)
Not regulated.
Not regulated.
CERCLA
CERCLA Hazardous
Hazardous Substance
Substance List
List (40
(40 CFR
CFR 302.4)
302.4)
Not listed.
Not listed.
Clean Air
Clean Air Act
Act (CAA)
(CAA) Section
Section 112(r)
112(r) Accidental
Accidental Release
Release Prevention
Prevention (40
(40 CFR
CFR 68.130)
68.130)
Not regulated.
Not regulated.
Clean Air
Clean Air Act
Act (CAA)
(CAA) Section
Section 112
112 Hazardous
Hazardous Air
Air Pollutants
Pollutants (HAPs)
(HAPs) List
List
Not regulated.
Not regulated.
Superfund Amendments
Superfund Amendments andand Reauthorization
Reauthorization Act
Act of
of 1986
1986 (SARA)
(SARA)
Hazard categories
Hazard categories Immediate
Immediate Hazard
Hazard -
- No
No
Delayed Hazard
Delayed Hazard -- No
No
Fire
Fire Hazard
Hazard -- No
No
Pressure Hazard
Pressure Hazard -- No
No
Reactivity
Reactivity Hazard
Hazard -- No
No
SARA 302
SARA 302 Extremely
Extremely No
No
hazardous
hazardous substance
substance
SARA 311/312
SARA 311/312 Hazardous
Hazardous No
No
chemical
chemical
SARA
SARA 313
313 (TRI
(TRI reporting)
reporting)
Not regulated.
Not regulated.

Other federal
Other federal regulations
regulations
Safe
Safe Drinking Water
Drinking Water Act
Act Not
Not regulated.
regulated.
(SDWA)
(SDWA)
Food
Food and
and Drug
Drug Direct
Direct food
food additive
additive
Administration
Administration (FDA)(FDA)
US
US state
US state regulations
state regulations
regulations This product
This product
Warning: does
Thisdoes not contain
product
not contain
containsaasubstances
chemical known
chemical known
knowntoto
to the State
the
the ofof
State
State of California toto
California
California to cause cancer, birth
cause
cause cancer, birth
CA Proposition 65: defects
cancer or
or other
defectsand/or reproductive
birth
other defects or harm.
reproductive other reporductive harm.
harm.
(Health &US
USSafety Code Proposition
-- California
California Proposition 65
65 -- Carcinogens
Carcinogens & & Reproductive
Reproductive Toxicity
Toxicity (CRT):
(CRT): Listed
Listed substance
substance
Section 25249.5
Not listed.
Not listed.
US. Massachusetts
US. Massachusetts RTKRTK -- Substance
Substance ListList
Not
Not regulated.
regulated.
US.
US. Pennsylvania RTK
Pennsylvania RTK -- Hazardous
Hazardous Substances
Substances
Not regulated.
Not regulated.
US.
US. Rhode
Rhode Island
Island RTK
RTK
Not regulated.
Not regulated.
Inventory
Inventory status
status
Country(s)
Country(s) or
or region
region Inventory
Inventory name
name On
On inventory
inventory (yes/no)*
(yes/no)*
Canada
Canada Domestic
Domestic Substances
Substances List
List (DSL)
(DSL) Ye
Yes
Ye
Canada
Canada Non-Domestic Substances
Non-Domestic Substances List
List (NDSL)
(NDSL) ss
No
United
United States
States &
& Puerto
Puerto Rico
Rico Toxic
Toxic Substances Control Act (TSCA) Inventory
Substances Control Act (TSCA) Inventory No
Yes
No
*A
*A "Yes"
"Yes" indicates
indicates that
that all
all components
components of
of this
this product
product comply
comply with
with the
the inventory
inventory requirements
requirements administered
administered by
by the
the governing
governing country(s)
country(s) Ye
Ye
16. Other Information ss

LEGEND
LEGEND HEALTH / 1
1
HEALTH /
0
Severe 4 FLAMMABILITY
FLAMMABILITY 0
0
Severe 4
Serious
Serious 3
3 1 0
Moderate 2 PHYSICAL HAZARD
PHYSICAL HAZARD 0
0
Moderate 2
Slight
Slight 1
1 PERSONAL
PERSONAL
Minimal
Minimal 0
0 PROTECTION X
X
PROTECTION
Disclaimer For an updated SDS, please contact the supplier/manufacturer listed on the first page of the
document.
Information contained herein was obtained from sources considered technically accurate and
reliable. While every effort has been made to ensure full disclosure of product hazards, in some
cases data is not available and is so stated. Since conditions of actual product use are beyond
control of the supplier, it is assumed that users of this material have been fully trained according to
the requirements of all applicable legislation and regulatory instruments. No warranty, expressed
or implied, is made and supplier will not be liable for any losses, injuries or consequential damages
which may result from the use of or reliance on any information contained in this document. The
above SDS reflects the latest information on file with respect to hazards, properties and handling
of this product. No warranty however, expressed or implied, is made with regard to the use of this
information. The information in the sheet was written based on the best knowledge and experience
currently available.
Issue date Draft version.
Effective date 01-March-2015
Expiry date 01-March-2018
Further information Not available.
Prepared by Diamond
Dell TechKLaboratories,
Gypsum, Inc.Ltd.Phone: (435)
Phone: 896-8870
(519) 858-5021
Other information This SDS conforms to the ANSI Z400.1/Z129.1-2010 Standard.