CHIC Je :
i ps3 ae. Ch ns !
Axton = Eled 5 inchenistty"
— |__ Lourdematna Coment Marc Hr. See. School,
|
|
|
= 5 (os sae Tw pata
dor the equslibyrum ranclion, for fov ent i
Which) Phe equililerium Censre) i oalk
i given by onpexsion Keo SOU aS Ji eere gion
INGE kpeke (RD Ke ale ke)
ANO+ bho <= 4Nil + 50° = 2N0q)
a] Wath Kp ond Ke fox the following
reaction 2WHyDigyt 2, ae, A HCleayt Orca
Ker EMCO gp = Fc A Pe
Taser Coy Tos Pat
slDorve Ke-Nalue-for dissociaher of |
Pals CPcisJ Cod.
_ Preis Cou
oe eee ee a a
4] Find ect the 2ng valixes cod waite
|the ke and kp Yelation for the
| eqysilibyiann veachions | Kp=k-(an™
| i> Decomposition OF armenia - |
1D Nocayt Once)
KpekecePake 3[KpeKe] |
Wh) Haig OtgyS 212000)
Nt Osesy
v
") aNi5y S Nowy t+ BH20)
i Formatien No - j i |¥) Pels cy) => Pelacayt Clreay
IPNHgcayS Nita + 3ieo) By - Ve.
Ang #47222 3e338 Kpake(@n
wpeke CRD goit ([Ke>ke]
|3 Kp=Ke Cray 3 Kp> Ke « 33); In one role 04 Ply is heabd |
WN, +0. —=2N0- 20 3 in one Litre chord Containes .
| ang =2-220 sg Tf 6.4 mo & cliorine is foun)
kp=ke (RTS + » OA eoyrilibviun , Coleutata the
Kp=ke (RT)? Kp=Ke - Valine Bd Coysilibvius Constant)
= oth est
10] For the readion ExCosgiPSrOast Og) Sven [els dist, sea
|the value. e{ equilibrium constant
kp= PT 1002K « CelsJey = 0-6 mot dwi?
| ke Sor the veootion. Pols = Petz teh -
[Pe lea> 0-6 mole dn3 .
CPcledeay= 0-4 rwote dns
APelA Lets, O-b%xO°4
c aoe oli
ke = 0-9
| GyCoxs) S Sree + 02259
ang =1-0=1
| #:Rp=keter) -
9:0 MIOP= ke Cor!) C1002) - @
\3-The equilibrium Constant for the
Fetlpesing reaction 1 o-lsot 248k
1 coed prennt f
Na On cay 2NO2@)*
| Ane = 51-32% mot":
The veadtion Conditions’ ere atteud
| as detours:
a) The reattion temperabar 1d
te 100% Keoping the proxsuae oct
| odin » Cakeulats the,
| Minlty= No eerwlviotadaty ST |
250g of tap sates contains’ 20mg ES ister tia Aaa
| of diselvedl Astels wWhal {the — | iio 4 #4 glycine = He aye
is
"FDS Volur in ppro?, molar mao od
' aya
TPS Volutin_ Maw of the dies =Bzo1
PP eink ee ; a
Mata id Motaily = 0! = 9.2m
| : os teg
2 20103 piobenoopoms which Solution hoa the leuan
[Se ee Pees Of Mithoned
3-1 Aomple Bru SUwembad CtHso#) In 100 9 oF water ay 20g of
Higdinchlevie: axid® tayo density &thano! ceathonytn 200g OF Usater-
a Hy a OT = Kem
| bagi Galeiitats fee motality - | Pe “
Melality =|2MHcI7 Derstty = 1-2.gL7 Mayon? <2 —.23125m
| 12M Het = Io mols of Her. a
Molatity = No 0h moles of solete "ousou > a Stan
Man of the Solent Cinta) ier in’ hosying PRIMA is one
cotta max of wata Csetvent) - ee pines # will rove
Mars vd [lihe Hel Souidion = density r lave freaxing Port °
| Volume .
=} -) :
it fgehaen Oa 2 S.JAMUNA use moni.wtea?
; PG Asst. in Chemistry |
Mow Vd CLE root imoty @ Hel xmobe Cia iri Sen
Udur
a trom vd Hele THew rey dds poaticles
in one Vibe td 10“ Potaniunn
1 M Knind4g = Io~molus 4 Kasq, «
KS0, -(ontaind inns Cok 18077) -
Imole of KsS0q4 Contains 2x6 023x10%ions »
tot moles Cd k.$0, contains 3 Abrorsx10%
e tot:
ele. 069 110T Ener. y Aon, smi]
|| Mebane in benzene 16 42%165mm |
| Hq at a prtticuter content Jomperitan |
A this Coleulcte “the Selubilcly
| @% methane at i) 50mm Wg i)Seommigt
(Ki Yeoman? 4:2A10 rm Hg «
Solubility © Mothane *?
| P= Soremtig P=840 mm Hg.
| Accosd?ng to Hanrys Leo
P= Kit Xin sotection «
150 ron Hg = 42X10 7am Hg: Xin Aotution
Xi, ee.
4 eo Xie
WO Aolubility= 18-6x10>-
aby ot P = B40 fomi
Solubility = S42“ 20x 10
Ave
| 19: The pbiorved dipronion in -fraazing |
] | | Potnt af wata for o: cudan
| Solution is 0-093'c che the
| | Conartahion of the Solution th
| mootality -Guven that motel cepranion
aia for wal 186 K keg mil!
ATg = 0-093°C =0092K-
m2? kp = 1-86°Ckg moi!
2% km:
m= Ae. Cogs os.
ke 186K Kg mot!
20-05 mot Kg" 9.05m «
"
© Herny’s lauo constarl for Solubiity of |
prewrt |io-The Yipour prosere of pura benzene
ote) at a given temperctiae 1s 610
fig 229 eo non- volatile Solute t+
Jaddecl to'40q of bonzone -The vapour
|Powue the Solution iy Gao mm
[Hig - collate He nota, mow Ot
the: solute
Fei, = bto em tty
W, = 224 Won yolatr Soleite)
Wi= 409 Chenzen) |
Paolution = bo mm tg jaz=7
FP \ 640-600 ny
ee |
b40 natn, |
APs ey 0.08252 EAM.
60S ae” Mew |
22K 18 i
M, > Seri aes be ctgmrt 1)
00625 X40
WTF Bog ed Kou is praumt in
A) 600ml and 4)! lHfre ed sokution ||
Calentat is eaab,
jee eng oh
maw & kow =569
b> el mets = 5:6 = 6.) mol -
be
Volume te solution: Svoml=
O-5L:
Volume 84 the Solution = 1 L .
molonity 2 no "dh melas eh Soludn
Volume vd Aotudion Line
ol
oR
? Volume C4 the Apliction =| Lb
molarity = 2. pin
t
= 02M
S.WJAMUNA se, Mp MES.
PG Asst. in Chemistry
Lado Comer: Se S064
‘Udumaipet 642154 lig.2-56 Soest = ar
|18-2-56 g ®. dulphur is i . =
| to0g ef Coakondisulphice “ihe Aol dibo| PUT: FS ea |
| boils Ct 319# 692k « What tathemool = The RR Bi
| mas of Aalphua in “The. ort : Bais
| Beiling pei of CSz is 3}9-450K-Guon Jor wotenic Solution 4648
thet Ky for 0% = 242K Kg rnet TT, -T: silt
Wee W)=100g “Te SIt 2K - a ops Wet 344)
pera | ohio del |
| 4th = (314-642 - 319450) K + a ek we E|
2 O242K - | ee Peaks
Wee Kp XWs R100, 2.AoXa5bKlOCO, Bie ae2 th pedi O
| 37% XW, O242R100 fa}, 0.2 m agyenus Sotutfon td Key |
| Mes 25 6met'- Frooes at —O-b8% Caleulat Von t/a
| Moteeelaa mars of Sulpluia =a54gmot! factor » Kp for wabs fs 19b K egmel
Ab moos tf | rwote. of Sudphuere $2 sales Observed pr Z
FNoe@ ators ing _ gob_g TTuoritical proporty (coluulated?
| ‘i oe Alp = Ob80K 7M: 0.2~m
| Hoe rwoleondaa formula &4 Autpluece “a F012 0:2:
| uo | AT} (obier ved) =0-b8Ot +
fae 28 A Tk EAT Goteulat)) = tein -
\'4 of a nen-clocholyk solute
- Th "159 | = 1-86 Kkg mots 0-2 mot wg!
| the ae ir bonxeno by 000K) | #.0°972 Kk .
ie ard Fa ina | t2_(ep) obfomed —. obo
the meter reve oenind setae! ate Coludatel — 0-372
Wa= 29 Ww, = 159 2182
ATE *O2K ~ Kp 25-12 Kegmel!, 72, Caladaty the molality td the
Mae? Selution wntaining 459 %
wes REAWEAIOO _ pin naxtooo disewed in 2 “ef eas att
02x 15
Number meter % doluk _ 180 _ 0-02
Mas 04 the CoWantGneg) = > >
I * = ee 20-25m.
20. what. a the Trans 4 ofiscoe 23) Cabelas the ps ee
| CigHis0,) in one. Ishre Aetuttion | ef sediurn hohe Rated heed,
| which ia Bolte with gL" | cmd the satuhin, wns made vp teem
| Wren Cnty (ONH,) ” (ee
| gsmncie prosuns. of wren Studion MORN = TR ant) ——
| = Tis RT | or Oss
eVeg te = = 02M
| ae kT= joe os WY
124. Olewtods The = : z
pares dad Mrs POET te, [eg a ae
Avtuhi tora
wing a A hae up t bom} 6 sf int 2orng
Noel MR prt oat op. Now ed om len
ai ae Od. Achction Cin) Man 04 thee coates |
2 ccouvead a = 20x03
= bynes eaieodl et ae Into ® 2400 ppm
Volume 04 Aolution nL) 01 50;
= S38 so5N, lp The doprerien in Proozing pet
- oo j ig 0-24% obtained by dissolving
Se eee Mae ipso serge
cmd the Solution wos Neil
wing a Standard’ flask -
Aownalidy = No 04 Formula mous 04 Sotech,
Volume 8d Sotuction Cin L)
= Be nag
58S5KO5L
[2b Neomycin, Gri Gis me
Gear contains 300 mq a4
Pie tie 2 The active se iad ago
va on fe Sa eel
Naw td Aolutiencing) -
} = 289 x10 = 1% wiv
30g
[27 Galo Vole 7-50 wa a Fincoa |
| of bomein om umbisepte Solution Combis)
ib mL of bengein The volume 7. of
| kenzetn +
Melaa mons 4 soa Repamaie
bole
AT xno WéPlod
2 1006 KI-S6 RI
| = fa |
D-2pX Doo 8 IgM
Theoretical Malan mau v4 nig):
ES oabearaelates 25,
Exporimantal motor mans
538s
Be
33-15
[31 At_ 400 K 15 gtd unknown
Substoree 16 dunehed in a
Zowent and The is
mode bSL Ets vsmotic
| prokurr 14 found to be o2ba
\Colowah the metar maw o4
=1-50-
| vite « Veta dhe bonxain in
| Ce Aoludien (in mt)
10 yop = 207 VV
38 -Coltulot. wi ]y 7. oi a8 ome BL
| towet paralidtice oral Surporivr
| Lovetai 3g od atau The mand
| povinles Poraictoned 1's
WNy. = Mans Unme
Soe Jvdudion Lin mb)
= ext =5% Wy °
the. inva 4ubstenee «
Molen = mo & anttrexon Aobde.
aS
corer x Volumeek
15x 8-314 X17K oe
OSK
= 1d eS gram mot"
"S.JAMUNA mise. mii. mea?
PG Asst. in Chemistry
Lourdemaha Gonvat fate Hi Sec. Sciol,
Uduralpet 642154 ea An- copii: Avlution 04 a
B ethylene glycet Clsyo.) can be pao Aolute Grorts O
aed os om ambifreoxe In the yodiabpy| of hee hen at tho betling
-Colewtak ths Jomperttun | pink ts Aotword « whet
il kag | the velar mow od. tte folate
from a mistine With 29 mom | when Bers L013 baa?
percent of glycol in coat wedin | AP__ Wextn |
tht a 1 Kp for wotr=18bag Fe “Watwn
giyeet 15 62-4 mol. Tn 2y. Kolutiun = 24 Selutronf
wegit 94 SNK Ol) = 20-7, 220906 a8 9 a Sovane:
: Faw gl AP = Px-Protutter 10131004
weight ed seWwont teoata) ~
W, = 100-20 = 804
AT# =Kem -
* | = 70-004 .
oF) me.» Bxwoxntn
z APXWe
Mg = 2x 18K [013k 4ex 6-009.
= kp xws moo, 8)
MgXW $3) = ALB geet
elses lee 2s i Lesson 2
ee ae} | Quantum MecHanicaL MDOFL
Dips TSK: Ae OF IaTOM «
cTompp et which tee Wil i Calewod, the Scien wae
agin to opaate = 2IB—TEK enerth of a praticle who
= 2b55K: momentum 14 bb 2bA1O eg msl
Ge ee hy
33)015 G@f om. Unknown Aubstarce | acab = bbb a 1x1
is diswlvad in 200.4: SeWart «Tt he) Pb. 26x10
ca boil! Petre Ts O15 2. Calewlats the toto! number of |
and nurtod. if amgular orc fodial nocles prosert
Tos kekg mot tuen Cedeulats 32 | plod oral 4 oxen P
wiste, ous ot UNkneLen Substance, ee
|. | Radial [a Tob! |
Tp = Kom forbial|n |x | ube [ie Aral |
a °
= Keaws XlooofMaxw,- | ad | | ae
t
Dati ennateeoim aw," |e aL |
EEK OTEK (000/ 0154 3: Cal cule he onda ria |
=
= = 200) Uleckons that con be accomoclatd |
= 18t5g mol in L shou: on |
PL n=2. #orbials |
MP 2X, OPKs Op, # 2fe-2G508 | ao calatodieeragi aera.
Yodial Wwodes
| pros in see lal
Orbital) eal Praca)
ad la lato 4 es |
[of G43 1 eae to
Dasa ee Fel P|
orbital Tye
L=VaCeiD hb.
Tor A otitis
ded
Le Vamos = We
on
omgalar momenkn dan ein
dl orbital = hve
ow 7 a a
Ps eee aie
omgulaa’ st tan ein
F orto) = eae: ;
8) Coleetoti “tho. — Don
obekon that ras been accelerated
fyem west “thro'a potential
olifference bq | Kev:
atelerceze! polontiat > [Key -
yp mvs ev
mv*=Dev
my*2 Imey =7\M te gmev
| mv: yomev i 4+ heyy. bh
my
>a 31
m= Aino Fkg she bb2b xo «
leve Wore" 5 [kev ees |
leas. i
— ekon® Te: Pav tads ae
ner
[ren
bb2bx0F4)s
Vo a1 x10 Py 110d KU Kid
2) eee ag
[Batzexie? 7D mae
Azo 10308 (ohh wad
] a 3-38 xto7'm
[7 Calculate the uncortainity in the
| Position of an electoon if the
| Wncartalinity in its velocity 15
1A to ms, o
Az
Ares 1 x10% ms! Ax? Zi]
srbp > bh_s =
h ek :
“ ae Ese sa
= §2gxio?® 22)
Ea Og.
Ax-dp S528 Kio
aed cpaemie*igies
arise a Re TAM
Ax bolt xm -
8: How orbital at tex in
Ath anergy level 2 (nea):
neg 5 420/123,
aq Aub Sheth SP of:
Ged mhz 0 => 1 4S orbitod
Be | whe -Lo,tiey BAP orbitals
Beg me2/W0,41/42 27 5 4d orbHols
JES men Zer24 D/A ADAS m7 AF
evan 1b orbitals art poutbl -
i which ten haw Stable eleckronic
fi ‘on 2 mimor fest
Be i, geet ze bast Pas ad"
Ecof NP 33308
wf let) a i ed
seoa
Contd fonae— in 3d ond 4f orbitals -
STITT ZT ROE] Waal oie | 4 |
jemi? (2 tins fal "pe Hae ot
Ears a Z [on |i Poker Can be aceolectal in
# 7 lee i a particle aceoleralors Calculate “ie
ae Cin A) vf “Such.
WyEnegy OF an elachon. in hydrogen en roving cd 28smo
atom in ground stah is -12-bev: msl (the mas ed protor 15
What juaths anergy od-tie 673x102 Wa)
in the Agvond Sucied Atak 7 | ye aes aio? ms!
aed ox | mp= betaaic7 "kg
Aurord 2ueiteel State Aah 2 bosbritleg mist
neg 2 Ba: bev: MV [+ BIS KIO™KgX2854 15
se ms!
Bz =-i-dlev- A 21989 MOF Hy A= 1 389M OK,
2 Fue wong unpabad ebors 5° a ee
Gan” prem in the ground stobeed |wowalergth Ul em) ode V0 J
o% (z226) mr? Cz225,end Cricket ball bravdlling at
argon CZ=18)7 . 40 Km hy": 7
Ec of Ae? is 18'2st2ph 36° phys’ ee may %4 tha crite? bal
| Fhe unyaied etecbrons - 2 Ihog: ob kg
| 2 veloc clot baby =
| ease ad* vege SS ee
| gt of Mn? is 1g2caphse aptaczds) 40 N03 2
ns = mS" = 98: 88ms
boxe
Five umpaited elector
de broglia equation “A= b—
0
Electronic Config
of Ar :[s2s?2pb 3573p be b26 x10 a
‘ age)
unpalned electrons es tare Saha
a Ob ey X B98 rfl.
le ppom tre Ineaning |f the 4ymbel |
= bb 2bx 10°24
| 4% a eee eee 1 ee
| Turbos for the elecbons: Sees:
|
}
|
| no % eleckons 4
| $-ovbital Wawe length inom = LOS ICD
| Shesmiepames = 065K 102um
eee 1065 Kio 30 «
nea, # ovbitol 4-3 mj = 3-200 “S.JAMUNA
ees peasy RE 5 LA ae YA Mo. Mh
MN Dal, Md
Spotty a =) Mp2 inate er
Tn Ualimalpet 643154 3 @
Ib» Show that the measwament | 1¢ Glee the Electronic ConFigesation,
OF the urncotainity fn the | Of Mn2+ and cr?>
locettion 84 the So oiee aan Mn (== 25)
to th eine eure | Ro pt: J
Se reas yee mnt 1s%25*opbas apt sd”
Volority av) 13 eoyaalte Var} or {z024)
| OF tu” velocity Cy). ev |s*98' Poph ae apt ads. }
Ax = ObA® Ci is } S 4
aut } “LESSON -3
Be 2h. | PERIODIC. CLASSIFICATION OF
ips BLEMENTS -
=e! bs Coleutat the effective nuclear
> Leotn*Kgnne!. — chage of the last eUeben In
Dp & - Eb2eROtegmig! orm ctor Looe con figuration
| i eees| j4 [st 25% aptactap> *
ARB 14 X OOK [OTP a)
> bbb xto4xIp!? a8
abba Ripe zrez SGN th
ee ae
| ap > 0-8142K 10" Kgms!. ad ete agro rey i st
7 gag
om B192- x10 Kg ms". ai] + [100 xTot no td 2M in
= oO tnney At}
Ap> 9.8 x10" kg ms" ES aE — (c0-25%6)+ Co8sxadr
It what 4 the de-Broglio. wowe 53 si : e1¥2z)-
langth 4 om elichon whthis Zo fo TIT le-Ae bi.
eeieal «
jaccelerated Avorn tha vO Nise ies i eee)!
eS 'C'
| potontiil iffosaree ed. loov 7 -Colculat the Effechye nuclear
Potatial dMaare *V=(00V eno 3p OY in aluminium
sa e ) chlorine +
Polenta energy = eV = Loox 16x10" Ain= ier 2539p"
| de-Broglie: wae length bd om een Win tps
, ne n-i ites
Ae aoe
amev gt 2z-8
nb2bx toe ei 5
aioe be enle nds £13 -L 03s x now 2Minnth
DX 41x 1073! w1o0A Mx _ Shel
to? + [0.85 X no % essing)
A = [22X10 hell
rs + LI We td OM iy in-ashad
ae = 13 -[b-"10 46.804 2.00)
; — Ee aeetsoe gin (Zorg) Pi = 3.57 | Lesson — |
Elubyonte Configuration of Chdoring Basic ConcEPTs OF CttemisTRY |
SF 98” 2ph ag 3p a AND CHEMICAL CALCULATIONS |
| be? peo nr io ” hy of
| ay Hh rel
zat-$ al | ce aaa produce 10 mbes
=e aes on rbngheuh Gf Carmmonia ?
Co-gs x ho 8 &™in(n- a
C1 no. a C7in (N-27 hu Notgyt 3#2g— 2NH3ca)
Sida fone 6842) 217-109 | To produce 2 metus oq. onemoniar,
| ENG=TrS 8 meus ef hydaagen ore Aequived.
| elpslod | 2. Te produue 0 mele v4 arrmrenia)
aie | |S aPey* gee He
(Zeya > Cat) 3 Hone | atrmotes egnnis TAIL 9 |
eT ne See = 16 maples of ty
3-Frogy 04 om election in the
Blake Of the hupdaogen cctoro [pcalinlads te, amount 8.
Yo o19x 108): Colatatrtie tater produced by +he Combustion
Tonisation enthalpy of choi: hyphage 4 22.4 ey methane -
in tors 8] KS mot!
Enogy ot om olpttion is the igo se — Osea BOLE) |
Ato, of the buplingencibor 18X10" — Corobustion of | mmm (169) He
Hye Proditces 2 mets (0x18 =3bq) OF
recut tose J eal
Meese 2: 32.9 CLC Oh Combustion produas
Es eee broagnio??
Bbq Pat,
= 19130 X 105 J rot! BO) nS Chy 2112. hho
Lae taint Jnl ppg veenn PINT
wo _ | ew much
cH Ko vi Shue Od. coabenda-
2b mies | orice id pant ikn oo3 |
a ce °{ calcium. Coakonak 75 he
cae (eee
S.JAMUNA gt (ALD, —— > COQ COzap'
PG Asst. ct 3c)
” Upurdematna Co: Produces | mele Cotes »
ASTP ,f mole Of CO. ocenpina |
| Volume vg 22-7 Utes - |
At STP, 50g 64 Cato On heating
produces
2257 Litres CO.
100g Cats
= 13s" bites of (Oe ee
4 How much Volume of chlorine is
jred to form WoL of Helak |
273K ond fedm prewure?
| Hoeq) + Clegy —¥ 2HC ea) °
To produce 9 moles 64. Hel, |rmole
of chlorine Gos is acquired -
To produce 428 Litres 04 He]. 22.4
tes of Chiorine gas a requivd
wT produce M2 litvos Od HC}
22a ble x yd og HC
aaa og Cla
= Sb tthe 4 Korine art Yequbal
Fa
50g Colds «
Het eb ite wy ME
Aad 224 BA Aad
Te = x = Ne x22
448
2 9b
Caleutake tye... parentage conpor
| 5
| of the
| cankonete~ Hoo mony Kilogram of
to, cam be Obleined by eating
eq 0 Arh Pune. mrognesione
| Carborals.:
| Mgcos 2>™90 +,
| Molar mam ti Mgcos is 84 great
Percentage od Ug
84g Cates Conain 24 q
Od M.
|
SS rere corioth) |
= A OM x 100g mig tos - | |
BAG Males a]
2 285799” zai
=528
| Mgeoy hq ers 00 g548
84 ay 34 84 Saie
% of Mg 228-577, a
| Percertage e4 Carbon
849 8 Hgcda tontain 124%
2. 1004 Mgevs pete
ete eat &4
aq ugios 8 OR
24-24 9 O4 Carbon’ 7, ©
Poruntoce 4 Goabon 14:24 i
Bo RBS
BAG Matos torrtain 48 9 OY9|
| + 100g Mgcos Cenfains "ye; ©
4&5 0 84 4%
Ba g Mgeng *1°0. INI 0c ‘6
= 5T14 GY Oy” 488
849 © 1007 pure MgO,
oh heoting 449 oF co, -
1000 g Pf qo. puarHgco, Giver
2745 _ xqu7. X(o00g .
S4gXl007-
=a4ge g Ae
= O41) Ky 0d 02. g Colurlah
ta Orygen in HaDs
H20,= 2Ct)t22 =0
axsc-2 =» Be
FrGoleulok the oxidation stata of
oe” in 20, and Ko, -
0 = 2C1tax=0
oms-2 =>
©) bupes omidles ko,
+1 42220 ge
Hie HOLT AAS
go.07 gmt
Ti) acetone [oncocud -
Cc! 3x Idol= 3603
Hi & X10 > “ob
0. 9 xX 1b glows '
G80? gmol
oe a
i) bore. Quid CHsBOsy -
Ht 3xtor= 3:03
Bv 1X to = (0:00
0: 3X Ib “48-00 "i
“grog greet
Gib
~ SJAMUNA i150, 3
PG Asst. in Chemisty
——Loundr ie S00
x Udumalpet 642154
| 3649 HELE = eS
1599
| iia 600.07: Potamium clichoreak
Krgrdg+ 28
Oto 5 2"* 104
Oeuris 2112
294 4
vik) Sucorse Copa Ho2011)
Cs taet2= 144 |
H Bam) *. 2Aey
pot NAT 7b
3429
1x) Culecos2 CC, Hire) °
@i bates 72
Hiine 17 12
oserie 7
180 g
sues 2 |. Colewlak the equivalent mary * Coledatethe number 04 moles |
| % Sulphuric. ovid « BRE Aiton
Molar mew 4 ethane
- a QHe = ¢2*I2) t€6x0.#30g.mol".
| =e at No 64. moles = TO O09 :
| Basra 2 ayer motamar “30g mel
Melar maw Of H2So, AICS TONLE coe ek A
ae oe |25 0-469 4 a metal gives,
Green Ooyivalatroas a gg oboe aj Th Chloride Cabustan
Hsog * Te the equivalent Mam vd-the metal:
249.997" | Maw Wy te metal = w= 0-456g
Maxs Od sArtal Chlovidle ew, > o-ecty
Mars Of on
aid
ren | Motea rmaus Som cud
oe | Mais YY cldorine= 4, -w,
i v4 the baw 2 0.b0b— 0456
Equivalent > Motea maw | peste -
s se
ams 04 boue, Acidity 6d the baw O'59 wy le aE
ida i. 0-4569 od metal :
ae ee “3559 04 chloride wi combine
| Weloa maw vd KDW = N89 +A RIOGW) : at aca ‘|
| = Bb gmat". with CAE k 35+5 = 101-42. 94
| = Bb ese geq 2% Balamatn 5
By KOH ie ergy 8, "9
|pa-Colelah tye equivalnt mom ed ‘| KemDy 4 er +
lad 3 TE + W804 > k,SOa+
om oridicing agant CkmnOa)
| 9 ere’, St Cralsadet Ty +Hr0
Kano, is em onidising . vals
= (x39)+ Ck 55) taxiy) oan gee aa
See role re gee ea
oa ee: |
0 = sts iS
Grow Coyei veered mam 04 > * 3 a3 u
= 155 3y- ri s og 2
keno, = 98 23I6 9 Ff g gee a
| + 93§ a9 33
Toe = es =<
ot ee
ea a
F§ley SS
2°" 3.83 ; @
oe ‘at
")\kMndq + NQ2S0; —7MnO2 + N@rSoq + Hot
+1 4 +4 +o
KMnO, + NGSo, —7 Mno, + No go, +koy
% v e
327 ze
2KMNOy 4 3N4250, —> Mnp,
2
“Aainty és 3Na2 Sq —) 2™Mn0, + 3NG S04, +KOH .
+ 8NasSo+ 10 —> 2Mnd, 4 Sse + 20H
ee ee er
Un Hoy > ext
Cu + HN0, —» CuCNds), tNO, +Hyo
o +s~
cu + HNO; —>
+NQ@sS0, +Kon -
4a
O4CNO2)2 + No, tho
ge BE
Ut + 2HNO, —¥ CHCNOs)) +NOs + 20
C+ Bina; tad, —> C4ONOS), to vu, | 2Mao
Gu + 44N03 —y cadwor), 4F2N03+ 21,6
= TT a
iv) kM o
MnO, + “he + HoS0,—y Kaba + Wison +'do, tung.
: “
Fem
lear
ZENO +5126 Ont HyS0, KS MSO, +024 Ho .
PRMNOR+ 5 HsC.04 +1280, —? K2804 +2. Minsoy 410.6034 Hoo -
SKN. + EHC. 4 Sigg
PKS t 2Mn600 t10Co. +8 tbo . |
20)Balene the following equations by Ten oleebon Method). |
1) kmno4 + Snel + Hc} — Mntla + Sncl4 + H20+ KCl
Nine47 — Mn —O
“$n — srt —@
+
® & mMno, + ayt 4 se°———9 M44 AH2d
= = Sart SH, 90>
@_JAMUNA Mise.
Sarees
onan COO Oxr =F 2Mn0y + (gHt+ oe") OMn™ + BHO
Grs = 58n7*—¥ 5Sntt+ 1007
2Mno,~ + 6SIPH [bYL—y 2Mn™y SSK BH2O
9 CaOy"+ Ong R208 T ost Cb) Gin euch ageoliom)
| Gaz" yep, <€
neoprene
| O- C0F—_y 200. +f 9.07 —®
exo ray —ya0e4 tao —O
@x ee bC0a + po cae, :
7 —“
CDP HAWG RO FTO
CY0F"4 ace? + igut —y 207744 60, 1H 2°
|) N@S.02 + TZ, 5 N@2840, +Nar mee
He
| S502" —y $406 ——O
Tate © :
a2
Ope 280. 7 SOE Oo BY
22
no
@ aA
ees
©+@ > 282 2240, 7 $40.7 42T
i en + NOs an Entiéin anid Mund
es | Noe > No)
O—- xn pa Py ee
| ® Nis t Ga FAN ear NO TOTP
@xS azn —> azn +46
K2 2NONt 66" t+8ut__y 2NO+4%RO
a
Udumaloet 642164
‘Lourdomatna Convent hairs LEsson -1) hychayen = 2% 0-54 ;
= *030
JUNDAMENTALS OF ORGANIC if
log 0 Aulstemic Conatins
CHEMISTRY-
=. 2K 0-54 n1o0g .
|. 080g of a Aubstonce wives 180-30
| 0-88 g 04 Carbendionde omf "= 20g @ hydvogin
| 0-54 9 of. Wolr Coleulabetine Peaerilage rf hycbopn: 20%.
poxonllye od carbon emd Wydungn Fp, ammonia Wolveel fom |
in it: 0:20 g 64 O79 Organic Compound
|
Woight ef organic Compourd=0209 ‘aeldah method neubaliced)
Weigic of Carbondioaicle = 0 889 I5mA Od ni/20 Aulphure Cute
Woight: Of water = 0-549 Solution Caludak Max pononlags
Percontuge of Carbon = ; | Weight Forganic Cong = 0:20
44g if Gabondionide contains, 4 94 cud = Nino d
Goakon =12-4 Volume 64 Atomdand acid nevelrclay
0-889 @ Caxbondien‘ele cxrrkatns by onemonia = 15 m4:
| taten > 12x 0:88 - locoml In) auid= 149 O¢ ih
wend e
tml of aid ef nomality N
0-309 substance contains, Carbon Contains Nitrogen = Pers a
= 12K 0-88 9 026 9 a (cox 20 i
Pale * hitrogen = 1415)
loo G Bubsterie contains inne
_ 12K0288 ) Ibo | 100: a
2 STR 0° = S0q Of Garton. i Compound Centains
a ow 9 nibogen= _14x154 (00
Ponontoge of Caabon = 80 1000 X20 K 0:20
Powentace 2d bphegin: Sage
18.g_ 04 tackta contains hydrapens2y °- penoritage Of a
0-bAg P wala contains .
hihogen = 2x0-54 3
ig | al
0-309 & Substance tonics SAAMUNA 25 we |
| “-yourdemetmar Convent Matric Hr: Sec. School, [3-029 of om, Organic Compound oF nehrogen in the Compoure |
| Jone 0-287 G Of Ailveachtoride | wos Sa -
| in, the Comuas Methwdl-Gleulat ert ee
| the perantage of Chbovine fn the Gace eed:
| Cornpnurd | Temporahuoa T= 15+ 273
Weight, OF He Organic Brubstance +049 = 288 Ic
Waight Gi Agel is =0.2879 Pressure P = 160 mm -
43-04 ey Agu Contains 365g of Porerttoge aN = 28XV, loo |
| chlonne - 22100 W |
| 0-287 0 Agel Contains SE, 0.287 = 28%201 , 100-7299 |
435 0.994 22400 359
| Uglies OEE BA pee coiege Gl i TE
425 0284 © 0-236 9 04 an Organic
LL =24.56 - | Sama tenlaining C,H 26
I t rd, OP Combustion givesS0.27549|
4) 0-229 Of an, Organic. Cenapoara, a |
afb heating with farming nityic acid Seiya onion o
and baaium nthol. oystal in a | C)H.omd 8 in. tht Organic
Saalrd tube game 0-469 % barium feared, Dessay 13-04
| gulphati - Determine the perortage | weight Ei ovanic
OF. Salphua in rhe compoaind: oS Aubstemce cui)” 0 3Hbg-|
Man 04 Aolution Substance taken =029 waight 8 walrrca) = 0-27549
Mas FF Casey formed 2 04 bbg Weight Of (0s) = o-bhgag «
Melee trays 04 Basd, > 137432464 Poaitge BE tahoe,
ey
aaa
Then mars Of O-4bbg OL Bakog
na Pitta, wg Se2I17.
233
Ree 8 in D466 X32-X (00 eo a te
Onl Sea 7 TS oa3yp 10 |
pee eno. | eee
|@In the estimation of nihigen Poreontage:. oF. Onygen
| Prmaent in On organic cl by= Leo - (529174 13.042)= l00-L52)
| Dumas methed 0-254 yielded = 34,197:
ar netyOgth Ca SJAMUNA ise. Mp, MEd.
pare aee ise ra PG Asst: in Chemistry
‘Tem pessurxe Culcdat the pononbae “towcata co
Se
Udumaipet 642184 @o.w. of om Organic arb. ‘ ; ic Compound
Was lec we oobi tala oe (Ooze Celie, gowe
1,504 atiol -Formool wor protipitdleel | 0.597 9. cl Ha.Ps07 by theanalyis
with Bock The mam oF Baso, was alee ie a ‘
0-259 Find the pouentage 04 Sulphur’ sy Compound es
Weight % Omanic Subaredi)=0bg 222 P-3) es
Weighh af Baaium Aulphatitx)=0-259 Waight Of Oganiic Aubs face w)=0-29
Perontoge rf ulphan SE x x 100 Weight 21M 9,P.0,(x) =0-3979 .
= = y 035 x00 Porcontage of Photphonous
2SBE OUD = ye 62 , 0-347,
Sy X xloo= 52 x0
a 222 wxico
2 ae oes ieks et 322 0-33
0-10 ta
= B0-04%/. (0-39 % on Crgaric Comprund
ie Bretdahis Pala
@orss g of on organic Compound oromonia £ just nouhalie
when treated with CBrcHnds cred 3p mL Of ON Hy80y *Colewake the
sine nichat. ane 09009 84 Silver Percentage of nitrogen inthe. Corgan.
bromiole Calova. the 7. 4 brymint Waighet € Orgpnnic. Compound (w)-0.329
in ie Conpoletneng -Baupeeaey Shorgth babphuaic oud udev: o-W.
Weight 4 Organic Substae (w)=0-1869 volume ® Sulphuric ceriol wind cy)=20m),
Weight 04 Atlver Todids @)z 03209 . Bomb of ON Sullphuaic Guid = Som og
Poxortoge 4 iodine = 80_ xX xj0o Fa MS iy
Bs Ww | Poontage hitiogen
= 30_ 4232 nrI00 | Resse es
235 O185 14X0.1K30
B ae sa — boss x03 /=A7-
0.109 Of orn Todo Substitute @o.244 ob nie Compound
og compound gove ea ee”. cael que
Foc of jadine ‘in the Compound) war, by the ul cel
(Ag = (08,2 =127)* aaa inthe s
wi a organic. dubstancel))=0-409 ‘ ie Compound
mS Woghr ed Organi
Weight 0 Ailver fodiole O1)=0:2369. waist of ig. Be, ae)
Pononbage of iodine’=!27 xX x19 "SJAMUNA itse.0ii% mca. |
_ jal, O25 \i00 235 WwW - "BG Asst. in Chemisiry
eke gaie 2 Ot inna cient | 2229 84 MgpP,0+ Contains 629 oP 058259 64 Baba, Corains
| Obb g Conains (25 x048)g 04 P
Ponordage og p 62 x ot nico
[02849 a on organic subetang
OMe 0-287 Agel in a (aris
method for the estimation of
halogen « Fiel the Pomentage
Pt. cl in the Compound -
Weight 64 the nic
aa yom 0284 F °
Wight. agehis = 02879
435g & Ag Contains 35:9
64 chlorine -
| 0-287 % Agel Contains
PER ORT,
435 0284
7. vd dulorine is 2235 0:287 100
435 0284
= 24-987 -
Typ dn | een) Ostimedion oq Sulph
by Corius method, 0.21759 oF
the dubstarw gove 05825 4
| | Bado,* Coleulati the
soe pteee
233 2s
Pewartoge of § = 325 ©-B8x100
| of 233 0-275
026g ad ono orgpnic Composed
awe 0-039 9) fe water ond
jo! joxide en
OAs Deon tajaslale the
Parentage oC %H
weight organic compo: 0249,
woight wal = 0-0399 .
woigid ed (Or + 02459
te fd buyclragen: -
13g of coaley contain 29
Porneentode 04, . corben'-
AAY od co, ebntain 29 AC.
02459 04 CO, Cevdestins 12-4224
A+ ob
compostti Sin
| fon 7 & Corben Sia pose:
A 026
| the ‘
| wight ed Organic Compeure)
OnIbg -
weight OF Beso o-5825 4
293.4 Dd Bosoy Contains 82g ads
i
= 25647
2 SJAMUNA
ee MSc. M phil
<—-PGAsst. in Chemisty
Lourdematna onvent Matric Hr. So
Sere wehamalpet 642 83 @
la. Calowob the enbopy ¢
Pests at
Alp (eo)= —242 KJ ort!
the ae
total Soni chem Io | Wa eay+tagy—> COcat H2Dcw *
ae Gerad Pro) Aye. Corby )py — secelont
| in which 245 J of aad Fina» ; in
| ot cea ck The, te the Hn > [Atl 0) + 2 crated —
ot 25c: CAth C00) tarp cd]
nade 2 THES 350k
a
| gare ae a 2 834913 > ae
A Sso6-= aps seo amg Ort se
Tig 35°
| AS Ste = VE. oli
| Tays Sob
|. BSuniv3 ASS ese
—or1 sK14 ogi.
The Standard enthalpies
formatron of $02 ond SOs
-2471 Kjmet! and
vely for the ¥
+140, —>SO2 -
396 Kinet!
on?
8a +
AW (502) = — 207 yreat™:
SH (803)= - 29% KI mat!
802+ Lo, > S03 :Ath=?
|
|
|
\
|
|
|
Atty = 396 Kirent = (-29-7kdenat HO).
AW, = -39b Kimotog7-
| AM’, 94 KS not!,
[ii= aleulads Ave for che reaction |
COacgy, + Haeqy —Y COcay HOw)
given “thesk ANG for COs, 0%)
nnd HyD@) arr —3935, -IN-31 ad 7
242 KI mat! qospochialy »
AvF dy) = -3935 Ki nu?,
AME Coo) = Ul3y Mey raat!
AWY At coos toast Bava)
M3) + (2429) -f-3935+q]
= £3933 + 3235)
4H; = 40:19 '
wy Pt = 44018 KS mot
Th = 12a 2127 +273 = 400K
Te cate H4tt513 =320kK..
% efficiency b=?
2 Teche: ‘e
a X100 =
Ty a3
400-320 35
Ds eee EEE RO gS
400 =
<
~ Brivo is
=
oO
» |9= 207]
|!3- 20-4 KI 15 neguived to meh
one mote Bd ere
The enhopy
Galak Eset a
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