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    GOC

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    ops1948
    1. Certain conditions favor free radical reactions, including low temperatures and polar solvents. 2. Carbon-containing fragments that are electrophilic in nature can participate in free radical reactions, such as carbocations, carbenes, nitrenes, and dichlorocarbene. 3. Compounds containing polar pi-bonds, such as carbonyl and sulfonyl groups, are also electrophilic and can take part in free radical reactions.

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    GOC

    Uploaded by

    ops1948
    4 views22 pages
    1. Certain conditions favor free radical reactions, including low temperatures and polar solvents. 2. Carbon-containing fragments that are electrophilic in nature can participate in free radical reactions, such as carbocations, carbenes, nitrenes, and dichlorocarbene. 3. Compounds containing polar pi-bonds, such as carbonyl and sulfonyl groups, are also electrophilic and can take part in free radical reactions.

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    1. Certain conditions favor free radical reactions, including low temperatures and polar solvents. 2. Carbon-containing fragments that are electrophilic in nature can participate in free radical reactions, such as carbocations, carbenes, nitrenes, and dichlorocarbene. 3. Compounds containing polar pi-bonds, such as carbonyl and sulfonyl groups, are also electrophilic and can take part in free radical reactions.

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    4 views22 pages

    GOC

    Uploaded by

    ops1948
    1. Certain conditions favor free radical reactions, including low temperatures and polar solvents. 2. Carbon-containing fragments that are electrophilic in nature can participate in free radical reactions, such as carbocations, carbenes, nitrenes, and dichlorocarbene. 3. Compounds containing polar pi-bonds, such as carbonyl and sulfonyl groups, are also electrophilic and can take part in free radical reactions.

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    of 22

    GOC

    Favourable condn3
    - Generally 3
    ① Denismore

    ② low temp .

    ③ ions

    ④ Polar solvent

    Near
    *

    [ free radical)

    ka -
    Scarbocation]
    H %
    · c -H
    -

    1/2
    -
    H Ge
    -
    -s
    H
    Ge Nitrene
    7e7
    Carbene
    Carbon free
    radical - 4
    :c
    -
    d

    (Dichlorocarbene)
    >
    Limp
    .

    Polar M-band
    c) compounds having
    All Polar it-band compound
    containing
    are

    Electrophilic in nature

    +S -
    S

    egi- O C =0
    -
    -

    -
    -

    O
    It
    S
    eg
    :

    /
    -

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