Professional Documents
Culture Documents
Coal Ash Components As Partial Cementitious Resource in Production of Artificial Coral Reef (Anthozoa)
Coal Ash Components As Partial Cementitious Resource in Production of Artificial Coral Reef (Anthozoa)
In Partial Fulfillment
Of The Requirements
For
Research Electives
Antenero, Earl
Calvario, Christna
10 - Leeuwenhoek
ii
TABLE OF CONTENTS
Page
COVER TITLE i
TABLE OF CONTENTS ii
CHAPTER
1 INTRODUCTION
Rationale 4-6
Conceptual Framework 13
2 THE PROBLEM
Hypothesis 14
3 RESEARCH METHODOLOGY
Research Design 15
Research Environment 15
Research Instrument
Research Procedures
DEFINITION OF TERMS 18
REFERENCES 19-21
iv
LIST OF FIGURES
CHAPTER 1
INTRODUCTION
RATIONALE
For decades, utilities have disposed of coal ash dangerously, dumping it in unlined
ponds and landfills where the toxins leak into groundwater (Mapping the Coal Ash
Contamination, 2020). Coal ash contains contaminants like mercury, cadmium and
arsenic. Without proper management, these contaminants can pollute waterways,
ground water, drinking water, and the air (US FPA, 2014a). Despite the protests of
many whose lives have been affected by this demonstrably toxic substance, the US
Environmental Protection Agency has for years refused to classify coal ash as
hazardous waste(Coal Ash Is Hazardous. Coal Ash is Waste. But According to the
EPA, Coal Ash is Not "Hazardous Waste.,”n.d.). During coal combustion, large amounts
of ash are created along with carbon dioxide and other gases. The fine particle ash that
rises up with the flue gases is known as fly or flue ash while the heavier ash that does
not rise is called bottom ash(Hannan, 2015).
The sheer amount of fly ash that exists is a problem. The EPA estimates that 140
million tons of coal ash are generated each year, with fly ash making up a majority of
this ash. Some power plants dispose of coal ash in surface impoundments - known as
wet ash ponds because the ash is kept wet to ensure it does not fly away - or in
landfills, while others get rid of the ash by putting it into a waterway(Fly Ash - Energy
Education, n.d.).There are different problems related to fly ash like requirement of large
area of land for disposal and toxicity caused by fly ash which leach to groundwater.
Bottom ash is a type of coal ash that is generated during the combustion of coal in
power plants. It is the heavier ash residue that settles at the bottom of the combustion
chamber or boiler. Disposal of bottom ash can be a concern due to its potential impact
on the environment and public health. Bottom ash from coal combustion can contain
various pollutants, including heavy metals and other toxic substances, which can have
adverse effects on the environment and public health if not properly managed. When
bottom ash is disposed of improperly, it can potentially contaminate soil, water, and air,
and pose risks to human health and wildlife.
6
Today, fly ash is used widely in concrete because it is rich in siliceous and aluminous
compounds and has high potential to be used as a raw material to produce pozzolan
cement or fine aggregate, especially it was used as pozzolanic material to partially
replace cement in concrete (Lamond, 1983; Bijen, 1983; Ravina, 1997; Sarkar et al.,
1995). Benefits of fly ash result in three main advantages: firstly, the use of a zero-cost
raw material, secondly, the conservation of natural resources, and thirdly, the
elimination of waste (Ferreira et al., 2003). Since the amount of bottom ash
accumulated keep on increasing, the cost for opening new landfill area, transporting to a
disposal site and maintaining the reclamation facilities will increase significantly. This
huge amount of waste has become a global issue and required serious attention from
those countries that consume coal for their energy resources. Therefore, plant operators
started to collaborate with researchers and industries in order to fully utilize the vast
amount of accumulated bottom ash. Bottom ash generally disposed of in slurry
condition by mixing with water and being discharged into ash ponds. Researchers
commonly collect samples from ash pond and ensure that they are in compliance with
local authority standard. In recent years, the utilization of bottom ash in engineering field
has received considerable attention due to its potential application including aggregate
replacement, concrete products, embankment fill, road construction and reclamation
work. In order to utilize bottom ash, the physical, chemical properties as well as the
method of application must be studied(Abdullah et al., 2019).
In the past several years, fly ash Philippines has been introduced and used as an
additive to cement. Cement batching plants nationwide and all over the world use fly
ash to improve the strength of concrete mix. When used as a Portland cement
replacement, the class F fly ash shows increased resistance to sulfate attack, increased
late compressive strengths, after approximately 28 days, increased resistance to alkali-
silica reaction (ASR), and increased pore refinement, as compared to unmodified
Portland cement. In recent years, the global construction market has been creating a
paradigm shift of creating a more sustainable and greener approach to development
with the use of fly ash. This shift in the market has enabled the demand for fly ash to
become an additive in a wide variety of uses in the construction field(“Fly Ash
Philippines,” 2020). In the Philippines also, several studies have been conducted to
investigate the use of bottom ash in concrete. These studies have shown that
incorporating bottom ash in concrete can improve the strength and durability of
concrete, as well as reduce its environmental impact. By using bottom ash as a partial
replacement for cement, it is possible to reduce the demand for cement, which is a
major contributor to carbon emissions during its production. This can contribute to
reducing greenhouse gas emissions and lowering the carbon footprint of concrete.
7
The utilization of coal ash, including fly ash and bottom ash, in various applications
can have both positive and negative impacts on different stakeholders. If coal ash is not
properly managed, it can pose risks to public health. Coal ash may contain hazardous
substances such as heavy metals, polycyclic aromatic hydrocarbons (PAHs), and other
toxic compounds, which can potentially leach into groundwater or surface water, or
become airborne as dust during handling or transportation. Exposure to these
hazardous substances can pose risks to human health, including respiratory issues,
skin irritations, and potential long-term health effects. Communities located near coal
ash disposal sites or facilities that utilize coal ash may be affected by issues such as
dust, noise, odor, and traffic associated with the handling, transportation, and storage of
coal ash. If proper environmental and health safeguards are not in place, communities
may experience concerns about potential impacts on their health, quality of life, and
property values.
Coal ash has been used in some cases as a component in artificial coral reef
construction. Artificial coral reefs are created to provide habitats for marine organisms,
enhance fish populations, and support overall marine biodiversity. : Fishermen may see
the use of coal ash as an artificial coral reef as a positive economic opportunity. Artificial
reefs can create new fish habitats and attract fish populations, potentially leading to
increased fish abundance and diversity. This could benefit local fishermen by providing
new fishing grounds and potentially increasing their catch, which could improve their
livelihoods and income. Beneficial use of coal ash can produce positive environmental,
economic and performance benefits such as reduced use of virgin resources, lower
greenhouse gas emissions, reduced cost of coal ash disposal, and improved strength
and durability of materials(US EPA, 2014). Utilization of ash residues, including coal
ash, oil ash, and municipal solid waste combustion ash, for the construction of artificial
reefs at sea has been investigated by many researchers throughout the world for nearly
20 years(Shieh & Duedall, 1995). Now, researchers claim that artificial reefs are more
effective at getting the job done than the ones that form naturally(Artificial Coral Reefs
Boost Fish Colonies Better Than Natural Reefs, Say Scientists, 2021). The goal of
these artificial reefs is generally to provide a stable growing area for corals, and habitat
for fishes and all the other organisms that you would find on a natural reef.
8
Coal ash can contain particulates (a mixture of solid particles and liquid droplets
found in the air, volatile and semi-volatile organic compounds, and heavy metals (Coal
Ash, 2019). Coal ash is the mineralized residue left over from burning coal to generate
electricity. It's actually a collection of different types of materials, called coal combustion
products or coal combustion residuals: fly ash, flue gas desulfurization products, bottom
ash, and boiler slag. The type and amount produced depends on the kind of coal used
and the type of furnace and combustion process(A New Life For Coal Ash, n.d.). Coal
ash is produced mainly from burning coal in coal-fired power plants. Two main by-
products of coal ash combustion (the process of burning it) result from coal-fired
operations:
Fly ash is a very fine powdery residue from coal-fired plants (like factories). Fly ash is
captured in the stack. Onsite coal ash ponds should mainly consist of fly ash, which is
made up of heavy metals (for example, mercury, arsenic, copper, and chromium). Fly
ash may pose an inhalation hazard when dry. Dry fly ash can cause respiratory irritation
similar to flu-like symptoms. Fly ash is a fine, powdery material that is a byproduct of
burning coal in power plants to generate electricity. It is also known as coal ash, coal
combustion residuals (CCR), or coal-fired power plant waste. Fly ash is carried away in
the exhaust gases of coal-fired power plants and is collected using particulate matter
control devices such as electrostatic precipitators or baghouses. It is composed of tiny
particles that are primarily made up of silica, alumina, iron, and calcium, along with
smaller amounts of other elements and compounds.
Fly ash has been used in a wide range of applications, including as a partial
replacement for Portland cement in the production of concrete, as a component in the
manufacture of bricks, blocks, and tiles, as a soil amendment in agriculture, and in
various construction and engineering applications. It is valued for its pozzolanic
properties, which allow it to react with calcium hydroxide in cement to form additional
cementitious compounds, improving the strength, durability, and workability of concrete
(Coal Ash, 2019).
9
Bottom ash is a heavier, coarse material that is captured at the bottom of the coal
furnace during the combustion process in coal-fired power plants. It consists of larger,
heavier particles that do not rise with the flue gases and are not captured in the stacks
like fly ash. Bottom ash typically contains a lower concentration of heavy metals
compared to fly ash, but it can contain other potentially hazardous substances such as
cresol and semivolatile organic compounds like polycyclic aromatic hydrocarbons
(PAHs) which are known to be harmful to human health and the environment. Unlike fly
ash, bottom ash is usually not stored in coal ash ponds, as it is typically disposed of
immediately after combustion and sent to a landfill or used in other applications such as
construction materials. Proper handling and disposal of bottom ash, including
adherence to regulatory guidelines and industry best practices, are important to prevent
potential environmental contamination and protect human health.
Fly ash and bottom ash can be mixed together in various proportions to create a
blended coal ash mixture that can be used as a partial replacement for Portland cement
in the production of concrete. This approach is sometimes referred to as "ash blending"
or "ash utilization." The specific proportions of fly ash and bottom ash in the mixture
would depend on their properties, the desired properties of the concrete, and any
regulatory requirements or guidelines. Generally, fly ash is used in smaller proportions
compared to bottom ash due to its higher pozzolanic reactivity. Fly ash typically ranges
from 15% to 30% by mass of the total cementitious material content in concrete, while
bottom ash is usually used as a replacement for fine aggregates, such as sand, and can
typically replace up to 100% of the fine aggregate in concrete. The blended coal ash
mixture can be used in various types of concrete, including structural and non-structural
applications, such as in buildings, roads, bridges, and other infrastructure projects. The
use of blended coal ash in concrete can offer benefits such as improved workability,
reduced permeability, increased durability, and reduced carbon footprint compared to
traditional concrete mixes that use only Portland cement.
Fly ash is known for its pozzolanic reactivity, which contributes to its ability to improve
the properties of concrete. Bottom ash, on the other hand, typically has lower
pozzolanic reactivity. Mixing bottom ash with fly ash may result in a blended ash mixture
with reduced pozzolanic activity, which can impact the strength, durability, and other
properties of the concrete. Proper proportioning and testing of the blended ash mixture
are important to ensure that it meets the desired performance requirements(Nanda &
Rout, 2021).
10
When fly ash and bottom ash are properly treated and used in the production of
concrete, it can be beneficially reused, and their potential hazards can be mitigated. In
fact, incorporating fly ash and bottom ash into concrete has been a common practice in
many countries for several decades, as it can improve the performance and durability of
concrete, reduce the use of cement (which is a major source of carbon emissions), and
provide a sustainable solution for managing these waste materials.
Through a process called pozzolanic reaction, fly ash and bottom ash react with the
calcium hydroxide in cement to form additional cementitious compounds, which
contribute to the strength and durability of concrete. This process helps to immobilize
any potential hazardous elements in the ash, reducing their leachability and overall
environmental impact. However, it's important to note that the safe use of fly ash and
bottom ash in concrete depends on proper handling, storage, and quality control
measures. It's crucial to follow established guidelines and regulations for the beneficial
use of these materials in concrete production to ensure that potential hazards are
effectively managed and minimized.
Pozzolanic property refers to the ability of certain materials to react with calcium
hydroxide (Ca(OH)2) in the presence of water to form cementitious compounds. These
cementitious compounds contribute to the strength, durability, and other properties of
concrete. The materials that exhibit pozzolanic properties are commonly referred to as
pozzolans. Pozzolanic materials can be of natural or artificial origin. Some examples of
natural pozzolans include volcanic ash, calcined clay, and diatomaceous earth, while
examples of artificial or industrial pozzolans include fly ash, silica fume, and blast
furnace slag.
When pozzolanic materials are finely ground and mixed with calcium hydroxide and
water, they undergo a chemical reaction called pozzolanic reaction. During this reaction,
calcium hydroxide reacts with the silica and alumina present in the pozzolanic material
to form calcium silicate hydrates (C-S-H) and calcium aluminate hydrates (C-A-H),
which are similar to the hydration products formed during the cement hydration process.
These cementitious compounds contribute to the strength and durability of concrete by
filling in the pores and voids in the concrete matrix, reducing permeability, and
improving the overall microstructure of the concrete.
11
During the curing process, concrete may be susceptible to cracking when exposed to
direct sunlight. This is primarily due to the effects of temperature variations, rapid
drying, and insufficient moisture. Understanding and implementing proper curing
practices can help minimize the risk of cracking under the sun.
One factor that can contribute to cracking is temperature variations. When concrete is
exposed to intense sunlight, the outer surface can heat up more quickly than the inner
portions, leading to thermal stresses. If these stresses become excessive, they can
cause the concrete to crack.Rapid drying is another concern when curing concrete in
sunlight. Sunlight can accelerate the evaporation of moisture from the surface, causing
it to dry too quickly. As a result, the surface may shrink and develop tensile stresses,
which can result in cracking.Furthermore, the availability of moisture is vital during the
curing process. Excessive evaporation caused by the sun can deplete the concrete of
necessary moisture, affecting its hydration and strength development. Insufficient
moisture can weaken the concrete and increase the likelihood of cracking.To mitigate
the risk of cracking under sunlight during concrete curing, it is essential to follow proper
curing practices. Moist curing is crucial,involving the application of water, wet burlap, or
curing membranes to keep the concrete moist. This helps maintain a favorable moisture
balance and reduces the potential for drying-related cracks.Controlling the temperature
of the curing environment is also important. Direct sunlight, especially during hot and
sunny conditions, should be avoided. Using shading techniques like sunshades or
reflective covers can help minimize temperature fluctuations and reduce the risk of
thermal stress-induced cracking.Extending the duration of the curing process beyond
the initial setting time is recommended. This allows the concrete to continue gaining
strength and decreases its susceptibility to cracking.Providing early-age protection,
such as using plastic sheeting or curing blankets, can also help retain moisture and
prevent excessive evaporation during the critical early stages of curing.By implementing
these proper curing techniques and taking precautions to minimize the effects of direct
sunlight, the potential for cracking in cured concrete can be significantly reduced. This
results in stronger, more durable concrete structures.
While fly ash, bottom ash, and coral reef are all materials, they do not share many
common components.Fly ash and bottom ash are byproducts of coal combustion,
whereas coral reef is a natural formation made up of living organisms. However, there is
one component that fly ash, bottom ash, and coral reef share, and that is calcium.
Calcium is a significant component found in all three materials. In fly ash and bottom
13
ash, it originates from the calcium compounds present in coal, such as calcium
carbonate. In coral reef, calcium is derived from the calcium carbonate structures built
by marine organisms.In fly ash and bottom ash, calcium oxide (CaO) is a common
component, which is derived from calcium carbonate. In coral reef, the calcium
carbonate structures are made up of calcium, carbon, and oxygen (CaCO3).While
calcium is the only significant common component among fly ash, bottom ash, and coral
reef, it plays a crucial role in the properties and behavior of each material. In fly ash and
bottom ash, calcium oxide influences the reactivity and alkalinity of the ashes. In coral
reef, calcium carbonate provides the structural support for the reef and contributes to
the overall stability of the marine ecosystem.Overall, while fly ash, bottom ash, and
coral reef have very different origins and properties, they share calcium as a common
component, which is essential to their composition and behavior.
CONCEPTUAL FRAMEWORK
Coal Ash
Cementitious
Pozzolanic
Geopolymer
Observation
THE PROBLEM
The purpose of this study is to determine the best main byproduct to use as a partial
cementitious resource in production of artificial coral reef. This study specifically ought
to determine the following questions:
1. How does the amount of water affect the compactibility of the byproduct in the
concrete?
2. What extent does the humidity underwater affect the curing process of the concrete?
HYPOTHESIS
16
Alternative Hypothesis: If the byproduct in the concrete withstand underwater then it can
be a good partial cementitious in production of artificial coral reef.
Null Hypothesis: If the byproduct in the concrete cannot withstand underwater then it
will not be a good partial cementitious in production of artificial coral reef.
The Toledo community will be benefited of this study, since most of them depend on
fishing for all or part of their incomes.
The focus of this study will determine the best main byproduct to use as a partial
cementitious resource in production of artificial coral reef. This study will use fly ash and
bottom ash from GBP, water, tie wire, shovel, trovel, scissors paint brush, screen
mesh, pliers, and large Bukag. This study will be conducted on _______ at Toledo City
Science High School, Ilihan, Toledo City.
RESEARCH METHODOLOGY
Research Design
The researchers used the quantitative research method to collect and analyze
numerical data. Definition of the quantitative research is that researchers use to test
theories based on numerical and statistical evidence.
Research Environment
17
The researchers will gather the materials and produce their artificial coral reef in Toledo
City. They will conduct their experiment in Toledo City Science High School (TCSHS).
The testing area will be specifically in Global Business Power Corporation.
Research Instruments
To create concrete and mortar that adhere to the appropriate building industry
standards, high-quality cement is required. A wide variety of sample preparation and
cement testing equipment is designed and produced by ELE International in accordance
with international standards for the evaluation of fineness, consistency, setting time,
workability, flow, strength, soundness, heat of hydration, and chemical composition.
specific gravity (relative density) of hydration cement and fly ash Including the Blaine
Apparatus that is used to employed for fineness determination. In determining The air
content and density of mortar, masonry cement and lime can be determined by the
pressure method, using an air entrainment meter.
Research Procedure
Definition of Terms
Fly Ash and Bottom Ash – This materials are the main variable.
Water - the key ingredient, which when mixed with cement, forms a paste that
Hand trovel – Used to apply the mixture to the bukag that is covered by screen mesh.
Screen Mesh – Used to cover the bukag making the final product more stable and no
BIBLIOGRAPHY
Akhtar, M. N., Tarannum, N., Akhtar, M. N., & Tarannum, N. (2018). Flyash as a
Resource Material in Construction Industry: A Clean Approach to Environment
Management. In Sustainable Construction and Building Materials. IntechOpen.
https://doi.org/10.5772/intechopen.82078
Artificial Coral Reefs Boost Fish Colonies Better Than Natural Reefs, Say Scientists.
(2021, October 6). IndiaTimes. https://www.indiatimes.com/technology/science-and-
future/artificial-coral-reefs-scientific-study-551038.html
https://www.ispatguru.com/fly-ash
Abdullah, M. H., Rashid, A. S. A., Anuar, U. H. M., Marto, A., & Abuelgasim, R. (2019).
012006. https://doi.org/10.1088/1757-899X/527/1/012006
https://blogs.qub.ac.uk/geopolymer/geopolymer-background/
Hannan, J. (2015, June 2). Chemical Makeup of Fly and Bottom Ash Varies
https://www.thermofisher.com/blog/mining/chemical-makeup-of-fly-and-bottom-
ash-varies-significantly-must-be-analyzed-before-recycled/
Nanda, B., & Rout, S. (2021). Properties of concrete containing fly ash and bottom ash
Singh, N. B., Kumar, M., & Rai, S. (2020). Geopolymer cement and concrete:
https://doi.org/10.1016/j.matpr.2020.04.513
Walker, R., & Pavía, S. (2011). Physical properties and reactivity of pozzolans, and their
K Slump Test of concrete | Workability of Concrete Test |. (2018, July 13). CIVIL READ.
https://civilread.com/k-slump-test-of-concrete/
P,
A.
I. (2020, May 23). Fly Ash—Uses, Properties, Classification and Advantages—Civil
Wale. https://civilwale.com/fly-ash/
septech_admin. (2021, April 30). The Environmental Benefits Of Using Fly Ash In
Concrete | STET. ST Equipment & Technology (STET). https://steqtech.com/the-
environmental-benefits-of-using-fly-ash-in-concrete/
Shieh, C.-S., & Duedall, I. W. (1995). Possible Use of Ash Residues for the
Construction of Artificial Reefs at Sea. Chemistry and Ecology, 10(3–4), 295–304.
https://doi.org/10.1080/02757549508037685
US EPA, O. (2014, December 16). Frequent Questions about the 2015 Coal Ash
Disposal Rule [Other Policies and Guidance]. https://www.epa.gov/coalash/frequent-
questions-about-2015-coal-ash-disposal-rule
3 Ways Moisture Affects Concrete Strength. (n.d.). Retrieved March 16, 2023, from
https://www.polygongroup.com/en-US/blog/3-ways-moisture-affects-concrete-strength/