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Acids, Bases and Salts Notes
Acids, Bases and Salts Notes
Acids, Bases and Salts Notes
Khan
7.2
pH is a measure of the Hydrogen ion (H+) concentration (degree of acidity) in a solution. The pH
scale is a numbered scale from 0 to 14. A pH of 7 indicates that the solution is neutral. A pH of
less than 7 indicates that the solution is acidic. A pH of greater than 7 indicates that the solution
is alkaline. pH can be measured using universal indicators (paper or liquid). When placed in a
solution to be tested, the universal indicator changes to different colours which is then compared
with a colour chart that corresponds to different pH values. To get an accurate measure of pH, an
electronic pH meter can be used.
7.3
The strength of an aqueous acid or alkali can be determined by finding its pH and is dependent
on degree of ionization when dissolved in water.
A strong acid is fully ionized when dissolved in water. The acid molecules fully ionize making
the concentration of H+ ions very high leading to low pH values.
Egs. HCl (aq) → H+ (aq) + Cl- (aq) Hydrochloric Acid
HNO3 (aq) → H+ (aq) + NO3- (aq) Nitric Acid
H2SO4 (aq) → 2H+ (aq) + SO42- (aq) Sulfuric Acid
H3PO4 (aq) → 3H+ (aq) + PO43- (aq) Phosphoric Acid
A weak acid is only partially ionized when dissolved in water. The acid molecules partially
ionize giving a mixture of acid molecules and H+ ions. The concentration of H+ ions is low
leading to pH values of < 7 to about 4.
Egs. CH3COOH (aq) H+ (aq) + CH3COO- (aq) Ethanoic Acid
H2CO3 (aq) 2H+ (aq) + CO32- (aq) Carbonic Acid.
A strong alkali is fully ionized when dissolved in water. The alkali ions fully ionize making the
concentration of OH- ions very high leading to very high pH values.
Egs. NaOH (aq) → Na+ (aq) + OH- (aq) Sodium Hydroxide
KOH (aq) → K+ (aq) + OH- (aq) Potassium Hydroxide
A weak alkali is only partially ionized when dissolved in water. The alkali molecules partially
ionize giving a mixture of alkali molecules and OH- ions. The concentration of OH- ions is low
leading to pH values of >7 to about 11.
Eg. NH3 (g) + H2O (l) NH4+ (aq) + OH- (aq) Ammonia gas to Ammonium cation
CSEC Chemistry: Section A – Principles of Chemistry Mr. Khan
7.4
Reactions of non-oxidizing acids.
1) Reaction with reactive metals
Acids react with reactive metals to form a salt and Hydrogen gas.
Eg. Zn (s) + 2HCl (aq) → ZnCl2 (aq) + H2 (g)
Zn (s) + 2H+ (aq) → Zn2+ (aq) + H2 (g) (ionic equation)
Hydrogen gas is a colourless, odourless gas. When a lighted splint is placed in the gas collected
in a test tube, a “pop” is heard.
2) Reaction with carbonates.
Acids react with carbonates to form a salt, water and carbon dioxide gas.
Eg. Na2CO3 (aq) + H2SO4 (aq) → Na2SO4 (aq) + H2O (l) + CO2 (g)
CO32- (aq) + 2H+ (aq) → H2O (l) + CO2 (g) (ionic equation)
Carbon Dioxide gas is a colourless, odourless gas. When the gas is bubbled through colourless
lime water (Calcium Hydroxide solution), the lime water turns white (a white precipitate forms).
If excess gas is bubbled, the precipitate redissolves and the solution turns colourless.
3) Reaction with Hydrogen Carbonates.
Acids react with hydrogen carbonates to form a salt, water and carbon dioxide gas.
Eg. Mg(HCO3)2 (aq) + 2HCl (aq) → MgCl2 (aq) + 2H2O (l) + 2CO2 (g)
HCO3- (aq) + H+ (aq) → H2O (l) + CO2 (g) (ionic equation)
4) Reaction with bases.
Acids react with bases to form salt and water. This is a neutralization reaction.
Egs. CuO (s) + H2SO4 (aq) → CuSO4 (aq) + H2O (l)
CuO (s) + 2H+ (aq) → Cu2+ (aq) + H2O (l) (ionic equation)
2NaOH (aq) + H2SO4 (aq) → Na2SO4 (aq) + 2H2O (l)
OH- (aq) + H+ (aq) → H2O (l) (ionic equation)
CSEC Chemistry: Section A – Principles of Chemistry Mr. Khan
7.6
Reactions of bases
1) Reaction with acids
Bases react with acids to form a salt and water in a neutralization reaction.
2) Reaction with Ammonium salts
Bases react with ammonium salts to produce a salt, water and ammonia gas.
Eg. When heated: (NH4)2SO4 (s) + Ca(OH)2 (s) → CaSO4 (s) + 2H2O (l) + 2NH3 (g)
When heated: 2NH4Cl (s) + CaO (s) → CaCl2 (s) + H2O (l) + 2NH3 (g)
NH3 (g) or ammonia gas is a colourless gas with a pungent odour. This gas turns moist red litmus
paper blue.
7.7
Solubilities of salts and bases
Salts
1) Sulfates – All sulfates are soluble in water except Barium, Lead and Calcium.
2) Nitrates – All nitrates are soluble in water.
3) Chlorides – All chlorides are soluble in water except Lead and Silver. In hot water, Lead
Chloride becomes soluble.
4) Carbonates – All carbonates are insoluble in water except Sodium, Potassium and
Ammonium.
Bases
1) Oxides – All are insoluble in water except Calcium, Potassium and Sodium which react to
form Hydroxides in water.
2) Hydroxides – All are insoluble in water except Sodium, Potassium and Ammonium. Calcium
Hydroxide is slightly soluble.
CSEC Chemistry: Section A – Principles of Chemistry Mr. Khan
(ii) Magnesium Sulfate – This is the major component of Epsom salt. When taken orally, it acts
as a laxative. When added to bath water, it is believed to relieve stress, ease aches and pains,
reduce inflammation, and help cure skin problems.
7.9
A monobasic acid produces one H+ ion per molecule of acid in aqueous solution.
Egs. HCl (aq) → H+ (aq) + Cl- (aq) Hydrochloric Acid
HNO3 (aq) → H+ (aq) + NO3- (aq) Nitric Acid
A normal salt is formed when all of the H+ ions in an acid are replaced by metal or ammonium
cations.
Eg. H2SO4 (aq) + 2NaOH (aq) → 2H2O (l) + Na2SO4 (aq)
H3PO4 (aq) + 3NaOH (aq) → 3H2O (l) + Na3PO4 (aq)
Sodium Sulfate and Sodium Phosphate are normal salts because all of the H+ ions from the acids
they were formed from were replaced by Na+ cations.
An acid salt is formed when the H+ ions in an acid are partially replaced by metal or ammonium
cations.
Egs. H2SO4 (aq) + NaOH (aq) → H2O (l) + NaHSO4 (aq)
H3PO4 (aq) + 2NaOH (aq) → 2H2O (l) + Na2HPO4 (aq)
H3PO4 (aq) + NaOH (aq) → H2O (l) + NaH2PO4 (aq)
Sodium Hydrogen Sulfate, Sodium Hydrogen Phosphate and Sodium Dihydrogen Phosphate are
acid salts because all of the H+ ions from the acids they were formed from were not replaced by
Na+ cations.
NB: With Sulfuric Acid and Sodium Hydroxide, to form the normal salt, 1 mole of acid reacts
with 2 moles of the base, and to form the acid salt, 1 mole of acid reacts with 1 mole of the base.
CSEC Chemistry: Section A – Principles of Chemistry Mr. Khan
7.10
Neutralization reactions
Determining neutralization point in a neutralization reaction
1) Indicators – Indicators are used to determine whether a solution is an acid or an alkali. They
contain dyes that are one colour in an acidic solution and another colour in an alkaline solution.
Commonly used indicators are given in the table below.
Indicator Colour with acid Colour with alkali
Litmus Red Blue
Methyl Orange Red Yellow
Phenolphthalein Colourless Pink
Screened Methyl Orange Red Green
The neutralization point or equivalence point is the point in a neutralization reaction when the
number of moles of H+ ions is equal to the number of moles of OH- ions, that is, neutralization
occurs and the pH of the mixture is 7. When a titration is being carried out, the endpoint is
determined when some sort of physical change occurs to indicate neutralization (colour change,
temperature change, electrical conductivity change). The endpoint corresponds to the
neutralization point.
Using a pipette, a fixed volume of the alkali is placed into a conical flask. A few drops of an
indicator are added to the flask. The burette is filled with acid and the initial reading is recorded.
The acid is then released into the flask slowly until the colour of the solution changes when a
single drop of acid is added from the burette. This burette reading is the final reading and is
recorded. When the initial burette reading is subtracted from the final burette reading, the volume
of acid required to completely neutralize the specific volume of alkali in the flask is found, that
is, the neutralization point is found.
2) Temperature changes – Using a pipette, a fixed volume of an alkali is added to an insulated
container. The temperature of this alkali is recorded. The burette is filled with acid. Small
increments of acid of the same volume are added to the alkali and the temperature of the mixture
in the insulated container after each addition is recorded. The experiment is stopped after a few
readings of consecutive temperature drops are recorded. A graph is drawn of temperature vs
volume of acid added. Two straight best fit lines are drawn and where the lines intersect, the
corresponding acid volume is extrapolated. This represents the volume of acid required to
completely neutralize the specific volume of alkali in the insulated container, that is, the
neutralization point is found. This type of titration is called a thermometric titration. In this graph
drawn, there is a line of positive gradient that represents temperature increasing as the reaction is
still going on and heat is being given off when acid is added, there is a line of negative gradient
that represents temperature decreasing as no reaction is occurring so the mixture is cooling when
acid is added, and there is the point of intersection of the lines that represents the neutralization
point where the reaction ended.
CSEC Chemistry: Section A – Principles of Chemistry Mr. Khan
Example
CSEC Chemistry: Section A – Principles of Chemistry Mr. Khan
CSEC Chemistry: Section A – Principles of Chemistry Mr. Khan
Quantitative Analysis
Example #1
CSEC Chemistry Paper 2 Jan 2006 Question 1
In titrations, you are using a substance of known concentration (Standard solution/titrant) to find
the concentration of another substance (analyte/titrand).
1. (a) (i)
Titration 1 Titration 2 Titration 3
Final Burette Reading (cm3) 25.50 37.30 40.50
Initial Burette Reading (cm3) 0.50 12.20 15.45
Volume Solution X Used (cm3) 25.00 25.10 25.05