Material Safety Date Sheet

Cancel and replaces

MSDS - 001 Review: 05 Date: 13/06/2016 version: All the previous
ones
Pág: 1 de 14
KAMORAN

Section 1 – Product and Company Identification

Manufacturer:
Química Real Ltda.
Emergency Phone:
Rua Nair Pentagna Guimarães, 762.
Química Real: +55 (31) 3427-4545
Heliópolis – Belo Horizonte / MG
CHEMTREC:
CEP: 31.741-545
1-800-424-9300 (América do Norte)
Tel: +55 (31) 3057-2000
1-703-527-3887 (Internacional)
Fax: +55 (31) 3057-2036
E-mail: quimicareal@quimicareal.com.br

Commercial Name: Kamoran

Main use: Mixture used for ethanol fermentation

Section 2 – Hazards Identification

Product Hazard Classification: Oral / Inhalation Acute Toxicity – Category 2

Classification system: Norma ABNT –NBR 14725-2:2009 – reviewed version 2:2010.

Globally Harmonized System for the classification and labeling of chemical products, ONU.

Other hazards that do not result in a classification: People with a history of allergies,
contact dermatitis or chronic rashes should take special precautions to avoid contact or
exposure to the product dust.

PTOPER ELEMENTS LABELING

Pictograms:

Word of warning: DANGER

 Material Safety Date Sheet

Cancel and replaces

MSDS - 001 Review: 05 Date: 13/06/2016 version: All the previous
ones
Pág: 2 de 14
KAMORAN

Hommel Diamond:

Química Real Laboratory Code:

Health: 3 Fire 1 Reactivity 0

Hazard statements: Fatal if swallowed

Fatal if inhaled

Precautionary Statements: (Acute Toxicity – Oral)

Precautionary prevention statements: Wash the hands carefully after use.

Do not eat, drink or smoke during the use of this product.
Precautionary statements in response to emergency: In case of ingestion: Contact
immediately the CENTRO DE INFORMAÇÃO TÓXICOLOGICA / TOXICOLOGICAL
INFORMATION CENTER (0800 721 3000) or a doctor.
For specific treatment consult a doctor.
Wash the mouth.
Precautionary statements for storage: Store in locked place.
Precautionary statements for disposal: Dispose the contents / container in suitable
location.

Precautionary Statements: (Acute Toxicity – Inhalation)

Precautionary prevention statements: Do not inhale dust/ fume/ gas/ mist /vapors /spray.
Contaminated work clothes cannot leave the work place.
Use breath protection equipment.
Precautionary statements in response to emergency in case of inhalation: Remove victim
to a ventilated place and keep it in rest in comfortable position for breathing.
Contact immediately the CENTRO DE INFORMAÇÃO TÓXICOLOGICA/
TOXICOLOGICAL INFORMATION CENTER (0800 721 3000) or a doctor.
Precautionary statements for storage: Store in ventilated place.
 Material Safety Date Sheet

Cancel and replaces

MSDS - 001 Review: 05 Date: 13/06/2016 version: All the previous
ones
Pág: 3 de 14
KAMORAN

Precautionary statements for disposal: Keep the containers tightly closed.

Dispose of contents/container in suitable place.

Section 3 – Composition and Information about the Ingredient s

Antibacterial mixture
Common Chemical Name or technical name: Kamoran
Chemical Nature: Semi - synthetic origin.

Ingredients contributing to the hazard:

Chemical Name / Hazard Classification Concentration

CAS
Common Range
T Toxic
Monensin Sodium 22373-78-0 > 80%
Category 2
The product is not classified as
SLS hazardous according to < 20%
Regulation (CE) No. 1272/2008
The product is not classified as
Silica hazardous according to < 5%
Regulation (CE) No. 1272/2008.

Section 4 – First Aid Actions

Eyes: Hold eyelids open and wash with water for 15 minutes. Seek medical attention
immediately. Immediate rinsing may prevent permanent damages.

Skin: Remove contaminated clothing and wash the affected regions with soap and water.
If irritation occurs, seek medical advice.

Inhalation: Remove the victim from the affected area immediately. Take to fresh air and if
necessary perform artificial respiration (mouth to mouth). Seek medical attention.
 Material Safety Date Sheet

Cancel and replaces

MSDS - 001 Review: 05 Date: 13/06/2016 version: All the previous
ones
Pág: 4 de 14
KAMORAN

Ingestion: Request a physician or contact the poison control center. Drink 1-2 glasses of
water, if the victim is conscious. Do not induce vomit. Do not give anything by mouth if the
victim is unconscious.
The most important symptoms and effects, both acute and delayed: Kamoran
contains Monensin Sodium, highly toxic and may cause burns or permanent damages to
the eye tissues. It may be irritating to the skin and the respiratory system, and may
probably cause allergic reactions. The effects of the exposure may include changes in the
heartbeat/rhythm and in the tissues of the heart and muscles.

Notes to the physician: There is no specific antidote. But symptomatic and supportive
treatment. Toxic if swallowed. Irritating to the respiratory system and the skin. Risk of
permanent eye damage.

Section 5 – Firefighting Measures

Appropriate Fire Extinguishers: Water, carbon dioxide, chemical powder, foam or Halon.

Specific hazards of the substance or mixture: As a particulate material, there is the

possibility to form some dust mixtures in the air that may explode if in contact with an
ignition source .It may generate toxic fumes when exposed to heat or fire.

Firefighting team protective measures: Respiratory system protective equipment and

full protective clothing. Fight fire or monitor the nozzles from the maximum possible
distance. If possible fight fire to the downwind side. For large fires use hose supports or
monitor the nozzles. If this is not possible leave the area.

Section 6 – Control Measures for Spill or Leak

Personal precautions:

For people who are not part of the emergency services: Eliminate all the ignition
sources. Do not smoke in the risk area and avoid occurring sparks or flames. Isolate the
area within a 100 meters radius in all directions. Do not touch the damaged containers or
the spilled material without appropriate clothing. Avoid inhalation, eye and skin contact.
Use personal protective equipment as described in section 8.
 Material Safety Date Sheet

Cancel and replaces

MSDS - 001 Review: 05 Date: 13/06/2016 version: All the previous
ones
Pág: 5 de 14
KAMORAN

For the staff who are part of the emergency services: Use full PPE with safety glasses,
PVC protective gloves and waterproof clothing.

Precautions to the environment: Avoid contact with water ways, reservoirs and lakes.
Moderate to slightly toxic for aquatic animals

Methods and materials for containment and cleaning: If possible stop the spill/leak flow
and make embankments, preventing the material to reach the drains, soil and water ways.
Prevent the dust dispersion in the air and stay tuned to possible risks of explosions when
using electrical equipments. For final disposal proceed according to FISPQ section 13.
Major proportion spills resulting from traffic accidents, etc, should be immediately reported
to CHEMTREC and Quimica Real, in order to receive assistance.

Differences in the actions in large and small leaks: There are no differences between
the actions in large and small leaks of this product.

Section 7 – Handling and Storage

Appropriate Technical measures for handling

Precautions for safe handling: For the product safe handling it is recommended the use
of PPE (gloves, respiratory protective masks and glasses), as well as to avoid skin contact
with the product, with strong oxidizing agents and the use of compressed air equipment
so as there is no dispersion of the product.

Hygiene Measures: Eating and smoking is forbidden in the work place. It is also
recommended to wash the hands after handling the product, remove contaminated cloths
and protective equipments before entering eating areas

Safe storage conditions including any incompatibility: Store in dry place and protected
from light. Protect against moisture, heat and strong oxidizing agents (permanganates,
peroxides, nitric acid). Maximum stacking four 10kg boxes. The product should not be
used after the expiring date printed in the package.
 Material Safety Date Sheet

Cancel and replaces

MSDS - 001 Review: 05 Date: 13/06/2016 version: All the previous
ones
Pág: 6 de 14
KAMORAN

Section 8 – Exposure Control and Personal Protection

Control Parameters:

Occupational exposure Limits: Monensin Sodium - CAS 22373-78-0 - LEG: 15

micrograms/m3 TWA per 12 hours.

Engineering Control Measures: Promote mechanical ventilation and exhaustion system

direct to outside. These measures help to reduce the exposure to the product. It is
recommended to have emergency showers and eye washers available in the worksite.
Keep the substance concentrations or mixtures below the required occupational exposure
limits.

Personal protection measures:

Respiratory Protection: Use approved respiratory protection equipment

Eyes / Face Protection: Use chemical resistant eye protector and/or face protector.

Skin and body Protection: In the production environment use chemicals resistant
clothing, gloves, and safety goggles.

Thermal hazards: There are no thermal hazards.

Other Handling Precautions: DANGEROUS FOR HUMANS AND PETS – KEEP AWAY
FROM CHILDREN´S REACH.

PRODUCT NOT INTENDED TO HUMANS CONSUMPTION.

 Material Safety Date Sheet

Cancel and replaces

MSDS - 001 Review: 05 Date: 13/06/2016 version: All the previous
ones
Pág: 7 de 14
KAMORAN

Section 9 – Physical and Chemical Properties

Aspect: Solid. Microcrystalline white to brown powder, with water-soluble packaging.

Odor: Slight musty
pH: 6,0 to 9,0 (50% aqueous solution)
Melting Point: below 269 C
Boiling Point: Not applicable
Flashing Point: Not applicable
Evaporation Rate: Not applicable
Flammability: Not applicable
Flammability or explosiveness lower / upper limits: Not applicable
Vapor Pressure: Not applicable
Vapor Density: Not applicable
Density: Not available
Solubility in water: Slightly soluble
Partition Coefficient – n-octane/water: Not available
Auto ignition Temperature: Not available
Decomposition Temperature: Not available
Viscosity: Not applicable

Section 10 – Stability and Reactivity

Stability and Reactivity: Stable under normal temperature and pressure conditions.

Possibility of Hazardous Reactions: May emit toxic fumes when heated to the
decomposition point.

Conditions to be avoided: The powder dispersion in the air may cause explosion under
ignition source.

Incompatible Materials: May react with strong oxidizing agents (ex.: peroxides,
permanganates, nitric acid, etc.) and acids.
 Material Safety Date Sheet

Cancel and replaces

MSDS - 001 Review: 05 Date: 13/06/2016 version: All the previous
ones
Pág: 8 de 14
KAMORAN

Hazardous Decomposition Products: By burning, toxic fumes emission of POx and

SOx. Plus CO and CO2.

Section 11 – Toxicological Information

There are no data available related to the product mixture or formula. Please see below
information about the related ingredient(s) or material (s)

Information about Monensin Sodium in 24% solution.

Acute Toxicity

DL50 oral (rats): 34mg/Kg

DL50 cutaneous (rabits): 500mg/Kg
CL50 inhalation (rats): 370 mg/Kg per 1hour.

Serious eye damage/ eye irritation: the contact with the solid may cause permanent
damages.

Skin corrosion/irritation: contact with the solid may cause irritation

Skin or respiratory sensitization: the contact with the solid may change heart beat. It is
not expected the product cause skin sensitization.

Germ cells Mutagenicity: It is not expected that the product cause germ cells
mutagenicity.

Carcinogenicity: It is not expected that the product presents Carcinogenicity.

Reproductive Toxicity: No effects were identified in studies with animals.

Toxicity to the organs – specific targets – single exposure: In-coordination, reduced

activity, body muscles weakness, diarrhea, reduced weight gain. Slightly irritant to the skin.
Corrosive to the eyes, however immediate rinsing prevents permanent damages
.
 Material Safety Date Sheet

Cancel and replaces

MSDS - 001 Review: 05 Date: 13/06/2016 version: All the previous
ones
Pág: 9 de 14
KAMORAN

Toxicity to the organs – specific targets – repeated exposure: Effects to the heart
(degenerative and reparative changes on the tissues, ECG changes and congestive heart
failure), effects on the muscles (change in the skeletal muscles, high enzyme levels in the
blood from muscles origin). Reduced body weight gain, weight increase of kidneys, thyroid
gland, adrenal gland, prostate, testicles, liver and spleen.

Aspiration Hazards: It is not expected that the product presents hazards due to
aspiration.

Section 12 – Ecological Information

Environmental effects, product procedures and impacts

There are no environmental data available about the product mixture or formula. Please
see below the environmental information about the related ingredient (s) or material (s).

Monensin Sodium

Ecotoxicity: Moderate to slightly toxic to fish. Moderately toxic to aquatic invertebrates

and “bobwhite quail” (bird). Practically no toxic for ducks and worms.

Persistence and degradability: It is not believed that the product volatilization occurs. It
is not expected that there is the material bioconcentration in aquatic organisms.

Bioaccumulative Potential: The substance is not persistent in the environment due to the
biodegradation and photolysis procedures.

Soil Mobility: Not determined.

Other adverse effects: Not determined.

Section 13 – Considerations about treatment and disposal

Recommended methods for treatment and disposal applied to:

 Material Safety Date Sheet

Cancel and replaces

MSDS - 001 Review: 05 Date: 13/06/2016 version: All the previous
ones
Pág: 10 de 14
KAMORAN

Product or waste: should be carried out according to all the applicable laws or in
appropriate locations according to current local regulations

Product waste or remains: The disposal of any material used in the product cleaning,
as well as the remains should be carried out according to all the concerning laws or in
appropriate location according to the current local regulations.

Contaminated packaging: Do not re-use empty packaging. They may contain the product
remains and should be kept closed and sent for disposal according to all the concerning
laws or in appropriate locations according to the current local regulations.

Section 14 – Information about Transport

National and International Regulations

Regulatory Organizations:

ANTT / DOT (Land Transport):

ONU: 2811
Proper Shipping Name: Toxic Solid Organic Product, n.o.s. (Monensin Sodium)
Risk Class /Subclass: 6,1
Risk Number: 60
Packaging Group: II
Hazards to the environment: Avoid contact with waterways, reservoirs or lakes

DAC / ICAO / IATA (Air Transport):

ONU: 2811
Proper Shipping Name: Toxic Solid Organic Product, n.o.s. (Monensin Sodium
Risk Class /Subclass: 6,1
Risk Number: 60
Packaging Group: II
Hazards to the environment: Avoid contact with waterways, reservoirs or lakes
 Material Safety Date Sheet

Cancel and replaces

MSDS - 001 Review: 05 Date: 13/06/2016 version: All the previous
ones
Pág: 11 de 14
KAMORAN

ANTAQ / IMO (Waterways transport):

ONU: 2811
Proper Shipping Name: Toxic Solid Organic Product, n.o.s. (Monensin Sodium
Risk Class /Subclass: 6,1
Risk Number: 60
Packaging Group: II
Hazards to the environment: Avoid contact with waterways, reservoirs or lakes
Section 15 – Information about regulations

Please see below some information about the applicable laws and regulations, selected
mainly for possible use by Química Real. This section should not be understood as a
complete analysis, or the integral reference to all the applicable regulations information.
All the laws and regulations applicable in your country/state must be considered

Regulations: Norm ABNT-NBR 14725:2012

USA Regulations:

Monensin Sodium
TSCA - No
CERCLA - Not included in this list
SARA 302 - Not included in this list
SARA 313 - Not included in this list
Specific substance identified by OSHA – No

SLS
TSCA - Yes
CERCLA - Not included in this list
SARA 302 - Not included in this list
SARA 313 - Not included in this list
Specific substance identified by OSHA – No

Classification and Risk and Safety Statements and Safety established by EC:

Contain Monensin Sodium (C > 80%)

Contain SLS (C < 20%)
T (Toxic)
 Material Safety Date Sheet

Cancel and replaces

MSDS - 001 Review: 05 Date: 13/06/2016 version: All the previous
ones
Pág: 12 de 14
KAMORAN

Xi (Irritant)

Risk Statements:

R 25 – Toxic if swallowed.
R 37/38 – Irritant for the respiratory system and the skin.
R 41 – Risk of serious eye damage.
R 52 – Harmful for aquatic organisms.
Safety Statements:

S 20 – Do not eat or drink during product handling.

S 26 – In case of eye contact, rinse immediately with plenty of water and seek medical
advise
S 28 – Wash skin immediately after contact with the product.
S 36/37/39 – Use appropriate protection clothing, gloves and appropriate eye/face
protection.
S 45 – In case of accident or malaise, seek medical advice immediately (if possible show
the product label).
S 61 – Prevent product release in the environment. Refer to the special isntructions/
Safety Sheets.

Section 16 - Other Information

Please see in this document all the information available about this material handling in the
work place, updated until the date of this publication. All this information is given in good
faith, so we understand it is correct . THIS SAFETY DATA SHEET SHALL NOT BE
UNDERSTOOD AS WARRANTY OF ANY KIND (INCLUDED THE PRODUCT QUALITY
ASSURANCE FOR MARKETING PURPOSES OR ANY OTHER PURPOSE). In case
there is any occurrence involving this material, we do not intend that the information
presented in this safety data sheet replace consultation with duly trained professionals. In
addition, we do not intend that the data contained in this document replace the literature
issued jointly with the final product. Any other use of this product that involves its
combination with other materials, besides ways of use different of those indicated, is the
user´s absolute responsibility. The warning is that any chemical substance handling
requires previous knowledge by the user about the hazards. In the workplace it is for the
product ´s user company to provide the employees and contractors training concerning the
possible risks from the exposure to the chemical product.
 Material Safety Date Sheet

Cancel and replaces

MSDS - 001 Review: 05 Date: 13/06/2016 version: All the previous
ones
Pág: 13 de 14
KAMORAN

For further information please contact:

Química Real Ltda.
Telephone: 55 31 3057-2000

GLOSSARY:

ABNT-NBR = Associação Brasileira de Normas Técnicas

ANTT = Agência Nacional de Transporte Terrestre
ANTAQ = Agência Nacional de Transporte Aquaviário
CAS = Chemical Abstract Service Registry Number (Número Designado pela Organização
de Cadastramento de Informações Publicadas sobre Produtos Químicos)
CERCLA = Comprehensive Environmental Response Compensation and Liability Act (of
1980) (Lei de Responsabilidade e Compensação pela Contaminação do Meio Ambiente -
1980)
CHEMTREC = Chemical Transportation Emergency Center (Central de Emergências de
Transporte de Produtos Químicos)
CO = Monóxido de carbon= Carbon Monoxide
CO2 = Dióxido de Carbono= Carbon Dioxide
DAC = Departamento de Aviação Civil
DL50 = Dosagem Letal = Lethal Dosage
DOT = Department of Transportation (Departamento de Transportes)
EC = Comunidade Européia
EPI = Equipamento de proteção Individual= Personal Protecion Equipment = PPE
FISPQ = Ficha de Informação de Segurança de Produtos Químicos
ICAO/IATA = International Civil Aviation Organization/International Air Transport
Association (Organização Internacional de Aviação Civil/Associação Internacional de
Transporte Aéreo)
IMO = International Maritime Organization (Organização Marítima Internacional)
LEG = Lilly Exposure Guideline (Diretriz da Lilly quanto à Exposição)
MSDS = Material Safety Data Sheet (Ficha de Dados de Segurança)
NA = Não Aplicável, exceto na Seção 14, onde NA = América do Norte
 Material Safety Date Sheet

Cancel and replaces

MSDS - 001 Review: 05 Date: 13/06/2016 version: All the previous
ones
Pág: 14 de 14
KAMORAN

ONU = São números de quatro dígitos atribuídos pelo Comitê de Peritos das Nações
Unidas sobre o Transporte de Mercadorias Perigosas tem o objetivo de identificar as
substâncias perigosas. Por exemplo
OSHA = Occupational Safety and Health Administration (Departamento de Saúde e
Segurança Ocupacional)
POx = Óxido de Fósforo= Phosphorus Oxide
PVC = Policloreto de Vinila = Polyvinyl Chloride
SARA = Superfund Amendments and Reauthorization Act (Lei de Aditamentos e Nova
Autorização da Superfund)
SOx = Óxido de enxofre= Sulfur Oxide
TSCA = Toxic Substances Control Act (Lei de Controle de Substâncias Tóxicas)
TWA = Time Weighted Average (Concentração Média Ponderada pelo Tempo) - 8 horas,
a não ser que seja especificado outro valor
UN = United Nations (Nações Unidas)