CoSHH Assessments

Revision date: 08/01/2020 Revision: 3 Supersedes date: 09/10/2017
SAFETY DATA SHEET

K99 Water Resistant Grease
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier

Product name K99 Water Resistant Grease
Product number 7999
Internal identification GHS22054
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Lubricating grease.
1.3. Details of the supplier of the safety data sheet

Supplier Morris Lubricants
Castle Foregate
Shrewsbury
Shropshire
SY1 2EL
+44 (0) 1743 232200
+44 (0) 1743 353584
sds@morris-lubricants.co.uk
1.4. Emergency telephone number

Emergency telephone +44(0)1743 232200 (08.45 - 17.00 GMT)
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture

Classification (EC 1272/2008)
Physical hazards Not Classified
Health hazards Not Classified
Environmental hazards Not Classified
Classification (67/548/EEC or -
1999/45/EC)
2.2. Label elements

Hazard statements NC Not Classified
Supplemental label EUH210 Safety data sheet available on request.

information
2.3. Other hazards

SECTION 3: Composition/information on ingredients
3.2. Mixtures
1/5
Highly refined mineral oil (C15 - C50) 60-100%

CAS number: —
Classification Classification (67/548/EEC or 1999/45/EC)

Not Classified -
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
Composition comments The data shown are in accordance with the latest EC Directives.
SECTION 4: First aid measures
4.1. Description of first aid measures

General information Get medical attention if any discomfort continues.
Ingestion Do not induce vomiting. Get medical attention if any discomfort continues.
Skin contact Remove contaminated clothing immediately and wash skin with soap and water.
Eye contact Rinse immediately with plenty of water. Remove any contact lenses and open eyelids wide
apart. Continue to rinse for at least 15 minutes. Get medical attention promptly if symptoms
occur after washing.
4.2. Most important symptoms and effects, both acute and delayed
4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor Treat symptomatically
SECTION 5: Firefighting measures
5.1. Extinguishing media

Suitable extinguishing media Extinguish with foam, carbon dioxide, dry powder or water fog.
5.2. Special hazards arising from the substance or mixture

5.3. Advice for firefighters
Protective actions during Control run-off water by containing and keeping it out of sewers and watercourses.
firefighting
Special protective equipment Wear self-contained breathing apparatus.

for firefighters
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions For personal protection, see Section 8. In case of spills, beware of slippery floors and
surfaces.
6.2. Environmental precautions

6.3. Methods and material for containment and cleaning up
Methods for cleaning up Collect spillage for reclamation or disposal in sealed containers via a licensed waste
contractor. Avoid water contacting spilled material or leaking containers.
6.4. Reference to other sections

SECTION 7: Handling and storage
7.1. Precautions for safe handling
2/5
Usage precautions Always remove oil with soap and water or skin cleaning agent, never use organic solvents. Do
not use oil-contaminated clothing or shoes, and do not put rags moistened with oil into
pockets. Avoid spilling, skin and eye contact.
7.2. Conditions for safe storage, including any incompatibilities

Storage precautions Store in tightly-closed, original container in a dry, cool and well-ventilated place.
Storage class Miscellaneous hazardous material storage.
7.3. Specific end use(s)

SECTION 8: Exposure controls/Personal protection
8.1. Control parameters

Occupational exposure limits
Highly refined mineral oil (C15 - C50)
Long-term exposure limit (8-hour TWA): 5 mg/m³
8.2. Exposure controls
Protective equipment
Eye/face protection The following protection should be worn: Chemical splash goggles or face shield.
Hand protection It is recommended that gloves are made of the following material: Polyvinyl chloride (PVC).
Hygiene measures Wash promptly with soap and water if skin becomes contaminated.
Respiratory protection No specific recommendations. Respiratory protection must be used if the airborne
contamination exceeds the recommended occupational exposure limit.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties

Colour Pale straw
Odour Odourless.
Auto-ignition temperature >200°C
9.2. Other information

SECTION 10: Stability and reactivity
10.1. Reactivity
10.2. Chemical stability
Stability Stable at normal ambient temperatures and when used as recommended.
10.3. Possibility of hazardous reactions

10.4. Conditions to avoid
Conditions to avoid Avoid heat, flames and other sources of ignition.
10.5. Incompatible materials

Materials to avoid Strong oxidising agents.
10.6. Hazardous decomposition products
3/5
Hazardous decomposition Oxides of carbon.

products
SECTION 11: Toxicological information
11.1. Information on toxicological effects
General information This product has low toxicity. Only large quantities are likely to have adverse effects on
human health.
Inhalation Unlikely to be hazardous by inhalation because of the low vapour pressure of the product at
ambient temperature.
Ingestion No harmful effects expected from quantities likely to be ingested by accident.
Skin contact Skin irritation should not occur when used as recommended. Repeated exposure may cause
skin dryness or cracking.
Eye contact May cause temporary eye irritation.
SECTION 12: Ecological information
12.1. Toxicity
12.2. Persistence and degradability
Persistence and degradability The product is not readily biodegradable.
12.3. Bioaccumulative potential

Bioaccumulative potential Bioaccumulation is unlikely to be significant because of the low water-solubility of this product.
12.4. Mobility in soil

Mobility The product is non-volatile. The product contains substances which are insoluble in water
and which sediment in water systems.
12.5. Results of PBT and vPvB assessment

12.6. Other adverse effects
SECTION 13: Disposal considerations
13.1. Waste treatment methods

Disposal methods Dispose of waste to licensed waste disposal site in accordance with the requirements of the
local Waste Disposal Authority.
Waste class European Waste Catalogue (EWC) Code: 20 01 26* (greases)
SECTION 14: Transport information
General The product is not covered by international regulations on the transport of dangerous goods
(IMDG, IATA, ADR/RID).
14.1. UN number
Not applicable.
14.2. UN proper shipping name

Not applicable.
14.3. Transport hazard class(es)

No transport warning sign required.
14.4. Packing group
4/5
Not applicable.
14.5. Environmental hazards
Environmentally hazardous substance/marine pollutant

No.
14.6. Special precautions for user

Not applicable.
14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78
and the IBC Code
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations Health and Safety at Work etc. Act 1974 (as amended).
Control of Substances Hazardous to Health Regulations 2002 (as amended).
EU legislation Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16
December 2008 on classification, labelling and packaging of substances and mixtures (as
amended).
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18
December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of
Chemicals (REACH) (as amended).
Guidance Workplace Exposure Limits EH40.

Safety Data Sheets for Substances and Preparations.
15.2. Chemical safety assessment

No chemical safety assessment has been carried out.
SECTION 16: Other information
Revision comments NOTE: Lines within the margin indicate significant changes from the previous revision.
Revision date 08/01/2020
Revision 3
Supersedes date 09/10/2017
SDS number 22054
This information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate
and reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability or
completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.
5/5
SAFETY DATA SHEET

Dot 4 ESP Brake Fluid

Product name Dot 4 ESP Brake Fluid
Product number 7558
REACH registration number n/a Mixture
Identified uses Hydraulic fluid for use in automotive brake and clutch systems
Uses advised against No specific uses advised against are identified.

Castle Foregate
Shrewsbury
Shropshire
SY1 2EL
+44 (0) 1743 232200
+44 (0) 1743 353584


Physical hazards Not Classified
Health hazards Not Classified
Environmental hazards Not Classified
Classification (67/548/EEC or Not classified

1999/45/EC)
2.2. Label elements

Hazard statements NC Not Classified
Supplemental label EUH210 Safety data sheet available on request.

information
2.3. Other hazards

This product does not contain any substances classified as PBT or vPvB.
1/10
3.2. Mixtures
2,2'-OXYBISETHANOL 5-10%
CAS number: 111-46-6 EC number: 203-872-2 REACH registration number: 01-
2119457857-21-0000

Acute Tox. 4 - H302 Xn;R22
STOT RE 2 - H373
2-(2-METHOXYETHOXY)ETHANOL 1-5%
2119475100-52-0000

Repr. 2 - H361d Repr. Cat. 3;R63
2-(2-butoxyethoxy)ethanol 1-5%
2119475104-44-0000

Eye Irrit. 2 - H319 Xi;R36.

General information Get medical attention if any discomfort continues.
Inhalation If spray/mist has been inhaled, proceed as follows. Move affected person to fresh air and
keep warm and at rest in a position comfortable for breathing. Get medical attention if any
discomfort continues.
Ingestion Get medical attention if any discomfort continues. Do not induce vomiting.
Skin contact Remove contaminated clothing immediately and wash skin with soap and water.
Inhalation Upper respiratory irritation.
Ingestion May cause discomfort if swallowed.
Skin contact Prolonged contact may cause redness, irritation and dry skin.
Notes for the doctor Medical personnel seeking to administer first aid are referred to the services of the Poisons
Information Service, who can advise in such instances. There is no specific antidote and
treatment of over exposure should be directed at control of symptoms and the patient's clinical
condition.
2/10
Suitable extinguishing media Extinguish with foam, carbon dioxide, dry powder or water fog.
Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media

Specific hazards Heat from fire could result in drums bursting
Hazardous combustion Fire may also create other unidentified organic gases some of which may be toxic.
products

Protective actions during Control run-off water by containing and keeping it out of sewers and watercourses. Eye
firefighting protection should be worn.
Special protective equipment Wear self-contained breathing apparatus.

for firefighters

Personal precautions For personal protection, see Section 8. In case of spills, beware of slippery floors and
surfaces. Avoid contact with skin, eyes and clothing.

Environmental precautions The product is insoluble in water and will spread on the water surface. Avoid the spillage or
runoff entering drains, sewers or watercourses. Contain spillage with sand, earth or other
suitable non-combustible material.

Methods for cleaning up In case of spillage on water prevent the spread by use of suitable barrier equipment Contain
and absorb spillage with sand, earth or other non-combustible material. Collect and place in
suitable waste disposal containers and seal securely. Residues and empty containers should
be taken care of as hazardous waste according to local and national provisions.

Reference to other sections For personal protection, see Section 8. See Section 11 for additional information on health
hazards. For waste disposal, see Section 13.

Usage precautions Avoid spilling. Avoid the formation or spread of mists in the air Do not eat, drink or smoke
when using this product. Wash hands thoroughly after handling.

Storage precautions Store in tightly-closed, original container in a dry, cool and well-ventilated place. Brake fluid
absorbs water from the atmosphere - always keep containers tightly closed. Avoid
contamination with any other substances and in particular with mineral oils which are
incompatible. Do not store in lined tanks or drums. Suitable bulk storage vessels are
mild/stainless steel tanks fitted with a dry air breathing system or tight head steel drums.
Storage class Miscellaneous hazardous material storage.

Specific end use(s) The identified uses for this product are detailed in Section 1.2.
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2,2'-OXYBISETHANOL
Long-term exposure limit (8-hour TWA): WEL 23 ppm 101 mg/m³
Short-term exposure limit (15-minute): WEL
2-(2-METHOXYETHOXY)ETHANOL
8 hrs TWA 10ppm; 15 mins 50.1 mg/m3
2-(2-butoxyethoxy)ethanol
Long-term exposure limit (8-hour TWA): WEL 10 ppm 67.5 mg/m³
Short-term exposure limit (15-minute): WEL 15 ppm 101.2 mg/m³
WEL = Workplace Exposure Limit
2,2'-OXYBISETHANOL (CAS: 111-46-6)
DNEL Workers - Dermal; Long term systemic effects: 106 mg/kg/day

Workers - Inhalation; Long term systemic effects: 60 mg/m³
Consumer - Dermal; Long term systemic effects: 53 mg/kg/day
Consumer - Inhalation; Long term systemic effects: 12 mg/m³
PNEC - Water, Fresh water; 10 mg/l

- Water, marine water; 1 mg/l
- Water, Intermittent release; 10 mg/l
- STP; 199.5 mg/l
- Sediment (Freshwater); 20.9 mg/kg/sediment dw
- Soil; 1.53 mg/kg
2-(2-butoxyethoxy)ethanol (CAS: 112-34-5)
DNEL Workers - Inhalation; Short term local effects: 101.2 mg/m³

Workers - Dermal; Long term systemic effects: 20 mg/kg/day
Consumer - Inhalation; Short term local effects: 50.6 mg/m³
Consumer - Oral; Long term systemic effects: 1.25 mg/kg/day
PNEC - Water, Fresh water; 1.0 mg/l

- Water, marine water; 0.1 mg/l
- Water, Intermittent release; 3.9 mg/l
- STP; 200 mg/l
- Sediment (Marinewater); 0.4 mg/kg/sediment dw
- Soil; 0.4 mg/kg
2-(2-METHOXYETHOXY)ETHANOL (CAS: 111-77-3)
DNEL Workers - Dermal; Long term systemic effects: 0.53 mg/kg/day

Workers - Inhalation; Long term systemic effects: 50.1 mg/m³
Consumer - Dermal; Long term systemic effects: 0.27 mg/kg/day
4/10
PNEC - Water, Fresh water; 12 mg/l

- STP; 10000 mg/l
- Soil; 2.44 mg/kg
2-[2-(2-BUTOXYETHOXY)ETHOXY]ETHANOL (CAS: 143-22-6)
DNEL Workers - Dermal; Long term systemic effects: 50 mg/kg/day

Consumer - Oral; Long term systemic effects: 2.5 mg/kg/day
PNEC - Water, Fresh water; 1.5 mg/l

- STP; 200 mg/l
- Soil; 0.45 mg/kg
Oral - ; 111 mg/kg
Appropriate engineering Provide adequate general and local exhaust ventilation. Observe any occupational exposure
controls limits for the product or ingredients.
Eye/face protection Eyewear complying with an approved standard should be worn if a risk assessment indicates
eye contact is possible. The following protection should be worn: Chemical splash goggles or
face shield.
Hand protection The most suitable glove should be chosen in consultation with the glove
supplier/manufacturer, who can provide information about the breakthrough time of the glove
material.
Hygiene measures Use engineering controls to reduce air contamination to permissible exposure level. Wash
promptly with soap and water if skin becomes contaminated.
Respiratory protection No specific recommendations. Respiratory protection must be used if the airborne
contamination exceeds the recommended occupational exposure limit.
Thermal hazards Not anticipated under normal conditions of use. The product is combustible if heated
excessively and an ignition source is applied.

Appearance Clear liquid.
Colour Colourless to amber (although some brake fluids may be dyed.)
Odour Bland.
5/10
Odour threshold Very low odour.
pH 7.0 to 11.50
Melting point <-50°C
Initial boiling point and range >260°C @
Flash point > 120°C
Evaporation rate Negligible.
Upper/lower flammability or Not known.

explosive limits
Other flammability Product is not flammable but on excessive heating may become combustible.
Vapour pressure <2 mbar @ 20°C
Vapour density Not established as non-volatile.
Relative density 1.03-1.09 @ 20°C
Solubility(ies) In water: miscible in any ratio

In ethanol: miscible in any ratio
Decomposition Temperature >300°C
Viscosity 5-10 cSt @ 20°C
Explosive properties Not considered to be explosive.
Explosive under the influence Not considered to be explosive.

of a flame
Oxidising properties Material is considered non-oxidizing.

10.1. Reactivity
Reactivity There are no known reactivity hazards associated with this product.


Possibility of hazardous Glycol Ethers can form peroxides on storage. Glycol Ethers can react with light metals with
reactions the evolution of hydrogen.

Conditions to avoid Do not distil to dryness without testing for peroxide formation.

Materials to avoid Strong oxidising agents. For user safety, brake fluid should never be contaminated with any
other substance.

Hazardous decomposition None known.
products
6/10

Acute toxicity - oral
Notes (oral LD₅₀) Based on available data the classification criteria are not met.
ATE oral (mg/kg) 10,000.0
Acute toxicity - dermal

Notes (dermal LD₅₀) Based on available data the classification criteria are not met.
Acute toxicity - inhalation

Notes (inhalation LC₅₀) The product is unlikely to present any significant inhalation hazard at ambient temperatures
and under normal conditions of use.
Serious eye damage/irritation

Serious eye damage/irritation May cause mild, short lasting discomfort to eyes.
Respiratory sensitisation
Respiratory sensitisation No evidence to suggest the product will be a respiratory sensitiser.
Skin sensitisation
Skin sensitisation Based on available data the classification criteria are not met.
Reproductive toxicity
Reproductive toxicity - fertility Major ingredients have not been shown to cause significant fertility or development problems
at levels which are not themselves toxic to the animal concerned. One minor ingredient -
methyl diglycol - has been shown to affect foetus development in some studies and is
classified as H631d.
Specific target organ toxicity - single exposure

STOT - single exposure Based on available data the classification criteria are not met.
Specific target organ toxicity - repeated exposure

STOT - repeated exposure Based on available data the classification criteria are not met.
Aspiration hazard
Aspiration hazard Kinematic viscosity > 20.5 mm²/s. The product viscosity is greater than the upper limit
assigned for classification.
Inhalation Unlikely to be hazardous by inhalation because of the low vapour pressure of the product at
ambient temperature. Gas or vapour in high concentrations may irritate the respiratory
system.
Ingestion Product is of low acute oral toxicity.-LD50 (oral)= >5000 mg/kg. (Sparse experience indicates
lethal dose in man could be less.) However, if any significant amount is ingested, there is a
risk of renal damage which in extreme cases could lead to kidney failure, coma or death.
Other symptoms of overexposure include CNS effects, abdominal discomfort, metabolic
acidosis, headache and nausea.
Skin contact Skin irritation should not occur when used as recommended. Repeated exposure may cause
skin dryness or cracking. Acts as a defatting agent on skin. May cause cracking of skin, and
eczema.
7/10
Ecotoxicity Based on available data the classification criteria are not met. Not regarded as dangerous for
the environment.
12.1. Toxicity
Toxicity Based on available data the classification criteria are not met.
Acute aquatic toxicity

Acute toxicity - fish LC₅₀, 96 hours: >100 mg/l, Oncorhynchus mykiss (Rainbow trout)
Acute toxicity - aquatic Based on available data the classification criteria are not met.
invertebrates

Persistence and degradability Product is inherently biodegradable and is expected to be readily biodegradable based on
ingredients.
Biological oxygen demand Not determined.
Chemical oxygen demand Not determined.

Bioaccumulative potential Not expected to bio-accumulate. Log POW for all main ingredients = <2.0

Mobility Soluble in water and will partition to aqueous phase. Volatilisation from water to air not
expected. Mobile in soil until degraded.
Henry's law constant Not determined.

Results of PBT and vPvB This product does not contain any substances classified as PBT or vPvB.
assessment

Other adverse effects Not relevant.

General information This material and its container must be disposed of as hazardous waste. Dispose of waste to
licensed waste disposal site in accordance with the requirements of the local Waste Disposal
Authority.
Disposal methods Waste, residues, empty containers, discarded work clothes and contaminated cleaning
materials should be collected in designated containers, labelled with their contents. Dispose of
waste via a licensed waste disposal contractor. Controlled incineration or recycling is
recommended. Do not dispose of to landfill or drains. It is recommended that contaminated
packaging is either incinerated or cleaned and sent for recycling.
Waste class European Waste Catalogue (EWC) number: 16 01 13
General The product is not covered by international regulations on the transport of dangerous goods
(IMDG, IATA, ADR/RID).
14.1. UN number
8/10
Not applicable.

Not applicable.

No transport warning sign required.
14.4. Packing group

Not applicable.

No.

Not applicable.
and the IBC Code
National regulations Health and Safety at Work etc. Act 1974 (as amended).
Control of Substances Hazardous to Health Regulations 2002 (as amended).
The Carriage of Dangerous Goods and Use of Transportable Pressure Equipment
Regulations 2009 (SI 2009 No. 1348) (as amended) ["CDG 2009"].
EH40/2005 Workplace exposure limits.
EU legislation Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18
amended).


Inventories
Canada - DSL/NDSL
All the ingredients are listed or exempt.
US - TSCA
Australia - AICS
9/10
Korea - KECI
China - IECSC
Philippines – PICCS
New Zealand - NZIOC

Abbreviations and acronyms ADR: European Agreement concerning the International Carriage of Dangerous Goods by
used in the safety data sheet Road.
CAS: Chemical Abstracts Service.
DNEL: Derived No Effect Level.
GHS: Globally Harmonized System.
IATA: International Air Transport Association.
IMDG: International Maritime Dangerous Goods.
REACH: Registration, Evaluation, Authorisation and Restriction of Chemicals Regulation
(EC) No 1907/2006.
vPvB: Very Persistent and Very Bioaccumulative.
Issued by Regulatory Affairs
Revision 2
SDS number 22807
Hazard statements in full H302 Harmful if swallowed.

H319 Causes serious eye irritation.
H361d Suspected of damaging the unborn child.
H373 May cause damage to organs (Kidneys) through prolonged or repeated exposure if
swallowed.
10/10
K2EP Longlife Grease
Safety Data Sheet
according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878
Reference number: 21805
Issue date: 29/03/2023 Revision date: 29/03/2023 Supersedes version of: 29/03/2023 Version: 1.1

Product form : Mixture
Product name : K2EP Longlife Grease
Product code : 7902
Type of product : Lubricating grease
Product group : Trade product
1.2.1. Relevant identified uses
Main use category : Industrial use,Professional use
Use of the substance/mixture : Lubricants and additives
Function or use category : Lubricants and additives
1.2.2. Uses advised against

Restrictions on use : No specific uses advised against. Use only for the intended applications
Supplier
Morris Lubricants
Castle Foregate
SY1 2EL Shrewsbury – Shropshire
United Kingdom
T +44 (0) 1743 232200

Emergency number : +44 (0) 1743 232200
08.45 - 17.00 GMT

Classification according to Regulation (EC) No. 1272/2008 [CLP]
Not classified
Adverse physicochemical, human health and environmental effects

To our knowledge, this product does not present any particular risk, provided it is handled in accordance with good occupational hygiene and safety
practice.
2.2. Label elements

Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Precautionary statements (CLP) : P501 - Dispose of contents and container to a hazardous or special waste collection point.
EUH-statements : EUH210 - Safety data sheet available on request.
2.3. Other hazards

Contains no PBT/vPvB substances ≥ 0.1% assessed in accordance with REACH Annex XIII
The mixture does not contain substance(s) included in the list established in accordance with Article 59(1) of REACH for having endocrine disrupting
properties, or is not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation
(EU) 2017/2100 or Commission Regulation (EU) 2018/605 at a concentration equal to or greater than 0,1 %
29/03/2023 (Revision date) GB - en 1/10

Safety Data Sheet
3.1. Substances
Not applicable
3.2. Mixtures
Name Product identifier % Classification according to

Regulation (EC) No. 1272/2008
[CLP]
Hydrotreated Heavy Naphthenic Distillate CAS-No.: 64742-52-5 ≥ 70 Not classified
substance with national workplace exposure limit(s) EC-No.: 265-155-0
(GB); substance with a Community workplace EC Index-No.: 649-465-00-7
exposure limit REACH-no: 01-2119467170-
45
Calcium carbonate (Limestone) CAS-No.: 1317-65-3 ≥ 1 – < 10 Not classified

(GB)
Dilithium sebacate CAS-No.: 19370-86-6 ≥1–<5 Acute Tox. 4 (Oral), H302 (ATE=500
EC-No.: 242-999-8 mg/kg bodyweight)
REACH-no: 01-2120119384-
60
Phosphorodithioic acid, mixed 0,0-bis(2-ethylhexyl CAS-No.: 85940-28-9 ≥1–<5 Skin Irrit. 2, H315
and iso-Bu and iso-Pr)esters, zinc salts EC-No.: 288-917-4 Eye Dam. 1, H318
REACH-no: 01-2119521201- Aquatic Chronic 2, H411
61
Specific concentration limits:

Name Product identifier Specific concentration limits
Phosphorodithioic acid, mixed 0,0-bis(2-ethylhexyl CAS-No.: 85940-28-9 ( 15 ≤C < 100) Skin Irrit. 2, H315
and iso-Bu and iso-Pr)esters, zinc salts EC-No.: 288-917-4 ( 15 ≤C < 20) Eye Irrit. 2, H319
REACH-no: 01-2119521201- ( 20 ≤C < 100) Eye Dam. 1, H318
61
Full text of H- and EUH-statements: see section 16

First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Get medical
advice/attention if you feel unwell.
First-aid measures after skin contact : Gently wash with plenty of soap and water. Take off contaminated clothing and wash it
before reuse. If skin irritation occurs: Get medical advice/attention.
First-aid measures after eye contact : Rinse immediately with plenty of water. Remove contact lenses, if present and easy to do.
Continue rinsing. Obtain medical attention if pain, blinking or redness persists. If eye
irritation persists: Get medical advice/attention.
First-aid measures after ingestion : Rinse mouth out with water. If you feel unwell, seek medical advice. Do NOT induce
vomiting. Move affected person to fresh air and keep warm and at rest in a position
comfortable for breathing.
Symptoms/effects after inhalation : Inhalation of mists or vapours at elevated temperatures may cause respiratory irritation.
Symptoms/effects after skin contact : Prolonged or repeated contact may cause skin to become dry.
Symptoms/effects after eye contact : May cause slight irritation.

Safety Data Sheet
Symptoms/effects after ingestion : None under normal conditions. May cause irritation to the digestive tract. Ingestion may
cause nausea and vomiting.
Treat symptomatically.

Suitable extinguishing media : dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2).
Unsuitable extinguishing media : Do not use a heavy water stream.

Fire hazard : Will ignite if exposed to intensive heat.
Explosion hazard : No direct explosion hazard. Prolonged exposure to fire may cause containers to
rupture/explode.
Hazardous decomposition products in case of fire : Toxic fumes may be released. Carbon monoxide. Carbon dioxide. Nitrogen oxides (NOx).
Sulphur oxides (SOx).

Precautionary measures fire : Evacuate area.
Firefighting instructions : Eliminate all ignition sources if safe to do so. Use water spray or fog for cooling exposed
containers.
Protection during firefighting : Do not attempt to take action without suitable protective equipment. Self-contained
breathing apparatus. Complete protective clothing.

General measures : Spill area may be slippery. Prevent soil and water pollution. Prevent entry to sewers and
public waters.
6.1.1. For non-emergency personnel

Protective equipment : Wear recommended personal protective equipment.
Emergency procedures : Ventilate spillage area. Evacuate unnecessary personnel. Do not touch or walk on the
spilled product. Caution : this product can cause the floor to be very slippery.
6.1.2. For emergency responders

Protective equipment : Use personal protective equipment as required.

Avoid release to the environment. Do not allow to enter drains or water courses.

For containment : Stop leak without risks if possible. Contain any spills with dikes or absorbents to prevent
migration and entry into sewers or streams.
Methods for cleaning up : Clean up any spills as soon as possible, using an absorbent material to collect it. Shovel or
sweep up and put in a closed container for disposal. This material and its container must be
disposed of in a safe way, and as per local legislation. Clean contaminated surfaces with an
excess of water.
Other information : Dispose of materials or solid residues at an authorized site.

For further information refer to section 8: "Exposure controls/personal protection".

Safety Data Sheet

Additional hazards when processed : Not expected to present a significant hazard under anticipated conditions of normal use.
Precautions for safe handling : Wear personal protective equipment. Avoid contact with skin, eyes and clothing. Ensure
good ventilation of the work station.
Hygiene measures : Wash hands and other exposed areas with mild soap and water before eating, drinking or
smoking and when leaving work. Wash contaminated clothing before reuse. Do not eat,
drink or smoke when using this product.

Storage conditions : Store in a well-ventilated place. Keep container tightly closed. Keep cool. Keep only in
original container.
Incompatible products : Oxidizing agent. Strong acids. Strong bases.
Maximum storage period : 5 year
Storage temperature : 0 – 40 °C
Storage area : Store away from heat.
Special rules on packaging : Store in a closed container.

No additional information available
SECTION 8: Exposure controls/personal protection

8.1.1 National occupational exposure and biological limit values
Hydrotreated Heavy Naphthenic Distillate (64742-52-5)

EU - Indicative Occupational Exposure Limit (IOEL)
IOEL TWA 5 mg/m³
IOEL STEL 10 mg/m³
United Kingdom - Occupational Exposure Limits
WEL TWA (OEL TWA) [1] 5 mg/m³
WEL STEL (OEL STEL) 10 mg/m³
Calcium carbonate (Limestone) (1317-65-3)

Local name Calcium carbonate (Limestone, Marble)
WEL TWA (OEL TWA) [1] 10 mg/m³ total inhalable

4 mg/m³ respirable
Regulatory reference EH40/2005 (Fourth edition, 2020). HSE
8.1.2. Recommended monitoring procedures

8.1.3. Air contaminants formed

8.1.4. DNEL and PNEC

8.1.5. Control banding


Safety Data Sheet

8.2.1. Appropriate engineering controls
Appropriate engineering controls:

Ensure good ventilation of the work station.
8.2.2. Personal protection equipment
Personal protective equipment:

Gloves. Protective goggles. Protective clothing. Use barrier cream. Respiratory protective device with a combined gas and particle filter.
Personal protective equipment symbol(s):
8.2.2.1. Eye and face protection

Eye protection:
Safety glasses. Use eye protection according to EN 166, designed to protect against dusts.
8.2.2.2. Skin protection
Skin and body protection:

Protective clothing
Hand protection:
Gloves. Chemical resistant gloves (according to European standard NF ISO 374-1 or equivalent)
Other skin protection

Materials for protective clothing:
Nitrile rubber
8.2.2.3. Respiratory protection

Respiratory protection:
No respiratory protection needed under normal use conditions. In case of inadequate ventilation wear respiratory protection. Standard EN 143 -
Respiratory protective devices - Particle filters - Requirements, testing, marking.
8.2.2.4. Thermal hazards

8.2.3. Environmental exposure controls

Environmental exposure controls:
Avoid release to the environment.

Physical state : Solid
Colour : red.
Appearance : Grease.
Odour : Not available
Odour threshold : Not available
Melting point : > 260 °C
Freezing point : Not available
Boiling point : Not available
Flammability : Not flammable
Explosive limits : Not applicable
Lower explosion limit : Not applicable
Upper explosion limit : Not applicable
Flash point : > 200 °C PMCC
Auto-ignition temperature : Not applicable

Safety Data Sheet
Decomposition temperature : Not available

pH : Not available
pH solution : Not available
Viscosity, kinematic : 150 mm²/s @40C
Solubility : insoluble in water.
Partition coefficient n-octanol/water (Log Kow) : Not available
Vapour pressure : Not available
Vapour pressure at 50°C : Not available
Density : Not available
Relative density : 0.91
Relative vapour density at 20°C : Not applicable
Particle size : Not available

9.2.1. Information with regard to physical hazard classes
9.2.2. Other safety characteristics

10.1. Reactivity
The product is non-reactive under normal conditions of use, storage and transport.

Stable under normal conditions of use.

No dangerous reactions known under normal conditions of use.

None under recommended storage and handling conditions (see section 7).

Oxidizing agent.

Carbon dioxide. Carbon monoxide. Nitrogen oxides (NOx). Sulphur oxides (SOx).
11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008

Acute toxicity (oral) : Not classified
Acute toxicity (dermal) : Not classified
Acute toxicity (inhalation) : Not classified

LD50 oral rat > 5000 mg/kg Source: IUCLID
LD50 dermal rabbit > 5000 mg/kg
Phosphorodithioic acid, mixed 0,0-bis(2-ethylhexyl and iso-Bu and iso-Pr)esters, zinc salts (85940-28-9)
LD50 oral rat 3080 mg/kg bodyweight Animal: rat, Guideline: other:, Guideline: OECD Guideline 401
(Acute Oral Toxicity), 95% CL: 2570 - 3700

Safety Data Sheet
LD50 dermal rabbit > 20000 mg/kg bodyweight Animal: rabbit, Guideline: other:, Guideline: OECD Guideline
402 (Acute Dermal Toxicity)
LC50 Inhalation - Rat > 2.3 mg/l/4h Animal: rat, Guideline: OECD Guideline 403 (Acute Inhalation Toxicity)
Skin corrosion/irritation : Not classified
Serious eye damage/irritation : Not classified
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : Not classified
STOT-single exposure : Not classified
STOT-repeated exposure : Not classified
NOAEL (oral, rat, 90 days) 125 mg/kg bodyweight Animal: rat, Guideline: OECD Guideline 407 (Repeated Dose 28-
Day Oral Toxicity Study in Rodents)
Aspiration hazard : Not classified

Viscosity, kinematic 150 mm²/s @40C

11.2. Information on other hazards

12.1. Toxicity
Ecology - general : The product is not considered harmful to aquatic organisms nor to cause long-term adverse
effects in the environment.
Hazardous to the aquatic environment, short–term : Not classified
(acute)
Hazardous to the aquatic environment, long–term : Not classified
(chronic)
Not rapidly degradable

LC50 - Fish [1] > 5000 mg/l Source: IUCLID
EC50 - Crustacea [1] > 1000 mg/l Source: IUCLID
EC50 96h - Algae [1] > 1000 mg/l Source: IUCLID
EC50 - Crustacea [1] 5.4 mg/l Test organisms (species): Daphnia magna
EC50 72h - Algae [1] 2.1 mg/l Test organisms (species): other:
EC50 72h - Algae [2] 2 mg/l Test organisms (species): other:
EC50 96h - Algae [1] 2.1 mg/l Test organisms (species): other:
EC50 96h - Algae [2] 2 mg/l Test organisms (species): other:

Safety Data Sheet

Persistence and degradability Not established.

Partition coefficient n-octanol/water (Log Pow) 3.9 – 6 Source: IUCLID


12.6. Endocrine disrupting properties


Additional information : No other effects known

Waste treatment methods : Dispose of contents/container in accordance with licensed collector’s sorting instructions.
Product/Packaging disposal recommendations : Beware of residues or vapours which remain in the drums. Completely empty the packaging
prior to decontamination. Dispose of contents/container to a hazardous or special waste
collection point.
European List of Waste (LoW) code : 20 01 26* - oil and fat other than those mentioned in 20 01 25
HP Code : HP14 - “Ecotoxic:” waste which presents or may present immediate or delayed risks for one
or more sectors of the environment

In accordance with ADR / IMDG / IATA / ADN / RID
ADR IMDG IATA ADN RID
14.1. UN number or ID number

Not applicable Not applicable Not applicable Not applicable Not applicable


14.4. Packing group


No supplementary information available

Safety Data Sheet
Overland transport
Not applicable
Transport by sea
Not applicable
Air transport
Not applicable
Inland waterway transport

Not applicable
Rail transport
Not applicable
14.7. Maritime transport in bulk according to IMO instruments

Not applicable
15.1.1. EU-Regulations
REACH Annex XVII (Restriction List)

Contains no substance(s) listed on REACH Annex XVII (Restriction Conditions)
REACH Annex XIV (Authorisation List)

Contains no substance(s) listed on REACH Annex XIV (Authorisation List)
REACH Candidate List (SVHC)

Contains no substance(s) listed on the REACH Candidate List
PIC Regulation (Prior Informed Consent)

Contains no substance(s) listed on the PIC list (Regulation EU 649/2012 concerning the export and import of hazardous chemicals)
POP Regulation (Persistent Organic Pollutants)

Contains no substance(s) listed on the POP list (Regulation EU 2019/1021 on persistent organic pollutants)
Ozone Regulation (1005/2009)

Contains no substance(s) listed on the Ozone Depletion list (Regulation EU 1005/2009 on substances that deplete the ozone layer)
Explosives Precursors Regulation (2019/1148)

Contains no substance(s) listed on the Explosives Precursors list (Regulation EU 2019/1148 on the marketing and use of explosives precursors)
Drug Precursors Regulation (273/2004)

Contains no substance(s) listed on the Drug Precursors list (Regulation EC 273/2004 on the manufacture and the placing on market of certain
substances used in the illicit manufacture of narcotic drugs and psychotropic substances)
15.1.2. National regulations


No chemical safety assessment has been carried out

Safety Data Sheet
Full text of H- and EUH-statements:

Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4
Aquatic Chronic 2 Hazardous to the aquatic environment – Chronic Hazard, Category 2
EUH210 Safety data sheet available on request.
Eye Dam. 1 Serious eye damage/eye irritation, Category 1
Eye Irrit. 2 Serious eye damage/eye irritation, Category 2
H302 Harmful if swallowed.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H411 Toxic to aquatic life with long lasting effects.
Skin Irrit. 2 Skin corrosion/irritation, Category 2
The classification complies with : ATP 12
Safety Data Sheet (SDS), EU
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental
requirements only. It should not therefore be construed as guaranteeing any specific property of the product.

SAFETY DATA SHEET

Workshop PRO White Spray Grease

Product name Workshop PRO White Spray Grease
Product number 7955-16
Identified uses Spray-on Lubricant
Uses advised against Recreational Inhalant Abuse

Castle Foregate
Shrewsbury
Shropshire
SY1 2EL
+44 (0) 1743 232200
+44 (0) 1743 353584


Physical hazards Aerosol 1 - H222, H229
Health hazards Skin Irrit. 2 - H315 STOT SE 3 - H336
Environmental hazards Aquatic Chronic 2 - H411
Classification (67/548/EEC or -
1999/45/EC)
Human health Vapours and spray/mists in high concentrations are narcotic. Symptoms following
overexposure may include the following: Headache. Fatigue. Dizziness. Nausea, vomiting.
Environmental The product contains a substance which is toxic to aquatic organisms and which may cause
long-term adverse effects in the aquatic environment.
Physicochemical The product is extremely flammable.
2.2. Label elements
1/9
Hazard pictograms
Signal word Danger
Hazard statements H222 Extremely flammable aerosol.

H229 Pressurised container: may burst if heated.
H336 May cause drowsiness or dizziness.
Precautionary statements P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P211 Do not spray on an open flame or other ignition source.
P251 Do not pierce or burn, even after use.
P261 Avoid breathing vapour/ spray.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves.
P302+P352 IF ON SKIN: Wash with plenty of water.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P410+P412 Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F.
Contains NAPHTHA (PETROLEUM), HYDROTREATED LIGHT (Contains <0.5% n-Hexane)
2.3. Other hazards

3.2. Mixtures
NAPHTHA (PETROLEUM), HYDROTREATED LIGHT 30-60%

(Contains <0.5% n-Hexane)
2119475133-43-0000

Flam. Liq. 2 - H225 Xn;R65. R66,R67.
Skin Irrit. 2 - H315
STOT SE 3 - H336
Asp. Tox. 1 - H304
Aquatic Chronic 2 - H411
PETROLEUM GASES, LIQUEFIED; PETROLEUM GAS 30-60%

(contains <0.1% 1,3-butadiene)
2119485911-31-0000
Classification
Flam. Gas 1 - H220
Press. Gas (Comp.) - H280
2/9

General information Move affected person to fresh air and keep warm and at rest in a position comfortable for
breathing. Never give anything by mouth to an unconscious person. Get medical attention if
any discomfort continues.
Inhalation Remove affected person from source of contamination. Place unconscious person on their
side in the recovery position and ensure breathing can take place. When breathing is difficult,
properly trained personnel may assist affected person by administering oxygen.
Ingestion Rinse mouth thoroughly with water. Give plenty of water to drink. Give milk instead of water if
readily available. Keep affected person under observation. Do not induce vomiting. If vomiting
occurs, the head should be kept low so that vomit does not enter the lungs. Get medical
attention immediately. Show this Safety Data Sheet to the medical personnel.
Skin contact Wash skin thoroughly with soap and water. Get medical attention if irritation persists after
washing.
Eye contact Remove any contact lenses and open eyelids wide apart. Continue to rinse for at least 15
minutes. Get medical attention promptly if symptoms occur after washing.
Inhalation Prolonged inhalation of high concentrations may damage respiratory system.
Skin contact Prolonged contact may cause redness, irritation and dry skin.
Eye contact Prolonged or repeated exposure may cause severe irritation.

Suitable extinguishing media Extinguish with the following media: Alcohol-resistant foam. Carbon dioxide (CO2). Dry
chemicals, sand, dolomite etc. Cool aerosol containers exposed to heat with water spray and
remove container, if no risk is involved.
Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media

Specific hazards The product is flammable. Heating may generate flammable vapours. Closed containers can
burst violently when heated, due to excess pressure build-up. Thermal decomposition or
combustion products may include the following substances: Toxic gases or vapours.
Hazardous combustion Irritating gases or vapours.

products

Protective actions during Control run-off water by containing and keeping it out of sewers and watercourses. Cool
firefighting containers exposed to heat with water spray and remove them from the fire area if it can be
done without risk.
Special protective equipment Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective
for firefighters clothing.
3/9
Personal precautions Wear protective clothing as described in Section 8 of this safety data sheet. No smoking,
sparks, flames or other sources of ignition near spillage. Avoid inhalation of vapours and
contact with skin and eyes.

Environmental precautions Do not discharge into drains or watercourses or onto the ground. Spillages or uncontrolled
discharges into watercourses must be reported immediately to the Environmental Agency or
other appropriate regulatory body. Collect and place in suitable waste disposal containers and
seal securely. Label the containers containing waste and contaminated materials and remove
from the area as soon as possible.

Methods for cleaning up Keep combustible materials away from spillage. Absorb in vermiculite, dry sand or earth and
place into containers. Flush contaminated area with plenty of water. Wash thoroughly after
dealing with a spillage.

Reference to other sections For personal protection, see Section 8. For waste disposal, see Section 13.

Usage precautions Keep away from heat, sparks and open flame. During application and drying, solvent vapours
will be emitted. Do not use in confined spaces without adequate ventilation and/or respirator.
Observe any occupational exposure limits for the product or ingredients. Avoid inhalation of
vapours and spray/mists. Avoid spilling, skin and eye contact.
Advice on general Do not eat, drink or smoke when using this product. Wash promptly with soap and water if
occupational hygiene skin becomes contaminated.

Storage precautions Aerosol cans: Must not be exposed to direct sunlight or temperatures above 50°C. Keep away
from oxidising materials, heat and flames. Store in a cool and well-ventilated place. Keep
separate from food, feedstuffs, fertilisers and other sensitive material.
Storage class Flammable compressed gas storage.

Specific end use(s) For further information, see attached Exposure Scenario.

NAPHTHA (PETROLEUM), HYDROTREATED LIGHT (Contains <0.5% n-Hexane)
Long-term exposure limit (8-hour TWA): WEL 1000 mg/m³ 250 ppm
PETROLEUM GASES, LIQUEFIED; PETROLEUM GAS (contains <0.1% 1,3-butadiene)
Long-term exposure limit (8-hour TWA): WEL 1750 mg/m³ 1000 ppm gas and aerosol mists
Short-term exposure limit (15-minute): WEL 2810 mg/m3 1250 ppm gas and aerosol mists
WEL = Workplace Exposure Limit
Ingredient comments WEL = Workplace Exposure Limits
NAPHTHA (PETROLEUM), HYDROTREATED LIGHT (Contains <0.5% n-Hexane) (CAS: 64742-49-0)
4/9
DNEL Workers - Dermal; Short term systemic effects: 13964 mg/kg/day

Workers - Inhalation; Short term systemic effects: 5306 mg/m³
Consumer - Dermal; Short term systemic effects: 1377 mg/kg/day
Consumer - Inhalation; Short term local effects: 1131 mg/m³
Appropriate engineering Provide adequate general and local exhaust ventilation. Observe any occupational exposure
controls limits for the product or ingredients.
Eye/face protection Contact lenses should not be worn when working with this chemical. The following protection
should be worn: Chemical splash goggles. Personal protective equipment for eye and face
protection should comply with European Standard EN166.
Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn if
a risk assessment indicates skin contact is possible. To protect hands from chemicals, gloves
should comply with European Standard EN374. The selected gloves should have a
breakthrough time of at least 8 hours.
Other skin and body Use engineering controls to reduce air contamination to permissible exposure level. Wear
protection appropriate clothing to prevent any possibility of liquid contact and repeated or prolonged
vapour contact. Provide eyewash station. Use of suitable barrier/afterwork creams to protect
skin may be beneficial.
Hygiene measures Provide eyewash station. Wash promptly if skin becomes contaminated. Promptly remove
non-impervious clothing that becomes contaminated. Do not eat, drink or smoke when using
this product.
Respiratory protection Unlikely to be necessary in normal circumstances; if vapour levels are high, wear a respirator
conforming to EN 140 with a type A filter or better.
Environmental exposure Do not discharge into drains or watercourses or onto the ground.
controls

Appearance Aerosol, emitting off-white coloured spray
Colour Off-white.
Odour Paraffinic
Odour threshold No specific test data are available.
pH No information available.
Melting point No specific test data are available.
Initial boiling point and range No specific test data are available.
Flash point < 0°C
Evaporation rate No information available.
Flammability (solid, gas) Extremely flammable
5/9
Upper/lower flammability or Lower flammable/explosive limit: 0.8 % Upper flammable/explosive limit: 9 %

explosive limits
Vapour pressure No specific test data are available.
Vapour density No specific test data are available.
Relative density No information available.
Solubility(ies) The product is insoluble in water. Soluble in the following materials: Organic solvents.
Partition coefficient No specific test data are available.
Viscosity No information available.
Explosive properties Not considered to be explosive.
Oxidising properties The mixture itself has not been tested but none of the ingredient substances meet the criteria
for classification as oxidising.

Volatile organic compound This product contains a maximum VOC content of 74.4 %.
10.1. Reactivity
Reactivity There are no known reactivity hazards associated with this product.


Possibility of hazardous Does not decompose when used and stored as recommended.
reactions

Conditions to avoid Avoid heat, flames and other sources of ignition. Avoid exposure to high temperatures or
direct sunlight. Avoid freezing.

Materials to avoid Strong oxidising agents. Strong acids. Strong alkalis. Flammable/combustible materials.

Hazardous decomposition In case of fire, toxic gases (CO, CO2, NOx) may be formed.
products
General information Prolonged and repeated contact with solvents over a long period may lead to permanent
health problems.
Inhalation Vapours may irritate throat/respiratory system. Symptoms following overexposure may include
the following: Headache. Dizziness. Drowsiness. Vapours have a narcotic effect. Symptoms
following overexposure may include the following: Headache. Fatigue. Dizziness. Nausea,
vomiting.
6/9
Ingestion Irritating. Symptoms following overexposure may include the following: Nausea, vomiting.
Stomach pain. Swallowing concentrated chemical may cause severe internal injury.
Skin contact Product has a defatting effect on skin. Repeated exposure may cause skin dryness or
cracking. Irritating to skin.
Eye contact Repeated exposure may cause chronic eye irritation.
Acute and chronic health Gas or vapour displaces oxygen available for breathing (asphyxiant). Vapour from this product
hazards may be hazardous by inhalation. Prolonged or repeated contact with used oil may cause
serious skin diseases, such as dermatitis and skin cancer.
Ecotoxicity The product contains substances which are toxic to aquatic organisms and which may cause
long-term adverse effects in the aquatic environment.
12.1. Toxicity
Persistence and degradability Liquefied petroleum gas is expected to be readily biodegradable.

Bioaccumulative potential Bioaccumulation is unlikely to be significant because of the low water-solubility of this product.
Partition coefficient No specific test data are available.

Mobility The product is immiscible with water and will spread on the water surface. The product
contains volatile substances which may spread in the atmosphere.

Results of PBT and vPvB This product does not contain any substances classified as PBT or vPvB.
assessment

Other adverse effects None known.

General information This material and its container must be disposed of as hazardous waste. Dispose of waste to
licensed waste disposal site in accordance with the requirements of the local Waste Disposal
Authority.
Disposal methods Dispose of waste via a licensed waste disposal contractor. Containers should be thoroughly
emptied before disposal because of the risk of an explosion. Do not puncture or incinerate,
even when empty.
Waste class European Waste Catalogue number = 14 06 03* (other solvents and solvent mixtures)
General As supplied, this product is consigned under the Limited Quantities provisions.
14.1. UN number
UN No. (ADR/RID) 1950
UN No. (IMDG) 1950
7/9
UN No. (ICAO) 1950
UN No. (ADN) 1950

Proper shipping name AEROSOLS
(ADR/RID)
Proper shipping name (IMDG) AEROSOLS
Proper shipping name (ICAO) AEROSOLS
Proper shipping name (ADN) AEROSOLS

ADR/RID class 2.1
ADR/RID classification code 5F
ADR/RID label 2.1
IMDG class 2.1
ICAO class/division 2.1
ICAO subsidiary risk 2.1
ADN class 2.1
Transport labels
14.4. Packing group

Not applicable.
ADR/RID packing group None
IMDG packing group None
ICAO packing group None
ADN packing group None

EmS F-D, S-U
ADR transport category 2
Tunnel restriction code (D)
8/9

and the IBC Code
National regulations The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (SI 2009
No. 716).
EH40/2005 Workplace exposure limits.
EU legislation Dangerous Substances Directive 67/548/EEC.

Dangerous Preparations Directive 1999/45/EC.
amended).


Inventories
EU - EINECS/ELINCS
Issued by Regulatory Affairs
Revision 4
SDS number 22733
Hazard statements in full H220 Extremely flammable gas.

H222 Extremely flammable aerosol.
H225 Highly flammable liquid and vapour.
H229 Pressurised container: may burst if heated.
H280 Contains gas under pressure; may explode if heated.
H304 May be fatal if swallowed and enters airways.
H336 May cause drowsiness or dizziness.
9/9
Versimax HD12 15W-40
Safety Data Sheet

Product name : Versimax HD12 15W-40
Product code : 7443
Type of product : Lubricant for diesel engines
Use of the substance/mixture : Lubricants and additives
Function or use category : Lubricants and additives

Manufacturer
Morris Lubricants
Castle Foregate
United Kingdom
T +44 (0) 1743 232200

08.45 - 17.00 GMT

Not classified

2.2. Label elements

EUH208 - Contains 2,5-Furandione, polymer with 1-hexadecene, 2-methyloxirane polymer
with oxirane bis(2-aminopropyl) ether and 2-methyl-1-propene, 4-
(phenylamino)phenylimide, Benzenesulfonic acid, methyl-, mono-C20-24-branched alkyl
derivs, calcium salts, Alkyl (C18-C28) toluenesulfonic acid, calcium salts, borated. May
produce an allergic reaction.
2.3. Other hazards


Safety Data Sheet
Component
Phenol, dodecyl-, branched (121158-58-5) This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII
Component
Phenol, dodecyl-, branched(121158-58-5) The substance is included in the list established in accordance with Article 59(1) of
REACH for having endocrine disrupting properties, or is identified as having endocrine
disrupting properties in accordance with the criteria set out in Commission Delegated
Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605
3.1. Substances
Not applicable
3.2. Mixtures

[CLP]
Distillates,hydrotreated heavy paraffinic CAS-No.: 64742-54-7 ≥ 70 – < 90 Not classified
(BE, BG, CZ, DK, FI, GB, GR, HU, IE, LT, LV, NL, PL, EC Index-No.: 649-467-00-8
PT, RO, SE, SK, IS, NO, CH) REACH-no: 01-2119484627-
25
Distillates,hydrotreated heavy paraffinic CAS-No.: 64742-54-7 ≥ 5 – < 10 Asp. Tox. 1, H304

25, UK-01-1759217276-5
Highly refined mineral oil (C15 - C50) - ≥ 5 – < 10 Not classified

substance with national workplace exposure limit(s)
(BE, BG, CZ, DK, FI, GB, GR, HU, IE, LT, LV, NL, PL,
PT, RO, SE, SK, IS, NO, CH)
2,5-Furandione, polymer with 1-hexadecene, 2- CAS-No.: 873694-48-5 ≥ 0.1 – < 5 Skin Sens. 1, H317
methyloxirane polymer with oxirane bis(2-
aminopropyl) ether and 2-methyl-1-propene, 4-
(phenylamino)phenylimide
Benzenesulfonic acid, methyl-, mono-C20-24- CAS-No.: 722503-68-6 ≥ 0.1 – < 1 Skin Sens. 1B, H317
branched alkyl derivs., calcium salts EC-No.: 682-731-9
REACH-no: 01-2119513207-
49
Alkyl (C18-C28) toluenesulfonic acid, calcium salts, EC-No.: 953-650-0 ≥ 0.1 – < 1 Skin Sens. 1B, H317
borated Repr. 2, H361d
Phenol, dodecyl-, branched CAS-No.: 121158-58-5 < 0.1 Skin Corr. 1C, H314
substance listed as REACH Candidate (Phenol, EC-No.: 310-154-3 Eye Dam. 1, H318
alkylation products (mainly in para position) with C12- EC Index-No.: 604-092-00-9 Repr. 1B, H360F
rich branched alkyl chains from oligomerisation, REACH-no: 01-2119513207- Aquatic Acute 1, H400 (M=10)
covering any individual isomers and/ or combinations 49, UK-01-1625361544-3 Aquatic Chronic 1, H410 (M=10)
thereof (PDDP))

Safety Data Sheet
Specific concentration limits:

Name Product identifier Specific concentration limits
2,5-Furandione, polymer with 1-hexadecene, 2- CAS-No.: 873694-48-5 ( 2.51 ≤C < 100) Skin Sens. 1, H317
methyloxirane polymer with oxirane bis(2-
aminopropyl) ether and 2-methyl-1-propene, 4-
(phenylamino)phenylimide
Alkyl (C18-C28) toluenesulfonic acid, calcium salts, EC-No.: 953-650-0 ( 7.15 ≤C < 100) Repr. 2, H361d
borated
Comments : A petroleum product. DMSO extract < 3 % weight (IP 346)

This material contains one or more components that have a branched alkylphenol impurity
that is highly toxic to aquatic organisms. The components containing the impurity have been
tested and are not toxic to aquatic organisms. Therefore the data in Section 3 for the
alkylphenol impurity should not be used to classify the product for aquatic toxicity.

First-aid measures general : If you feel unwell, seek medical advice.
First-aid measures after inhalation : Move the affected person away from the contaminated area and into the fresh air. If you feel
unwell, seek medical advice.
First-aid measures after skin contact : Take off contaminated clothing and wash it before reuse. Gently wash with plenty of soap
and water.
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion : Get medical advice/attention if you feel unwell. Do NOT induce vomiting.
Symptoms/effects after inhalation : None under normal use. Inhalation may cause irritation (cough, short breathing, difficulty in
breathing).
Symptoms/effects after skin contact : Repeated exposure may cause skin dryness or cracking.
Symptoms/effects after ingestion : Although not classified, the product contains mineral oil. If aspirated into the lungs e.g.
through vomiting after ingestion, admit to hospital immediately.

Suitable extinguishing media : Dry chemical, CO2, dry sand, or alcohol-resistant foam.

Explosion hazard : Heat may build pressure, rupturing closed containers, spreading fire and increasing risk of
burns and injuries.
Hazardous decomposition products in case of fire : Toxic fumes may be released. Carbon monoxide. Carbon dioxide.

Precautionary measures fire : Keep container closed when not in use.
Firefighting instructions : Prevent fire fighting water from entering the environment. Use water spray or fog for cooling
exposed containers.

Safety Data Sheet
Protection during firefighting : Self-contained breathing apparatus.

Emergency procedures : Evacuate unnecessary personnel. Caution : this product can cause the floor to be very
slippery.


Do not allow to enter drains or water courses. Notify authorities if liquid enters sewers or public waters.

For containment : Contain any spills with dikes or absorbents to prevent migration and entry into sewers or
streams.
Methods for cleaning up : Clear up rapidly by scoop or vacuum. Collect leaking and spilled liquid in sealable
containers as far as possible. Absorb remaining liquid with sand or inert absorbent and
remove to safe place. Notify authorities if product enters sewers or public waters. This
material and its container must be disposed of in a safe way, and as per local legislation.


Precautions for safe handling : Do not eat, drink or smoke when using this product.
Hygiene measures : Wear personal protective equipment. Wash contaminated clothing before reuse. Wash
hands and other exposed areas with mild soap and water before eating, drinking or smoking
and when leaving work.

Technical measures : Store in a well-ventilated place. Keep container tightly closed.
Storage conditions : Do not expose to temperatures exceeding 50 °C/ 122 °F. Keep container closed when not in
use. Store in a dry place.
Storage area : Store in a well-ventilated place.



Safety Data Sheet
Distillates,hydrotreated heavy paraffinic (64742-54-7)

WEL TWA (OEL TWA) [1] 5 mg/m³ 8H
Regulatory reference EU OEL (Europe).

Highly refined mineral oil (C15 - C50)

WEL TWA (OEL TWA) [1] 5 mg/m³
WEL STEL (OEL STEL) 10 mg/m³





Ensure good ventilation of the work station. Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any
potential exposure.

Eye protection:
Chemical goggles or face shield


No respiratory protection needed under normal use conditions


Safety Data Sheet


Physical state : Liquid
Colour : amber.
Appearance : Liquid.
Odour : mild.
Melting point : Not available
Boiling point : > 320 °C
Flammability : Not flammable,Heating may cause a fire.
Explosive limits : Not available
Lower explosion limit : Not available
Upper explosion limit : Not available
Flash point : 210 °C PMCC
Auto-ignition temperature : Not available
pH : Not available
Viscosity, kinematic : 107.4 mm²/s @40C
Solubility : Material nearly insoluble in water. Soluble in organic solvents.
Partition coefficient n-octanol/water (Log Kow) : ≈ 7 Not determined. Typical for mineral oil
Relative vapour density at 20°C : Not available
Particle characteristics : Not applicable


Additional information : The product is a complex mixture, the majority of which would not be classed as a VOC.
However it cannot be discounted that trace or low levels of VOCs may be present.
10.1. Reactivity



Extremely high or low temperatures. Moisture.


Safety Data Sheet

Under normal conditions of storage and use, hazardous decomposition products should not be produced.

Acute toxicity (oral) : Not classified (Based on available data, the classification criteria are not met)

LD50 dermal rabbit > 5000 mg/kg Source: IUCLID
Phenol, dodecyl-, branched (121158-58-5)

LD50 oral rat 2200 mg/kg bodyweight Animal: rat, Guideline: OECD Guideline 401 (Acute Oral Toxicity)
Skin corrosion/irritation : Not classified (Based on available data, the classification criteria are not met)
Additional information : Repeated exposure may cause skin dryness or cracking.
Serious eye damage/irritation : Not classified (Based on available data, the classification criteria are not met)
Respiratory or skin sensitisation : Not classified (Based on available data, the classification criteria are not met)
Germ cell mutagenicity : Not classified (Based on available data, the classification criteria are not met)
Additional information : This product contains mineral oils which are considered to be severely refined and not
considered to be carcinogenic under IARC. All of the oils in this product have been
demonstrated to contain less than 3% extractables by the IP346 test
Reproductive toxicity : Not classified (Based on available data, the classification criteria are not met)
STOT-single exposure : Not classified (Based on available data, the classification criteria are not met)
STOT-repeated exposure : Not classified (Based on available data, the classification criteria are not met)
Additional information : Although not classified, the product contains mineral oil. If aspirated into the lungs e.g.

Viscosity, kinematic 107.4 mm²/s @40C


11.2.1. Endocrine disrupting properties
Component
Phenol, dodecyl-, branched(121158-58-5) The substance is identified for having endocrine disrupting properties but there is no
additional data available
11.2.2. Other information

12.1. Toxicity
(acute)

Safety Data Sheet
Hazardous to the aquatic environment, long–term : Not classified.

(chronic)
Additional information : Based on available data, the classification criteria are not met.

LC50 - Fish [1] > 5000 mg/l
Phenol, dodecyl-, branched (121158-58-5)

EC50 - Crustacea [1] 92.7 μg/l Test organisms (species): Daphnia magna
EC50 72h - Algae [1] > 0.765 mg/l Test organisms (species): Desmodesmus subspicatus (previous name:
Scenedesmus subspicatus)


Partition coefficient n-octanol/water (Log Kow) ≈ 7 Not determined. Typical for mineral oil


Component
Phenol, dodecyl-, branched (121158-58-5) This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII
Component
Phenol, dodecyl-, branched(121158-58-5) The substance is identified for having endocrine disrupting properties but there is no
additional data available


Product/Packaging disposal recommendations : Dispose of contents/container to a hazardous or special waste collection point.
European List of Waste (LoW) code : 13 02 05* - mineral-based non-chlorinated engine, gear and lubricating oils

Safety Data Sheet


Not regulated Not regulated Not regulated Not regulated Not regulated


14.4. Packing group


Overland transport
Not regulated
Transport by sea
Not regulated
Air transport
Not regulated

Not regulated
Rail transport
Not regulated

Not applicable



Contains substance(s) listed on the REACH Candidate List in concentrations ≥ 0.1 % or SCL: Phenol, alkylation products (mainly in para position)
with C12-rich branched alkyl chains from oligomerisation, covering any individual isomers and/ or combinations thereof (PDDP) (EC 310-154-3,
CAS 121158-58-5)

Safety Data Sheet





United Kingdom
British National Regulations : GB CLP.

Abbreviations and acronyms:

CAS-No. Chemical Abstract Service number
CLP Classification Labelling Packaging Regulation; Regulation (EC) No 1272/2008
ADR European Agreement concerning the International Carriage of Dangerous Goods by Road
ATE Acute Toxicity Estimate
BOD Biochemical oxygen demand (BOD)
COD Chemical oxygen demand (COD)
DNEL Derived-No Effect Level
EC-No. European Community number
ED Endocrine disrupting properties
IARC International Agency for Research on Cancer
LC50 Median lethal concentration
LD50 Median lethal dose
OEL Occupational Exposure Limit
PBT Persistent Bioaccumulative Toxic
PNEC Predicted No-Effect Concentration
REACH Registration, Evaluation, Authorisation and Restriction of Chemicals Regulation (EC) No 1907/2006
SDS Safety Data Sheet
STP Sewage treatment plant
VOC Volatile Organic Compounds
WGK Water Hazard Class
vPvB Very Persistent and Very Bioaccumulative

Safety Data Sheet
Data sources : ECHA (European Chemicals Agency). REGULATION (EC) No 1272/2008 OF THE
EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on
classification, labelling and packaging of substances and mixtures, amending and repealing
Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006.
Supplier's safety documents.
Training advice : Normal use of this product shall imply use in accordance with the instructions on the
packaging.

Aquatic Acute 1 Hazardous to the aquatic environment – Acute Hazard, Category 1
Aquatic Chronic 1 Hazardous to the aquatic environment – Chronic Hazard, Category 1
Asp. Tox. 1 Aspiration hazard, Category 1
EUH208 Contains 2,5-Furandione, polymer with 1-hexadecene, 2-methyloxirane polymer with oxirane bis(2-aminopropyl) ether
and 2-methyl-1-propene, 4-(phenylamino)phenylimide, Benzenesulfonic acid, methyl-, mono-C20-24-branched alkyl
derivs, calcium salts, Alkyl (C18-C28) toluenesulfonic acid, calcium salts, borated. May produce an allergic reaction.
Eye Dam. 1 Serious eye damage/eye irritation, Category 1
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H360F May damage fertility.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
Repr. 1B Reproductive toxicity, Category 1B
Repr. 2 Reproductive toxicity, Category 2
Skin Corr. 1C Skin corrosion/irritation, Category 1, Sub-Category 1C
Skin Sens. 1 Skin sensitisation, Category 1
Skin Sens. 1B Skin sensitisation, category 1B

Triad 32 Hydraulic Oil
Safety Data Sheet

Product name : Triad 32 Hydraulic Oil
Product code : 7589
Type of product : Hydraulic oil
Use of the substance/mixture : Hydraulic fluids and additives
Function or use category : Hydraulic fluids and additives

Manufacturer
Morris Lubricants
Castle Foregate
United Kingdom
T +44 (0) 1743 232200

08.45 - 17.00 GMT

Not classified

2.2. Label elements

2.3. Other hazards


Safety Data Sheet
3.1. Substances
Not applicable
3.2. Mixtures

[CLP]
Distillates,hydrotreated heavy paraffinic CAS-No.: 64742-54-7 ≥ 50 – < 70 Not classified
25, UK-01-1759217276-5
Distillates,hydrotreated heavy paraffinic CAS-No.: 64742-54-7 ≥ 30 – < 50 Asp. Tox. 1, H304

25, UK-01-1759217276-5
Comments : A petroleum product. DMSO extract < 3 % weight (IP 346)


First-aid measures general : If you feel unwell, seek medical advice.
First-aid measures after inhalation : Move the affected person away from the contaminated area and into the fresh air. If you feel
unwell, seek medical advice.
First-aid measures after skin contact : Take off contaminated clothing and wash it before reuse. Gently wash with plenty of soap
and water.
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion : Get medical advice/attention if you feel unwell. Do NOT induce vomiting.
Symptoms/effects after inhalation : None under normal use. Inhalation may cause irritation (cough, short breathing, difficulty in
breathing).
Symptoms/effects after ingestion : Although not classified, the product contains mineral oil. If aspirated into the lungs e.g.


Safety Data Sheet

Explosion hazard : Heat may build pressure, rupturing closed containers, spreading fire and increasing risk of
burns and injuries.
Hazardous decomposition products in case of fire : Toxic fumes may be released. Carbon monoxide. Carbon dioxide.

Precautionary measures fire : Keep container closed when not in use.
Firefighting instructions : Prevent fire fighting water from entering the environment. Use water spray or fog for cooling
exposed containers.
Protection during firefighting : Self-contained breathing apparatus.

Emergency procedures : Evacuate unnecessary personnel. Caution : this product can cause the floor to be very
slippery.


Do not allow to enter drains or water courses. Notify authorities if liquid enters sewers or public waters.

For containment : Contain any spills with dikes or absorbents to prevent migration and entry into sewers or
streams.
Methods for cleaning up : Clear up rapidly by scoop or vacuum. Collect leaking and spilled liquid in sealable
containers as far as possible. Absorb remaining liquid with sand or inert absorbent and
remove to safe place. Notify authorities if product enters sewers or public waters. This
material and its container must be disposed of in a safe way, and as per local legislation.


Precautions for safe handling : Do not eat, drink or smoke when using this product.
Hygiene measures : Wear personal protective equipment. Wash contaminated clothing before reuse. Wash
hands and other exposed areas with mild soap and water before eating, drinking or smoking
and when leaving work.

Technical measures : Store in a well-ventilated place. Keep container tightly closed.
Storage conditions : Do not expose to temperatures exceeding 50 °C/ 122 °F. Keep container closed when not in
use. Store in a dry place.
Storage area : Store in a well-ventilated place.


Safety Data Sheet








Ensure good ventilation of the work station. Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any
potential exposure.

Eye protection:
Chemical goggles or face shield


No respiratory protection needed under normal use conditions



Safety Data Sheet

Colour : amber.
Odour : mild.
Melting point : Not available
Boiling point : > 320 °C
Flammability : Not flammable,Heating may cause a fire.
Flash point : 213 °C PMCC
pH : Not available
Viscosity, kinematic : 32.9 (≤ 40) mm²/s
Solubility : Material nearly insoluble in water. Soluble in organic solvents.
Partition coefficient n-octanol/water (Log Kow) : ≈ 7 Not determined. Typical for mineral oil


Additional information : The product is a complex mixture, the majority of which would not be classed as a VOC.
However it cannot be discounted that trace or low levels of VOCs may be present.
10.1. Reactivity



Extremely high or low temperatures. Moisture.


Under normal conditions of storage and use, hazardous decomposition products should not be produced.

Safety Data Sheet

Acute toxicity (oral) : Not classified (Based on available data, the classification criteria are not met)

LD50 dermal rabbit > 5000 mg/kg Source: IUCLID

Skin corrosion/irritation : Not classified (Based on available data, the classification criteria are not met)
Additional information : Repeated exposure may cause skin dryness or cracking.
Serious eye damage/irritation : Not classified (Based on available data, the classification criteria are not met)
Respiratory or skin sensitisation : Not classified (Based on available data, the classification criteria are not met)
Germ cell mutagenicity : Not classified (Based on available data, the classification criteria are not met)
Additional information : This product contains mineral oils which are considered to be severely refined and not
considered to be carcinogenic under IARC. All of the oils in this product have been
demonstrated to contain less than 3% extractables by the IP346 test
Reproductive toxicity : Not classified (Based on available data, the classification criteria are not met)
STOT-single exposure : Not classified (Based on available data, the classification criteria are not met)
STOT-repeated exposure : Not classified (Based on available data, the classification criteria are not met)
Additional information : Although not classified, the product contains mineral oil. If aspirated into the lungs e.g.

Viscosity, kinematic 32.9 (≤ 40) mm²/s


12.1. Toxicity
(acute)
(chronic)
Additional information : Based on available data, the classification criteria are not met.

LC50 - Fish [1] > 5000 mg/l


Safety Data Sheet

Partition coefficient n-octanol/water (Log Kow) ≈ 7 Not determined. Typical for mineral oil






Product/Packaging disposal recommendations : Dispose of contents/container to a hazardous or special waste collection point.
European List of Waste (LoW) code : 13 01 13* - other hydraulic oils




14.4. Packing group


Overland transport
Not regulated

Safety Data Sheet
Transport by sea
Not regulated
Air transport
Not regulated

Not regulated
Rail transport
Not regulated

Not applicable








United Kingdom
British National Regulations : GB CLP.


CAS-No. Chemical Abstract Service number
CLP Classification Labelling Packaging Regulation; Regulation (EC) No 1272/2008

Safety Data Sheet

ADR European Agreement concerning the International Carriage of Dangerous Goods by Road
ATE Acute Toxicity Estimate
BOD Biochemical oxygen demand (BOD)
COD Chemical oxygen demand (COD)
DNEL Derived-No Effect Level
EC-No. European Community number
ED Endocrine disrupting properties
IARC International Agency for Research on Cancer
LC50 Median lethal concentration
LD50 Median lethal dose
OEL Occupational Exposure Limit
PBT Persistent Bioaccumulative Toxic
PNEC Predicted No-Effect Concentration
REACH Registration, Evaluation, Authorisation and Restriction of Chemicals Regulation (EC) No 1907/2006
SDS Safety Data Sheet
STP Sewage treatment plant
VOC Volatile Organic Compounds
WGK Water Hazard Class
vPvB Very Persistent and Very Bioaccumulative
Data sources : ECHA (European Chemicals Agency). REGULATION (EC) No 1272/2008 OF THE
EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on
classification, labelling and packaging of substances and mixtures, amending and repealing
Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006.
Supplier's safety documents.
Training advice : Normal use of this product shall imply use in accordance with the instructions on the
packaging.

Asp. Tox. 1 Aspiration hazard, Category 1

Ultralife MAX Antifreeze
Safety Data Sheet
Issue date: 25/04/2023 Revision date: 25/04/2023 Version: 1.0

Product name : Ultralife MAX Antifreeze
Product code : 7863
Type of product : Antifreeze
Intended for general public
Use of the substance/mixture : Anti-freezing agents
Function or use category : Anti-freezing agents

Supplier
Morris Lubricants
Castle Foregate
United Kingdom
T +44 (0) 1743 232200

08.45 - 17.00 GMT

Acute toxicity (oral), Category 4 H302
Reproductive toxicity, Category 2 H361d
Specific target organ toxicity – Repeated exposure, Category 2 H373

2.2. Label elements

Hazard pictograms (CLP) :
GHS07 GHS08
Signal word (CLP) : Warning
Contains : ethanediol; 2-Ethylhexanoic acid, Sodium salt
Hazard statements (CLP) : H302 - Harmful if swallowed.
H361d - Suspected of damaging the unborn child.
25/04/2023 (Issue date) GB - en 1/10

Safety Data Sheet
H373 - May cause damage to organs (kidneys) through prolonged or repeated exposure
(oral).
Precautionary statements (CLP) : P102 - Keep out of reach of children.
P202 - Do not handle until all safety precautions have been read and understood.
P260 - Do not breathe mist, spray, vapours.
P280 - Wear protective clothing, eye protection, face protection.
2.3. Other hazards

PBT: not relevant – no registration required
vPvB: not relevant – no registration required
3.1. Substances
Not applicable
3.2. Mixtures

[CLP]
ethanediol CAS-No.: 107-21-1 ≥ 90 Acute Tox. 4 (Oral), H302 (ATE=500
substance with national workplace exposure limit(s) EC-No.: 203-473-3 mg/kg bodyweight)
(GB, NO); substance with a Community workplace EC Index-No.: 603-027-00-1 STOT RE 2, H373
exposure limit REACH-no: 01-2119456816-
28
2-Ethylhexanoic acid, Sodium salt CAS-No.: 19766-89-3 ≥ 5 – < 10 Acute Tox. 4 (Oral), H302 (ATE=500
EC-No.: 243-283-8 mg/kg bodyweight)
REACH-no: 01-2119979083- Repr. 2, H361d
31

First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. If experiencing respiratory
symptoms: Call a poison center or a doctor.
First-aid measures after skin contact : After contact with skin, take off immediately all contaminated clothing, and wash
immediately with plenty of water. If skin irritation occurs: Get medical advice/attention.
First-aid measures after eye contact : If eye irritation persists: Get medical advice/attention. IF IN EYES: Rinse cautiously with
water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing.
First-aid measures after ingestion : Move affected person to fresh air and keep warm and at rest in a position comfortable for
breathing. Rinse mouth out with water. Drink plenty of water. Get immediate medical
advice/attention.
Symptoms/effects after inhalation : In high concentrations vapours cause anaesthetic and narcotic effect. Depression of the
central nervous system, headaches, dizziness, drowsiness, loss of coordination.
25/04/2023 (Issue date) GB - en 2/10

Safety Data Sheet
Symptoms/effects after ingestion : Harmful if swallowed. In case of repeated or prolonged exposure : Damage to kidneys.
If several ounces (60 - 100 ml) of ethylene glycol have been ingested, early administration of ethanol may counter the toxic effects (metabolic
acidosis, renal damage). Consider hemodialysis or peritoneal dialysis & thiamine 100 mg plus pyridoxine 50 mg intravenously every 6 hours. If
ethanol is used, a therapeutically effective blood concentration in the range of 100 - 150 mg/dl may be achieved by a rapid loading dose followed by
a continuous intravenous infusion. Consult standard literature for details of treatment. 4-Methyl pyrazole (Antizol®) is an effective blocker of alcohol
dehydrogenase and should be used in the treatment of ethylene glycol (EG), di- or triethylene glycol (DEG, TEG), ethylene glycol butyl ether
(EGBE), or methanol intoxication if available. Fomepizole protocol: loading dose 15 mg/kg intravenously, follow by bolus dose of 10 mg/kg every 12
hours; after 48 hours,
increase bolus dose to 15 mg/kg every 12 hours. Continue fomepizole until serum methanol, EG, DEG, TEG or EGBE are undetectable. The signs
and symptoms of poisoning include anion gap metabolic acidosis, CNS depression, renal tubular injury, and possible late stage cranial nerve
involvement. Respiratory symptoms, including pulmonary edema, may be delayed. Persons receiving significant exposure should be observed 24-
48 hours for signs of respiratory distress. In severe poisoning, respiratory support with mechanical ventilation and positive end expiratory pressure
may be required. Maintain adequate ventilation and oxygenation of the patient. If lavage is performed, suggest endotracheal and/or esophageal
control. Danger from lung aspiration must be weighed against toxicity when considering emptying the stomach. If burn is present, treat as any
thermal burn, after decontamination.
Treatment of exposure should be directed at the control of symptoms and the clinical
condition of the patient.


Hazardous decomposition products in case of fire : Thermal decomposition generates : Carbon dioxide. Carbon monoxide.

Firefighting instructions : Use water spray or fog for cooling exposed containers. Contain the extinguishing fluids by
bunding.
Protection during firefighting : Use self-contained breathing apparatus and chemically protective clothing.

Emergency procedures : Do not breathe spray, mist. Avoid contact with skin and eyes.

Protective equipment : Use self-contained breathing apparatus and chemically protective clothing.

Notify authorities if product enters sewers or public waters.

For containment : Cover spill with non combustible material, e.g.: sand, earth, vermiculite. Flush contaminated
areas with plenty of water. Place in an appropriate container and dispose of the
contaminated material at a licensed site.

25/04/2023 (Issue date) GB - en 3/10

Safety Data Sheet

Precautions for safe handling : Avoid contact with skin and eyes. Avoid breathing spray, mist. Provide adequate ventilation
to minimize dust and/or vapour concentrations.

Storage conditions : Store in original container. Store in a well-ventilated place. Keep cool.


ethanediol (107-21-1)
EU - Indicative Occupational Exposure Limit (IOEL)
Local name Ethylene glycol
IOEL TWA 52 mg/m³
IOEL TWA [ppm] 20 ppm
IOEL STEL 104 mg/m³
IOEL STEL [ppm] 40 ppm
Remark Skin
Regulatory reference COMMISSION DIRECTIVE 2000/39/EC
Local name Ethane-1,2-diol
WEL TWA (OEL TWA) [1] 10 mg/m³ particulate

52 mg/m³ vapour
WEL TWA (OEL TWA) [2] 20 ppm vapour
WEL STEL (OEL STEL) 104 mg/m³ vapour
WEL STEL (OEL STEL) [ppm] 40 ppm vapour
Remark Sk (Can be absorbed through the skin. The assigned substances are those for which there
are concerns that dermal absorption will lead to systemic toxicity)
Regulatory reference EH40/2005 (Fourth edition, 2020). HSE




25/04/2023 (Issue date) GB - en 4/10

Safety Data Sheet


Ensure good ventilation of the work station.

Eye protection:
Chemical goggles or safety glasses
Skin and body protection:

Wear suitable protective clothing
Hand protection:
Protective gloves
Hand protection
Type Material Permeation Thickness (mm) Penetration Standard
Butyl rubber, EN ISO 374

Polyvinylchloride (PVC)
In case of inadequate ventilation wear respiratory protection.
Respiratory protection
Device Filter type Condition Standard
Filter A2/B2, Type P3 EN 136, EN 140,

EN 143, EN 145,
EN 149



Colour : Orange.
Odour : mild.
Melting point : -18 °C
Boiling point : Not available
25/04/2023 (Issue date) GB - en 5/10

Safety Data Sheet
Flammability : Not available

Flash point : 122 °C
pH : 8.65
Viscosity, kinematic @ 40°C : Not available
Solubility : Soluble in water.
Partition coefficient n-octanol/water (Log Kow) : Not available
Partition coefficient n-octanol/water (Log Pow) : -1.36


10.1. Reactivity


No dangerous reactions known under normal conditions of use.

High temperature.

Oxidizing agent. Strong acids. Strong bases.

Carbon dioxide. Carbon monoxide. May liberate toxic gases.

Acute toxicity (oral) : Harmful if swallowed.

ATE CLP (oral) 500 mg/kg bodyweight
25/04/2023 (Issue date) GB - en 6/10

Safety Data Sheet
Skin corrosion/irritation : Not classified

pH: 8.65
pH 6 – 7.5 Source: GESTIS
Serious eye damage/irritation : Not classified
pH: 8.65
pH 6 – 7.5 Source: GESTIS
Respiratory or skin sensitisation : Not classified
Germ cell mutagenicity : Not classified
Reproductive toxicity : Suspected of damaging the unborn child.
STOT-single exposure : Not classified
STOT-repeated exposure : May cause damage to organs (kidneys) through prolonged or repeated exposure (oral).
STOT-repeated exposure May cause damage to organs through prolonged or repeated exposure.

12.1. Toxicity
Ecology - general : The product components are not classified as environmentally hazardous.
However, this does not exclude the possibility that large or frequent spills can have
a harmful or damaging effect on the environment.
(acute)
(chronic)
LC50 - Fish [1] 72860 mg/l Source: ECHA
EC50 - Crustacea [1] 13900 – 57600 mg/l Source: ECHA
EC50 96h - Algae [1] 6500 – 13000 mg/l Source: ECHA
NOEC (chronic) ≥ 1000 mg/l Test organisms (species): Americamysis bahia (previous name: Mysidopsis
bahia) Duration: '23 d'

Biodegradation 90 % > 10 days OECD 301A

Partition coefficient n-octanol/water (Log Pow) -1.36
Partition coefficient n-octanol/water (Log Pow) -1.36
25/04/2023 (Issue date) GB - en 7/10

Safety Data Sheet

Additional information soluble in water
Mobility in soil 0.2 Source: HSDB

PBT: not relevant – no registration required
vPvB: not relevant – no registration required



Product/Packaging disposal recommendations : Dispose of contents/container to hazardous or special waste collection point, in accordance
with local, regional, national and/or international regulation.
European List of Waste (LoW) code : 16 01 14* - antifreeze fluids containing dangerous substances
HP Code : HP5 - “Specific Target Organ Toxicity (STOT)/Aspiration Toxicity:” waste which can cause
specific target organ toxicity either from a single or repeated exposure, or which cause
acute toxic effects following aspiration.
HP6 - “Acute Toxicity:” waste which can cause acute toxic effects following oral or dermal
administration, or inhalation exposure.




14.4. Packing group


25/04/2023 (Issue date) GB - en 8/10

Safety Data Sheet
Overland transport
Not applicable
Transport by sea
Not applicable
Air transport
Not applicable

Not applicable
Rail transport
Not applicable

Not applicable










25/04/2023 (Issue date) GB - en 9/10

Safety Data Sheet

Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4
H302 Harmful if swallowed.
H373 May cause damage to organs through prolonged or repeated exposure.
Repr. 2 Reproductive toxicity, Category 2
STOT RE 2 Specific target organ toxicity – Repeated exposure, Category 2
25/04/2023 (Issue date) GB - en 10/10

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Revision date: 08/01/2020 Revision: 3 Supersedes date: 09/10/2017

SAFETY DATA SHEET

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product number 7999

Internal identification GHS22054

1.3. Details of the supplier of the safety data sheet

1.4. Emergency telephone number

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Health hazards Not Classified

Environmental hazards Not Classified

2.2. Label elements

Supplemental label EUH210 Safety data sheet available on request.

2.3. Other hazards

K99 Water Resistant Grease

Highly refined mineral oil (C15 - C50) 60-100%

Classification Classification (67/548/EEC or 1999/45/EC)

SECTION 4: First aid measures

4.1. Description of first aid measures

SECTION 5: Firefighting measures

5.1. Extinguishing media

5.2. Special hazards arising from the substance or mixture

Special protective equipment Wear self-contained breathing apparatus.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

6.2. Environmental precautions

6.4. Reference to other sections

7.1. Precautions for safe handling

K99 Water Resistant Grease

7.2. Conditions for safe storage, including any incompatibilities

Storage class Miscellaneous hazardous material storage.

7.3. Specific end use(s)

8.1. Control parameters

8.2. Exposure controls

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Auto-ignition temperature >200°C

9.2. Other information

10.3. Possibility of hazardous reactions

10.5. Incompatible materials

10.6. Hazardous decomposition products

K99 Water Resistant Grease

Hazardous decomposition Oxides of carbon.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Ingestion No harmful effects expected from quantities likely to be ingested by accident.

Eye contact May cause temporary eye irritation.

SECTION 12: Ecological information

12.3. Bioaccumulative potential

12.4. Mobility in soil

12.5. Results of PBT and vPvB assessment

13.1. Waste treatment methods

Waste class European Waste Catalogue (EWC) Code: 20 01 26* (greases)

SECTION 14: Transport information

14.2. UN proper shipping name

14.3. Transport hazard class(es)

14.4. Packing group

K99 Water Resistant Grease

14.5. Environmental hazards

Environmentally hazardous substance/marine pollutant

14.6. Special precautions for user

SECTION 15: Regulatory information