VISHNU DHARM SCHOOLS

Subject : Chemistry Paper Set : 1

Standard : 11
11EM CHEM CH 6 EQUI Date : 04-03-2024
Total Mark : 400 Time : 1H:0M

(8) Change in volume of the system does not

......... Chemistry - Section A (MCQ) .........
alter the number of moles in which of the
following equilibrium
(1) In the reversible reaction A + B ⇌ C + D,
the concentration of each C and D at (A) N2(g) + O2(g) ⇌ 2N O(g)
equilibrium was 0.8 mole/litre, then the (B) P Cl5(g) ⇌ P Cl3(g) + Cl2(g)
equilibrium constant Kc will be
(C) N2(g) + 3H2(g) ⇌ 2N H3(g)
(A) 6.4 (B) 0.64
(D) SO2 Cl2(g) ⇌ SO2(g) + Cl2(g)
(C) 1.6 (D) 16
(2) Partial pressures of A, B, C and D on the (9) In which of the following reaction, the value
basis of gaseous system A + 2B ⇌ C + 3D are of Kp will be equal to Kc
A = 0.20; B = 0.10; C = 0.30 and D = 0.50 atm. (A) H2 + I2 ⇌ 2HI (B) P Cl5 ⇌ P Cl3 + Cl2
The numerical value of equilibrium (C) 2N H3 ⇌ N2 + 3H2 (D) 2SO2 + O2 ⇌ 2SO3
constant is
(A) 11.25 (B) 18.75 (10) For the reaction P Cl3(g) + Cl2(g) ⇌ P Cl5(g) at
250 o C, the value of Kc is 26, then the value
(C) 5 (D) 3.75 of Kp on the same temperature will be
(3) Unit of equilibrium constant for the (A) 0.61 (B) 0.57
reversible reaction H2 + I2 ⇌ 2HI is (C) 0.83 (D) 0.46
(A) mol−1 litre (B) mol−2 litre
(11) If the equilibrium constant of the reaction
(C) mol litre−1 (D) None of these 2HI ⇌ H2 + I2 is 0.25, then the equilibrium
(4) The decomposition of N2 O4 to N O2 is carried constant of the reaction H2 + I2 ⇌ 2HI
out at 280 K in chloroform. When would be
equilibrium has been established, 0.2 mol of (A) 1 (B) 2
N2 O4 and 2 × 10 mol of N O2 are present in
−3
(C) 3 (D) 4
2 litre solution. The equilibrium constant
(12) In which of the following equilibria, the
for reaction N2 O4 ⇌ 2N O2 is
value of Kp is less than Kc
(A) 1 × 10−2 (B) 2 × 10−3
(A) H2 + I2 ⇌ 2HI (B) N2 + 3H2 ⇌ 2N H3
(C) 1 × 10−5 (D) 2 × 10−5
(D) CO + H2 O ⇌
(5) For the reaction 2SO2 + O2 ⇌ 2SO3 , the units (C) N2 + O2 ⇌ 2N O CO2 + H2
of Kc are
(A) litre mole−1 (B) mol litre−1 (13) Two gaseous equilibria SO2(g) + 12 O2(g) ⇌
SO3(g) and 2SO3(g) ⇌ 2SO2(g) + O2(g) have
(C) (mol litre−1 )2 (D) (litre mole−1 )2 equilibrium constants K1 and K2
(6) In a chemical equilibrium, the rate constant respectively at 298 K. Which of the following
of the backward reaction is 7.5 × 10 and−4 relationships between K1 and K2 is correct
the equilibrium constant is 1.5. So the rate (A) K1 = K2 (B) K2 = K12
constant of the forward reaction is (C) K2 = K12 (D) K2 = K11
(A) 5 × 10−4 (B) 2 × 10−3 1

(14) In which of the following reaction Kp > Kc

(C) 1.125 × 10−3 (D) 9.0 × 10−4
(A) N2 + 3H2 ⇌ 2N H3 (B) H2 + I2 ⇌ 2HI
(7) Equilibrium concentration of HI, I2 and H2
is 0.7, 0.1 and 0.1 M respectively. The (C) P Cl3 + Cl2 ⇌ P Cl5(D) 2SO3 ⇌ O2 + 2SO2
equilibrium constant for the reaction I2 + H2 (15) In the manufacture of ammonia by Haber’s
⇌ 2HI is process, N2(g) + 3H2 ⇌
(A) 36 (B) 49 2N H3(g) + 92.3 kJ,which of the following
(C) 0.49 (D) 0.36 conditions is unfavourable

1
 (A) Increasing the temperature
(B) Increasing the pressure
(C) Reducing the temperature
(D) Removing ammonia as it is formed
(16) Consider the following reversible reaction
at equilibrium, 2H2 O(g) ⇌ 2H2(g) + O2(g) ; (22) In reaction N2(g) + 3H2(g) ⇌
∆H = 241.7 kJ Which one of the following
changes in conditions will lead to maximum
decomposition of H2 O(g)
(A) Increasing both temperature and
pressure
(B) Decreasing temperature and increasing
pressure
(C) Increasing temperature and decreasing
pressure
(D) Increasing temperature at constant
pressure
(17) In the reaction, A2(g) + 4B2(g) ⇌ 2AB4(g)
∆H < 0 the formation of AB4 is will be
favoured at
(A) Low temperature, high pressure
(B) High temperature, low pressure
(C) Low temperature, low pressure
(D) High temperature, high pressure
(18) The formation of SO3 takes place according
to the following reaction, 2SO2 + O2 ⇌ 2SO3 ;
∆H = −45.2 k cal The formation of SO3 is
favoured by
(A) Increasing in (B) Removal of oxygen (25) The gas phase reaction
temperature
(C) Increase of volume(D) Increasing of
pressure
(19) Following gaseous reaction is undergoing in
a vessel C2 H4 + H2 ⇌ C2 H6 ; ∆H = −32.7 Kcal
Which will increase the equilibrium
concentration of C2 H6
(A) Increase of temperature
(B) By reducing temperature
(C) By removing some hydrogen
(D) By adding some C2 H6
(20) The effect of increasing the pressure on the
equilibrium 2A + 3B ⇌ 3A + 2B is
(A) Forward reaction is favoured
(B) Backward reaction is favoured
(C) No effect
(D) None of the above
(21) Reaction in which yield of product will
increase with increase in pressure is
(A) H2(g) + I2(g) ⇌ 2HI(g)
(B) H2 O(g) + CO(g) ⇌ CO2(g) + H2(g)
(C) H2 O(g) + C(s) ⇌ CO(g) + H2(g)
(D) CO(g) + 3H2(g) ⇌ CH4(g) + H2 O(g)
2N H3(g) ; ∆H = −93.6 kJ, the yield of
ammonia does not increase when
(A) Pressure is increased
(B) Temperature is lowered
(C) Pressure is lowered
(D) Volume of the reaction vessel is
decreased
(23) The equilibrium which remains uneffected
by change in pressure of the reactants is
(A) N2(g) + O2(g) ⇌ 2N O(g)
(B) 2SO2(g) + O2(g) ⇌ 2SO3(g)
(C) 2O3(g) ⇌ 3O2(g)
(D) 2N O2(g) ⇌ N2 O4(g)
(24) In what manner will increase of pressure
affect the following equation ?
C(s) + H2 O(g) ⇌ CO(g) + H2(g)
(A) Shift in the forward direction
(B) Shift in the backward direction
(C) Increase in the yield of H2
(D) No effect
2A(g) ⇌ A2 (g)
at 400 K has ∆G◦ = +25.2 kJmol−1 .
The equilibrium constant KC for this
reaction is ...... × 10−2 . (Round off to the
Nearest integ [ Use
: R = 8.3 Jmol−1 K −1 , ln 10 = 2.3
log10 2 = 0.30, 1 atm = 1 bar]
[ antilog (−0.3) = 0.501]
(A) 141 (B) 166
(C) 206 (D) 111
(26) In which of the following system, doubling
the volume of the container cause a shift to
the right
(A) H2(g) + Cl2(g) ⇌ 2HCl(g)
(B) 2CO(g) + O2(g) ⇌ 2CO2(g)
(C) N2(g) + 3H2(g) ⇌ 2N H3(g)
(D) P Cl5(g) ⇌ P Cl3(g) + Cl2(g)
(27) The equilibrium 2SO2(g) + O2(g) ⇌ 2SO3(g)
shifts forward, if
2
 (A) A catalyst is used solution of 0.01 M Ba2+ ions (Ks p = 1.0 × 10−9 )
(A) 10−9 (B) 10−8
(B) An adsorbent is used to remove SO3 as
soon as it is formed (C) 10−7 (D) 10−6
(C) Low pressure (36) The solubility of CaF2 is a moles/litre. Then
its solubility product is . . . ..
(D) Small amounts of reactants are used (A) s2 (B) 4s3
(28) H2(g) + I2(g) ⇌ 2HI(g) ∆H = +q cal, then (C) 3s2 (D) s3
formation of HI :
(A) Is favoured by lowering the temperature (37) Which is the correct alternate for hydrolysis
constant
√ of N H4 CN
(B) Is favoured by increasing the pressure (B) KaK×K
w
(A) Kw Ka b

(C) Is unaffected by change in pressure √

(D) Is unaffected by change in temperature (C) Kb
c (D) Ka
Kb

(29) Kp for the following reaction at 700 K is (38) Solubility product of BaCl2 is 4 × 10−9 . Its
1.3 × 10−3 atm−1 . The Kc at same temperature solubility in moles/litre would be
for the reaction 2SO2 + O2 ⇌ 2SO3 will be (A) 1 × 10−3 (B) 1 × 10−9
(A) 1.1 × 10−2 (B) 3.1 × 10−2 (C) 4 × 10−27 (D) 1 × 10−27
(C) 5.2 × 10−2 (D) 7.4 × 10−2 (39) Which pair will show common ion effect
(30) Review the equilibrium and choose the (A) BaCl2 + Ba (N O3 )2 (B) N aCl + HCl
correct statement
(C) N H4 OH + N H4 Cl (D) AgCN + KCN
HClO4 + H2 O ⇌ H3 O+ + ClO4−
(40) What is the minimum concentration of SO42−
(A) HClO4 is the conjugate acid of H2 O
required to precipitate BaSO4 in a solution
(B) H3 O+ is the conjugate base of H2 O containing 1.0 × 10−4 mol Ba2+ (Ksp for
(C) H2 O is the conjugate acid of H3 O+ BaSO4 is 4 × 10−10 )
−
(A) 4 × 10−10 M (B) 2 × 10−7 M
(D) ClO4 is the conjugate base of HClO4
(C) 4 × 10−6 M (D) 2 × 10−3 M
(31) Which of the following can act both as
(41) In hydrolysis of a salt of weak acid and
Bronsted acid and Bronsted base
(A) Cl− (B) HCO3 − strong base, A− + H2 O ⇌ HA + OH − , the
hydrolysis constant (Kh ) is equal to.. . .
(C) H3 O+ (D) OH − (A) K w
(B) K w
Ka Kb
(32) For two acids A and B, pKa = 1.2, pKb = 2.8 √
respectively in value, then which is true (C) KCa (D) KaK×K
w
b
(A) A and B both are equally acidic (42) The pH of a 0.001 M N aOH will be
(B) A is stronger than B (A) 3 (B) 2
(C) B is stronger than A (C) 11 (D) 12
(D) Neither A nor B is strong (43) pH value of a solution, whose hydronium
ion concentration is 6.2 × 10−9 mol/ l, is
(33) H3 BO3 is (A) 6.21 (B) 7.21
(A) Monobasic and weak Lewis acid
(C) 7.75 (D) 8.21
(B) Monobasic and weak Bronsted acid
(44) Hydrogen ion concentration in mol/L in a
(C) Monobasic and strong Lewis acid solution of pH = 5.4 will be
(D) Tribasic and weak Bronsted acid (A) 3.98 × 108 (B) 3.88 × 106
(34) The solubility product of a salt having (C) 3.68 × 10−6 (D) 3.98 × 10−6
general formula M X2 , in water is : 4 × 10−12 . (45) At 25 o C, the dissociation constant of a base
The concentration of M 2+ ions in the BOH is 1.0 × 10−12 . The concentration of
aqueous solution of the salt is Hydroxyl ions in 0.01 M aqueous solution of
(A) 2.0 × 10 M
−6
(B) 1.0 × 10 M
−4
the base would be
(A) 2.0 × 10−6 mol L−1 (B) 1.0 × 10−5 mol L−1
(C) 1.6 × 10−4 M (D) 4.0 × 10−10 M
(35) What would be the concentration of H2 SO4 (C) 1.0 × 10−6 mol L−1 (D) 1.0 × 10−7 mol L−1
necessary to precipitate BaSO4 from a (46) Which is a buffer solution

3
 (A) CH3 COOH + CH3 COON a (57) Which solution contains maximum number
of H + ion
(B) CH3 COOH + CH3 COON H4 (A) 0.1 M HCl (B) 0.1 M N H4 Cl
(C) CH3 COOH + N H4 Cl (C) 0.1 M N aHCO3 (D) 0.1 M N a2 CO3
(D) N aOH + N aCl (58) At 80 o C, distilled water has [H3 O+ ]
concentration equal to 1 × 10−6 mole/litre.
(47) pH values of HCl and N aOH solutions each
The value of Kw at this temperature will be
of strength 100
N
will be respectively
(A) 1 × 10−6 (B) 1 × 10−9
(A) 2 and 2 (B) 2 and 12
(C) 1 × 10−12 (D) 1 × 10−15
(C) 12 and 2 (D) 2 and 10
(59) What is the dissociation constant for
(48) The dissociation constant of an acid HA is N H4 OH if at a given temperature its 0.1 N
1 × 10−5 . The pH of 0.1 molar solution of the solution has pH = 11.27 and the ionic
acid will be product of water is 7.1 × 10−15 (antilog
(A) 5 (B) 4 0.73 = 5.37 )
(C) 3 (D) 1 (A) 3 × 10−5 (B) 1.86 × 10−6
(49) 0.02 M monobasic acid dissociates 2% hence, (C) 1.75 × 10−5 (D) 2.86 × 10−5
pH of the solution is (60) One litre of an aqueous solution contain
(A) 0.3979 (B) 1.3979 0.15 mole of CH3 COOH (pKa = 4.8) and
(C) 1.699 (D) 3.3979 0.15 mole of CH3 COON a. After the addition
of 0.05 mole of solid N aOH to this solution,
(50) Components of buffer solution are
the pH will be
0.1 M HCN and 0.2 M N aCN . What is the pH
(A) 4.5 (B) 4.8
of the solution
(A) 9.61 (B) 6.15 (C) 5.1 (D) 5.4
(C) 2 (D) 4.2 (61) KSP of AgCl at 18 o C is 1.8 × 10−10 . If
concentration of Ag + is 4 × 10−3 mol/litre the
(51) What will be the pH of a 10−8 M HCl solution
concentration of Cl− that is required for
(A) 8 (B) 7
AgCl precipitation
(C) 6.958 (D) 14.04 (A) 4.5 × 10−8 mol/l (B) 4 × 10−3 mol/l
(52) When 10 ml of 0.1 M acetic acid (pKa = 5.0) is (C) 7.2 × 10−13 mol/l (D) 4.5 × 10−7 mol/l
titrated against 10 ml of 0.1 M ammonia (62) What will be the pH and α (degree of
solution (pKb = 5.0), the equivalence point hydrolysis) respectively for the salt BA of
occurs at pH 0.1 M concentration? (Given: Ka for
(A) 5 (B) 6 HA = 10−6 and Kb for BOH = 10−6 )
(C) 7 (D) 9 (A) 5, 1% (B) 7, 10%
(53) N aOH(aq) , HCl(aq) and N aCl(aq) concentration (C) 9, 0.01% (D) 7, 0.01%
of each is 10−3 M . Their pH will be (63) A beer has a pH of 4.30. What is the [H3 O+ ] ?
respectively (A) 3.0 × 10−4 (B) 2.0 × 10−4
(A) 10, 6, 2 (B) 11, 3, 7
(C) 2.0 × 10−5 (D) 5.0 × 10−5
(C) 10, 2, 6 (D) 3, 4, 7
(64) The approximate pH of a solution formed by
(54) A buffer solution has equal volumes of mixing equal volumes of solution of 0.1 M
0.2 M N H4 OH and 0.02 M N H4 Cl. The pKb of sodium propanoate and 0.1 M propanoic
the base is 5. The pH is acid (if the dissociation constant of
(A) 10 (B) 9 propanoic acid is 1.3 × 10−5 ) will be
(C) 4 (D) 7 (A) 1.52 (B) 3.62
(55) The pH of 10−7 N HCl is (C) 4.89 (D) 5.52
(A) 6 (B) 6.97 (65) What will be the pH of an aqueous solution
(C) 8 (D) 10 of 1.0 M ammonium formate ? (Given:
pKa = 3.8 and pKb = 4.8)
(56) If pOH of a solution is 6.0 , then its pH will (A) 7.5 (B) 3.4
be
(A) 6 (B) 10 (C) 6.5 (D) 10.2
(C) 8 (D) 14 (66) If Ksp of Ag2 CO3 is 8 × 10−12 , the molar

4
 solubility of Ag2 CO3 in 0.1 M AgN O3 is (A) H3 P O4 (B) H2 P O4 −
(A) 8 × 10−12 M (B) 8 × 10−11 M
(C) H3 O+ (D) P O43−
(C) 8 × 10 −10
M (D) 8 × 10 −13
M (77) Calculate [H + ] of 0.01 M A+ B − salt solution if
(67) The pKb of CN is 4.7. The pH of solution
Θ
Ka HB = 10−12
prepared by mixing 2.5 mol of KCN and (A) 10−2 M (B) 10−7 M
2.5 mol of HCN in water and making the
(C) 6.2 × 10−3 (D) 1.6 × 10−12 M
total volume upto 500 mL is.
(A) 10.3 (B) 9.3 (78) What is the percent ionization (α) of a
0.01 M HA solution ? .......% (Ka = 10−6 )
(C) 8.3 (D) 4.7
(A) 9.5 (B) 1
(68) At 90 o C pure water has
H3 O+ = 10−6 mol litre−1 . The value of Kw at (C) 10.5 (D) None
90 o C is (79) HCO3− is a conjugate acid of :-
(A) 10−6 (B) 10−12 (A) H2 CO3 (B) HCOOH
(C) 10−14 (D) 10−8 (C) CO32− (D) CO2
(69) The degree of hydrolysis of which salt is (80) If pKb of a base is 5, then Ka of its conjugate
independent of the concentration of salt acid will be
solution ? (A) 105 (B) 10−5
(A) CH3 COON a (B) N H4 Cl
(C) 10−9 (D) 10−14
(C) CH3 COON H4 (D) N aCl
(81) The hydrogen ion concentration of a 0.006 M
(70) Find out Ka for acid when degree of
benzoic acid solution is (Ka = 6 × 10−5 )
hydrolysis of 0.1 M CH3 COON a is 1%
(A) 0.6 × 10−4 (B) 6 × 10−4
(A) 10−5 (B) 10−9
(C) 6 × 10−5 (D) 3.6 × 10−4
(C) 10−7 (D) 10−13
(82) Calculate the amount of (N H4 )2 SO4 in grams
(71) Calculate the pOH of a solution at 25 o C that
which must be added to 500 ml of
contains 1 × 10−10 M of hydronium ions, i.e.
0.200 M N H3 to yield a solution with
H3 O +
pH = 9.35 (Kb for N H3 = 1.78 × 10−5 ) ........gm
(A) 1 (B) 7
(A) 10.56 (B) 15
(C) 4 (D) 9
(C) 12.74 (D) 16.25
(72) A weak acid HA has a Ka of 1.00 × 10−5 . If
0.100 mol of this acid is dissolved in one litre (83) What is the pH of a 1 M CH3 COOH −5 a
of water the percentage of acid dissociated solution K a of acetic acid = 1.8 × 10 .
−14 2 −2
at equilibrium is closest to.....% K = 10 mol litre
(A) 9.4 (B) 4.8
(A) 0.100 (B) 99
(C) 3.6 (D) 2.4
(C) 1 (D) 99.9
(73) The solubility product of AgCl is (84) If the hydrogen ion concentration of a given
1.5625 × 10−10 at 25 o C. Its solubility in grams solution is 5.5 × 10−3 mol litre−1 , the pH of the
per litre will be solution will be
(A) 2.26 (B) 3.4
(A) 143.5 (B) 108
(C) 3.75 (D) 2.76
(C) 1.57 × 10−8 (D) 1.79 × 10−3
(85) The strongest Bronsted base in the following
(74) What should be the degree of hydrolysis of
anion is
0.01 M Lithium formate solution at 25 o C, if
K = 3.175 × 10−5 (A) CN −
h
(A) 5.63 × 10−3 (B) 5.63 × 10−4 (B) Cl−
(C) 5.63 × 10−2 (D) 5.63 × 10−1 (C) I −
(75) pH of a mixture which is 0.1 M in (D) Br−
CH3 COOH and 0.05 M in (CH3 COO)2 Ba is
[pKa of CH3 COOH = 4.74] (86) The solubility of Ca(OH)2 in water is ....... .
(A) 4.74 (B) 5.04 [Given : The solubility product of Ca(OH)2
in water = 5.5 × 10−6 ]
(C) 4.44 (D) 7.56 (A) 1.77 × 10−6 (B) 1.11 × 10−6
(76) What is the conjugate acid of HP O4 2− ? (C) 1.11 × 10−2 (D) 1.77 × 10−2
5
(87) P bCl2 is dissolved in water to make its (A) KCl (B) N aN O3
saturated solution. What will be the
(C) CH3 COOK (D) K2 SO4
freezing point of this solution.
Given : Kf (H2 O) = 2 K kg mole−1 , Ksp (P bCl2 ) (95) A white salt is readily soluble in water and
= 4 × 10−6 gives a colourless solution with a pH of
(Assume molarity to be equal to molality) about 9. The salt would be
.....o C (A) N H4 N O3 (B) CH3 COON a
(A) −0.04 (B) −0.06 (C) CH3 COON H4 (D) CaCO3
(C) −0.02 (D) −0.6 (96) Solubility of BaF2 in a solution Ba(N O3 )2
(88) Phosphine decomposes at 300 K and 3 will be represents by the concentration term
atmosphere as (A) [Ba+2 ] (B) [F − ]
4P H3 (g) ⇌ P4 (g) + 6H2 (g) (C) 12 [F − ] (D) 2 [N O3− ]
Calculate the vapour density of phosphine if (97) The hydrogen ion concentration of the
it dissociates to the extent of 30% oceans is about 2 × 10−9 M. What is the pH
(A) 18.14 (B) 10
(A) 8.85 (B) 9.3
(C) 13.8 (D) 11.14
(C) 7.85 (D) 8.7
(89) Solubility product is (98) Select the set of amphiprotic species?
(A) The ionic product of an electrolyte in its (A) (B)
saturated solution H3 O+ , HP O4−2 , HCO3− H2 O, HP O3−2 , H2 P O2−
(B) The product of the solubilities of the ions (C) (D) All of these
of the electrolyte H2 P O4− , H2 P O3− , H2 O
(C) The product of solubilities of the salts
(99) In which of the following combinations, is
(D) The product of the concentration of the buffer action expected
ions 1. N H3 + N H4 Cl
(90) Solubility product of a salt AB is 1 × 10−8 in 2. HCl + N aCl
a solution in which concentration of A is 3. N H3 + HCl in 2 : 1 mole ratio
10−3 M . The salt will precipitate when the Select the correct answer using the code
concentration of B becomes more than given below
(A) 10−4 M (B) 10−7 M (A) 1 and 2 (B) 1 and 3
(C) 10−6 M (D) 10−5 M (C) 2 and 3 (D) 1, 2 and 3
(91) The hydride ion H is stronger base than its (100) Which hydroxide will have lowest value of
−

hydroxide ion OH − . Which of the following solubility product at normal temperature

reaction will occur if sodium hydride (N aH) (25 o C)
is dissolved in water (A) M g (OH)2 (B) Ca (OH)2
(A) H (aq) + H2 O → H2 O
−
(C) Ba (OH)2 (D) Be (OH)2
(B) H (aq) + H2 O (l) → OH + H2
− −

(C) H − + H2 O →No reaction

(D) None of these
(92) An aqueous solution of ammonium acetate
is
(A) Faintly acidic (B) Faintly basic
(C) Fairly acidic (D) Almost neutral
(93) A litre of solution is saturated with AgCl. To
this solution if 1.0 × 10−4 mole of solid N aCl
is added, what will be the [Ag + ], assuming
no volume change
(A) More (B) Less
(C) Equal (D) Zero
(94) In which of the following salt hydrolysis
takes place