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N

M
6 0
x 2x
6−x 2x
ⴄⴄ

solving for x at equalibrium


6−x=2 x
x=2 kmoles
¿ material balance ,
Q
V ¿)¿ But Q=¿
ZF

V ( C 1−C2 ) = ¿
zF
VzF (C 1−C 2)
Hence t=
I
n
Using C=
V
(6 ×1000)
C 1=
2
−3
¿ 5000 mol m
(4 ×1000)
C 2=
2
−3
¿ 3333.33 mol m
Obtaining the total current
¿ V Applied =V ohm+ V min +η a+ ¿ ηC ∨¿ …………………………………...1

But ηa=0.3+0.18 log ⁡(i a)∧ηc =−0.15−0.2 log (i c ¿)¿

But V ohm=0 ( due ¿resistance ) , V min =1.25 V ,V applied=1.7 V

Substituting into equation … … … … .. 1


1.7=0+1.25+0.3+ 0.18 log(i a ¿ )+0.15+0.2 log (ic ¿ )¿¿
since I =i× A
I
Therefore i a=
Aa

I
ic =
Ac

I I
1.7=1.7+0.18 log ( ¿ )+0.2 log ( )¿
Aa AC

0.18 log ⁡¿ )¿ 0
I =174.52
VzF (C 1−C 2)
Therefore time t=
I
2× 1.2× 96500(5000−3333.33)
t=
174.52
t=2,211,785.3 seconds .

¿ VIt=n ∆ H + q
n∆ H q
VI = +
t t
q n∆ H
=VI −
t t
q 4 ×1000 ×148 ×1000
=( 1.7 × 174.52 )−( )
t 2,211,785.3
q
=29.057 watts
t

Question 4

¿ CSTR design Equation


N ( C 1−C2 ) =kδ C 2 A C
Where N is the volumetric flowrate=ss

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