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NCERT REVIEW A

192
1800PM-> CONCEPT
MOLE dectre 3

SPECIAL CLASS - FREE

F:OOPM - MOLE CONCEPT

pyaw LIVE
⑭
I --

I
⑭
 ↑ BLOCK

5-6 dective

↳ 3-4 dus
-
--

Theortical
*

* Short
Notes -
⑲
P BLOCK

I shieldingeffect:
-

z-0
screening
Zeff
* =

e- ↓
e- -

e-
2 Slate's
① e- -e e
constant
e
e-

single system
e e

Multi
order?
-
-
-

e-system
>P>cf =>
reason:-shape of obtal
 right Zeff4
Zeffsiring effect
to
Left
-

Top
to Bottom-
Zeff
INERT
*
PAIR EFFECT8 -

ns np
16 Down the
effect
group, screening -
is door due to d and abelal,
L I
Four atte"* Nucleus attracts more;
of
↳ ·: cannot be removed
: Becomes INERT
Oxidation
State:-
--
INERY PAIR EFFECT
-

2
913 no up"
-

1 1OS: -
B* <Al< Ga*<Int<Te
Lower OS
3
Alt3> Gat> In" > Tet
30S:-
+ BT3>
night us
 ⑧

COMTEMT No
compromise
-

nnp
914
*

-
-

-2 OS 8 - < SitLat <Sn" <Pbt2

Lower OS

+n OS.-ct4> Sit>(>snt>Pbt4
right.
OS

INERT

higher OS-stability
his down
group PAIR

Lower OS -> s Yes i 11 EFFECT

 SPARTARNMY
NCERT REVIEW nup"->Man
A
0s= + 3
913

all is not - + 4

415 ns2 np3 - +5

+D
A3
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IMP
A

- ANOMALOUS BEHAVIOUR i-

small
size
*

Absence a-orbital
of
*

is 2 p" xd
(B] - as

Wh
Gobital-4Bonds -
-

d-
abitats [Al]->[e] 3s30'3d"
EIEN1]
Gobital - 6 Bonds
-
-
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Al
NCERT REVIEW A
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↳ RADLOACTIVE
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A. -

BG GaCAl <In < Te

↓
d-electron
↳ poor
screening
↓
Ga
-
-
Zeff*
↓
h
size
&-Block contraction
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NCERT REVIEW
Ionisation
A

Enugy
DHAMAAL MOVIE
Be
Bo ·Th ↳
Th
Ga
·-> ⑧

Al ·
In
Al" in
1E:- Bx T1 > 4a) Al> In
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NCERT REVIEW A

E B> T1 > In> Ga> Al

-
utti
-
-

Reason-> Network solid

C
-

I
giant
-

- structure
A/R
-
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NCERT REVIEW A
 + 1
Ints and Last element
In
Less stable Mor stable
It good
is

3
Last element
oxidisingagent. Why?
H +

Th Th

More stable Less stable Tet 3 - Te+h

Less More
stable stable

agent. Why
+1
is
In
- reducing
reducing
- +3
ovidation
aguel In" -> In

Less stable More stable

 Halides Baron 1s2 2122P" ·

of B Youbelal
--

#17
-

Lewis And
~

↳ -
deferent
->
-
-

2 -
2 2 -
3 2 -
4 2- I

BF3 BUs BBME B13

as

· L
00
: -00

B - F:
00
Lewis B -
I:

·Ose--it
Acid 0

·.
o
-
-

Back
Bonding: -
BF3>BU, BBRS BIS
Acid: -BF3 [BU3 [BB3 < BI3
Levis
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Al-> Protective

Laye
->
-

B203 -
Ander

Al2O3 G9203- Ampho

Ina03 T103- Basic
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COMPLEX
-
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NCERT REVIEW A

T13 does not exist

↳ Tet 3
unstable

Eisen
↳ Steric
-

herderance

Bleed
-
-
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78
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BEAD TEST

COBALT
OXIDE

Sno-wall of
-

BORAN
-
-
8 - *u]
Nas (Buo,
-

crystalisation

[ I
Chayo--on
A
strong Base Weak Acid

·
OH,O
So be
se
in
⑳
 SPARTARNMY
NCERT REVIEW H3B03
A

-> Boric oxide

meta Boric
Boric Acid HzBOS ⑳

Auch
-

or

B(On)3 Layved
structure
⑧ -
--

member Sheet like structure

-

-
⑧
-

ray ↳ Due to H-
-

n 1 Planer
= -
sp -
-

OH-

<non
BCN), + 4,0 -> [B(on),]' + nt
onion
acceptor ad
-
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Redurung
ut
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-

NCERT REVIEW
↑

A
↓ O

Boric amde
-

Hydrolysis
of
Be H6
Beto- e-

I deficient
00

0 O Adduct
-

IMORGANIC
BENZENE

↑
 -
INORGANIC BENZENE
Reachurly
->

B3Nz H6
in Indganini 7 Bregene

Y
4 -
N N -
4
I H
4 -
B B -
H

& N-
is
 Bridge 4
·

Batts
structure
of - 3C-2e BOND -DS
-> JBANANA

!
~ -
BOND)
H
Ha
·
-
-
4

-
B B -

In/y-Tuminal
-
~
H H
BOND NO. OF A TOMS
-

22 26 IN

NDS ONE PLANE - 6

Bat -(B4y]-+ (B42]

samine(Bridgonezmons
S e
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BOND STRENGTH: -Tuminal Bridge

BOND LENGTH: -Tuminal
Bridge
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Melallugy
~

I
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413-no up"
Gin-nup2

<Si <ae<S<Pb
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IE ⑧
-

<Si) al) Pb> Sn

ulti
-

-> EN:-C>Pb> SiGen

-
2.5 109 1.8
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MP/BP G14> 413

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414 8- no p
-
-

20S
+
c Sit (" <Sn"<P*
Lower OS

40S
+
C
+
4> sit> Get> Snt>Pb+ y
OS
Higher
INERT PAIR EFFECT

Isnet Pai
effect
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RA
A

-
Sn thution
int
Less stable More stable

OA reduction 12
-
pyty --
Pb
Less stable More stable
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Acidic oxide
40
-
-

CO2 SiO2 CO2

oxide
Amphotive
SnO SnO2
PbO PbO2

Neutral Oxide
IMP
- CO
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+4

FAJAN's Rule

Covalent characte
Anion
↳ small cation
large
↳
High change
er.-
+2
Stability
M PoXa > Ob Xn
Sixa < SnXy
Luxa < Gexy
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AIR Sicu + 420

d

Si (only silicie
I acid
Silly
nee
 Cy
Hydrolysisof
420 NO Run
Cay + ->
-
-

Platon ·- (has orbital

unfty
no
-

sily-empty d-orbita-hydrolysis-
clu - no orbital-hydrolysis
empty X
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catenation
-
-
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conductor
of
A
heat - network solid

of electricity
conductor
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Heat

Electricity A
↳ Free e
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(Angraphite O

⑪4) carbon Fo
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combustion
Incomplete

-
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10:00 PM
↳ IUPAC t1
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IMP
-

carbony-harmo
globien
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A
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MP/BP- UEG4 I NETWORK SOLID
A

I
MEMBER
RANG
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Siva-dehydrating
aguit
-
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RaSiCz

ALKY Halide

POLYMER
-
--

(3) SiO-
RaSiO
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NCERT REVIEW A

Rasina -

Polymer
R3 SiCOn) -> No
Polymer
R R
(Dimu)
is a

Si-on yo-i-R
I

R = -> R-Si-0-Si-R
a R ⑨ a
Dime
-
-
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Side"
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