2015 é\y :ôy) fu-s tp| cèb-; :iJl-:Jt 4iu-ll y'-; a-elyrll A{tâ)l

p-/,'Jt:ArU Ja"A.Jt

dJYl eJ.àdl ,Jo L.bTl ;',-at]r

S r 0 j - , , nr + 2 H , 0 n , o n )= S ( , , + , S O 2 ( e )* 3 H 2 0 ( t )

0,25x3

: r*Jl &\ii^ll +:-i -2

0,25 - r . o * = 0 + x , n r * = f r 0 :1c f \= 0,5x0'480=0'24mol

0,25 -2*,nu^=0+
no'-=""
x * -â. . = x - 5x0'02 =0,05mo1
2 2 2
3'5 Xmax: 0,05mol 3 H3O+iuqlI .u^Jt glctiill a-r""3
0,25
HrOo , SrOl- : r*.,lr^icGiil ui-slJI-3
0,25 "'l'"J4rùtjll

4,25 3-eJt;o: j i-F_llil)+ rloliljl êrii J*ii Jt-$^ çrÀ: &uill4+4}-lt 4-!l .-iJ*i -i -4
I -d' x . , \ , , , , -
= -x
v .v. ^ , o 431&llr (sbilJ
t v û

1 do(r ) dx 1 do(t ) 20,6- o(t )

=-
vuot € rc- =tnî-= :ûLr-r+lr-c,
"*"Tۈ--- do( t ) "r"T
0,25x2 4r4r
- d t= --1704
d r r+., o(r) = 20,6- 170x Ë;rJl ;^ 3i

V u =o -/ J - * d o ( r )* + 0 " { ' ) : - t 7 o + + = - } 7 y v u o ,
l70V dr V dt Y dt

:;*^Jta-!li^$ - -+

o)s I 0 - r5xx.,'
u- 4 rr'
, 1 2-7,53mo1' 's-l
x rnit 's-l = 1,53xl0-3mol 'fl
1 7 0 x 0 , 5 x 1 0 - '1 5 8 , 7 - 0 'r.,v
- .l ,- 1
\ ,\'

. Skill 4i^;É, i. - JÊtrill ê$i L:U tj)Jt cl"-lt :r :Jrliill LÀÉi ùaj.+J'i -r
0,25

4,25 o( t,,r )= 20,6^170x0,025

= 16' 35(I5m) :+'*
t t172: 48,3s :r+.,ub+lltr-l
0.25 ( 4 o, â-
\-'--
é--
i+iiJl 4+J"ll elilt .ts: :il=>*
"rÀ d)"

161
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A-ùrJt
61j+^
cbTt gÉ-rll !L-. Tl -.xatis
eJ"+. ".!o
(.hl3i 03) ;(J'itiltu*nijt
 l r l s- 1
:'*!l-'2C - I X + -l e''.'l<;rll
4,25x2 t l t t* ' l x = z = 6 - ( - i ) = 7s A = 1 4 - o = 1 4
tlc-troN*-fe:a--r
0,25
.Lrjt ;,!u _l _2
4,25x2 E,('tC): (6m,+8m,- mç'!c17.c2
= (6x 1,00728+ -13,99995)x
8x 1,00866 = 105,268815MeV
931,5
Ett'lr-t 105,21
-J-ril-; = t.>2MeV I nuc '. 14 r,,f_.,Sll
Ëlll4+-d .JSll+jl i-{Lt -ç
0,25 t4 14
3r0
.14 O-*él: 12 ùr-ÉJla;yluc -i-l
0,15x 6,0_2x7023
0,25 N(,, C) - = 7,525 xlOztnoyaux
12
0,25 x l'2xr0-r2 = 9, 03x 10enoyaux
^Io(toC) = 7,525x 1021
-e'r
: Ao çJTl5+Yllât'i'ill
ln(2)x No=
u = ).N,,-
,4^ u i{l to-t ",t12.,:0.03468q
tr,, 5730x31536x10'
0,25x2
j119
t,,-*ln 4 5730x1,r9
0,25x2 "' A(t) - a'023 =3375,76ans
:{$ilr yc -
t=
':? Y: -.-.1:L:-*----â-',
(.hr: Of) :éJtijt ot"-Fjt
çO
* r :q+,,Ul Lrél j"* -i- 1
f-Jll f 1 tL - F* = ^â + p *t : *â '.dÉC jtsl 6ylJiJl -,,'
ar+t3+
4,25
o
+ l
ut

mg- Kv = ma= ^4 * L* Lu = g : OZ.È lb)!-r

0,25x2 P l d t d t m
d - v -y,^ k m g

3'0
0,25x2
i
I
-
dt
(r:>
*
,i- = I I vr*
=
I
'v1;' !:':Jl 4t-"Jl Ë-'rl+t-'+

I
ltjn, : 2,0 mls. \ii gj''r^JJ,rs!l ..'-ltiJl ÊJôi"*llet -l'2
4,25 lz
k =!Ê = lrl =l,ylls-l =lullrl-,:,r
=lu=]l:l?-,1' -+
ô:--r
A,25xZ L r L -- r L - I
vri. [ u , , _]
+r("/t) [r ][r ]-'
I Kg/s Q ftËrr-la'ra3
0 ?5x? l ' 7 ,ffi -vIi,n=Z=0.2st"+r4+r=11 4.È!l ;:!. cr :mlk idl.-l . -
|
l .
/ /
i
r
k g l0
0 ?5 l , / t .éhll etÀill Èrt* * er"+-r Jtii:yl ltl^ill rJ)-i,-;";Jt -l-r-.r+..,-!1r+ftL-3ll -3
0,25 I i'gt :flrill .,.àdyt$tbiJI4.c-"Jl ,-i:l^ -4
0

tl l2 ia,.i*
2015 ôljrr :ôyr {.f+,bps **r{ :i.r.iJl aibi1ljl1rl'Jt,lrt, }"aJt d-: *-qir"rll i{q)l

c5Ttgg-àdl crJe!t+Yl vaLir:

3,5) ;n+l;JlctpÉll
-1
:'ricil-p-:Êll ê^+ Ô-*'t!d#lJ+ :4J;tlilt ÂJrLJl )b+l
di
*(R+r)i=L= r!!+(R+r)f = E euo*uu=E
0,25x2 d t L L d r
. L t < .ùï lilç À r
(\ 2
- .\/. .. .. .. .. .. ......4. L
d+t ai = F
^ E ''ii{iirtÀ^lt't
0,25x2 F=T ) a, = R * '
L
;dJl ua JiJl -2
S ; R
0,25x2 = p € f , - o ' * q L - q 1 r - " ' = '0 e ? d= Ên- "' +- : t- ( 1 - e- o')
t i( t) d
d a
.r+tàli:ll il:L'^ll )- ;À1Jl illt'Jt e-u"3
: u6(t) i-.r!'-3

,.\ , di ., , E _, E ,-"Y,
u t ( t ) = " * * r t = L - LLr-,T, *,
R+r R+r

-I;) .# =#
: E,-Y'(, *# =*r,*R"-Y')
ru-T'
a+F! -ri
R+r, ,R+r R*1, R-t,
h-
un!): E-uo = E- N(l*e L )=(À+r)1- N + kle L =rI+Nea-' =-!-7r+Re'')
R+ r
L,r :3;lr - i - 4
Up

0,25

; ra, OlJt ei -.:

o?5 E:6V ;rl3,"Llrgt',)aSllislt ;;ilt -
l,5R 1 , 5x 1 5 Fr
r:- :5Ç)e
0,25 E -1,5 6-1,5 R+r
r =25ms:drJll d+li -
0,25 -
L = r(R* r) = 0,025x20 = 0,5H :e=ril-:ll
0,25
- R * ' ,'
I , 1
. i2 = -'- 71 =:--
F ^
- u t ' â+LJllâ3uJtirti. -i -5
Errt= )' (t )'
2 2 R + r
Er: Li' / 2 çl_rll .J+
i+S -e
: prl-rJlplÀill çr â-ËlJ.ll

0,25 E ( , , = î , : = f , r [ # ) ' = t * o , r [ , r = )=' r , 2 5 x . t - z r

163 ll | 3 e2,Àê
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cbYl t3,àdt .,t" tçVl ;r.al,b

3,5 ) :tl*lSll cl*yill

4,25 _> .B : A,-x dytt ,-JÈâlll"ll!eçi+U-i -t

0,25 P
û, Eppn+ Ern-l wr*,(f) ,ooo + Ecu
irx l:
h n - h u= A B x s i n d . , m & ( h e - n ) * I * v 2 u= f x A B. , .
q|: / .u3
,: - ) 8 0 ( 1 0 x5 0 x 0 , 5- 0 , 5 x 2 0 2 ) _ o ^ À r
, _ m ( g x A B x s i n a 0 , 5 .v ' ? _
" AB 50 :4--r
: âS-olli.'+t +:=î -ç
0,25 X'X.'l.ti-)t 14; = ^â> p * n *t =mâ
{
mgsina-.f =ma>a- gsina-J -çte
m
0,25 :terl.b p iS;r=ll a.r^,
êt-Eijl+ê
v ' 4 o o= +. m, /)
o= s-
4,25 2*=ioo
.s-oi ,-iJt dl""j-l ùfu
: _r.:+J;UJl ;3,rËt é*ti+ : _11*llâJ.rl,--/
â*g=>,F-,:F=*à
; r.r"i y;ç'' .rL lLL)!
a" : 0 à V, - [/" è x(t 1 =Y"',
0,25
: .+, yy' .,lc !i-Yl-r
nt<
V,: -gt + c =-gt *+=-g
c=0<-t:$:r--rY € ay= -g
dt
i , d y
. ' - -gI
Y - - - P t -+ c ' e V -=
/. dt

0,25 c ' = h < - t = 0 : O Y-V = -2! S" t ' + h

4,25 8 ^ x ' + h < -t = x

'y = -
2V"' V"

V' =V| +Y] =V/ +(-gt)1 -î -3

;;_1t,Jl

o)5 Y2 : g?tz+V/ ,q BIÀil'll-

0?s vc =laml s ev] :Io0m2i s2:t"b -.:
0,25
V t i= l 5 m / s e V ; = 2 2 5 m 2l s 2 s
:r+..,E : C cr+4-â1J.11 j e ér.tq : h glii-rYl - r
0?5 , v -: - v .' ' 2 2 5 - t o \: 6 , 2 ) m
ll=
2-g 20
t E . -:1.,- rrr Ajj^jll il:lJl cjl-'j-l 4EJt .JS

ll 14 za,À_a
L64
2015 ôi3* :ô19r,'rL; ç*S cptr-; piJall:ô^:t LriCl d-: a*if."il ;{tâ}l
:i-r.iJl Ul.,.i-Âll

ctsTtg*Cl ,"!o tt-Jl *,;^aLir

1l.Lii 3,5 ; ;,rru+:ll r.t*..r:Jl

+ H rOu, : CrH rOrro,tlI H 3Onvq1 :,Jrtiill ilrL- -l-1
C rH aorçon1
0,25
-cJ
cJ-1":r+
JJ+
âlrLll C r H u O i t o s +) H r O ( , ) = C r H r O u t " r )+ H z O * { o q )
0,50 lLJtÂ11- ê.:ill $lr;rt-lt cit*.<
4rilJSrl 0 ng â,pr 0 0
I k--'l
4,lltl.!I X fIO-X x X
4#L(r Xéq oo-Xéc Xéo Kéo

' Â-JÉtJ4JSll
:l,2iYt 5t; *
z ' += 3 , 9 8 x 1 o - 3 m o l I L
luro.f nn=lQ
o ?5x?
l r r o r o ; 7 n r = l t I3 0 * l n n = ? = 3 , 9 8 rx0 - 3 r n o l l L
-lo ro*f = 3 , 9 8x 1 0 - 3= 9 , 6 x 1 0 - 2 m o
f c u uu o r f n n= c n, 0,1-
/ Ll

lc ^a,o;f =
0,25 pka = pH - log i=-:--ig 2,4 - log 0, 04145 = 3,78 : pka a;;'*JJ '-'il-i-:
lC'H uorJn,
b,,l * u J
C3II6O3@q)* HO- ç,q1= CrH rO, ,,r) * H rOt,., : ;iLJl TJil-
0,50

:C" j$-lït -'--'

' jÂlsill $c

C o 'You x28,3
0,25x2 L,A
= 2xl}-z = 0 , 0 5 6 6 m o 1I L ç C , , ' V o= C r - V u ,
vo 10
4,25 Co = 100C, = 5,66mol/ [, 13^3
MC, MCo _ 9 0 x 5 , 6 6_
{J,25 45,0 8 = 45Yo : llnl Àr-.Jl--+
-
L / -

ljd l'11
l0x-4 1 o, .
p' 1
_ 509'4 =0,4508= 45% âil*llu p ,-L-^3î
l L Ê J t r i l + é l ] r rp = ' ' '
rn 1130
n?5
C-rM 4i-X1 *t çr:S t" 6i eli;

16s ll I 5 â-Àê
 :oy.: ëVS tfS apt4
2A15 rrl_5ra :aor*Jt Uq,i"iJll:ÀJt :ô.:t L";'rll C-J ;ïui9"rJl 4l?)l

;t3t gl;s"Jl ,,Jo qbYl ;l.oLie

(.hti:09) :.ldl-1,
''gl(ÀillâJrL^ -1 -l
:''r- 'rtu^Re -+tllOs+
lX
0,25x2 'lf ne-+'lfos+ -le o j * sZ = 7 5 - 7 6 = - I ; A = 1 8 6 - 1 8 6 = 0
\:'
-'r'
0,25 P- : dJ'ill L^i

o?5 JJ o:-,+ cJJ*.,.r'"!-dru: Ë$l uc j uÉ":lsl'e+él !-tYl ,=t'Ôr+ : P- 4-'

in- lp* -in :âlriJl éÀJUrJisll :l*J 6^c.rs-u

Ao = 4 xl}e Bq . r+, ùt;.rllrr : A0 i^S 6E:i*t -\-Z

-Ç
4,25 JJ i{Jll"l,ij u,-IUi,i; ar;Jt agiÎ so ,-iu-.i,rl<itl ;;)JI cl.Jl _* :t172l-!r:i
3r0 (d--ill
4,25 '\2:3,5jours : r+r çb

- ln2 lnz =
4,25 À- - = " 0.198i- t = 2.3x10*6,ç- r:l i +$ * - +
Itrz 3,5

tIurReâr-ylrre -3
.tr *

O)\x) 4 x 1 0 er * 0 , l e 8 x l 0
= 2 - 4x l 0 ' an o v a u x
2,3 x10-b

A,25xZ l , 2 x l O t ax i 0 f z . + " l o t -a+ r o m L

V= = 5,0m1
' e 1
2,4xl)ta t r,2xlota--+Y

ll I 6 t',,;*
r66
 l

2tl5 ôfj* :ôy; ëtt PS a&lrl :i*r-Jl UIJJJI p3trll :ô11* Lr;Ct d-J Ar"lj-Jl !lt)l

4.l)lrll
;ii+. ;tltt g+a.rtt ,"t" tt^Jl ;rLlç
8i.+r
(;Àii 3.5) :crtill +Ystt
0,25 .ËJtit _l
ËJ
: 'ri diltll gç 4i!i é#.t+ -2
)-,
u*, uc> Rcrytuc=Eeur*uo=E
dt
E
A,25xZ -+

d r , _ -Ae
+.#:#* _ l
r e ur(t): A(7- e ') :ota..xjl-3
dt T
'4.,Làli3Jlâlrl*ll,'lp
.J-JJ'il!-t
-r1 1,, A E_=o*!u-;*A_uu-l=L
A u' ( ; - 'r RC RC- RC
Rd* nc- nc
-!- -!- I 1
: + n sA e 7 + 0 :e A"-7(!-=^l- Q"'!-
r RC'
0,25x2 n = E j-- j-=g
A=E= *
RC RC ÀC RC
1
^ - - - j1- = 0
T : R C e
T R C
RC) 4r^J
. iJ*à\nlli.lrt Jl cJ- p u"(t)= E(|-e
315 | -L -t-
ln(E- u")= -' +lnE e E-ur, = Ee ' Ç uc = E- Ee' : â ' â ) tÔ
* lSl l - 4
0,25 t
tut# -5
' Àiltlll ôJGll : E ;'^$-f
:a+^ ln( E -uc ) = at *ô
0')5
l n ( E- u r ) = - 1 0 0 0 r + 1 , 5oe= -( # J-= - 1 0 0 0; b = 1 , 5
1,5-0/x10-'
'
lnE :1' 5 => E = 4,5V ' r r iÀ1 }^l Lr 'l
0,25 z 0
v '0v v0r1 - : i : =1 --
- == -
C :l0.0uF eî 0 , 0 0 I s : C - r . r , - * . J si + _ ç
À 100 1000
0,25x2
E (,(t) = Lcur, = LcE, (l- u-#), -1-6
: allLlti$-llt;_,r.'Jr
L /'
0,25 ' i'.,*tll t-rt"'':' -c-

1 -
F,-\
Lclt)
lcc'(1 -r-')t
-Z - ( 1-
)' = 0,4
0,25 J|,ctoo)
1
!CE,
"'t
^
z
(-
- ÂC
C,^= € C JrQ . x , R= € r :!-:C'L!Âç16-7
0,25 n
.+ 4 4
.4i,tJl liKll C JiJ-dl .i. f+; iriS^ll+r"-r
I 1-1=4-r=]- 1=l*1
0,25 ç ' : 9 =_t3-0 J-JJUr
' c
ç:-=
' C , , C C C C C O , C C '
=
3
ll I 7 1e,À.."

167
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;Élt g-raCl uJe dil+Tl yl.ic

(aÀït3 .5) :e[ijl uu;ll
+
N H ; ( o q ) = N H t ( o q t * H (as)
0,25 * = H
H (o, I + H o (-nq) zO ( /)
g*\-l -rra,"- gloLi:iJla-t".9
cj:r+ -c+
0,25x2 NH 3(oq)* HrO (r)
NH Tt.nt+ HA loq):
J/q;r[Jl cJ;.s

:13'"te e$.tlr

x*o, : CrY, : fro: 0,15 x ZAx 10*3: 3 x 1A'3mol e Ctvl - x-* = 0

0,25 x^ o , = C rV , = fr'o= 0,15 x l0x 10- 3: 1,5x 10- 3mol ç Cr Y, - x * * = 0
0,25x2 :J"lflr.J HO- 9 r*lt jeÉiJl 4tJ
.x.u* = 1,5 x 1 0-3mol
3'5
:ôta:ll-+
0,25x2 = n'a- xno)
fruocro-)
- ,lo-lrognr)**V,
*no= ,'o- flno("o,., = i, -la-t*," *Y,

x n o= 1 , 5 x 1 0 - 3- 1 6 - 1 a + e
x3' z0 x 1 0 - 3= I , 5 x l 0 - 3 m o l
:cj.liill e.iil a+krll i'+-:lt -.t
xëo t
O)\x) .68 Lleljijl <- L { - - - '

Xrro

0.25x2
,, =+= 9 # - 1 1= a , 2 u m
t Lo t
;A:"r,Jtos èJjïl ilîS e.rl,*-

l l m o l - + 2 8s
n t ( r ) 1 , 9 6 g€ { -+
o ?5 f o , z s x 2 5 ox 1 o - 3 m o l m ,
'Âr-Jill i.l.'ili er.L^ -cr
rq6
g 6 N: " " N= ^ ' -" = 0 , 3 3= 3 3 % o
0,25 trt 6

.Ai-)ll .'t' +S l- gl.U+ hÀJ

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;titt gÉs"ll L.bYl yLb

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lij*,i Ë;g-^-aB aLiill Ldl .ç^, ùilt i:iU:^tt :r.': :iL)-
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:;rill dÈ": -1

0,25

: c+.,^*ilcr):l-Jl -f
\| = F = *â
/
F-
,^ prl
û#l;f
, i,Ér$-:rjll ..,1rÂjJr

î
=, € 0 = ffie*:(ox)sle!ti-)l.-
0,25 x(t) = v ot : kl.b L-Lri^ 4^r!i*" (ox) e*.9ÂSll 4r""J
: (oy) J" lu)! -

v, = -gt + c e o, =ff = -g æ -mg= mqy

dy
r, : -gr = :;;s vor = c =0 +- r = 0 -r
4,25
- - 7 Lf " d
+ c' €
v -gt :a.,-ts
Y
;l=

y ( t' ) = - ! f r ' +hç ) )= - c ' = h + t = 0

2
:-,11*iti.lrLr^-J
0,25x2 x
= --g-'x'+ h - - 4 . 1 0 - 3' x 2 + 2 , 2 < - t =
"v 2ri vo
'-, d+ill ù-* tél >a cb -4
x:12,2m '1LJl ilrt- u-i &-r,):
0,25x2 ! r . = - 4 ' 1 0 - 3x ( I 2 , 2 ) ' + 2 , 2 - l , 6 m > 0 , 9 2 m
. AS+rlt qJJÊJ"r 6JSll 4-',"J

' . A r ^yJB = 0 : c t F B ë , à d l $ c - 5

0,25x2 x,, -: fu- = 23.45m

> 7 8 , 7 m< = - 4 . 1 0 - 3 ' xu' * 2 , 2 = 0
! o ,o o +
.LJ"G. JI-JYI4i"J

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3.5) :u*tÀll cr*,;rgll

0,25x2

: .r:$;l3l rrrii3l JË+l

I % = 4 + A * r ^ + 7 = * n â : ( A )4 + - F J l
0,25 Tn - -f = ffiAa .. .(1) (X'X) ,r!" lLi-)q

Z, F*, =71 * n * n = ffiBâ : @)tytt

4,25 mug sina -Tn = rltBQ ....(2) (Y'Y) ,JÊ'lli-Ytr
0,25 mug sina -f =a(mn *mu) :$^-i Tn=Tu:AISlla&+;:É+ll
, r\ dv , "f - mugsina _
=n
V )........ u
4,5 dt*-;;^ :+i.r
0,25
t-eL\ls .,,,r- .als.ilrrr
p =f,-: ** p:0 \Fsr
0,25 mA+mB dt

o'5 2
: qY Jsl &ldl ,rj'iJl +"=: -i-2
0,25 LJr\l
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