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University Of Thi-Qar
College Of Science
Department of Chemistry
Nanotechnology:Lecture 4: MSc-2nd course
Asst. prof. Dr. Saad Shahad AL-Omary
Nanocomposite
The idea behind nanocomposites is to use building blocks with
dimensions in the nanometre range to design and create new
materials with unprecedented flexibility and improvements in
their physical properties.
This concept is founded in many naturally occurring materials,
such as bone, which is a hierarchical nanocomposite built from
ceramic tablets and organic binders. When designing the
nanocomposite, scientists can choose constituents with different
structures and composition and, hence, properties, so that
materials built from them can be multifunctional.
Definition: Nanocomposites are broad range of materials
consisting of two or more components, with at least one
component having dimensions in the nm regime (i.e. between 1
and 100 nm).
Nanocomposites consist of two phases (i.e nanocrystalline phase
+ matrix phase).
Ministry of Higher Education and Scientific Research University Of Thi-Qar
College Of Science Department of Chemistry
وزارة التعليم العالي والبحث العلمي جامعة ذي قار كلية العلوم قسم الكيمياء
Classification of Nanocomposites
Nanocomposite materials can be classified in the following way
based on the presence or absence of polymeric material in the
composite.
The nanocomposites in which the compositions do not contain
any polymers or polymer-derived materials are called non-
polymer-based nanocomposites. The nanocomposites contain
polymers or polymer-derived materials are called polymer-based
nanocomposites.
Non-polymer-based nanocomposites are also known as inorganic
nanocomposites.
Phase may be inorganic-inorganic, inorganic-organic or organic-organic.
.قد تكون المرحلة غير عضوية غير عضوية أو غير عضوية أو عضوية عضوية
a chemical compound from the group of oxides, nitrides, borides, silicides etc.
.مركب كيميائي من مجموعة األكاسيد والنيتريدات والبوريدات ومبيدات السيليكات وغيرها
Ideally both components, the metallic one and the ceramic one, are finely
dispersed in each other in order to obtain the particular nanoscopic properties.
بدقة في بعضهما البعض من أجل، المعدن والسيراميك، يتم تشتيت كال المكونين،من الناحية المثالية
.الحصول على الخصائص النانوية المحددة
resistance properties.
.خصائص المقاومة
CMNC prepartaion methods Many methods have been described for the
preparation of ceramic matrix nanocomposites.
تم وصف العديد من الطرق لتحضير مركبات نانوية ذات مصفوفةCMNC طرق تحضير
.سيراميكية
MMNC prepartaion methods The most common techniques for the processing
of metal matrix nanocomposites are Spray pyrolysis, Liquid metal infiltration,
Rapid solidification, Vapour techniques (PVD, CVD), Electrodeposition and
Chemical methods, which include colloidal and sol-gel processes.
التقنيات األكثر شيوًع ا لمعالجة المركبات النانوية ذات المصفوفة المعدنيةMMNC طرق تحضير
PVD،( وتقنيات البخار، والتصلب السريع، وتسلل المعدن السائل،هي االنحالل الحراري بالرش
. والتي تشمل العمليات الغروية والهالمية، والترسيب الكهربي والطرق الكيميائية،)CVD
PMNC prepartaion methods Many methods have been described for the
preparation of polymer nanocomposites.
. تم وصف العديد من الطرق لتحضير مركبات البوليمر النانويةPMNC طرق تحضير
The most important ones are Mixing, In-situ polymerization and Sol-gel
process.
.وأهم هذه العمليات هي الخلط والبلمرة في الموقع وعملية سول جل
Simple
بسيط
Sol-Gel Process
عملية سول جل
Greater shrinkage and lower amount of voids, compared to the mixing method
انكماش أكبر وكمية فراغات أقل مقارنة بطريقة الخلط
Simple; effective.
.بسيط؛ فعال
Template Synthesis
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