Repeated Questions

Physical Chemistry
● Derive expression for the rate constant of 2nd order reaction with
different initial concentrations
of both reactants
● State law of mass actiom and derive equilibrium constant
expression for general reversible reaction. Derive relationship
between different equilibrium constants ( Kc,Kp,Kx,Kn) for
gaseous reactions. Under what condition these are equal?
● Differentiate between rate constant and specific rate confront.
● Describe collision theory of Biomolecular reactions rate.
● Write detailed notes on Le Chatlier's Principle.
● Differentiate between order of reaction and molecularity
● Discuss the kinetics of 2nd order reaction with similar
concentrations of both the reactants
● State Le Chatlier's Principle and discuss it's applications to the
preparation of Ammonia on industrial scale.
● Define the following terms
1) Activation Energy 2) Order of reaction 3) Rate constant
Rate law
● Derive relationship between Kc and Kp for gaseous reactions
● Describe any two methods for the determination of order of
reaction
● What is Arrhenius Equation/Theory and it's derivation.
● Derive relationship between different equilibrium constants (
Kc,Kp,Kx,Kn)
● What is Le Chatlier's Principle.. Discuss the effect of
concentration and pressure or volume on equilibrium
● Define Gibb's rule? And How will explain the water system ?
● Discuss the thermal decomposition of acetaldehyde?
● What is Transition state theory?Also Postulates and derivation in
detial?
● What is Side chain reaction? How can derive it with example?
 Organic Chemistry
● Define Aromaticity.Discuss the De-Bye Huckle Rule of
Aromaticity.
● Differentiate between Aromaticity and Antiaromaticity. Also
explain Aromaticity in 1) 1,3-Cyclohepyatriene 2) 10π electron
system
● Write down mechanism of following
1) Friedal-Craft Acylation 2) Reimer Tiemann Reaction
● Write a note on confirmational analysis of Cyclohexane.
● What is the difference between
1) Optical and Specific Rotation 2) Enantiomers and Diastereomers
3) Absolute and Relative Configuration
● What is geometric isomerism? Describe various methods for
assigning Cis or Trans configuration to different isomers.Give two
methods for inter-conversion of geometric isomerism.
● What is optical activity and optical isomerism. Give measurement
of optical activity.
● Discuss the reactivity of Pyridine towards Electrophilic
Substitution reactions. Explain with examples.
● Write a note on Confirmational isomerism in n-Butane.
● Write down five Electrophilic Substitution reactions of Pyrole.
● Discuss optical isomerism in BiPyenyle and Spiranes.
● Explain the structure and Basicity of Pyrole.
● What is Racemate and Racemization ? Explain various methods
of Resolution of Racemix mixture.
● What is Tautomerism ? (2 marks )
● Explain the Basicity and Electrophilic Substitution reactions of
Pyridine.
● Define following terms with examples
1) Enantiomer 2) Chiral Carbon 3) Racemix mixture
● What is Mesoform and Racrmicform ?
● Give two reactions for preparation of Pyridine.
● Differentiate between Centre of Symmetry and Axis of Symmetry.