(Batches: e-SANKALP-2325 S1, T1 & P1)

I I T – JEE, 2 3 2 5 Paper Code

100918
(CLASS XI)
Time: 2 Hours Maximum Marks: 126
INSTRUCTIONS
A. General
1. Write your Name, Enrolment number in the space provided on this booklet as soon as you get the paper.
2. Blank papers, clipboards, log tables, slide rules, calculators, cameras, cellular phones, pagers, and electronic
gadgets of any kind are NOT allowed in the examination hall.
3. Use a ball point pen do darken the bubbles on OMR sheet as your answer besides Name, Enrolment
number, Phase, Paper sequence, Venue, Date along with your signature on OMR sheet.

B. Question Paper Format

The question paper consists of three parts (Physics, Chemistry and Mathematics). Each part consists of
three sections.
4. Section–1 (01 – 06) contains (06) Multiple Choice Questions which have Only One Correct answer. Each
question will be evaluated according to the following marking scheme.
Full Marks : +3 If only (all) the correct option(s) is (are) chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –1 In all other cases
5 Section–2 (07 – 09) contains (03) Multiple Choice Questions which have one or more than one
correct answer. Each question will be evaluated according to the following marking scheme.
Full Marks : +4 If only (all) the correct option(s) is (are) chosen;
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen and
both of which are correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a
correct option;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.
6. Section–3 (10 – 12) contains (03) Non-Negative Numerical Value Questions, the answer to each
question is a Non-Negative Numerical Value. For each question, enter the correct numerical value
corresponding to the answer and each question carries +4 marks for correct answer. There is no
negative marking.

Enrolment No. :

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Batch : . . . . . . . . . . . . . . . . . . . . . . .Session :. . . . . . . . . . . . . . . . . . . . . . Date:. . . . . . . . . . . . . . . .

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eSANKALP2325S1, T1 & P1-PCM-Paper-(100918)-2

PART I : PHYSICS
SECTION – 1 : (Only One Option Correct Type)

This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONLY ONE option is correct.

1. An ideal pendulum was oscillating with an angular amplitude  = /3 inside a


stationary elevator. When the pendulum was passing through equilibrium position,
the lift suddenly starts moving upward with an acceleration a = g. Find the new
angular amplitude of the oscillation
(A) /3 (B) /6
(C) cos1(3/4) (D) /2

2. A simple pendulum having a natural frequency of ‘f’ has a metal bob at its bottom. If the bob is
charged negatively and is allowed to oscillate with a positively charged plate placed under it, its
frequency will be
(A) f (B) < f
(C) > f (D) 0

 
3. A pendulum oscillates with an angular amplitude    . The ratio of the maximum tension to
 2 
the minimum tension in the string will be [ is the angle made by the string with the vertical]
(A) 3cos  + 1 (B) 3 sec   2
(C) 1 + 2sin  (D) 2 + 3 cos 

Space for Rough work

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 eSANKALP2325S1, T1 & P1-PCM-Paper-(100918)-3

4. A uniform spring has a certain block suspended from it

and its period for vertical oscillation is T1. The spring is
1 2
now cut into two parts of lengths rd and rd of
3 3 m
original length and these springs are connected to the
same block as shown in the figure. If time period of
oscillation now is T2 then T1/T2
9
(A) (B) 1 : 1
2
2
(C) 1 : 3 (D)
9

5. A particle executes S.H.M. between x =  A and x = +A. The minimum time taken for it to go from
3
x = 0 to x = +A/2 is T1 and to go from x = A to x = + A is T2 , then
2
(A) T1  T2 (B) T1  T2
(C) T1  T2 (D) 2T1  T2

6. A particle of mass m is executing oscillations about the origin on the x - axis. Its potential energy
is V(x) = k|x|3 where k is a positive constant. If the amplitude of oscillation is a, then its time
period T is
1
(A) proportional to (B) independent of a
a
(C) proportional to a (D) proportional to a3/2

Space for Rough work

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eSANKALP2325S1, T1 & P1-PCM-Paper-(100918)-4

SECTION – 2 : (One or More Than One Options Correct Type)

This section contains 3 multiple choice type questions. Each question has four choices (A), (B), (C)
and (D) out of which ONE or MORE THAN ONE are correct.

7. Two particles A and B are performing SHM along x and y-axis respectively with equal amplitude
and frequency of 2 cm and 1 Hz respectively. Equilibrium positions of the particles A and B are at
the co-ordinates (3, 0) and (0, 4) respectively. At t = 0, B is at its equilibrium position and moving
towards the origin, while A is nearest to the origin and moving away from the origin. Choose the
correct option(s) :
(A) The distance between A and B is 3 cm at t = t0 sec. It will again be 3 cm at t = (t0 + 1) sec.
(B) The distance between A and B can never be 5 cm.
(C) The maximum magnitude of force acting on each particle during the motion is same.
(D) Kinetic energy of the system (A and B) is conserved

8. Function x = A sin2 t + B cos2 t + C sin t cos t represents SHM

(A) for any value of A, B and C (except C = 0) (B) if A = B; C = 2B, amplitude = B 2
(C) if A = B; C = 0 (D) if A = B; C = 2B, amplitude = B

9. Three simple harmonic motions in the same direction having the same amplitude a and same
period are superposed. If each differs in phase from the next by 45, then
(A) the resultant amplitude (1 + 2)a
(B) the phase of the resultant motion relative to the first is 90
(C) the energy associated with the resulting motion is (3 + 22) times the energy associated with
any single motion.
(D) the resulting motion is not simple harmonic

Space for Rough work

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 eSANKALP2325S1, T1 & P1-PCM-Paper-(100918)-5

SECTION – 3: (Numerical Answer Type)

This section contains THREE questions. The answer to each question is a NUMERICAL VALUE. For
each question, enter the correct numerical value (in decimal notation, truncated/rounded‐off to the
second decimal place; e.g. xxxxx.xx).

10. A simple pendulum has time period T when on the earth’s surface and T 2 when taken in a tunnel
at depth 3R/4 along the diameter of earth, where R is the radius of earth. The value of T 1/T2.

11. In the arrangement shown in figure, pulleys are light and springs
are ideal k1, k2, k and k4 are force constants of the springs. k2 k4
Calculate angular frequency period of small vertical oscillations of
block of mass 2 kg in rad/s. Assume k1 = k2 = k3 = k4 = 128 N/m

k1 k3

12. A spring of mass M = 3 kg and spring constant k = 42 N/m. The spring lies
on a frictionless surface and one end of the spring is fixed to a wall as
shown in the figure. It can be assumed that at any time the velocity of any
point on the spring is directly proportional to its distance from the wall.
What is the time period of oscillation of the spring (in second) if the free
end of the spring is slightly pulled from its natural length and released.

Space for Rough work

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eSANKALP2325S1, T1 & P1-PCM-Paper-(100918)-6

PART II : CHEMISTRY
SECTION – 1: (Only One Options Correct Type)

This section contains 6 multiple choice type questions. Each question has four choices (A), (B), (C)
and (D) out of which ONE is correct.

1. Borax structure contains:

(A) Two tetrahedral and two triangular units (B) Four tetrahedral units only
(C) Two triangular units only (D) Two tetrahedral units only

2. Boron can be obtained by various methods but not by:

(A) Thermal decomposition of B2H6 (B) Pyrolysis of BI3
(C) Reducing BCl3 with H2 (D) Electrolysis of fused BCl3

3. Identify the only incorrect statement of the following:

(A) Vitamin B12 (named as cyanocobalamine) imparts blue colour to the flame when heated with
borax
(B) Boric anhydride can behave as a basic oxide when treated with P2O5
(C) Boric acid behaves as relatively stronger acid in the presence of ethylene glycol
(D) Boric acid behaves as relatively stronger acid in the presence of trans-cyclohexan-1,2-diol

4. Which statement is correct for B2H6:

(A) 4B – H bonds are of equal length and 4B – H bonds are different but equal length
(B) H – B – H angles are 120o and 97o
(C) B – H bonds length are 134 pm and 119 pm
(D) All of the above

5. Fluorine is more electronegative than either boron or phoshorus. What conclusion can be drawn
from the fact that BF3 has no dipole moment but PF3 does:
(A) BF3 is not spherically symmetrical, but PF3 is.
(B) BF3 molecule must be linear
(C) The atomic radius of P is larger than the atomic radius of B.
(D) The BF3 molecule must be planar triangular.

 
6. Borax   A  B  C
‘B’ is used in Borax bead test. Then which of the following statement(s) is/are correct?
(A) Hydrolysis of ‘A’ gives C.
(B) ‘C’ can also be prepared by heating orthoboric acid.
(C) Hydrolysis of ‘A’ gives acidic solution.
(D) ‘C’ can also be prepared by reacting diborane with ‘CO’.

Space for rough work

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 eSANKALP2325S1, T1 & P1-PCM-Paper-(100918)-7

SECTION – 2: (Multi Correct Choice Type)

This section contains 3 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONE OR MORE may be correct.

7. Which of the following product(s) may be formed by the reaction of diborane with ammonia?
(A) (BN)x (B) B2H6.2NH3
(C) B3N3H6 (D) B + H2 + N2

8. Which of the following statement is correct?

(A) Bauxite and Kernite are important minerals of aluminium.
(B) Ga can be used in high temperature thermometer.
(C) Aluminium is the most abundant metal in earth crust.
(D) Borohydrides are formed by reaction of metal hydrides with boric acid.

9. Which of the following statements is/are correct?

(A) Atomic radius of Ga is less than aluminimum due to poor screening effect of d-electron
(B) In  A  Ga  T   B (order of first ionization energy)
(C) B  A  Ga  In  T (order of stability of +1 oxidation state)
(D) Boron can form BF63 

Space for rough work

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eSANKALP2325S1, T1 & P1-PCM-Paper-(100918)-8

SECTION – 3: (Numerical Answer Type)

This section contains THREE questions. The answer to each question is a NUMERICAL VALUE. For
each question, enter the correct numerical value (in decimal notation, truncated/rounded‐off to the
second decimal place; e.g. xxxxx.xx).

10. If number of correct statements from following are ‘x’ and number of incorrect statements are ‘y’
x
then value of x  is?
y
(i) Hybridisation of boron in diborane is sp2.
(ii) Diamond is thermodynamically most stable form of carbon.
(iii) Reaction of BF3 with LiH gives diborane.
(iv) Diborane requires high temperature to react with O2.
(v) Hydrolysis of diborane gives weak alkaline solution.
(vi) Boric acid has hexagonal layer structure in which BO3 units are joined by H-bonds.
(vii) Diamond is used as abrasive.

11. If ‘x’ is number of 2C – 2e– bonds in diborane and ‘y’ is number of 3C – 2e – bonds in diborane
than value of x 2  y 2 is:
p x  y.z
12. If unit of borax is written as B x Oy  OH z  then what is the value of .
p

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 eSANKALP2325S1, T1 & P1-PCM-Paper-(100918)-9

PART III : MATHEMATICS

SECTION – 1: (Only One Options Correct Type)

This section contains 6 multiple choice type questions. Each question has four choices (A), (B), (C)
and (D) out of which ONE is correct.

1. A triangle is inscribed in a circle. The vertices of the triangle divide the circle in to three arcs
of length 3, 4 and 5 units, then area of the triangle is equal to,

(A)

9 3 1 3  (B)

9 3 3 1 
2 2

(C)

9 3 1 3  (D)

9 3 3 1 
2 2 2 2

2. In any triangle ABC, the sides a, b, c are in G.P. with common ration r  r  1 , then

(A) r 
1
2

5 1  (B) r 
1
2
 
5 1


(C) A   B  C (D) A  B  C
3

3. The inradius of an isosceles ABC is four times as small as that of circumradius of the triangle if
A = B. Then cos A is a root of the equation
(A) 8x2  8x + 1 = 0 (B) 4x2  4x + 1 = 0
(C) x  x  4 = 0
2 (D) x2  x  8 = 0

4. Sides of a ABC are in A.P. If a < min{b, c} and c > max{a, b}, then cosA is
3c  4b 3c  4b
(A) (B)
2b 2c
4c  3b 4c  3b
(C) (D)
2a 2b

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eSANKALP2325S1, T1 & P1-PCM-Paper-(100918)-10

5. If P be a point inside an equilateral ABC such that PA = 3, PB = 4 and PC = 5, then the side
length of the equilateral ABC is
(A) 25  12 3 (B) 13
(C) 25  12 3 (D) 17

6. ABCD is a trapezium with AB parallel to CD. M is the mid-point of AD. MCB = 150, BC = x and
MC = y. The area of ABCD in terms of x and y is
1
(A) xy (B) xy
2
(C) 2xy (D) none of these

SECTION – 2: (Multi Correct Choice Type)

This section contains 3 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONE OR MORE may be correct.

7. A circle of radius 4 cm is inscribed in a triangle ABC, which touches the side BC at D. If BD = 6

cm, DC = 8 cm, then
A 4
(A) the triangle is necessarily acute angled (B) tan 
2 7
(C) perimeter of the triangle is 42 cm (D) area of the triangle is 84 cm 2

8. ABCD is a cyclic quadrilateral as shown which of the following must be true?

A
a2  b2  c 2  d2
(A) cosB 
2  ab  cd a
B d
(B) ab + cd = 2(h1 + h2)R, where R is the circumradius of the h1
quadrilateral
1 h2
(C) area of the quadrilateral = (ab + cd) sinB b D
2 c
(D) if d1 and d2 are the length of the diagonals of the quadrilateral then
ac + bd = d1d2 C

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 eSANKALP2325S1, T1 & P1-PCM-Paper-(100918)-11

9. In the triangle ABC the medians from B and C are perpendicular. The value of cot B + cot C can
be
1 2
(A) (B)
3 3
4 5
(C) (D)
3 3

SECTION – 3: (Numerical Answer Type)

This section contains THREE questions. The answer to each question is a NUMERICAL VALUE. For
each question, enter the correct numerical value (in decimal notation, truncated/rounded‐off to the
second decimal place; e.g. xxxxx.xx).

10. If in a right angled triangle, having integer sides the perimeter of triangle is equal to the area of
triangle then the sum of area of possible triangles is

11. In a triangle ABC, the foot of the perpendicular from A divides the opposite side into parts of
22
lengths 3 and 17 and tanA = . Let a PQR be a right angle triangle (right angle at Q) such that
7
 Area  ABC  
A = P and PQ = 7 units, then   is _____________ (where [.] denotes the
 Area PQR  
greatest integer function)

12. If the angle at the vertex of an isosceles triangle having the maximum area for the given length l
of the median to one of its equal sides, is x then 5cosx is equal to ______________

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