HEER INSTITUTE OF CHEMISTRY

Chapter -5 Std 12 : Chemistry Date : 22/03/24

TOTAL:- GUJCET Time:2 hours
Section A
//X
• Choose correct answer from the given options. [Each carries 1 Mark] [49]

1. Which complex from the following is true most stable ?

(A) [Fe(H2O)6]3+ (B) [Fe(CN)6]3– (C) [Fe(C2O4)3]3– (D) [FeCl6]3–

2. Co-ordinate number, oxidation number, number of electrons in d-orbital and number of unpaired
electron of central metal Co in [Co(NH3)4CO3]ClO4 ?
(A) 6, 3, 6, 0 (B) 7, 2, 7, 1 (C) 6, 2, 7, 3 (D) 7, 1, 6, 4
3. Which statement of the following is not proper ?
(A) Ni(CO)4 – Tetrahedral, paramagnetic (B) Ni(CN)42– – Square plannar, diamagnetic

EM
(C) Ni(CO)4 – Octachedral, diamagnetic (D) [NiCl4]2– – Tetrahedral, paramagnetic

4. 1 mole compound from the following complex is reacted with excess AgNO3 then which complex
is given by excess AgCl
(A) [Co(NH3)6]Cl3 (B) [Co(NH3)5Cl]Cl2 (C) [Co(NH3)4Cl2]Cl (D) Na2[PtCl6)

5. In d-orbital of Cr+2, Mn2+, Fe2+ and Ni2+ contains 3d4, 3d5, 3d6 and 3d8 electrons respectively, then
CH
which of the following aqua complex possesses minimum paramagnetic property ?
(A) [Fe(H2O)6]2+ (B) [Ni(H2O)6]2+ (C) [Cr(H2O)6]2+ (D) [Mn(H2O)6]2+

6. Which of the following possesses geometrical as well as optical isomers ?

(A) Dichlorido bis (ethelene dyamine) cobaltate (III) ion.
(B) Penta ammine chlorido cobaltate (III) ion
(C) Tri ammine dichlorido cobaltate (III) ion
ER

(D) Tetra ammine dichlorido cobaltate (III) ion

7. Which of the following complex ion does not shows optical isomers ?
(A) [Co(NH3)2Cl3] (B) [Co(en)3]3+ (C) [Co(en)Cl2(NH3)2] + (D) [Co(en)2Cl2]+
8. Which complex contains D0 values is the minimum ?
(A) [Cr(CN)6]3– (B) [Co(NH3)6]3+ (C) [CoCl6]3– (D) [Cr(H2O)6]3+
HE

9. Ligand N[CH2CH2NH2]3 is....

(A) tridentate (B) hexadentate (C) tetradentate (D) didentate
10. Select the correct statement :
(A) Geometrical isomer may differ in dipole moment and visible UV spectra.
(B) No optical isomer exists for the complex trans- [Co(en)2Cl2]+
(C) Complexes of type [Ma3b3] can also have facial and meridional isomer.
(D) All of these
11. Which of the following is a pair of diamagnetic complexes ?
(A) [Fe(CN)6]3–, [CoF6]3– (B) [Fe(OX)3]3–, [FeF6]3–
(C) [Co(OX)3 ]3–, [FeF6]3– (D) [Co(NH3)6]3+, [Fe(CN)6]4–

12. Hybridization of which orbitals of an atom a complex of square planar shape structure is formed ?
(A) s ; px ; py ; dyz (B) s ; px ; py ; dx2 – y2 (C) s ; px ; py ; dz2 (D) s ; px ; py ; dxy
13. One mole aqueous solution of complex compound [Co(NH3)5Cl3] gives 3 moles of ions. So if 1 mole
of same compound reacts with 2 mole of AgNO3 and 2 mole AgCl(s) is obtained then what is the
formula of that complex ? vishal sir (M)9898538844
(A) [Co(NH3)3Cl3]2NH3 (B) [Co(NH3 )4Cl2]Cl · NH3
(C) [Co(NH ) Cl]Cl · NH (D) [Co(NH ) Cl]Cl
 One mole aqueous solution of complex compound [Co(NH3)5Cl3] gives 3 moles of ions. So if 1 mole
of same compound reacts with 2 mole of AgNO3 and 2 mole AgCl(s) is obtained then what is the
formula of that complex ?
(A) [Co(NH3)3Cl3]2NH3 (B) [Co(NH3 )4Cl2]Cl · NH3
(C) [Co(NH3 )4Cl]Cl2 · NH3 (D) [Co(NH3)5Cl]Cl2

14. Ni(Z = 28) metal combines with possessing same electronegativity unidentate and forms
paramagnetic compound [NiX4]–2, then what is its geometrical structure and number of common
ligand unpaired electrons in nickel ?
(A) 2 ; square planar (B) 1 ; tetra hedral (C) 2 ; tetra hedral (D) 1 ; square planar
15. What is co-ordination numbers of E in [E(en)2(C2O4)]NO2 complex and what is its oxidation state ?
(A) 6 and 3 (B) 6 and 2 (C) 4 and 2 (D) 4 and 3
16. What is the formula of hexa aqua manganese (II) phosphate ?
(A) [Mn(H2O)6](PO4) (B) [Mn(H2O)6](PO4) (C) [Mn(H2O)6]3(PO4)2 (D) [Mn(H2O)6](PO4)3

17. Which of the following facts about the complex [Cr(NH3)6]Cl3 is wrong ?

EM
(A) The complex involves d2sp3 hybridisation and is octahedral in shape.
(B) The complex is paramagnetic
(C) The complex gives white precipitates with AgNO3.
(D) The complex is outer orbital complex.

18. Low spin complex of d6 – cation in an octahedral field will have the following energy :
-12 -12 -2 -2
Do + P Do + 3P Do + P Do + 2P
(A)
CH (B) (C) (D)
5 5 5 5
[Do : Crystal field splitting energy in an octahedral field, P = electron pairing energy]

19. A magnetic moment at 1.73 B.M will be shown by one among the following...
(A) TiCl4 (B) [CoCl6]4– (C) [Cu(NH3)4]2+ (D) [Ni(CN)4]2–

20. The octahedral complex of a metal ion M3+ with four monodentate ligands L1, L2, L3 and L4 absorbs
wavelengths in the region of red, green, yellow and blue respectively. The increasing order of ligand
ER

field strength is....

(A) L3 < L2 < L4 < L1 (B) L1 < L3 < L2 < L4 (C) L4 < L3 < L2 < L1 (D) L1 < L2 < L3 < L4

21. Which of these statements about [Co(CN)6]3– is true ?

(A) [Co(CN)6]3– has no unpaired electrons and will be in a low-spin configuration.
(B) [Co(CN)6]3– has four unpaired electrons and will be in a low-spin configuration.
HE

(C) [Co(CN)6]3– has four unpaired electrons and will be in a high-spin configuration.
(D) [Co(CN)6]3– has no unpaired electrons and will be in a high-spin configuration.

22. Identify the correct trend :

[Atomic No. : Ti = 22, Cr = 24, Mo = 42]
(A) Do of [Cr(H2O)6]2+ < [Mo(H2O)6]2+and Do of [Ti(H2O)6]3+ < [Ti(H2O)6]2+
(B) Do of [Cr(H2O)6]2+ > [Mo(H2O)6]2+ and Do of [Ti(H2O)6]3+ < [Ti(H2O)6]2+
(C) Do of [Cr(H2O)6]2+ < [Mo(H2O)6]2+and Do of [Ti(H2O)6]3+ > [Ti(H2O)6]2+
(D) Do of [Cr(H2O)6]2+ > [Mo(H2O)6]2+ and Do of [Ti(H2O)6]3+ > [Ti(H2O)6]2+

23. The correct increasing order of trans- effect of the following specie is ..........
(A) NH3 > –CN > Br– > C6H–5 (B) –CN >Br– > C6H–5 > NH3
(C) –CN > C6H–5 > Br– > NH3 (D) Br– > –CN > NH3 > C6H–5

24. Pick out the correct statement w.r.t. [Mn(CN)6]3–.

(A) It is sp3d2 hybridised and octahedral. (B) It is dsp2 hybridised and square planar.
(C) It is d2sp3 hybridised and octahedral. (D) It is sp3d2 hybridised and tetrahedral.
vishal sir (M)9898538844
 Pick out the correct statement w.r.t. [Mn(CN)6]3–.
(A) It is sp3d2 hybridised and octahedral. (B) It is dsp2 hybridised and square planar.
(C) It is d2sp3 hybridised and octahedral. (D) It is sp3d2 hybridised and tetrahedral.

25. The [Co(H2O)6]2+ ion has three unpaired electrons. The hybridization of Co in [Co(H2O)6]2+ is ......
(A) sp3 (B) dsp2 (C) sp3d2 (D) d2sp3
26. In Wilkinson’s catalyst, the hybridisation of central metal ion and its shape are respectively
(A) dsp2, square planar (B) sp3d, trigonal bipyramidal
(C) sp3, tetrahedral (D) d2sp3, octahedral

27. The total number of possible isomers for square planar [Pt(Cl)(NO2)(NO3)(SCN)]2– is ............
(A) 16 (B) 8 (C) 24 (D) 12
28. Consider the following reaction and statements :
[Co(NH3)4Br2]+ + Br– ® [Co(NH3)3Br3] + NH3
(I) Two isomers are produced if the reactant complex ion is a cis-isomer.
(II) Two isomers are produced if the reactant complex ion is a trans-isomer.
(III) Only one isomer is produced if the reactant complex ion is a tran-isomer.

EM
(IV) Only one isomer is produced if the reactant complex ion is a cis-isomer.
The correct statements are :
(A) (I) and (II) (B) (I) and (III) (C) (III) and (IV) (D) (II) and (IV)
29. ) The coordination number of Th in K4[Th(C2O4)4(OH2)] is .......
(A) 10 (B) 6 (C) 8 (D) 14
112) Urea reacts with water to form A which will decompose to form B. B when passed through Cu+2(aq),
30.
CH
deep blue colour solution C is formed. What is the formula of C from the following ?
(A) Cu(OH)2 (B) CuCO3 · Cu(OH)2 (C) CuSO4 (D) [Cu(NH3)4]2+

31. ) Match List-A with List-B :

List-A List-B
(A) [PtCl4 ]2– (I) sp3d
(B) BrF5 (II) d2sp3
ER

(C) PCl5 (III) dsp2

(D) [Co(NH3)6]3+ (IV) sp3d2

(A) (A - II),(B - IV),(C - I),(D - III) (B) (A - III),(B - IV ),(C - I),(D - II)
(C) (A - III),(B - I),(C - IV),(D - II) (D) (A - II),(B - I),(C - IV),(D - III)
HE

32. ) The number of statement(s) correct from the following for copper (at no. 29) is/are .......
(A) Cu(II) complexes are always paramagnetic.
(B) Cu(I) complexes are generally colourless.
(C) Cu(I) is easily oxidized.
(D) In Fehling solution, the active reagent has Cu(I).
33. ) Which of the following spectrochemical series is true ?
(A) SCN– < NH3 < F– < en < CO (B) SCN– < F– < NH3 < en < CO
(C) SCN– < F– < en < NH3 < CO (D) SCN– < F– < en < CO < NH3

34. ) Which of the following statements is incorrect ?

(A) K4[Ni(CN)4] and K2[Ni(CN)4] both have same magnetic moment.
(B) K2[Ni(CN)4] is diamagnetic while K2[NiCl4] is paramagnetic.
(C) K4[Ni(CN)4] is square planar while K2[Ni(CN)4] is tetrahedral.
(D) K2[NiCl4] and K4[Ni(CN)4] both have same geometrical shapes.
35.7) Which is the correct formula for pentaamine-carbonatocobalt (III) chloride coordination compound ?
(A) [Co(NH3)5(CO3)]Cl (B) [Co(NH3 )5(CO3)]Cl2
(C) [Co(NH3)5(CO2)]Cl vishal sir (M)9898538844
(D) [Co(NH2)5(CO3)]Cl
 7) Which is the correct formula for pentaamine-carbonatocobalt (III) chloride coordination compound ?
(A) [Co(NH3)5(CO3)]Cl (B) [Co(NH3 )5(CO3)]Cl2
(C) [Co(NH3)5(CO2)]Cl (D) [Co(NH2)5(CO3)]Cl

36. ) According to CFT, which of the following option is appropriate for [FeF6]3–complex ion ?
(A) D0 < p and D0 > p (B) D0 < p (C) D0 > p (D) D0 ³ p

37. ) Which of the following complex ions is not expected to absorb visible light ?
(A) [Ni(CN)4]2– (B) [Cr(NH3)6]3+ (C) [Fe(H2O)6]2+ (D) [Ni(H2O)6]2+

187) [PtII(NH3)4] [PtIV Cl6] [PtIV (NH3)4Cl2] [PtIICl4] is an example of which isomerism ?
38.
(A) Linkage (B) Hydration (C) Ionic (D) Co-ordination
39. ) Which of the following complex compound does not posses tetrahedral geometry ?
(A) K4[Ni(CN)4] (B) [Ni(CO)4] (C) K[MnO4] (D) K2[Ni(CN)4]

40. ) Which of the following complex ion shows optical isomerism ?

(P) Trans – [Cr(en)2(CN)2] +
(Q) Cis – [Cr(en)2(CH)2] +

EM
(R) Facial – [Co(H2O)3 (NH3)3]+3
(A) P and Q both (B) Q (C) P (D) P, Q and R
41. ) Which of the following complex ion, splitting of octahedral crystal field is maximum ?
(A) [Ni(F)6]4– (B) [Ni(H2O)6]2+ (C) [Ni(CO)6]2+ (D) [Ni(CN)6]4–

42. ) Which of the following complex is useful in the dehydrogenation of alkanes ?

CH
(A) [(Ph3P)3 Rh Cl] (B) [(Ph3P) Rh Cl] (C) [(Ph3P)3 Rh2 Cl] (D) [(Ph3P)3 Rh Cl2]

43. ) Which of the following compounds does not show optical activity ?
(A) Cis - [CoBr2(en)2]+ (B) Cis - [Fe(NH3)2(CN)4]–
(C) Cis - [CrCl2(OX)2]3– (D) Cis - [PtCl2(en)2]2+

44. ) Number of possible isomers for [Cr(H2O)2 (C2O4)2]– are .......... .

(A) 2 (B) 4 (C) 3 (D) 6
ER

45. ) In which complex wavelength of absorbed light is lowest ?

(A) [CoCl(NH3)5]2+ (B) [Co(NH3)6]3+ (C) [Co(NH)6]3– (D) [Co(NH3)5H2O]3+

46. ) Which of the following pair is an example of linkage isometism ?

(A) [Cr(H2O)6 ]Cl3 and [Cr(H2O)5 Cl]Cl2 · H2 O
(B) [Co(NH3)6]3+ [Cr(CN)6]3– and [Cr(NH3)6]3+ [Co(CN)6]3–
HE

(C) [Co(NH3)5(NO3 )]Cl and [Co(NH3)5Cl]NO3

(D) [Co(NO2)(NH3 )5]Cl2 and [Co(ONO)(NH3 )5]Cl2
47. ) The limitation of crystal field theory led to the development of which of the following theories ?
(A) VSEPR (B) Molecular orbital theory
(C) Valance bond theory (D) Kossel Lewis approach
48. ) The type of hybridisation for central metal ion in an aqua complex formed by dissolving NiCl2 in water
is ...........
(A) d2sp3 (B) sp3d2 (C) sp3 (D) dsp2
49. ) Which of the following is the formula for Wilkinson Catalyst ?
(A) [(Ph3P)2RuCl] (B) [(Ph3P)3RhCl] (C) [(Ph3P)3RuCl] (D) [(Ph3P)2RhCl]

vishal sir (M)9898538844

 Section B
//X
• Write the answer of the following questions. [Each carries 1 Mark] [1]

120) In the cobalt-carbonyl complex: [Co2(CO)8], number of Co-Co bonds is "X" and terminal CO ligands
1.
is "Y". X + Y = .........

EM
CH
ER
HE

vishal sir (M)9898538844

 HEER INSTITUTE OF CHEMISTRY
Chapter -5 Std 12 : Chemistry Date : 22/03/24
TOTAL:- GUJCET Time:2 hours

Section [ A ] : 1 Mark MCQ

No Ans Chap Sec Que Universal_QueId

1. C Chap 5 S6 2 QP23P11B1212_P1C5S6Q2
2. A Chap 5 S6 6 QP23P11B1212_P1C5S6Q6
3. A Chap 5 S6 8 QP23P11B1212_P1C5S6Q8
4. A Chap 5 S6 12 QP23P11B1212_P1C5S6Q12
5. B Chap 5 S6 14 QP23P11B1212_P1C5S6Q14
6. A Chap 5 S6 18 QP23P11B1212_P1C5S6Q18
7. A Chap 5 S6 19 QP23P11B1212_P1C5S6Q19
8. C Chap 5 S6 24 QP23P11B1212_P1C5S6Q24
9. C Chap 5 S6 28 QP23P11B1212_P1C5S6Q28
10. D Chap 5 S6 31 QP23P11B1212_P1C5S6Q31
11. D Chap 5 S6 35 QP23P11B1212_P1C5S6Q35
12. B Chap 5 S6 36 QP23P11B1212_P1C5S6Q36
13. D Chap 5 S6 39 QP23P11B1212_P1C5S6Q39
14. C Chap 5 S6 45 QP23P11B1212_P1C5S6Q45
15. A Chap 5 S6 47 QP23P11B1212_P1C5S6Q47
16. C Chap 5 S6 51 QP23P11B1212_P1C5S6Q51
17. D Chap 5 S6 56 QP23P11B1212_P1C5S6Q56
18. B Chap 5 S6 59 QP23P11B1212_P1C5S6Q59
19. C Chap 5 S6 61 QP23P11B1212_P1C5S6Q61
20. B Chap 5 S6 63 QP23P11B1212_P1C5S6Q63
21. A Chap 5 S6 72 QP23P11B1212_P1C5S6Q72
22. C Chap 5 S6 79 QP23P11B1212_P1C5S6Q79
23. C Chap 5 S6 81 QP23P11B1212_P1C5S6Q81
24. C Chap 5 S6 83 QP23P11B1212_P1C5S6Q83
25. C Chap 5 S6 89 QP23P11B1212_P1C5S6Q89
26. A Chap 5 S6 91 QP23P11B1212_P1C5S6Q91
27. C Chap 5 S6 92 QP23P11B1212_P1C5S6Q92
28. B Chap 5 S6 97 QP23P11B1212_P1C5S6Q97
29. A Chap 5 S6 100 QP23P11B1212_P1C5S6Q100
30. D Chap 5 S6 112 QP23P11B1212_P1C5S6Q112
31. B Chap 5 S6 119 QP23P11B1212_P1C5S6Q119
32. A Chap 5 S6 122 QP23P11B1212_P1C5S6Q122

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33. B Chap 5 S6 135 QP23P11B1212_P1C5S6Q135
34. C Chap 5 S6 147 QP23P11B1212_P1C5S6Q147
35. A Chap 5 S6 157 QP23P11B1212_P1C5S6Q157
36. B Chap 5 S6 171 QP23P11B1212_P1C5S6Q171
37. A Chap 5 S6 182 QP23P11B1212_P1C5S6Q182
38. D Chap 5 S6 187 QP23P11B1212_P1C5S6Q187
39. D Chap 5 S6 190 QP23P11B1212_P1C5S6Q190
40. B Chap 5 S6 193 QP23P11B1212_P1C5S6Q193
41. A Chap 5 S6 196 QP23P11B1212_P1C5S6Q196
42. A Chap 5 S6 205 QP23P11B1212_P1C5S6Q205
43. B Chap 5 S6 214 QP23P11B1212_P1C5S6Q214
44. C Chap 5 S6 223 QP23P11B1212_P1C5S6Q223
45. C Chap 5 S6 220 QP23P11B1212_P1C5S6Q220
46. D Chap 5 S6 208 QP23P11B1212_P1C5S6Q208
47. B Chap 5 S6 188 QP23P11B1212_P1C5S6Q188
48. B Chap 5 S6 180 QP23P11B1212_P1C5S6Q180
49. B Chap 5 S6 175 QP23P11B1212_P1C5S6Q175

Section [ B ] : 1 Marks Questions

No Ans Chap Sec Que Universal_QueId

1. - Chap 5 S6 120 QP23P11B1212_P1C5S6Q120

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 HEER INSTITUTE OF CHEMISTRY
Chapter -5 Std 12 : Chemistry Date : 22/03/24
Total Marks : 49 GUJCET Time : 02 Hour

Student Name : _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _

Roll Number : 0 1 2 0 1 2 3 4 5 6 7 8 9 0 1 2 3 4 5 6 7 8 9

A B C D A B C D A B C D A B C D A B C D
1. 11. 21. 31. 41.
2. 12. 22. 32. 42.
3. 13. 23. 33. 43.
4. 14. 24. 34. 44.
5. 15. 25. 35. 45.
6. 16. 26. 36. 46.
7. 17. 27. 37. 47.
8. 18. 28. 38. 48.
9. 19. 29. 39. 49.
10. 20. 30. 40.

HEER INSTITUTE OF CHEMISTRY

Chapter -5 Std 12 : Chemistry Date : 22/03/24
Total Marks : 49 GUJCET Time : 02 Hour

Student Name : _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _

Roll Number : 0 1 2 0 1 2 3 4 5 6 7 8 9 0 1 2 3 4 5 6 7 8 9

A B C D A B C D A B C D A B C D A B C D
1. 11. 21. 31. 41.
2. 12. 22. 32. 42.
3. 13. 23. 33. 43.
4. 14. 24. 34. 44.
5. 15. 25. 35. 45.
6. 16. 26. 36. 46.
7. 17. 27. 37. 47.
8. 18. 28. 38. 48.
9. 19. 29. 39. 49.
10. 20. 30. 40.
 HEER INSTITUTE OF CHEMISTRY
Chapter -5 Std 12 : Chemistry Date : 22/03/24
Total Marks : 49 GUJCET Time : 02 Hour

OMR ANSWER SHEET

Marks Identifier :

A B C D A B C D A B C D A B C D A B C D
1. 11. 21. 31. 41.
2. 12. 22. 32. 42.
3. 13. 23. 33. 43.
4. 14. 24. 34. 44.
5. 15. 25. 35. 45.
6. 16. 26. 36. 46.
7. 17. 27. 37. 47.
8. 18. 28. 38. 48.
9. 19. 29. 39. 49.
10. 20. 30. 40.

HEER INSTITUTE OF CHEMISTRY

Chapter -5 Std 12 : Chemistry Date : 22/03/24
Total Marks : 49 GUJCET Time : 02 Hour

OMR ANSWER SHEET

Marks Identifier :

A B C D A B C D A B C D A B C D A B C D
1. 11. 21. 31. 41.
2. 12. 22. 32. 42.
3. 13. 23. 33. 43.
4. 14. 24. 34. 44.
5. 15. 25. 35. 45.
6. 16. 26. 36. 46.
7. 17. 27. 37. 47.
8. 18. 28. 38. 48.
9. 19. 29. 39. 49.
10. 20. 30. 40.
 HEER INSTITUTE OF CHEMISTRY
Chapter -5 Std 12 : Chemistry Date : 22/03/24
TOTAL:- GUJCET Time:2 hours
Section A
//X
• Choose correct answer from the given options. [Each carries 1 Mark] [49]

1.

2.

3.

4.

5.

6.

7.

8.

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9.

10.

11.

12.

13.

14.

15.

Welcome To Future - Quantum Paper

16.

17.

18.

19.

20.

21.

Welcome To Future - Quantum Paper

22.

23.

24.

25.

26.

27.

Welcome To Future - Quantum Paper

28.

29.

30.

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31.

32.

33.

34.

35.

36.

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37.

38.

39.

40.

41.

42.

43.

44.

45.

46.

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47.

48.

49.

Section B
//X
• Write the answer of the following questions. [Each carries 1 Mark] [1]

1.

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