#CARBON

Q BHy
->
--
- i
- - ->

H -
BHz

(-),B
H202
XBH =
-

8n+
X 43 B03

L
AnRR)without
rear.

Imp Ozonolysis

I
-

Oxidation
-

↓ ->
Reductive Oxidative
-n
=>

Ozonolysis Ozonolysis
03/2n 03/1282 Add (j)
on double
boud

CH=cH

of -

05
CH20 CHz8 zo
+
+

↓ ↓
TRICK · i = i2
-p-
H -

P
H H
+
-

2H28 Ct128
+
 s
NOTE
-
Alde
hyde Oxidation Carboxylic Acid

⑧
⑧
11 [8] 11
For C H -> c 8H
13 c
(Hz
- -
- -
+

so]
Ketone ->
Nrxa (in normal
condition)
8
11 conc. HNOS
>
(Hz c
(n) CHg (88H
-
-

03
> CH8 + HCH8
C+s
-

2n
2n8
+

-0

cu- 083, CH
-
cH8 HA
+

soid cosd
(Hz -288H H200+
+

Formic Acid

↓
H28 +

102
 03/In
->
Aldehyde Ketone
+

03/120c ->
Aldehyde Ketone
+

↓(0]
Carboxylic
Acid
-

8 ⑧
03
1
-
->
2n cHy -
-
4
cn-cho
+

↓.
03 - -
HcH0
C43 Az
+

-->
2n

00 ① ②
83
*
② ->
↓CH8 +HCH8
o * 2n
8
o
③
-
-
1B
 Ketone
Aldehyde

* to +
HC 18 +

m
↓ [0]

H208+

↓
H28 182+

-
0
- +282 2x
CHg -
9H0

[00]
CHz 188+
-

①
① ②

10 % HCH8 +
cHz
-
CHO +

③ 8 ③ - 4
- -
cty
P
①
↓ [8] ③
②
①
H288H +
cHz 180n +

11
↓ cu-coon
H20 182
+
aszy -
-
⑫
?

oxidative
-

Ous. cr(coon),
structure of A is

as
:N:
m
(b) ·fin
nore-(nl,-coon
nooc-cron

⑤ (d) (72)-100n
100-

nooc-cu-coon
D

#I ->
iF= D

d
D
0 ⑧

↓XX -
k -
n

1sY
 it (coon) =>
8
nooc-inc-coon

⑧
11
we
1 2
H -
c -
H
o ①

* X
Formaldehyde ?
8

.x o ↳C Aus)
-
n =

-
8 -

~ 11
4x H c k

I
- -

⑧
⑧

102 *03 8

1mo (
2x p
X.

oNx:
x X

·X

Ozonolysis of Benzene
·0
11 II

·Yz-H
03 3 x H -
C -
C -
H

08

roll.
H-
2x
t -
11
c -
H

y ⑧
11
1-
y
1x - c H
-
 ① ⑧ ⑧ 8

·SF
8

e11
x
-

cHz
+ 1x H -
C
11
-
11
C -
H

-
o

⑤ ·8

:I
1111

Te 2x2Hz c c 4 +
- - -
->
-8

c 1- n

#0
1x H -
-

of
I
⑧ ⑧

- 2 1 11
c cHs
-
- -

#
⑧ 8
11
3 2x H - d -
C - H

# Oxidation Rxn - kMuOy ->

Oxidising agent
on

KMNOu /OH- on
I
>
273k(80)
↳ cold.
-
-
kMn8y /H+
Δ
>
2.
↓
⑧
11

0
- + H -
C -
H

↓ kMnOy
⑧

H -
D -
0 -
M

+20
+
/
10
 +7
kMnOy 1Y
-

①
(Hz ctz =
-> CHz
-

CH2
273K
In on
↳ ⑧ j

Ton
1 A
Mn

g
// 10

(synen) ↳
Add

CH2 CH2
-

↓
ATM
↓ -
↓
Rule is Mn
Valid- X -
yu
y

A T M

S C M

S T R

48

OS On
② CH21st
-

CH2 =
CH2 - ·n
Osmia m

tetraoxide

①
+ 8 11

③ .. kMnOy/H
>
X
I # H -
C -
H

↓ kMnOu
H -
c80H
↓

H20 + 182
 ①
I kMnSy /HT 11
>2x 4
-
2 C
+
- -

↓ KMu8n

2ct c00n

#
polymerisation RxN

High T

n CH
2
=
C+
2
High P
>
tctz -

cHz -
n

Monomer
polymer
u
CHCM2
-
->
⑤
1)
tan -

c27u
ing d+z

(H2
-
-

(b -

(1)(k - (t
z - c+2 -

- c 2
+ -

12-
n
 D ienes double
-
-
=>
containing two bonds

1 - Cumulated (H c
=
=

ctz

(Allenes) -> below the

- >
-
H
1 NNXH plan
c c c
=
=

/ *
H I- above the
seven no
of plane
double bond)
H
7 -4 & -

in
c c c c the
plane
=

= =

/ - X
1 M
codd no.
of
double bond)
⑦

Conjugated N
#fo
->
2.

3. Isolated *

Order:
Stability Conjugated Isolated

cumulated

Rxu
Chemistry
= ->
Kinetics
Thermodynamic
* *

↓ ↓

Product stable Intermediate

stable
↓
↓
High Temp 10w
Temp
(cold cond")
 Diamond ->
Graphite Δ
G
= -
ve

at
Room
Billion
=>

ofyears Temp.

M
Intermediate

snag. Reactant

. . .

>
Product

Rxn coordinate

C12
XXX 3
↑
Xl
⑦
d

① CI

↑ ->
XXu
al
7

& f

(1,2-Add 4)
3

②
",,xXx
E
->
21
↓
3

(1,4-Add")
 ⑰CI ⑦

# 107X
>

Intermediate
④

stable

C1

1
15 N

24

,XXXc
11.2. Add*) 3

(1,4-Add")
↓ Product
stable
Kinetically ↓
controlled

Thermodynamic
controlled