Professional Documents
Culture Documents
Wa0010.
Wa0010.
Wa0010.
OR
Out of FeCl3 and HNO3 which will get hydrolyzed? What will be
the nature of solution?
OR
Q6. How many significant figures are present in 0.0025 and 2500?
OR
OR
Calculate the pH of 10 8 M HCl solution.
washing soda.
the system. What is the change in internal energy for the process?
OR
OR
OR
OR
(a) c
1 + 1 + 1 + 1 + 1 M
29.Out of CH3 COO¯ and OH¯ which is stronger base and why? 1
stable?
34. What would be the IUPAC name and symbol for the element
with atomic 1
number 120?
35. Write down Vander wall equation for one mole of real gas? 1
flask is then filled with water to the mark on the neck. What is the
molarity of
the solution? 2
OR
order of:
Li<B<Be<C<O<N<F<Ne 2
40.xplain why:-Be has higher ΔiH than B.O has lower than ΔiH
than N and F.
ΔH˚= -10.5KJ and ΔS˚= - 44.1 JK-1 mol-1 Calculate ΔG˚ for the
reaction and predict whether
HNO2, CN-
1.n=4, m= -1/2
STP. 3
(ii) Critical temperature for CO2 and CH4 are 31.1˚C and -81.9˚C
respectively. Which of these
CCl4(g)→C(g) + 4Cl(g)
Δf H˚(CCl4)=-135 KJ/mol
Δa H˚(c)=715.0 KJ/mol
Δa H˚(CCl2)=242 KJ/mol. 3
(a) Cl Br
(b) CHO
ii) Name the best and latest technique for isolation, purification and
a) KO2 + H2O →
b) Na(s) + H2O →
2+1+2=5
OR
(a) Lithium salts are commonly hydrated and those of other alkali
metal ions are usually
anhydrous.
significance? 1+1+1+2=5
59. (i) Give reasons for the following:
(iii) Describe inert pair effect with reference to 13th group. 2+1+2=5
OR
¯(143pm) differ.
an example.
1+1+1+2=5
OR
61.Ni atom’s electronic configuration is [Ar]18 3d8 4s2. It will lose two
electrons from the 4s orbital to form Ni 2+ with the electronic
configuration [Ar]18 3d8 4s0.
(a) An element
(b) a compound
(c) a solid
(d) a liquid
(a) Atom
(b) molecule
(a) 5
(b) 3
(c) 2
(d) 26
Ans: (c) 2
(a) 23
(b) 3
(c) 4
(d) 26
Ans: (b) 3
(a) giga
(b) exa
(c) kilo
(d) mega
(c) 1/12 g
(a) 40 ℃
(b) 94 ℃
(c) 93.3 ℃
(d) 30 ℃
72.. Which of the following pairs of gases contains the same number
of molecules?
(a) 16 g of O2 and 14 g of N2
Solution: Divide the given mass by its molar mass to get moles, then
multiply times 6.022×1023 to get the number of molecules.
(b) Chadwick
(c) Rutherford
(d) Priestley
(a) 10-10 cm
(b) 10-13 cm
(c)10-15 cm
(d) 10-8 cm
Solution: Atoms of the same element which have the same atomic
number but different mass number are called isotopes. So they have
Similar chemicals but different physical properties.
Ans: (d)
(a) (n + l) is minimum
(b) (n + l) is maximum
(c) (n + m) is minimum
(d) (n + m) is maximum
(a) n= 4, l = 3, m= 0
(b) n= 4, l = 2, m= 1
(c) n= 4, l = 4, m= 1
(d) n= 4, l = 0, m= 0
Ans: (c) n= 4, l = 4, m= 1
(b) 3
(c) 2
(d) 26
(a) 40 ℃
(b) 94 ℃
(c) 93.3 ℃
(d) 30 ℃
(a) Na+
(b) Al3+
(c) Mg2+
(d) Si4+
(a) △H >△U
(b) △H < △U
(c) △H = △U
(a) NO32-
(b) Cl–
(c) SO42-
(d) CH3COO–
(a) 0
(b) +2
(c) -2
(d) +6
90. The most powerful oxidising agent among the following is:
(a) H2SO4
(b) H3BO3
(c) HPO3
(d) H3PO4
91. The structure of 4-Methylpent-2-en-1-ol is:
(a) CH3CH2CH=CHCH2OH
(b) (CH3)2C=CHCH2CH2OH
(c) (CH3)2CHCH=CHCH2OH
(d) CH3CH(OH)CH-CH=C(CH3)2
Dry ether
a) CH4
b) CH3CH2
c) NaBr
d) CH3CH3
(a) 0
(b) +2
(c) -2
(d) +6
94. The pH of a solution of hydrochloric acid is 4. The molarity of the
solution is:
(a) 4.0
(b) 0.4
(c) 0.0001
(d) 0.04
(a) Sublimation
(b) distillation
(c) filtration
(d) crystallisation
97.. Which of the following compounds will exhibit cis-trans
isomerism?
(a) Butanol
(b) 2- Butyne
(c) 2-Butenol
(d) 2-Butene
a) 0.2 N
b) 0.3 N
c) 2.0 N
d) 3.0 N
SECTION – B
100. (a) Write the atomic number of the element present in the third
period and seventeenth group of the periodic table.
105. The value of Kc for the reaction 2HI (g) ⇋ H2 (g) + I2 (g) is 1
x 10-4. At a given time, the composition of reaction mixture is [HI] =
2 x 10-5 mol, [I2 ] = 1 x 10-5 mol. Determine the direction in which
the reaction will proceed?
SECTION – C
107. Professor of Delhi University found that some scraps emit high
energy radiations, which harmed a large number of people. There are
certain elements like Co-60 that emit radiations on their own and this
phenomenon is called radioactivity. There are three kinds of rays.
Zn (s) + NO3– → Zn2+ (aq)+ NH4 (aq) + H2O (In acid solution)
OR
110.. 1.0 mol of a monoatomic ideal gas is expanded from the state
(1) to state (2) as shown in Fig. 6.4. Calculate the work done for the
expansion of gas from the state (1) to state (2) at 298 K.
111. In DNA and RNA, nitrogen atoms are present in the ring system.
Can Kjeldahl method be used for the estimation of nitrogen present in
these? Give reasons.
SECTION -D
113. Read the passage and answer the questions that follow:
The attractive force which holds the two atoms together is called a
chemical bond. A covalent bond is formed by an equal sharing of
electrons. A coordinate bond is formed by unequal sharing of
electrons. An ionic bond is formed by the transfer of electrons from
one atom to another. Octet rule, although very useful but is not
universally applicable. According to valence bond theory, a covalent
bond is formed by overlapping of half-filled atomic orbitals resulting in
a lowering of energy and more stability. Bond order is the number of
bonds between atoms in a molecule. The higher the bond order more
will be stability and bond dissociation enthalpy but the smaller the
bond length. The polarity of a covalent bond depends upon the
difference in electronegativity. The covalent character of a bond
depends upon polarising power, smaller cation and bigger anions have
higher polarising power. VSEPR theory helps to predict the shapes of
molecules.
c) Out of CN+, CN–, NO, which has the highest bond order?
OR
Reason: Sometimes atoms other than carbon are also present in the
ring known as heterocyclic.
SECTION – E
OR
116. The intermediate carbocation formed in the reaction of HI, HBr
and HCl with propene is the same, and the bond energy of HCl, HBr
and HI are 430.5 kJmol−1, 363.7 kJmol−1 and 296.8 kJmol−1,
respectively. What will be the order of reactivity of these halogen
acids?
volume?
OR