JR CHEMISTRY HOLIDAY WORKSHEET DAY: 05

41. If liquids 𝐴 and 𝐵 from an ideal solution, the:

a) Enthalpy of mixing is zero
b) Entropy of mixing is zero
c) Free energy of mixing is zero
d) Free energy as well as the entropy of mixing are each zero
42. In which of the following cases entropy decreases?
a) Solid changing to liquid
b) Expansion of a gas
c) Crystals dissolve
d) Polymerisation
43. For the reaction N + 3H ⇌ 2NH : ∆𝐻 is
a) ∆𝐸 − 2𝑅𝑇 b) ∆𝐸 − 𝑅𝑇 c) ∆𝐸 + 𝑅𝑇 d) ∆𝐸 + 2𝑅𝑇
44. When one mole of monoatomic ideal gas at 𝑇 temperature undergoes adiabatic change under a constant
external pressure of 1 atm change in volume is from 1 L to 2 L, the final temperature in Kelvin would be
𝑇 2 2
a) ( / ) b) 𝑇 + c) 𝑇 d) 𝑇 −
2 3 × 0.0821 3 × 0.0821
45. In the combustion of 2.0 g of methane, 25 kcal heat is liberated. Heat of combustion of methane would be
a) 150 kcal b) 200 kcal c) 250 kcal d) 350 kcal
46. 1 mole of an ideal gas at 25℃ is subjected to expand reversibly ten times of its initial volume. The change in
entropy of expansion is:
a) 19.15 JK mol b) 16.15 JK mol c) 22.15 JK mol d) None of these
47. The heat of formation (∆𝐻 ) of H O(𝑙) is equal to:
a) Zero
b) Molar heat of combustion of H (𝑙)
c) Molar heat of combustion of H (g)
d) Sum of heat of formation of H O(g) and O (g)
48. The entropy change for the reaction given below,
2H (g) + O (g) → 2H O(𝑙)
Is…at 300 K. Standard entropies of H (g), O (g) and H O(𝑙) are 126.6, 201.20 and 68.0 JK mol
respectively.
a) −318.4 JK mol b) 318.4 JK mol c) 31.84 JK mol d) None of these
49. Heat of combustion ∆𝐻 for C(𝑠), H (g) and CH (g) are −94, −68 and −213 kcal/mole then ∆𝐻 for C(𝑠) +
2H (g) → CH (g)i𝑠 ∶
a) −17 kcal b) −111 kcal c) −170 kcal d) −85 kcal
50. A positive change in enthalpy occurs in :
1
a) H (g) + O (g) ⟶ H O(g)
2
b) N (g) + 3H (g) ⟶ 2NH (g)
c) MgCO (𝑠) ⟶ MgO(𝑠) + CO (g)
1
d) H (g) + O (g) ⟶ H O(𝑙)
2

KEY:

41) A 42) D 43) A 44) D 45) B 46) A 47) C 48) A 49) A 50) C