DPP NO.

(JEE MAIN+ADVANCED)
Max Marks: Max Time:

Draw a circle around the atom with the localized lone pair and
rectangle around the atom with delocalized lone pair in the

]
following molecules:

TB
[II
NH
N
N N
N
1.
NA
N N
N

N
RA

2. 5.

N NH
IN

N
NH

6. O
CH

NH2
3.
HN
NH2
SA

..
NH
N
7. NH2

4.

Page No. 1
 NH N O

N
8.

13. O

9. NH
O

]
TB
N

NH
10.

NH 14. [II N
NA
NH NH
11. N
RA

O
IN

15. NH
12. O
CH

NH

NH
SA

NH
16.

Page No. 2
 HN

O O
NH
17.

N 22. N

N N

18.

]
NH
NH

TB
NH
23. HN

HB

19. H2N
[II O
NA
N
24. O

20. NH NH
RA

NH
IN
CH

21. NH2

25. NH
SA

Page No. 3
 NH NH

26. H2N NH2

30. NH

NH
NH NH

]
TB
27. N

31. O

NH2

[II NH
NH
NA
NH

32. NH
RA

28. NH

HN NH
IN
CH
SA

29. N

Page No. 4
 ANSWERS

NH NH

N N
1. NH

N 6. O

HN
2. NH2

]
TB
N

7. NH2

NH N

3. NH2

8.
[II N
NA
N
..
NH
N
RA

4.

9. NH
IN

N
N N
N
CH

NH
N
N 10.
N
SA

5. NH

11. N

Page No. 5
 O
NH

NH

12. O
NH
16.
O

O O

]
17.

TB
N

13.

[II
O

O 18.
NA
NH
NH
RA

14. N 19. H2N

IN

NH NH N
CH

20. NH
SA

15. NH

Page No. 6
 NH NH

21. NH2

HN

25. NH
NH

]
NH

TB
22. N

[II
26. H2N

NH
NH2
NA
NH

23. HN
RA

HB

O 27. N
IN

24. O NH2
CH
SA

28. NH

Page No. 7
 HN NH NH NH

31. O

29. N NH

]
NH

TB
NH

N NH

30. NH
32.

[II NH
NA
RA
IN
CH
SA

Page No. 8
 DPP NO. (JEE MAIN+ADVANCED)
Max Marks: Max Time:

Q. Compare the acidic strength of the following compounds:

]
TB
COOH COOH

CH3

1. a. b. [II
NA
COOH COOH

CH3
RA

2. a. b.
IN
CH
SA

3. a. b.

Page No. 1
 O
O

4. a. O b.

O O O

OMe

]
5. a. b.

TB
O O

OH NH2

[II
NA
6. a. b.

OH NH2
RA

7. a. b.
IN

OH
CH

OH
SA

8. a. OCH3 b. CN

Page No. 2
 Cl

COOH
9. a. Cl b. COOH

10. a. OH b. OH

11. a. HF b. NH3

]
12. a. b. NH3

TB
13. a. CH4 b. NH3

OH O
[II
NA
14. a. O b. OH
RA
IN
CH
SA

Page No. 3
 ANSWERS

1. a>b
2. b>a
3. b>a
4. a>b
5. a>b
6. a>b
7. a>b

]
TB
8. b>a
9. b>a
10. b>a
11. a>b
12. a>b [II
NA
13. b>a
14. b>a
RA
IN
CH
SA

Page No. 4
 DPP NO. (JEE MAIN+ADVANCED)
Max Marks: Max Time:

Q. Compare the acidic strength of the following compounds:

]
TB
O OH

1. a. b.
Ph
[II
S

O
OH
NA
O

2. a. R OH b. R C OH
RA

HO O

HO O
IN

Me
CH

3. a. b. Me
SA

Page No. 1
 HO O

OH

4. a. Me b.

OH
OH

]
5. a. F b. F

TB
OH
OH C
+
6. a. b.

[II
NH2R3 N

7. a. CH4 b. HF
NA
8. a. HF b. HI

9. a. H2S b. H2O
RA
IN

10. a. b.
CH

11. a. N N b. O2N N

N
SA

12. a. N N b. O2N

Page No. 2
 O O

OEt H

OEt H

13. a. O b. O

N F
14. a. b.

15. a. CCl3OH b. CF3OH

]
TB
16. a. b.

OH
[II OH
NA
17. a. Cl b. Br

O O
RA

18. a. OH b. OH

O
IN

OH O
CH

19. a. b. OH
SA

20. a. CHCl3 b. HCF3

Page No. 3
 ANSWERS

1. b>a
2. b>a
3. a>b
4. a>b
5. b>a
6. a>b
7. b>a
8. b>a

]
9. a>b

TB
10. a>b
11. a>b
12. b>a
13. b>a
14. a>b
[II
NA
15. b>a
16. b>a
17. a>b
RA

18. a>b
19. a>b
20. a>b
IN
CH
SA

Page No. 4
 DPP NO. (JEE MAIN+ADVANCED)
Max Marks: Max Time:

Q. Compare the basic strength of the following compounds:

]
TB
NH2 NH2

CH3

1. a. b. [II
NA
NH2 NH2

CH3
RA

2. a. b.
IN
CH

3. a. N b. NH
SA

4. a. O b. NH

Page No. 1
 NH O N

5. a. b.

NH NH

6. a. b.

]
TB
[II
NA
RA
IN
CH
SA

Page No. 2
 ANSWERS

1. b>a
2. a>b
3. a>b
4. b>a
5. b>a
6. b>a

]
TB
[II
NA
RA
IN
CH
SA

Page No. 3
 DPP NO. (JEE MAIN+ADVANCED)
Max Marks: Max Time:

Q. Compare the basic strength of the following compounds:

]
TB
NH

1. a. N

NH2
b.

[II
NA
NH2
RA

2. a. CH3 b.
IN

NH2

CH3
CH

3. a. Ph NH Me b.
SA

Ph N Me

4. a. Ph NH Me b. Me

Page No. 1
 H2N C NH H2N C NH

5. a. NH2 b. CH3

NH2 NH2

Me Me

6. a. b.

]
N

TB
7. a. b. N

[II
O
NA
8. a. N b. NH

S
RA

9. a. NH b. NH

– –
IN

C CH
CH

10. a. b.
SA

Page No. 2
 – –
O CH2

11. a. b.

H2N NH

H2N NH

]
TB
12. a. b. NH2

H2N NH H2N

[II NH
NA
RA

13. a. NO2 b. Cl
IN
CH
SA

Page No. 3
 ANSWERS

1. b>a
2. a>b
3. a>b
4. b>a
5. a>b
6. a>b
7. b>a
8. b>a

]
9. a>b

TB
10. b>a
11. b>a
12. b>a
13. b>a
[II
NA
RA
IN
CH
SA

Page No. 4
 DPP NO. (JEE MAIN+ADVANCED)
Max Marks: Max Time:

Q. Which Nitrogen is more basic in the following compounds:

]
TB
Me
Nb

1. N
a
[II
NA
NH2
a
RA

NH
2. b
N c

b
IN

NH2

O
CH

H2N C
a
3.

a
SA

O Nb

4.

Page No. 1
 a
NH

H3C

5. b
NH2

a
NH

HN NH
c b

6.

]
TB
O

7. H2N NH

[II
a b

a NH
2
NA
RA

8. b
NH2
IN
CH
SA

Page No. 2
 ANSWERS

1. a>b
2. b>a>c
3. b>a
4. b>a
5. a>b
6. a>b=c
7. b>a
8. a>b

]
TB
[II
NA
RA
IN
CH
SA

Page No. 3