Question Paper [CODE - 16760]

V-star_Quiz-08
13th JEE (M+A) - Phase 1
KOTA

Date: 30-Sep-2023 Duration: 3 Hours Max Marks: 210

 MATHS

1. Let f(t) = |t| + |t–1| ∀ t ∈ R and 3. A circle of radius r = 4 units is inscribed in an

equilateral triantgle ABC, then an
g(x) = equilateral triangle is inscribed in the circle, a
max. (f (t)) , x − 1 ≤ t ≤ x, 0 ≤ x ≤ 1 circle again is inscribed in the later triangle and
{
3 − x 1 < x ≤ 2 so on. In this way the process continues
infinitely. If r, x1, x2, ..., xn, .... be the radii of
Number of points where g(x) is non-derivable in these circles respectively, then the sum of radii
[0, 2], is: of all the circles x1 + x2 + x3 ... ∞ is equals to

(A) 0 (A) 3

(B) 1 (B) 5

(C) 2 (C) 4

(D) 3 (D) 6

2. Let S be the circle x2 + y2 – 2x – 4y – 4 = 0 4. In Δ ABC, if ∠B = sec–1 (

5
) + cosec–1 √5 , ∠C
and M be any point on S. Let S1 be the set of all
4

= cosec–1( + cot–1( 13 ) and c = 3.

25 9
circles whose center is R (4+cosθ, 6 + sinθ) 7
)

∀θ ∈ R . MP and MQ are tangents to S1. Let L

and ℓ be the maximum and minimum values of Which of the following statements is incorrect ?
length of diameter of circumcircle of tringle MPQ (where all symbols used have their usual
then Lℓ is. meanings in a triangle)

(A) 5 (A) tan A, tan B, tan C are in arithmetic

progression.
(B) 7
(B) Inradius of the triangle is irrational
(C) 9
(C) Area of Δ ABC is rational.
(D) 11
(D) Semiperimeter is rational

5. Let xi, where i = 1, ...... n be the roots of n

degree polynomial P(x) = xn – 14xn–1 + 70xn–2
+ ..... If the standard deviation of all xi, i = 1,
2, .... n is 2, then find the number of
observation

(A) 4

(B) 5

(C) 6

(D) 7
 MATHS

6. The equation of straight line with gradient 1, 9. Let f be a real valued function satisfying f(x + y
passing through ( 2 , 2 ) where m, n ∈ R
m n
+ z) = f(x) f(y) f(z)∀x, y, z ∈R. If f(2) = 4 and f
'(0) = 3. Then
satisfies the equation 2
sec (n(m + 2)) + m
2
= 1

(where n ∈[
−π
,
π
]) can be (A) f(0) = 1
2 2

(B) f(0) = 0
(A) x + y = 0
(C) f '(2) = 12
(B) x − y = 0
(D) f '(2) = 10
(C) x − y + 4 = 0
π

10. Which of the following statements is (are)

(D) x − y − π
=0 correct ?
4

7. 4
(1 +
1

4
)(3 +
4 1

4
)(5 +
4 1

4
).....((2n−1) +
4 1

4
) [Note : [x] and {x} denote greatest integer less
Let A = 1 1 4 1
and if than or equal to x and fractional part of x
4 4
(2 +
4
)(4 +
4
)....((2n) +
4
)
respectively.]
L= lim (n
α
A) , then
x→∞
(A) f(x) = [lnx] + √{ln x} , x >1 is continuous
(A) the value of α for which L exist finitely and at x = e.
is non - zero is 2. 2
3x +ax+a+1
(B) If lim ( ) exists and equals l,
(B) the value of A equals 0.
2
x +x−2
lim x→2

then = 10.
n→∞ 1
a +
ℓ

(C) If L∈R, L≠0, then value of α + 8L is 3.

(C) f : [–1,1] → [–1,1], f(x) = x2 sgn(x) is a
(D) the value of of lim A equals 1. bijective function, where sgn x denotes signum
n→∞
function of x.
8. Let f : (0, ∞ ) → [1, ∞ ) be defined as f(x) =
1
(D) if f is continuous on [–1,1], f(–1) = 4 and
, 0 < x < 1
x f(1) = 3, then there exists a number r such that
[ x
, 1 ≤ x < ∞ |r| < 1 and f(r) = π.
[x]

where [x] denotes largest integer less than

or equal to x. Then which of the following
statements is (are) correct?

(A) f(x) is neither injective nor surjective.

(B) f(x) is continuous but non-derivable at x =

1.

(C) f(x) has non-removable discontinuity of

finite type at x = 2 with jump equals 1 .
2

(D) f '(e) = 2
1
 MATHS

Passage: Passage:

Let f be a real-valued continuous function Let f : R → R be a differentiable function such

defined on R0 as f(x) = that f (1) = 1, f (2) = 20, f (– 4) = – 4, f ' (0) =
0 and f (x + y) = f (x) + f (y) + 3xy(x + y) +
x
2 4
⎧ (p + qx + rx ) ,
|x| ≤ 1 − {0}
⎨ 2
bxy + c(x + y) + 4 ∀x, y ∈R, where b, c are
⎩
2(qx −r)
, |x| > 1 constants.
2
x −1

13. The value of (b + c) is equal to

where the equation rx4 + qx2 + p = 0 has a
root equal to zero and q, r > 0. (A) 8

[Note : R0 denotes the set of all real numbers (B) 9

except zero.]
(C) 10
11.
x
The value of lim (p + qx
2 4
+ rx ) is equal to
x→0
+ (D) 11

(A) 0 14. Number of solutions of the equation f(x) = x3 +

4ex is equal to
(B) 1
(A) 0
(C) 2
(B) 1
(D) 3
(C) 2
12. The left hand derivative of f(x) at x = 1 is equal
to (D) 3

(A) 0

(B) 2

(C) 3

(D) 5
 MATHS

15. Consider a parabola y2 = lx (l > 0) with its (B) (A) → P; (B) → S; (C) → S ; (D) → R
vertex at the origin 'O'.
(C) (A) → R; (B) → Q; (C) → P ; (D) → Q
Column-
Column-I
II (D) (A) → P,R; (B) → Q; (C) → R ; (D) → P
If origin is joined to any
point P on the given
parabola and a line l
(A) perpendicular to OP (P) 4
through P meet the axis
at Q, then projection of
PQ on the axis is equal to
A normal is drawn at any
arbitrary point P on the
parabola which meets l
(B) the axis at G. Locus of (Q) 2
the middle point of PG is
a parabola whose latus
rectum is
A variable parabola of
latus ractum l, touches
the given parabola, the
axes of the two curves
(C) being parallel. The locus (R) l
of the vertex of the
variable parabola is
another parabola whose
latus rectum is
The locus of the mid
point of the focal radii of
a variable point P moving
(D) (S) 2l
on the given parabola, is
a parabola whose
latusrectum is

(A) (A) → R; (B) → P; (C) → S ; (D) → Q

 MATHS

16. Let f : R → R be a continuous function such that 19. Let f be a differentiable function satisfying the
f(x + y) = f(x) + f(y) + f(x) f(y), ∀, x,y ∈ R. functions rule f(xy) = f(x) + f(y) +
x+y–1
, ∀ x, y
xy
f (4)
Also f'(0) = 1. Then [ ] equals > 0 and f'(1) = 2. Find the value of [f(e 100
)]−
f (2)
95.
([.] represents greatest integer function)
Note : [k] denotes the greatest integer less
17. 2
1
1
than or equal to k.
⎛ ( lim n (x n
−x n+1
)) ⎞
n→∞

Value of L = lim ⎜ 3
⎟ is of the 20. If f is a positive real valued differentiable
(x −1)
x→1
⎝ ⎠ function satisfying the functional rule
form a/b where a and b are coprime then the f2(x + y) = f 2(x) + f 2(y) –
2√x − 2√y + 2√x + y – 1 for all x, y ≥ 0
value a + b =
such that
18. Let W1 and W2 denote the circles x2 + y2 + 10x f (h)−2
= , then find the number of
1

– 24y – 87 = 0 and x2 + y2 – 10x – 24y + 153 Lim

h→1
h−1 2

= 0 respectively. Let m be the smallest positive solution(s) of the equation

value of 'a' for which the line y = ax contains f (|x|)

the centre of a circle that is externally tangent = 1 (λ > 0).

λ|x|+1

to W2 and internally tangent to W1. Given

that m2 = q where p and q are relatively prime
p

integers, find √(p + q)

 PHYSICS

1. A player caught a cricket ball of mass 150 g 4. A stationary hydrogen atom of mass M emits a
moving at a rate of 20 m/s. If the catching photon corresponding to the longest wavelength
process is completed in 0.1 s, the force of the of Balmer series. The recoil velocity acquired by
blow exerted by the ball on the hand of the the atom is
player is equal to
(R = Rydberg constant and h = planck's
(A) 150 N constant)

(B) 3 N (A)
Rh

(C) 30 N
(B)
Rh

4M
(D) 300 N
(C)
3 Rh

2. A man of 80 kg attempts to jump from the 4 M

small boat of mass 40 kg on to the shore. He

(D)
5 Rh

can generate a relative velocity of 6 m/s 36 M

between him and boat. His velocity towards

5. If a steel band were to fit snugly around the
shore is
Earth's equator at 25°C, but then was heated to
(A) 2 m/s 45°C, how high above the Earth would the band
be (assume equal everywhere)?
(B) 3 m/s
(Take : α for steel to be 12 × 10-6 /°C)
(C) 4 m/s
(A) 1.028 km
(D) 8 m/s
(B) 1.536 km
3. A cannon is mounted on a trolley initially at
rest. A cannon ball is fired at an angle θ and (C) 2.062 km
velocity vrel relative to trolley which is free to
(D) None of these
recoil frictionlessly on a smooth surface. Which
of the following trajectory (represented by dark
curves) of projectile for a ground is possible?

(A)

(B)

(C)

(D)

PHYSICS
 PHYSICS

6. A particle of mass m is going along surface of 9. Two blocks of mass m each are moving
smooth hemisphere of radius R in vertical plane. vertically downward under influence of an
At the moment shown, its speed is v. Choose external force of magnitude 2mg as shown in
correct option (s). figure.

(A) (A) Contact between blocks will break and

2
2 v
mg − N cos θ = m(g sin θ − cosθ)
R

normal reaction between blocks becomes zero.

2

(B)
mv
N − mg cos θ =
R (B) Both blocks move in combination with
2 common acceleration a = 2g
(C)
mv
mg − N sin θ =
R
(C) Contact force between blocks is mg
(D)
2
V
N sin θ = m(g sin θ cos θ − sin θ)
R
(D) Both blocks move in combination with
11 2 common acceleration a = g
7. Two bars of steel (Y = 2 × 10 N/m ) are
joined together as shown. The area of cross 10. Two particies A & B are moving along the tracks
section of the left bar is 15 cm2 and the area of as shown in figure. Tangential acceleration of A
right bar is unknown. The extension in both is aA = 2m/s2. B is moving with constant speed
bars is the same. 15 m/s

(A) The area of right bar is 10 cm2

(B) The stresses in left and right bar are in ratio

3:2

(C) The decrease in thickness of bar is more for

(A) Radial acceleration of B is 0.9 m/s2
the left bar
(B) Velocity of B with respect to A is nearly 26
(D) The decrease in thickness of bar is more for
m/s
right bar
(C) Velocity of A with respect to B is 45 m/s.
8. A monoatomic ideal gas undergoes a series of
processes 1–2–3–4 on T–P diagram as (D) Velocity of A after 2 sec. is 34 m/s.
shown.Choose the correct statement(s)

(A) The work done by gas during 2–3 is zero

(B) The gas is given heat during 1–2.

(C) Internal energy of gas increases only in 3–

4.

(D) Work is done by gas during 3–4.

 PHYSICS

Passage: Passage:

A small ball hanging by a thread undergoes One kg of a substance (initially solid at 0o C) is

circular motion in vertical plane. At the supplied heat at a constant rate of 2 kcal/min.
uppermost point of its path its velocity is 6 m/s. Coefficient of thermal expansion of the solid (α)
The tension in the thread is three times at the = 4 × 10-6 /oC Its temperature varies with time
lowermost point than at the uppermost point. as shown.

11. How long is the thread?

(A) 0.9 m

(B) 3.6 m

(C) 1.8 m

(D) None of these

12. What is the maximum velocity of the ball?

(A) 6√5m/s
13. Which of the following is not correct?

(B) 30 m/s (A) Melting point of the substance is 20oC

(B) Boiling point of the substance is 110o C

(C) 6√2m/s

(C) Latent heat of vapourization for the

(D) None of these substance is greater than the latent heat of
fusion

(D) Specific heat capacity of liquid is more than

that of the solid

14. Specific heat capacity of the liquid is -

(A) 3 cal/gmoC

(B) cal/gmoC
1

(C) 2 cal/gmoC

(D)
1 o
cal / gm C
2
 PHYSICS

15. Electrons having de-Broglie wavelength λ as (B) (A) QRSTP (B) R (C) S (D) PQR
shown in column-I are incident on a sample of
hydrogen gas in ground state. The atoms then (C) (A) PQRSTP (B) S (C) Q (D) RTP
emit photons corresponding to some series. (D) (A) RQSTP (B) S (C) Q (D) RTP
Match the wavelength of incident electrons with
series emitted.

Column-I Column-II

(A) 0.31 nm (P) Lyman

(B) 0.36 nm (Q) Balmer

(C) 0.38 nm (R) Paschen

(D) 0.34 nm (S) Brackett

(T) Pfund.

(A) (A) PQRST (B) P (C) P (D) PQR

 PHYSICS

16. An insulating piston separates a thermally 18. A light ray is incident on side AB of an
insulated vessel into two parts. The left part equilateral triangular prism at angle α (see fig.).
contains one mole of an ideal monatomic gas If α ≤ 90° some of the light emerges through
and right part is empty. The piston is connected side AC, but if α > 90°, no light emerges
to the right wall of the vessel, through a spring through this side. The refractive index of the
whose unstretched length is equal to length of prism glass is μ . The value of is
the vessel. The gas is heated by means of a
heating coil inside the gas chamber. Ignore
friction and heat capacities of the spring, vessel
and piston. If the pressure of gas becomes 2P0,
the temperature becomes nT0. Find n.

19. For the system shown in the figure, the speed of

sphere A is 9 m/s. The speed of sphere B (in
m/s) is v. Fill v/3 in OMR sheet

17. A spherical balloon whose initial radius was 3m

is expanded such that it's surface area is
increasing at a constant rate of 72πm2/sec.
What is the speed of a point (in m/s) on the
surface in the radially outward direction when
radius becomes 9m
20. A monochromatic source of light is radiating
waves of wavelength λ = 5000Å. The rays fall
on a metal surface, which in turn, liberates
photoelectrons. The work function of metal is
1.48 eV. The smallest de-Broglie wavelength of
the emitted electron (in nm) is_______. Round
off to nearest integer.
 CHEMISTRY

1. Which statement(s) is/are true about the 3. A solution containing 2. 665 gram of
relation between the following compounds? CrCl3 ⋅ 6H2 O is allowed to pass through a

cation exchange resin. The chloride ions

obtained in the solution give 2. 87 gram of AgCl
on treatment with excess of AgNO3 solution.
(a) (b) The structure of the compound is
[Cr = 52 g/ mol]

(A) [Cr (H2 O) ]Cl3

6

(B) [Cr (H2 O)

5
Cl]Cl2 ⋅ H2 O
(c)
(C) [Cr (H2 O)
4
Cl2 ]Cl − 2H2 O

(D) [Cr (H2 O) Cl3 ]

(I) a and b are tautomers 3

(II) b and c are resonating structures 4. Give the correct order of initials T (true) or F
(III) a and c are resonating structures (False) for following statements.
(IV) a and c are tautomers
I. In an anti-fluorite structure anions form FCC
(A) I & III
lattice and cations occupy all tetrahedral voids.
(B) II & IV
II. If the radius of cations and anions are 0.2 Å
(C) I, II & III
and 0.95 Å then coordinate number of cation in
the crystal is 4.
(D) I & IV
III. An atom/ion is transferred from a lattice site
2. 10 ml of 0.10M solution of a compound (Na2CO3 to an interstitial position in Frankel defect.
. NaHCO3 . 2H2O) is titrated against 0.05 M HCl.
IV. Density of crystal always increases due to
X ml of HCl is used when phenolphthalein is the
substitutional impurity defect.
indicator and Y ml of HCl is used when methyl
orange is the indicator in two separate titration, (A) TFFF
hence (Y – X) is
(B) FTTF
(A) 20 ml
(C) TFFT
(B) 40 ml
(D) TFTF
(C) 60 ml
5. Which of the following option(s) represent the
(D) None of these CORRECT IUPAC name of the given co-
ordination compounds?

(A) Li[CuMe2] : Lithium dimethylcuprate (II)

(B) [Os(Et)(NH3)5]Cl :
Pentaammineethylosmium (II) chloride

(C) K3[Co(CN)5H] : Potassium

pentacyanidoprotoniumcobaltate (I)

(D) [Co(en)3]Cl3 : Tris-(ethane-1, 2-

diammine)cobalt (III) chloride
 CHEMISTRY

6. Which of the following is not the correct 7. Two liquids A and B form a non-ideal solution
relationship with large positive deviation. The pressure vs
liquid composition graph is

Which of the following statement(s) is /are

correct regarding the solution?

(A) At any composition XB < X, the vapour at

equilibrium will have greater mole-fraction of 'B'
than its mole-fraction in liquid.

(B) At any composition XB > X, the vapour at

equilibrium will have greater mole-fraction of 'A'
than its mole fraction in liquid.

(C) At any composition XB < X, traces of pure

(A) II & IV are metamer liquid 'A' may be obtained by distillation but not
pure 'B'.
(B) I & II are functional isomer
(D) At any composition XB > X, traces of pure
(C) I & III are chain isomer liquid 'B' may be obtained by distillation but not
(D) I and IV are positional isomer pure 'A'.

8. Which of the following statements is incorrect ?

(A) Some of the four-coordinated complexes of

Ni2+ ion are square planar and some are
tetrahedral.

(B) The [Fe(H2O)6]3+ ion is more paramagnetic

than the [Fe(H2O)6]2+ ion

(C) CFSE of square planar complexes are more

than octahedral complexes for Pt.

(D) The [Fe(CN)6]4– ion is paramagnetic but

[Fe(CN)6]3– is diamagnetic
9. Which relationship is/are correct? 10. Which of the following is (are) correct
statement(s) (assuming oxidation number of
metal does not affect crystal field energy)
(A) Identical (A) Considering H2O to be a weak ligand then
on the basis of CFSE only, we can say that
[Co(H2O)6]2+ is more stable than [Co(H2O)6]3+

(B) On the basis of CFSE only [Fe(NH3)6]2+ is

(B) Position isomer more stable than [Fe(NH3)6]+3

(C) All octahedral complexes of Ni(II) are bound

to be outer d-complex

(D) The type of d-orbital involved in the

(C) Functional isomer hybridisation for a square planar complex (CN =
4) is dz2.

(D) Metamers
 CHEMISTRY

Passage: Passage:

0.25 mole of solid 'A" is taken in a 1L evacuated

flask at 27°C. Following two equilibrium exist
simultaneously.
A(s) ⇌ B(g) + C(g) .... (i) KC 1

2B(g) ⇌ D(g) + 2E(g) ....(ii) KC 2

Let 0.2 moles of solid decomposes upto

equilibrium & 0.1 mole of E was found at
equilibrium.
[Given : R = 0.08 L atm K–1 mol–1]
13. Calculate partial pressure of B at equilibrium.

(A) 1.2 atm

11. Correct order of C–H bond energy :
(B) 0.8 atm
(A) i > b > d
(C) 2.4 atm
(B) d > b > i
(D) None of these
(C) d > i > b
14. Calculate KC
1

(D) i > d > b

(A) 0.01
12. Correct order of basic strength is :
(B) 0.02
(A) e > j > f > h
(C) 2 × 10–4
(B) f > e > j > h
(D) None of these
(C) j > e > f > h

(D) h > e > j > f

 CHEMISTRY

15. An ion M
II
forms the complexes of the types (B) a - q, b - p, c - q
2+ 4− 2+
[M(H2 O) ]
6
, [MBr6 ] and [M(en) ]
3
. The (C) a - r, b - r, c - p
expected colour of the complexes, not
necessarily in order, are green, red and blue. ( (D) a - s, b - q, c - p
Δ0 a Strength of ligand and the colour observed

is the complimentary colour of the light

absorbed)

Select the correct matching :

Column - I Column - II
complex colour of complex
2+
(a) [M(H2 O) ]
6
(p) Green
4−
(b) [M(Br) ]
6
(q) Red
2+
(c) [M(en) ]
3
(r) Blue

(A) a - p, b - r, c - q
 CHEMISTRY

16. The crystal of a solid is square packing of 18. If total no. of structural isomers of C4H9OC4H9
identical spheres in each layer and spheres of is x then x2 is equal to? (Note: migration of
one layer are placed just above the voids made carbon atom is not allowed)
by spheres in previous layer. The
packing efficiency of such crystal (in %) is 19. Find the total number of isomers excluding
[p = 3.15, √2 = 1. 4 ] sterioisomers of the complex 'X'. IUPAC name of
the complex 'X' is Hexaamminecobalt(III)
hexacyanidocobaltate(III).
20. Nickel can form low spin as well as high spin
complex with different ligands. Number of
unpaired electrons in [Ni(CO)4 ] and
2−
[Ni(CN)4 ] is x and y respectively, then
2 + x + y is

17. Total number of geometrical isomers for the

+
complex: [Ir(acac)(SCN)(H2 O)(NH3 )(Py)]
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