#Challenge-1

Given below are two statements:

Statement I: Fluorine has most negative electron gain enthalpy in its
group.
Statement II: Oxygen has least negative electron gain enthalpy in its
group.
In the light of the above statements, choose the most appropriate
from the options given below.

A Both Statement I and Statement II are true

B Statement I is true but Statement II is false

C Both Statement I and Statement II are false

D Statement I is false but Statement II is true

Given below are two statements:
Statement – I: Along the period, the chemical reactivity of the
element gradually increases from group 1 to group 18.
Statement – II: The nature of oxides formed by group 1 element is
basic while that of group 17 elements is acidic.
In the the light above statements, choose the most appropriate from
the questions given below :

A Both statement I and Statement II are true.

B Statement I is true but Statement II is False.

C Statement I is false but Statement II is true.

D Both Statement I and Statement II is false.

Given below are two statements:
Statement (I) : The NH2 group in Aniline is ortho and para directing
and a powerful activating group.
Statement (II) : Aniline does not undergo Friedel- Crafts reaction
(alkylation and acylation).
In the light of the above statements, choose the most appropriate
answer from the options given below :

A Both Statement I and Statement II are correct

B Both Statement I and Statement II are incorrect

C Statement I is incorrect but Statement II is correct

D Statement I is correct but Statement II is incorrect

Given below are two statements :
Statement (I) : p-nitrophenol is more acidic than m-nitrophenol
and o-nitrophenol.
Statement (II) : Ethanol will give immediate turbidity with Lucas
reagent.
In the light of the above statements, choose the correct answer
from the options given below :

A Statement I is true but Statement II is false

B Both Statement I and Statement II are true

C Both Statement I and Statement II are false

D Statement I is false but Statement II is true

Given below are two statements:
Statement (I) : Aminobenzene and aniline are same organic
compounds.
Statement (II) : Aminobenzene and aniline are different organic
compounds.
In the light of the above statements, choose the most
appropriate answer from the options given below:

A Both Statement I and Statement II are correct

B Statement I is correct but Statement II is incorrect

C Statement I is incorrect but Statement II is correct

D Both Statement I and Statement II are incorrect

Given below are two statements : one is labelled as
Assertion (A) and the other is labelled as Reason (R).
Assertion (A) : Haloalkanes react with KCN to form alkyl
cyanides as a main product while with AgCN form isocyanide
as the main product.
Reason (R) : KCN and AgCN both are highly ionic compounds.
In the light of the above statement, choose the most
appropriate answer from the options given below :

A (A) is correct but (R) is not correct

B Both (A) and (R) are correct but (R) is not the correct
explanation of (A)
C (A) is not correct but (R) is correct

D Both (A) and (R) are correct and (R) is the correct explanation of (A)
Choose the correct statements about the hydrides of group 15 elements.
A. The stability of the hydrides decreases in the order NH3 > PH3 > AsH3 > SbH3 > BiH3
B. The reducing ability of the hydrides increases in the order NH3 < PH3 < AsH3 < SbH3 < BiH3
C. Among the hydrides, NH3 is strong reducing agent while BiH3 is mild reducing agent.
D. The basicity of the hydrides increases in the order NH3 < PH3 < AsH3 < SbH3 < BiH3
Choose the most appropriate from the option given below :

A B and C only B C and D only

C A and B only D A and D only

Given below are two statements :
Statement I: S8 solid undergoes disproportionation reaction
2- 2-
under alkaline conditions to form S and S2O3
-
Statement II: ClO4 can undergo disproportionation reaction
under acidic condition.
In the light of the above statements, choose the most
appropriate answer from the options given below :

A Statement I is correct but statement II is incorrect.

B Statement I is incorrect but statement II is correct

C Both statement I and statement II are incorrect

D Both statement I and statement II are correct

Given below are two statements :
Statement I: Aniline reacts with con. H2SO4 followed by heating at 453-473
K gives p-aminobenzene sulphonic acid, which gives blood red colour in
the 'Lassaigne's test'.
Statement II: In Friedel - Craft's alkylation and acylation reactions, aniline
forms salt with the AlCl3 catalyst. Due to this, nitrogen of aniline aquires a
positive charge and acts as deactivating group. In the light of the above
statements, choose the correct answer from the options given below :

A Statement I is false but statement II is true

B Both statement I and statement II are false

C Statement I is true but statement II is false

D Both statement I and statement II are true

Given below are two statements:
Statement-I: Since fluorine is more electronegative than nitrogen, the net
dipole moment of NF3 is greater than NH3.
Statement-II: In NH3, the orbital dipole due to lone pair and the dipole moment
of NH bonds are in opposite direction, but in NF3 the orbital dipole due to lone
pair and dipole moments of N-F bonds are in same direction.
In the light of the above statements. Choose the most appropriate from the
options given below.

A Statement I is true but Statement II is false.

B Both Statement I and Statement II are false.

C Both statement I and Statement II is are true.

D Statement I is false but Statement II is are true.

Given below are two statements:
Statement – I: High concentration of strong nucleophilic reagent with
secondary alkyl halides which do not have bulky substituents will
follow SN2 mechanism.
Statement – II: A secondary alkyl halide when treated with a large
excess of ethanol follows SN1 mechanism.
In the the light of the above statements, choose the most appropriate
from the questions given below :

A Statement I is true but Statement II is false.

B Statement I is false but Statement II is true.

C Both statement I and Statement II are false.

D Both statement I and Statement II are true.

Given below are two statements: One is labelled as Assertion A
and the other is labelled as Reason R.
Assertion A : H2Te is more acidic than H2S.
Reason R: Bond dissociation enthalpy of H2Te is lower than H2S.
In the light of the above statements. Choose the most
appropriate from the options given below.

Both A and R are true but R is NOT the correct

A
explanation of A.

Both A and R are true and R is the correct

B
explanation of A.

C A is false but R is true.

D A is true but R is false.

Choose the correct statements from the following
A. All group 16 elements form oxides of general formula EO2 and
EO3 where E = S, Se, Te and Po. Both the types of oxides are
acidic in nature.
B. TeO2 is an oxidising agent while SO2 is reducing in nature.
C. The reducing property decreases from H2S to H2Te down the
group.
D. The ozone molecule contains five lone pairs of electrons.
Choose the correct answer from the options given below:

A A and D only B B and C only

C C and D only D A and B only

Given below are two statements: one is labelled as Assertion
(A) and the other is labelled as Reason (R).
Assertion (A) : PH3 has lower boiling point than NH3.
Reason (R) : In liquid state NH3 molecules are associated
through van der waal’s forces, but PH3 molecules are
associated through hydrogen bonding.
In the light of the above statements, choose the most
appropriate answer from the options given below :

A Both (A) and (R) are correct and (R) is not the
correct explanation of (A)
B (A) is not correct but (R) is correct

Both (A) and (R) are correct but (R) is the

C
correct explanation of (A)

D (A) is correct but (R) is not correct

Given below are two statements :
Statement (I) : Potassium hydrogen phthalate is a primary
standard for standardisation of sodium hydroxide solution.
Statement (II) : In this titration phenolphthalein can be used as
indicator.
In the light of the above statements, choose the most appropriate
answer from the options given below :

A Both Statement I and Statement II are correct

B Statement I is correct but Statement II is incorrect

C Statement I is incorrect but Statement II is correct

D Both Statement I and Statement II are incorrect