M1 62

Th 1.
e
av
era
ge
rat
e
of
dis
ap
pe
ara
nc
e
of
oz
on
e
in
the
rea
cti
on
2O
3(g
)
→
3O
2(g
)
is
fou
nd
to
be
9.0
0×
10 -3

at
m
ov
er
ace
rtai
n
int
erv
al
of
tim
e.
W
hat
is
the
rat
e
of
ap
pe
ara
nc
e
of
O2

dur
ing
thi
s
int
erv
al?
1.35 × 10
-2
atm/s A.
9.03 × 10
-3
atm/s B.
6.01 × 10
-3
atm/s C.
3.05 × 10
-5
atm/s D.
2.74 × 10
-5
atm/s E.

Th 2.
e
fol
lo
wi
ng
dat
a
we
re
obt
ain
ed
for
the
rea
cti
on
of
N
O
wit
h
O.2

Co
nc
ent
rati
on
s
are
in
mo
lec
ule
s/c
m 3

an
d
rat
es
are
in
mo
lec
ule
s/c
m 3

⋅ s.
[O ]
2 0 [NO] 0

1 × 10 18
1 × 10
18

1 × 10 18
2 × 10
18

1 × 10 18
3 × 10
18

2 × 10 18
1 × 10
18

3 × 10 18
1 × 10
18

W
hic
h
on
e
of
the
fol
lo
wi
ng
is
the
cor
rec
t
rat
e
la
w?
Rate = k[NO][O ]2 A.
Rate = k[NO][O ]2
2
B.
Rate = k[NO] [O ]
2
2 C.
Rate = k[NO] D.
2

Rate = k[NO] [O ]
2
2
2
E.

A 3.
fir
st-
or
der
rea
cti
on
is
45
%
co
mp
let
e
at
the
en
d
of
35
mi
nut
es.
W
hat
is
the
len
gth
of
the
hal
f-
lif
e
of
thi
s
rea
cti
on
?
41 min A.
39 min B.
30. min C.
27 min D.
60 min E.

A certain reaction has an activation energy of 54.0 kJ/mol. As the 4.

temperature
is incresaed from 25oC to a higher temerature, the rate has incresaed by a
factor
of 7.00. Calculate the higher teperature.
-270 oC A.
3.42 oC B.
273 oC C.
0.0 oC D.
50.6 oC E.

W 5.
hic
h
on
e
of
the
fol
lo
wi
ng
sta
te
me
nts
be
st
de
scr
ibe
s
the
co
ndi
tio
n(s
)
ne
ed
ed
for
a
su
cc
ess
ful
for
ma
tio
n
for
a
pr
od
uct
ac
cor
din
g
to
the
col
lisi
on
mo
del
?
The A.
collisio
n must
involve
a
sufficie
nt
amount
of
energy,
provide
d from
the
motion
of the
particle
s, to
overco
me the
activati
on
energy.
The relative orientation of the particles has little or no effect on the B.

formation of the product.

The relative orientation of the particles has an effect only if the C.

kinetic energy of the particles is below some minimum value.

The relative orientation of colliding particles must allow for formation D.

of the new bonds in the product.

The E.
energy
of
collidin
g
particle
s must
be
above a
certain
minimu
m value
and the
relative
orientat
ion of
the
particle
s must
allow
for
formati
on
of new
bonds
in the
product
.

Of what use is it to find a rate law for a reaction? 6.

We can use the rate law to directly determine coefficients in the balanced A.
equation.
From the rate law we can evaluate potential reaction mechanisms. B.
The rate law gives us a good indication of the thermodynamic stability of C.
the products.
The rate law can lead us to determine the equilibrium constant for the D.
reaction.
The rate law is derived from the fast equilibrium step. E.

Th 7.
e
cat
aly
ze
d
pat
hw
ay
in
a
rea
cti
on
me
ch
ani
sm
has
a
__
__
__
__
__
act
iva
tio
n
en
erg
y
an
d
thu
s
ca
use
sa
__
__
__
__
__
rea
cti
on
rat
e.
higher, lower A.
higher, higher B.
lower, higher C.
lower, steady D.
higher, steady E.

W 8.
hic
h
on
e
of
the
oll
ow
ing
sta
te
me
nts
is
T
R
U
E?
A A.
catalyst
is an
 effectiv
e mean
of
changin
g the
position
of an
equilibr
ium.
The concentration of the products equals that of reactants and is constant at B.
equilibrium.
An C.
endothe
rmic
reaction
shifts
toward
reactant
s when
heat is
added
to the
reaction
.
When two opposing processes are proceeding at identical rates, the system D.
is at equilibrium.
The E.
equilibr
ium
constan
t is
indepen
dent of
tempera
ture.

Ca 9.
lcu
lat
e
K p

for
H 2

O(
g)
+
O(2
g)

H 2

O( 2

g),
usi
ng
the
fol
lo
wi
ng
dat
a:

K = 2.3 × 10
p
6

4.4 A.
×
10 43

9.8 × 10 24
B.
5.4 × 10 -13
C.
1.2 × 10 -4
D.
2.6 × 10 -31
E.

Fo 10.
r
the
rea
cti
on
bel
ow
,
K p

=
1.1
6
at
80
0
°C
.
CaCO (s) 3 CaO(s) + CO (g)
2

If
a
20.
0-
gra
m
sa
mp
le
of
Ca
C
O 3

is
put
int
oa
10.
0-
lite
r
co
nta
ine
r
an
d
he
ate
d
to
80
0
°C,
wh
at
per
ce
nt
of
the
Ca
C
O 3

wil
l
rea
ct
to
rea
ch
eq
uili
bri
um
?
14.6% A.
65.9% B.
34.1% C.
100.0% D.
7.3% E.

Co 11.
nsi
der
ing
the
fol
lo
wi
ng
eq
uil
ibr
iu
m:
H (g) + I (s)
2 2 2HI(g);
ΔH = +68.0 kJ/mol

wi
ch
on
e
of
the
fol
lo
wi
ng
sta
te
me
nts
ab
out
the
eq
uil
ibr
iu
m
is
F
A
LS
E?
If the system is heated, the right side is favored. A.
This is a heterogeneous equilibrium. B.
If the pressure on the system is increased by changing the volume, the left C.
side is favored.
Adding more H (g) increases the equilibrium constant. D.
2

Removing HI as it forms forces the equilibrium to the right. E.

Th 12.
e
eq
uili
bri
um
sys
te
m
2A

2B
+
C
has
a
ver
y
sm
all
eq
uili
bri
um
co
nst
ant
:K
=
2.6
×
10 -

6
.
Ini
tial
ly
3
mo
les
of
A
are
pla
ce
d
in
a
1.5
-L
fla
sk.
De
ter
mi
ne
the
co
nc
ent
rati
on
of
C
at
eq
uili
bri
um
.
0.014 M A.
0.022 M B.
0.033 M C.
0.044 M D.
2.0 M E.

Nit 13.
ro
ge
n
ga
s
(N 2

)
rea
cts
wit
h
hy
dr
og
en
ga
s
(H 2

)
to
for
m
am
mo
nia
(N
H) 3

ga
s.
N2
+
3H
2

2N
H3
At
20
0
C
in
a
clo
se
d
co
nta
ine
r,
1.0
at
m
of
nit
ro
ge
n
ga
s is
mi
xe
d
wit
h
2.0
at
m
of
hy
dr
og
en
ga
s.
At
eq
uil
ibr
iu
m,
the
tot
al
pre
ssu
re
is
2.0
at
m.
Ca
lcu
lat
e
the
par
tial
pre
ssu
re
of
hy
dr
og
en
ga
s
at
eq
uil
ibr
iu
m.
2.0 atm A.
0.50 atm B.
1.5 atm C.
0.0 atm D.
1.0 atm E.

Gi 14.
ve
n
tha
tK
for
the
rea
cti
on
is
0.0
1
at
20
00
°C.
Pr
ed
ict
th
e
dir
ect
io
n
in
w
hic
h
th
e
sy
ste
m
wi
ll
m
ov
e
to
re
ac
h
eq
uil
ibr
iu
m
at
20
00
°C
if
0.4
m
ole
s
of
N2
,
0.1
m
ole
s
of
O2,
an
d
0.0
8
m
ole
s
of
N
O
ar
e
pl
ac
ed
in
a
1.0
-
lit
er
co
nt
ai
ne
r.
The system remains unchanged. A.
The concentration of NO will increase; the concentrations of N and O
2 2 B.
will decrease
The concentration of NO will decrease; the concentrations of N and O
2 2 C.
will remain unchanged.
More information is necessary. D.
The concentration of NO will decrease; the concentrations of N and O
2 2 E.
will increase.

Which 15.
one of the
following
statements
is True?
The pH of a strong acid is always lower than the pH of a weak acid. A.
The pH of a solution can never be negative. B.
For a conjugate acid-base pair, Ka = 1/Kb. C.
The percent dissociation of a base decreses when concentration of the D.
base increases under same conditions.
Hydroiodic acid is weaker than hydrofluoric acid E.

Ho 16.
w
ma
ny
mo
les
of
be
nz
oic
aci
d,
a
mo
no
pr
oti
c
aci
d
wit
h
K a

=
6.4
×
10 -

5
,
mu
st
be
dis
sol
ve
d
in
50
0.
m
L
of
H 2

O
to
pr
od
uc
ea
sol
uti
on
wit
h
pH
=
2.5
0?
1.6 × 10-1
A.
2.0 × 10-2
B.
8.0 × 10-2
C.
0.50 D.
4.0X10-2 E.

2.0 liters of HCl with pH = 3.22 is mixed with 1.0 liter of NaOH solution of pH 17.
= 10.78. The final 3.0 liters should have a pH of
2.74 A.
3.22 B.
3.70 C.
5.74 D.
7.00 E.

Which one of the following, when added to water, will not change the pH? 18.
NaHCO3 A.
K2SO4 B.
KCN C.
(NH4)2SO4 D.
K3PO4 E.

Which one of the factors listed below is most important in determining the 19.
strength of an oxyacid?
the size of the molecule A.
the ability of the molecule to change atomic orientation B.
the identity of the central atom in the molecule C.
the number of ionizable protons in the molecule D.
the number of oxygen atoms present in the molecule E.

A 0.240 M solution of the salt NaA has a pH of 8.40. Calculate the K value of
a 20.
the acid HA.
6.6 x 10-17
A.
1.1 x 10 B.
-5

3.8 x 10 C.
-4

2.6 x 10-11
D.
-9
4.0X10 E.