Semester Project (ME)

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Semester Project

SUBJECT: Maintenance Engineering

TOPIC: Waste Water Treatment

SUBMITTED TO: Ms. Rabia Sabir

SUBMITTED BY: Usman Ali

ROLL NO: UW-20-BSC-CHE-020

SEMESTER: 7th

Department of Chemical Engineering


Wah Engineering Collage
University of Wah
Table of Contents
Abstract:.....................................................................................................................................3

Introduction:...............................................................................................................................4

DOMESTIC WASTEWATER:...............................................................................................4

CHARACTERIZATION OF DOMESTIC WASTEWATER:................................................5

Chemical oxygen demand (COD):.....................................................................................5

Biochemical oxygen demand (BOD):.................................................................................5

WASTE WATER TREATMENT TECHNOLOGIES:...........................................................6

SUSPENDED GROWTH PROCESSES:...........................................................................6

ATTACHED GROWTH PROCESSES :............................................................................6

Wastewater strength:...............................................................................................................7

Water availability and use:..................................................................................................7

Wastewater production and treatment:...................................................................................8

Wastewater Treatment:...........................................................................................................9

ANAEROBIC METHODS:.................................................................................................10

UPFLOW ANAEROBIC SLUDGE TREATMENT PROCESS ( UASB).......................10

ANAEROBIC DIGESTION:............................................................................................10

Applications:.........................................................................................................................11

Stages:...................................................................................................................................13

Digestive:..........................................................................................................................14

Wastewater use/disposal:......................................................................................................14

Policies and institutional set-up for wastewater management:.............................................15

Policy aspects and national strategy.................................................................................15

Research/practice on different aspects of wastewater:.........................................................17

Status and need for the knowledge and skills on the safe use of wastewater:......................18

Conclusions:.............................................................................................................................19

References:...............................................................................................................................20
Abstract:
Pakistan, once a water-surplus country, is now a water deficit country. The water availability
has decreased from 1,299 m³ per capita in 1996-97 to 1,100 m³ per capita in 2006 and it is
projected to less than 700 m³ per capita by 2025. Therefore, search for other non-
conventional water resources for irrigation i.e. wastewater, has become important. In
Pakistan, domestic and industrial wastewater is either discharged directly to a sewer system, a
natural drain or water body, a nearby field or an internal septic tank. Mostly, this wastewater
is not treated and none of the cities have any biological treatment process except Islamabad
and Karachi, and even these cities treat only a small proportion (<8%) of their wastewater
before disposal. The wastewater used for irrigation is valued by farmers, mainly because of
its nutrient contents and reliability of supply and exert positive impacts on agriculture land
values, households, monthly income and employment due to reuse of wastewater despite of
the ill effects of wastewater irrigation on soil physical and chemical properties in addition to
contamination of human food chain and related health risks. Limited information is available
in this regard. There seems no national policy in effect on sustainable use of wastewater in
this country. Problems of wastewater disposal tend to stem from distortions due to economy-
wide policies, failure of targeted environmental policies and institutional failures. Thus laws
and regulations have been formulated about treatment and disposal of wastewater but their
implementation due to lack of resources and skilled manpower is the real issue. There is
hardly any well organized study which focused on risk assessment in a systematic way. Some
of the systematic work has been done by IWMI and Pak-EPA with financial aid from foreign
donors. Therefore, a well-coordinated program is necessary to create awareness among
different sections of the society including the general public, organizations, industrialists and
farmers.
Introduction:
With the rapid growth in urbanization and industrialization, environmental
contamination has worsened due to the incessant discharge of toxic substances into water
bodies, which has become a worldwide problem [1]. Furthermore, the demand for water in
domestic and industrial activities has significantly increased, which has accordingly increased
the amount of wastewater that is released into sewage systems. Thus, the reuse and treatment
of wastewater have become important concepts in the attempt to increase water availability
[2]. The wastewater industry is in a state of transition [3] due to the recent wastewater
effluent standards and emerging contaminants such as pharmaceutical and personal care
products, and dyes in water bodies [4]. At present, several physicochemical methods (e.g.,
advanced oxidation process, adsorption, and membrane technologies), biological methods
(e.g., activated sludge process, phytoremediation, bioremediation, and anammox), and hybrid
methods have been developed to treat polluted water [1]. However, a treatment method with
maximum efficiency in the removal of all kinds of contaminants is still far being realized.
Moreover, the United Nations’ sustainable developmentgoal This SI discusses state-of-the-art
wastewater and water treatment technologies that could be used to develop a sustainable
treatment method in the future. On this topic, studies have focused on measurements,
modeling, and experiments under laboratory and field conditions.

DOMESTIC WASTEWATER:

Domestic wastewater is the water that has been used by a community and which contains all
the materials added to the water during its use. It is thus composed of human body wastes
(faeces and urine) together with the water used for flushing toilets, and sullage, which is the
wastewater resulting from personal washing, laundry, food preparation and the cleaning of
kitchen utensils. Fresh wastewater is a grey turbid liquid that has an earthy but inoffensive
odour. It contains large floating and suspended solids (such as faeces, rags, plastic containers,
maize cobs), smaller suspended solids (such as partially disintegrated faeces, paper, vegetable
peel) and very small solids in colloidal (ie non-settleable) suspension, as well as pollutants in
true solution. It is objectionable in appearance and hazardous in content, mainly because of
the number of disease-causing (‘pathogenic’) organisms it contains (Chapter 2). In warm
climates wastewater can soon lose its content of dissolved oxygen and so become ‘stale’ or
‘septic’. Septic wastewater has an offensive odour, usually of hydrogen sulphide. The organic
fraction of both is composed principally of proteins, carbohydrates and fats. These
compounds, particularly the first two, form an excellent diet for bacteria, the microscopic
organisms whose voracious appetite for food is exploited by public health engineers in the
microbiological treatment of wastewater. In addition to these chemical compounds, faeces
and, to a lesser extent, urine contain many millions of intestinal bacteria and smaller numbers
of other organisms.

CHARACTERIZATION OF DOMESTIC WASTEWATER:

Wastewaters are usually treated by supplying them with oxygen so that bacteria can utilize
the wastewater contents as food. The general equation is: wastewater + oxygen ➝ bacteria
treated wastewater + new bacteria The nature of domestic wastewater is so complex that it
precludes its complete analysis. However, since it is comparatively easy to measure the
amount of oxygen used by the bacteria as they oxidize the wastewater, the concentration of
organic matter in the wastewater can easily be expressed in terms of the amount of oxygen
required for its oxidation. Thus, if, for example, half a gram of oxygen is consumed in the
oxidation of each litre of a particular wastewater, then we say that this wastewater has an
‘oxygen demand’ of 500 mg/l, by which we mean that the concentration of organic matter in
a litre of the wastewater is such that its oxidation requires 500 mg of oxygen. There are
basically three ways of expressing the oxygen demand of a waste: 1 Theoretical oxygen
demand (ThOD) – this is the theoretical amount of oxygen required to oxidize the organic
fraction of the wastewater completely to carbon dioxide and water.

Chemical oxygen demand (COD):


This is obtained by oxidizing the wastewater with a boiling acid dichromate solution. This
process oxidizes almost all organic compounds to carbon dioxide and water, the reaction
usually proceeding to more than 95 per cent completion. The advantage of COD
measurements is that they are obtained very quickly (within 3 hours), but they have the
disadvantages that they do not give any information on the proportion of the wastewater that
can be oxidized by bacteria, nor on the rate at which bio-oxidation occurs.

Biochemical oxygen demand (BOD):


This is the amount of oxygen required for the oxidation of a wastewater by bacteria. It is
therefore a measure of the concentration of organic matter in a waste that can be oxidized by
bacteria (‘bio-oxidized’ or ‘biodegraded’). BOD is usually expressed on a 5-day, 20°C basis –
that is as the amount of oxygen consumed during oxidation of the wastewater for 5 days at
20°C. The correct concept of BOD is fundamental to wastewater treatment, and a rigorous
treatment of BOD removal kinetics is given in Chapter 5. From the foregoing it is apparent
that: ThOD > COD > BODu > BOD5 There is no general relationship between these various
oxygen demands. However, for untreated domestic wastewater a large number of
measurements have indicated the following approximate ratios: BOD5/COD = 0.5
BODu/BOD5 = 1.5 The presence of industrial or agricultural wastewaters alters these ratios
considerably

WASTE WATER TREATMENT TECHNOLOGIES:

The principal biological processes used for wastewater treatment are divided into two main
categories:
1) Suspended growth processes
2) Attached growth (or biofilm) processes.
SUSPENDED GROWTH PROCESSES:
In suspended growth processes the microorganisms responsible for treatment are maintained
in liquid suspension by appropriate mixing methods. Many suspended growth processes used
in municipal and industrial wastewater treatment are operated with a positive dissolved
oxygen concentration (aerobic), but applications exist where suspended growth anaerobic
processes are used, such as for high organic concentration industrial wastewater and organic
sludges. The most common suspended growth process used for municipal wastewater
treatment is the Activated Sludge Process.
ATTACHED GROWTH PROCESSES :
In attached growth processes, the microorganisms responsible for the conversion of organic
material or nutrients are attached on inert packing material. The organic material and
nutrients are removed from the water flowing past the attached growth also known as the
biofilm. Packing material in attached growth processes include rock, gravel, sand, slag,
redwood and range of plastics and other synthetic materials.
Attached growth processes are operated as aerobic or anaerobic processes. The packing can
be submerged completely in liquid or not submerged, with air or gas space above the biofilm
liquid layer. The most common aerobic attached growth process used is the Trickling filter.
Wastewater strength:

The higher the concentration of organic matter in a wastewater, the ‘stronger’ it is said to be.
Wastewater strength is often judged by its BOD5 or COD (Table 1.2). The strength of the
wastewater from a community is governed to a very large degree by its water consumption.
Thus, in the US where water consumption is high (350–400 l/person day) the wastewater is
weak (BOD5 = 200–250 mg/l), whereas in tropical countries the wastewater is strong (BOD5
= 300–700 mg/l) as the water consumption is typically much lower (40–100 l/person day).
The other factor determining the strength of domestic wastewater is the BOD (= amount of
organic waste) produced per person per day. This varies from country to country and the
differences are largely due to differences in the quantity and quality of sullage rather than of
body wastes, although variations in diet are important.

Water availability and use:


Pakistan has become a water deficit country due to depleting ground and surface water
resources, loss in surface shortage, prevailing droughts and shift of fresh water from
agriculture to more pressing domestic as well as industrial uses (Ensink et al., 2004).
Therefore, search for other non-conventional water resources for irrigation i.e. wastewater
has become important. The recent statistical data shows that the Indus System and its
tributaries provide an average 142 MAF of water annually. Out of which nearly 96 MAF is
utilized for irrigation, 36 MAF flows to sea and about 10 MAF is consumed by the system
losses which include seepage, evaporation and spill during floods. Presently, 40.5 MAF
groundwater is being pumped annually and about 36% of the groundwater is classified as
highly saline and 60-80% as saline (Anonymous, 2011). Overall water availability has
decreased from 1,299 cubic meters (m³) per capita in 1996-97 to 1,100 m³ per capita in 2006.
It is projected that water availability will be less than 700 m³ per capita by 2025 against the
international standard of 1500 m³ per capita (Pak-SCEA 2006).

The renewable water resources are estimated at 248 billion m3/year. Surface runoff is
estimated at 243 billion m3/year, while groundwater resources are about 55 billion m 3/year,
most being the base flow of the river system. Of which 96.8% is withdrawn for agricultural
purposes, 1.6% for domestic use and another 1.6% for industrial use. Pakistan would need
more additional water in future to meet irrigation and other requirements of the people. This
was not possible unless new storage dams were built.
Wastewater production and treatment:

Sr. No. Source Volume


m3/yr Percent %
1 Industry 395 6
2 Commercial 266 5
3 Urban residential 1,628 25
4 Rural residential 3,059 48
5 Agriculture 1,036 16
Total 6,414 100
Table 1: Sector wise estimated wastewater production in Pakistan

Urban Total % of % of Receiving water Body


City population wastewater Total Treated
(1998 produced
census)
Lahore 5,143,495 287 12.5 0.01 River Ravi, irrigation canals,
vegetable farms
Faisalabad 2,008,861 129 5.6 25.6 River Ravi, River Chenab and
vegetable farms
Gujranwala 1,132,509 71 3.1 - SCARP drains, vegetable
farms
Rawalpindi 1,409768 40 1.8 - River Soan and vegetable
farms
Sheikhupura 870,110 15 0.7 - SCARP drains
Multan 1,197,384 66 2.9 - River Chenab, irrigation canals
and farms
Sialkot 713,552 19 0.8 - River Ravi, irrigation canals
and farms
Karachi 9,339,023 604 26.3 15.9 Arabian Sea
Hyderabad 1,166,894 51 2.2 34.0 River Indus, irrigation canals
and SCARP drains
Peshawar 982,816 52 2.3 36.2 Kabul River
Other 19,475,588 967 41.8 0.7 -
Total Urban 43,440,000 2,301 100.0 7.7 -

Table 2: Wastewater Produced Annually by Cities (WB-CWRAS Paper 3, 2005)

Wastewater Treatment:

In Pakistan, domestic waste containing household effluent and human waste is either
discharged directly to a sewer system, a natural drain or water body, a nearby field or
an internal septic tank. Normally, municipal wastewater is not subjected to any
treatment and none of the cities have any biological treatment process except
Islamabad and Karachi, and even these cities treat only a small proportion of their
wastewater before disposal. Assuming that all the installed treatment plants are
working at their full installed capacity, it is estimated that about 8% of urban
wastewater is probably treated in municipal treatment plants (Table 2). Other estimates
suggest that the figure is not greater than 1 per cent. The treated wastewater generally
flows into open drains, and there are no provisions for reuse of the treated wastewater
for agriculture or other municipal uses. Table above (2) shows ten large urban districts
of the country, which produce more than 60% of the total urban wastewater including
household, industrial and commercial wastewater (WB-CWRAS Paper 3, 2005). A
negligible proportion i.e. 8% of wastewater in Pakistan is treated through
sedimentation ponds to a primary level only but most of the treatment plants are not
functional therefore the figure can be estimated around 1 per cent. There is no
prevailing concept of treatment at secondary and tertiary level in this country.
Although treatment facilities exist in about a dozen major cities, in some cases these
have been built without the completion of associated sewerage networks, and the
plants are often either under-loaded or abandoned (Pak-SCEA, 2006).
ANAEROBIC METHODS:

UPFLOW ANAEROBIC SLUDGE TREATMENT PROCESS ( UASB)


Upflow Anaerobic Sludge Blanket (UASB) technology, normally referred to as UASB
reactor, is a form of anaerobic digester that is used in the treatment of wastewater. The UASB
reactor is a methanogenic (methane-producing) digester that evolved from the anaerobic
clarigester. A similar but variant technology to UASB is the expanded granular sludge bed
(EGSB) digester. UASB uses an anaerobic process whilst forming a blanket of granular
sludge which suspends in the tank. Wastewater flows upwards through the blanket and is
processed (degraded) by the anaerobic microorganisms. The upward flow combined with the
settling action of gravity suspends the blanket with the aid of flocculants. The blanket begins
to reach maturity at around 3 months. Small sludge granules begin to form whose surface
area is covered in aggregations of bacteria. In the absence of any support matrix, the flow
conditions create a selective environment in which only those microorganisms, capable of
attaching to each other, survive and proliferate.
The blanketing of the sludge enables a dual solid and hydraulic (liquid) retention time in the
digesters. Solids requiring a high degree of digestion can remain in the reactors for periods up
to 90 days. Sugars dissolved in the liquid waste stream can be converted into gas quickly in
the liquid phase which can exit the system in less than a day.
ANAEROBIC DIGESTION:
Anaerobic digestion is a series of processes in which microorganisms break down
biodegradable material in the absence of oxygen. It is widely used to treat wastewater sludges
and organic wastes because it provides volume and mass reduction of the input material. As
part of an integrated waste management system, anaerobic digestion reduces the emission of
landfill gas into the atmosphere. Anaerobic digestion is a renewable energy source because
the process produces a methane and carbon dioxide rich biogas suitable for energy production
helping replace fossil fuels. Also, the nutrient-rich solids left after digestion can be used as
fertiliser.
The digestion process begins with bacterial hydrolysis of the input materials in order to break
down insoluble organic polymers such as carbohydrates and make them available for other
bacteria. Acidogenic bacteria then convert the sugars and amino acids into carbon dioxide,
hydrogen, ammonia, and organic acids. Acetogenic bacteria then convert these resulting
organic acids into acetic acid, along with additional ammonia, hydrogen, and carbon dioxide.
The technical expertise required to maintain anaerobic digesters coupled with high capital
costs and lower process efficiencies have so far limited the level of its industrial application
as a waste treatment technology.
Careful control of the digestion temperature, pH, and loading rates is crucial to obtaining
efficient breakdown of the material, and disturbances to a digest can lead to process failure.
Ensuring that the quality of input materials to the digesters is maintained and that the process
effectively monitored is essential for ensuring that a digester's performance is reliable.

Applications:

Anaerobic digestion is particularly suited to wet organic material and is commonly used for
effluent and sewage treatment. Anaerobic digestion is a simple process that can greatly
reduce the amount of organic matter which might otherwise be destined to be landfilled or
burnt in an incinerator.
Almost any organic material can be processed with anaerobic digestion. This includes
biodegradable waste materials such as waste paper, grass clippings, leftover food, sewage and
animal waste. The exception to this is woody wastes that are largely unaffected by digestion
as anaerobes are unable to degrade lignin. Anaerobic digesters can also be fed with specially
grown energy crops such as silage for dedicated biogas production. In Germany and
continental Europe these facilities are referred to as biogas plants. A co-digestion or
cofermentation plant is typically an agricultural anaerobic digester that accepts two or more
input materials for simultaneous digestion. In developing countries simple home and farm-
based anaerobic digestion systems offer the potential for cheap, low-cost energy for cooking
and lighting. Anaerobic digestion facilities have been recognised by the United Nations
Development Programme as one of the most useful decentralised sources of energy supply.
Pressure from environmentally-related legislation on solid waste disposal methods in
developed countries has increased the application of anaerobic digestion as a process for
reducing waste volumes and generating useful by-products. Anaerobic digestion may either
be used to process the source separated fraction of municipal waste, or alternatively
combined with mechanical sorting systems, to process residual mixed municipal waste. These
facilities are called mechanical biological treatment plants Utilising anaerobic digestion
technologies can help to reduce the emission of greenhouse gases in a number of key ways:
 Replacement of fossil fuels
 Reducing methane emission from landfills
 Displacing industrially-produced chemical fertilisers
 Reducing vehicle movements
 Reducing electrical grid transportation losses
Methane and power produced in anaerobic digestion facilities can be utilised to replace
energy derived from fossil fuels, and hence reduce emissions of greenhouse gases .This is due
to the fact that the carbon in biodegradable material is part of a carbon cycle. The carbon
released into the atmosphere from the combustion of biogas has been removed by plants in
order for them to grow in the recent past. This can have occurred within the last decade, but
more typically within the last growing season. If the plants are re-grown, taking the carbon
out of the atmosphere once more, the system will be carbon neutral.This contrasts to carbon
in fossil fuels that has been sequestered in the earth for many millions of years, the
combustion of which increases the overall levels of carbon dioxide in the atmosphere.
Digestate liquor can be used as a fertiliser supplying vital nutrients to soils. The solid, fibrous
component of digestate can be used as a soil conditioner. The liquor can be used as a
substitute for chemical fertilisers which require large amounts of energy to produce. The use
of manufactured fertilisers is therefore more carbon intensive than the use of anaerobic
digestate fertiliser. This solid digestate can be used to boost the organic content of soils.
The process
There are a number of bacteria that are involved in the process of anaerobic digestion
including acetic acid-forming bacteria (acetogens) and methane-forming bacteria
(methanogens). These bacteria feed upon the initial feedstock, which undergoes a number of
different processes converting it to intermediate molecules including sugars, hydrogen &
acetic acid before finally being converted to biogas.
Different species of bacteria are able to survive at different temperature ranges. Ones living
optimally at temperatures between 35-40°C are called mesophiles or mesophilic bacteria.
Some of the bacteria can survive at the hotter and more hostile conditions of 55-60°C, these
are called thermophiles or thermophilic bacteria. Methanogens come from the primitive
group of archaea. This family includes species that can grow in the hostile conditions of
hydrothermal vents. These species are more resistant to heat and can therefore operate at
thermophilic temperatures, a property that is unique to bacterial families.
As with aerobic systems the bacteria in anaerobic systems the growing and reproducing
microorganisms within them require a source of elemental oxygen to survive. In an anaerobic
system there is an absence of gaseous oxygen. In an anaerobic digester, gaseous oxygen is
prevented from entering the system through physical containment in sealed tanks. Anaerobes
access oxygen from sources other than the surrounding air. The oxygen source for these
microorganisms can be the organic material itself or alternatively may be supplied by
inorganic oxides from within the input material. When the oxygen source in an anaerobic
system is derived from the organic material itself, then the 'intermediate' end products are
primarily alcohols, aldehydes, and organic acids plus carbon dioxide. In the presence of
specialised methanogens, the intermediates are converted to the 'final' end products of
methane, carbon dioxide with trace levels of hydrogen sulfide. In an anaerobic system the
majority of the chemical energy contained within the starting material is released by
methanogenic bacteria as methane.
Populations of anaerobic bacteria typically take a significant period of time to establish
themselves to be fully effective. It is therefore common practice to introduce anaerobic
microorganisms from materials with existing populations. This process is called 'seeding' the
digesters and typically takes place with the addition of sewage sludge or cattle slurry.

Stages:

The key process stages of anaerobic digestion


There are four key biological and chemical stages of anaerobic digestion:
1. Hydrolysis
2. Acidogenesis
3. Acetogenesis
4. Methanogenesis
In most cases biomass is made up of large organic polymers. In order for the bacteria in
anaerobic digesters to access the energy potential of the material, these chains must first be
broken down into their smaller constituent parts. These constituent parts or monomers such as
sugars are readily available by other bacteria. The process of breaking these chains and
dissolving the smaller molecules into solution is called hydrolysis. Therefore hydrolysis of
these high molecular weight polymeric components is the necessary first step in anaerobic
digestion. Through hydrolysis the complex organic molecules are broken down into simple
sugars, amino acids, and fatty acids.
Acetate and hydrogen produced in the first stages can be used directly by methanogens. Other
molecules such as volatile fatty acids (VFA’s) with a chain length that is greater than acetate
must first be catabolised into compounds that can be directly utilized by methanogens. The
biological process of acidogenesis is where there is further breakdown of the remaining
components by acidogenic (fermentative) bacteria. Here VFAs are created along with
ammonia, carbon dioxide and hydrogen sulfide as well as other by-products. The process of
acidogenesis is similar to the way that milk sours.

Digestive:
Digestive is the solid remnants of the original input material to the digesters that the microbes
cannot use. It also consists of the mineralised remains of the dead bacteria from within the
digesters. Digestive can come in three forms; fibrous, liquor or a sludge-based combination
of the two fractions. In two-stage systems the different forms of digestive come from
different digestion tanks. In single stage digestion systems the two fractions will be combined
and if desired separated by further processing.
As per a review of literature, out of 388 cities of Pakistan, only 8 have wastewater
treatment facilities, that too up to primary level. According to the Pakistan Water
Situational Analysis, there are three wastewater treatment plants in Islamabad, of which
only one is functional. Karachi has two trickling filters, where effluents generally receive
screening and sedimentation. Lahore has some screening and grit removal systems, but
they are hardly functional. In Faisalabad, there is a wastewater treatment plant, in which
wastewater receives primary treatment. In rural areas, wastewater treatment is
nonexistent, leading to pollution of surface and groundwater.

Wastewater use/disposal:

Urban centres are the main cause of water pollution in this country. Typically, storm water
drains and nullahs collect and carry untreated sewage which then flows into streams,
rivers and irrigation canals. Although there are some sewerage collection systems,
typically discharging to the nearest water body, collection levels are estimated to be no
greater than 50% nationally (less than 20% in many rural areas). As per a careful
estimation, the wastewater generated in Pakistan is directly used for irrigating an area of
about 32,500 ha (Ensink et al., 2004).

Commonly grown crops include vegetables, fodder, cotton and to some extent rice.
Vegetables receive wastewater irrigation almost twice a week, fodder once a week and
cotton after 3 weeks. The crops grown in suburban areas while using wastewater include
vegetables, and fodder as these fetch high prices in nearby urban markets. The quantity of
N, P and K applied from sewage -

The wastewater used for irrigation is valued by farmers, mainly because of its nutrient
contents and reliability of supply. Reuse of wastewater has many positive impacts on
socio-economic aspects of the users. The data of Anwar et al. (2010) show that there is a
major increase in price of agriculture land due to availability of wastewater and the
average land value was Pak. Rs. 0.3 million per acre before the reuse of wastewater while
after the availability of wastewater as alternative irrigation source it has increased up to
Rs. 0.4- 0.6 million per acre. Similarly, monthly income of 87% households has increased
and 77% respondents replied that employment opportunities have been generated.

Land treatment of partially treated wastewater has been used as a low-cost method of
wastewater disposal for a very long time. In Haroonabad (Pakistan), land irrigated with
wastewater has a higher value than the canal irrigated land, and the land rents of
wastewater irrigated farms were on average three and a half times higher than those of
canal water irrigated lands (Hassan et al., 2001). Considering economics, impacts of
wastewater irrigation can be grouped under (1) potential yield losses, (2) loss of soil
productive capacity, (3) depreciation in market value of land, and (4) cost of additional
nutrients and soil reclamation measures. After initial study by Ensink et al. (2004), several
researchers of the country have focused on this area which was neglected in recent past.
Further working on this aspect may only encourage growers about less use of chemical
fertilizers unless they are equally educated about ill effects of wastewater irrigation on soil
chemical and physical properties in addition to contamination of human food chain and
related health risks.

Policies and institutional set-up for wastewater management:


Policy aspects and national strategy
There seems no national policy, in effect, on sustainable use of wastewater in this country.
Moreover, economic incentives have not been introduced for industries to acquire
environmentfriendly technology. Problems of wastewater disposal tend to stem from
distortions due to economy-wide policies, failure of targeted environmental policies, and
institutional failures. Uneconomic water pricing exacerbates the problem in urban areas,
where a flat rate is charged or water is provided free of charge, a policy that both
encourages the wasteful use of water and eliminates incentives for suppliers of water
services to upgrade their water supply, treatment, and disposal facilities. Laws and
regulations have been formulated about treatment and disposal of wastewater in this
country but their implementation due to lack of resources and skilled manpower is the real
issue. The result is that, while an appropriate and necessary administrative capacity exists
on paper, its effectiveness is seriously curtailed in practice due to these shortcomings. For
example, the NEQS for industry and municipal discharges were originally formulated in
1993, but even voluntary compliance and reporting have yet to be instituted because of a
lack of practical monitoring ability in the EPAs; the Environmental Impact Assessment
(EIA) system is mandatory but seldom followed in the public sector; and environmental
laboratories have been established in all provinces but function with skeletal staff and
budgets inadequate even for their routine equipment and chemical needs. Similarly,
environmental tribunals have been created but their capacity to deal with reported cases is
extremely restricted, as minimal personnel have been deputed in only two provinces to
collectively oversee the entire country (WB-CWRAS Paper 3, 2005).

The biggest challenge faced by policymakers at present, is how best to minimize the
negative effects of wastewater use, while at the same time obtaining the maximum benefits
from this resource. While most of the impacts of wastewater use, both negative as well as
positive, are generally known, a comprehensive valuation of the benefits and costs of these
impacts has not as yet been attempted.
Prime importance should be given to the treatment of industrial effluent before it is
allowed to pour in Drain. The environmental laws and their implementation need be dealt
more seriously and responsibly. The practice of usage of untreated wastewater for
irrigation of fields should be immediately stopped as it is harmful for the consumers of
those vegetables and crops. Pumping of groundwater near wastewater drains for drinking
purposes must be avoided. In some cases, sewage is auctioned by the municipalities to the
highest bidder, often a group of rich farmers, who then rent out their fields to poor
landless farmers. Under these conditions, the use of sewage is considered a win- a -win
situation by both the authorities those are responsible for sewage disposal and the farmers
who get its reliable supply with high nutrient content (Ensink et al., 2004). In relation to
wastewater irrigation, economic analyses should also have to conduct with precise
perspectives keeping in mind

Research/practice on different aspects of wastewater:

Up-till now, there is no centre for research on wastewater that deals exclusively with this
issue. Instead, various departments of educational and research bodies randomly do some
research work on this aspect. Most of the studies are published in local journals due to poor
quality of the project work. There is dire need to fortify such scattered efforts so that a
collective future action plan could be devised well in time. For example, up- till now, there
is no short term or long term study available that explains ill effects of wastewater, if any,
on soil physical properties, in this country. In Pakistan where safe effluent disposal
facilities and its treatment are non-existent or limited, raw sewage is used to irrigate
fodders, ornamental and food crops including vegetables (Murtaza et al., 2010).

In developing countries including Pakistan, little work is being conducted on this very
important research area. Limited information is available on the physical treatment of
effluents and soils, bioremediation of effluents and soils, advanced chemical oxidation
treatments, thermal remediation strategies, waste landfills and amendments to decrease
bioavailability. The restriction in research seems to be related solely to the high cost of
implementation on such research. Under these circumstances, at least crop restriction can
be used to protect the health of consumers when water of sufficient quality is not available
for unrestricted irrigation. For example, water of poorer quality can be used to irrigate non-
vegetable crops as cotton, lawns, ornamental or crops that are cooked well before
consumption. There is also lack of information regarding both the short and long term
effect of wastewater on soil physical properties which needs to be addressed. Moreover, if
polluted water treatment at the source is not economically feasible at this time then there
should be screening of crop genotypes which are hyper-accumulators of heavy metals in
their eatable portions, especially vegetables. Laws should be framed, to encourage farmers
to grow only those genotypes which accumulate relatively very low amounts of metals in
their eatable portions, especially around major cities of Pakistan. While genotypic/cultivar
differences in plant uptake of metals are well documented but absolutely no work has been
conducted in this regard in Pakistan. There is hardly any well organized study conducted in
this country which focused on risk assessment in a systematic way. Moreover, there are no
studies which concern heavy metals bioavailability employing animal trials. Some of the
systematic work has been done by IWMI and Pakistan Environmental Protection Agency
with financial aid from foreign donors.

Status and need for the knowledge and skills on the safe use of wastewater:

While a comprehensive national policy and institutional framework for environmental


management is in place, there are significant weaknesses in the current administrative and
implementation capacity, typical of a developing country setting like Pakistan. Principal
among these are a ubiquitous shortage of trained manpower and insufficient budgetary
allocations, a lack of clear definition of roles, work plans and targets, specific capacity gaps
on the safe use of wastewater in irrigation by individuals or institutions dealing with
wastewater management, and ineffective coordination and communication between federal,
provincial and local administrative entities. Most urgently needed is the availability of
skilled human resources for implementing national or international guidelines for the safe
use of wastewater in agriculture or other purposes. There are no regulations in existence
that guide what to be grown with wastewater. Farmers should be made aware of and
encouraged to grow resistant and non food plants (i.e. fiber crops, lawns, parks and
ornamental plants) with wastewater irrigation. A clear and practical strategy needs to be
defined to implement existing policies. There is dire need to minimize weaknesses in
coordination among different sections of the society including the general public,
organizations, industrialists and farmers. Moreover, there is also need to prioritize the
knowledge and skills and develop capacities within various institutions to deal with
different aspects of safe use of wastewater in agriculture.
Conclusions:
Pakistan’s water-resources have been diminishing at an alarming rate, as can be concluded
from the above-stated facts. It is now a water deficit country. The water availability has
decreased from 1,299 m³ per capita in 1996-97 to 1,100 m³ per capita in 2006 and that of
projected less than 700 m³ per capita by 2025. Therefore, search for other non-conventional
water resources for irrigation i.e. wastewater has become important. In Pakistan, it is
estimated that around 2,000 million gallons daily and 962,335 million gallons annually
wastewater is being produced and discharged to surface water bodies. This domestic and
industrial wastewater is either discharged directly to a sewer system, a natural drain or
water body, a nearby field or an internal septic tank. This wastewater is normally not
treated and none of the cities have any biological treatment process except Islamabad and
Karachi, and even these cities treat only a small proportion (<8%) of their wastewater
before disposal. The wastewater used for irrigation is valued by farmers, mainly because of
its nutrient contents and reliability of supply and exert positive impacts on agriculture land
values, households, monthly income and employment due to reuse of wastewater despite of
the ill effects of wastewater irrigation on soil physical and chemical properties in addition
to contamination of human food chain and related health risks. Limited information is
available in this regard and needs capacity development. There seems no national policy in
effect on sustainable use of wastewater in this country. While a comprehensive national
policy and institutional framework for environmental management is in place, there are
significant weaknesses in the current administrative and implementation capacity. A clear
and practical strategy needs to be defined to implement these policies. Moreover, economic
incentives have not been introduced for industries to acquire environment-friendly
technology. Problems of wastewater disposal tend to stem from distortions due to
economy-wide policies, failure of targeted environmental policies, and institutional
failures. Thus laws and regulations have been formulated about treatment and disposal of
wastewater but their implementation due to lack of resources and skilled manpower is the
real issue. There is hardly any well organized study conducted which focused on risk
assessment in a systematic way. Some of the systematic work has been done by IWMI and
Pak-EPA with financial aid from foreign donors. Therefore a wellcoordinated program is
necessary to create awareness among different sections of the society including the general
public, organizations, industrialists and farmers and to remediate polluted wastewater by
using modern techniques.

References:
 Anonymous. 2011. Government of Pakistan, Ministry of Economic Affairs and
Statistics, Statistics Division. "Overall Water Availability". Pakistan Statistical Year
Book 2011.
 http://www.pbs.gov.pk/sites/default/files/other/yearbook2011/AGRICULTURE/1-
15.pdf. Anwar, H.N., F. Nosheen, S. Hussain and W. Nawaz. 2010. Socio-
economics consequences of reusing wastewater in agriculture in Faisalabad. Pak. J.
Life Soc. Sci. 8(2): 102-105.
 Asano, T. and G.S. Pettygrove. 1987. Using reclaimed municipal wastewater for
irrigation. Calif.
 Ashfaq, M., P. Amerasinghe and I.A. Baig. 2010. Economic valuation of benefits
and costs of wastewater irrigation in Pakistan. Draft report: International Water
Management Institute. Lin, R.; Li, Y.; Yong, T.; Cao, W.; Wu, J.; Shen, Y.
Synergistic effects of oxidation, coagulation and adsorption in the integrated
fenton-based process for wastewater treatment: A review. J. Environ. Manag. 2022,
306, 114460.
 Sakr, M.; Mohamed, M.M.; Maraqa, M.A.; Hamouda, M.A.; Aly Hassan, A.; Ali, J.;
Jung, J. A critical review of the recent developments in micro–nano bubbles
applications for domestic and industrial wastewater treatment. Alex. Eng. J. 2021, in
press.
 https://www.pseau.org/outils/ouvrages/
earthscan_ltd_domestic_wastewater_treatment_in_developing_countries_2003.pdf

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