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Identification of Ions 2
Identification of Ions 2
Identification of Ions 2
Mg 2H01 My 42 H2
19
ESIN
Gases collection
Tests for anions &
Jar not measuring
cations
gas
Cylinder
delivery upward
lighterthan air
Deliverytube H2 1 1
20 288
Bung stopper
Downward delivery
Denser than Air
CO2 12 16 16 44728
Mr ofAir 28.8
86
This chapter is for paper 6 & must be learnt by heart
Gas
a Jar
Delivery
e tube
in it in i i i i i
87
water solublegases
Acidicgases Alkalinegas For Mix s fgases
Insoluble
Nits to
f
Act502,50
Ammoniagas
A euta ch
C. Collection Of Gases Over Water:
NO2 g COz
The insoluble neutral gases can be collected over water because they do
not dissolve in water.
Examples are oxygen, nitrogen, hydrogen,
memorize
methane…etc.
Note:
1) Do not try to collect acidic gases or
04 alkaline gases over water because they
ie
88
E. Tests for aqueous cations
Cation Effect of aqueous sodium Effect of aqueous ammonia
hydroxide (ammonia solution)
Ammonium Ammonia produced on warming
(NH4+)
Copper Light blue ppt., insoluble in Light blue ppt., soluble in excess.
(Cu2+) excess Giving a dark blue soluble
Iron II (Fe2+) Green ppt., insoluble in excess Green ppt., insoluble in excess
Iron III Red – brown ppt., insoluble in Red – brown ppt., insoluble in
(Fe3+) excess excess
Chromium III Green ppt., soluble in excess Grey-green ppt., insoluble in
(Cr3+) excess
Zinc (Zn2+) White ppt., soluble in excess, White ppt., soluble in excess,
giving a colourless solution giving a colourless solution
Aluminium White ppt. soluble in excess White ppt., insoluble in excess
(Al3+) giving a colourless solution
Calcium White ppt., insoluble in excess No ppt. or very slight white ppt.
(Ca2+)
NH3 gas
Al foil
NaOH
NH4+ NO3
N.B.: ammonia gas is liberated upon the reaction of ammonium salts
with any base (CaO) or alkali (NaOH)
89
G. Flame tests for metal ions
Metal ion Flame colour
lithium (Li )
+
red
sodium (Na+) yellow
potassium (K+) lilac
Calcium ( Ca2+) Orange - red
Barium ( Ba2+) Light green
copper(II) (Cu2+) blue-green
N.B.
• Tests performed by a Bunsen burner (continuous flame). Tests of aqueous
cations
• Tests performed by a lighted splint (match). Flammable substances (hydrogen,
oxygen, ethanol & organic compounds)
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Tets For gases
Name Conclusion
Test Result Observations
Carbondioxide
CO Add limewater Colourless
Turns milky
Ammonia NHz Add damp red litmus paper Turns blue
Chlorine Cla Add damp litmus Paper Bleach or removes colour
Hydrogen H2 Lighted splint POPS POP Sound
oxygen 02 glowing splint Relight
Add Acidified AqueousPotassium
syffuy.de
SO purple Colourless
Manganate V
Reducing agent
Oxidizing agent Chill Decolorized
Cr 979CroHl You
Felt 9 7 Felot Feldt k
Disseless
FEE Insoluble
in excess
Ej oH
iitate
whitesolid
2 Al a
Dissolve
turns
White ppt Precipitate NaOH
NaOH NaOH Naoh NAOH NAOH
x x x
Cation Tests Foranions 6 1
Anion
24
Ba 50 Baso
G
Agt CI Agc
Agt Br AgBr
Agt I AgI
91