Obafemi Awolowo UMWersity, Helte, Nigeria S BSe, (Chemistry) Degree Uae nation yy Harmattan Semester Examination, 2054/2019 Session tation and Analytical Chemistry $1 vYPE 4 Time Allowed CUM S11: Instr Instructions: Answer ALL Questions Jeo The following are primary standards except A. NayCOs NaOH « n of potassium hydrog g of the dried a 3% What is the concentration (ppm) prepared by dissolving 120 m solution? (KHP = 204.22 g/mol)) A. 0.587 ppm B, 480 ppm © 2.35 ppm or wn experiment to determine Ni?" concentration in an industria mL of DMG was added to 500.00 ml. of the water » dimethylglyoximate (CyllisNaNiOu, Molecular Weight drying yielded 5.89 g. What is the concentration (in mol/L. sample? ‘A, 0,040 mole/L and 2.28 g/L respectively B, 0,020 mole/L and 1.19 g/L. reper 20.040 mole/L. and 2.38 g/L respectively, 1D. 0,040 mole/L. and 1.19 g/l. respect L47~ Mohr’s indicator works best when the pH is mourn dalamres CL (7 OF wi, Hos phe, 0) at vickelT; 7. 3 Be 7 ca 9 D. 4 ware oe te 2 ved a is ie In the determination of chloride content of cooking sall, winchof the listed indicators involves back-titration technique? Wy mh A. Phenolphtalein B. Mohr C. Litmus 2, Volnay 4 vars eel on A - REN Ss oda Coniorry SenF) Butea ‘A 10 mL solution of NaCl was treated with excess ASNOs to prodyce white weciptat us! weighing 0.4368g, What is the molarity of CI’ in the unknown’? 1s oy oh x re o A. 3.048x 104M BF 3.048x 10'M_—C. 3,048x 102M D. 3.048%107M aring 50 mL of 0.125 M “To Which of the following represent the correct process of preps 35.5 ymiol) 7 NaCl solution; which of the following is correct? (Na= 23 g/mol, Cl= 1 A. Dissolve 365.63 mg NaCl salt in 50 mL distilled water a ih we B, Dissolve 0:3656 g NaCl salt in 50 mL distilled water . f x C. Dissolve 3.6563 mg NaCl salt in distilled water to make 50 mL “fu aa eA S.No on{DPissolve 365.63 mg NaCl salt in distilled water to make 50 ml ‘in the experiment for d&termination of CI’ in table salt using Volhard method, + nee Saquations describes the dark red colouration observed at the end pin? Ag ech ARCS) | Rttgt—aigk Hg Koren) - gtscw—> MICH Age +SCN" > AgSCN(s) c . 2 peta'scn > (FeSCNP* rere ngs" ons is 2Ag + CrOg" > AgCrOd(s) 9 Cc? ran * is aT . Aiatiod ot Y man The commonly used active drying agent in desiccators is; a y g ag ‘a0 Agel or AgO B. NaCl or NaO vegas One A. 2: CaCl; or CaO D. Fe203 or FeO ee What is the molar concentration of a potassium hydrogen phthalate (KHP) solution prepared by dissolving 2.55 g of pure and dried salt in distilled water to make 250 mL. solution? (KHP = 204.22 g/mole) A. 0.06 mol/L B. 0.055 mol/L C.0.045 moVL —_-B- 0.05 mol/L. Given the volume of AgNO; solution for the titration of a blank to be 0.50 cm’, calculate the concentration of chloride ion in a table salt solution, if 50.00 cm? of the sample was titrated to the end point with 11.30 cm’ of 0.125 M AgNO; solution. A. 0.028 M 0.027 C.0.030 M D.0.029M 32% Mohr’s indicator is AL 2% CrOr——sgr 5% KsC1Oy CC. S%AGSCN _D._AgCl ser% 7 Which of the following is NOT a factor to be considered when comparing chloride determination by Mohr’s method and Volhard’s techniques? A. Speed B, Precision C. Economy De Stability ‘0 measure the nickel content in steel, the alloy is dissolved in 12 M HCl and neutralized presence of citrate ion, which maintains iron in solution. The slightly basic and dimethlglyoxime (DMG) was added to precipitate the red > _DMG-Ni complex quantitatively. ‘The product was filtered, washed and dried at 110 °C. If 1.1634 g of steel gives 0.1795 gof precipitate, what is the percentage of Ni in the steel? (Formula mass (g/mol): Ni = 58.69; DMG = 116.2; Ni(DMG)2= 288.91} A) 90.132% (B)94.269% {P.134% —(D) 6.200% The preparation of Hexaminecobalt(III) Chloride, [Co(NHs)«]Cly, is represented with the in the solution is warmed, equation: 2CoClz-6H20(s) + 2NHsCl(s) + 10NH3(aq) + H,0,(aq) BSS 2{Co(NH)AICh(s) + 1442001) [Co = 59 g/mol; N = 14 g/mol; Cl=35.5 g/mol; O = 16 g/mol; H=1 g/mol.) « € 2 move} a0 ssl a| » £3} oy 4 F Jn an experiment for the preparation of Hexamineco Z ith the 8.81 g of CoC], 6H,O in hot solution of NH4C 7 Siar ‘ed water and heated to dissolve), 22.50 ML. of ammonia solution, 1.06 in and 1.00 g charcoal, Assuming all the CoCly6H,0 a LO. that will react and the mass of [Co(NH5),JCh produ A, 3.96 g and 19.80 g respectively B. 1.98 g and 19.80 gre 71.98 g ancl 9.90 g respectively D. 19.8 g and 3.96 g respectiv. a ic determination of Ni(II) as dimethylglyoximate, the ‘in the experiment for gravimetric determinatio ) yigly . dimethyiglyoxime is added to an acid solution of Ni (II) and the base generated by the hydrolysis of urea in-sim neutralize the base causing the precipitation of the complex. Which of the following represent the chemical equation for the hydrolysis of urea CO(NH2)2 + 3H,0 — CO, + 2NHa" + 20H" - \ COND: + | -2HO > COz + 2NH, ee C. CO(NE2)2 + HO — CO, + 2NH3 is Gg AS D.cOWHy» + 41hO — FCO; + 2NHS + 209" gf ceo. 04 JH Which of the following equations describes the red colouration observed at the end point of titration in the determination of CI’ using Mohr method? ~ Ag+ cl” — — AgCK(s) B. 2Ag+CrOx” > — AgoCrOx(s) Sd os G, Ag + SCN — — AgSCN(s) D. Fe?+SCN > [FeSCN}* “7 Which of the following is not a major characteristic of a primary standard? 14g+ A. High purity ~ B. Low hygroscopicity~ 2 uF High reactivity D. High equivalent weight~ 19 Which of the following is an example of a typical organic precipitants commonly used in the gravimetric determination of nickel? A. Tetrachloromethane 49 Dimethylglyoxime lobes UU C. Butanol D. Trimethylbutane wor rouse experiment for the preparation of Hexaminecobalt(III) chloride, 7.27 g of ~ (Cl I;)]Cls (dry product) was obtained with 10g of. CoClz:6HO(s) as starting material; zie the percentage yield of [Co(NHs)s]Cl. es ge 64.68% B. 73.43% C. 68.64% D. 65.00% oe Alll of the following concentration units are parts per million (ppm) except ” A. , pom |B. MLL / & mmm? DA1CLL mS 4 3 mee Ma hod ' ‘ ~<'ton® “fra|L = Mac populke KY, 39 cf orl