Spotlight_(XI)_(2023-24) Day-4_Test_Chemistry

Spotlight
(XI)

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MM : 60 SPOTLIGHT_DAY-4_TEST_JEE (Advanced) Time : 1 Hrs.

Answers
Chemistry

1. (A, B, C, D)
2. (D)
3. (B)
4. (A, B, D)
5. (D)
6. (A, C)
7. (70.00)
8. (01.50)
9. (64.00)
10. (04.00)
11. (02.00)
12. (15.00)
13. (B)
14. (A)
15. (A)
16. (B)
17. (11.00)
18. (05.00)
19. (48.00)

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Spotlight_(XI)_(2023-24) Day-4_Test_Chemistry

Chemistry Solution

1. Answer (A, B, C, D)
(A) Resonance effect bond length
F F F Br
(B) C=C C=C
H Br H F
cis-1-bromo-1,2 Z-1-bromo-1, 2
difluoro ethene difluoro ethene

geometrical isomers
COOH most acidic (eq. R.S.)
(C) CH2
COOH

(D)

2. Answer (D)

3. Answer (B)
–I F –I Cl
–I F C–CH2COOH –I Cl C–CH2COOH
–I F –I Cl

–I Br –I I
–I Br C–CH2COOH –I I C–CH2COOH
–I Br –I I
4. Answer (A, B, D)

(1)

(3) – I effect
5. Answer (D)
The correct order of heat of hydrogenation is (i) > (ii) > (iv) > (iii)
1
HOH 
stability of alkene

6. Answer (A, C)

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Spotlight_(XI)_(2023-24) Day-4_Test_Chemistry

Carbocation on is less stable than because of the dispersion of (+) charge through
resonance.
7. Answer (70.00)
8. Answer (01.50)
Solution For Q. No. 7 & 8
% of N in the givne compound
2  0.5  0.1 14
=  100
2
= 70% (y = 70)
 PV = nRT

608
 v  0.05  0.08  300
760
v = 1.5 L
9. Answer (64.00)
10. Answer (04.00)
Solution For Q. No. 9 & 10
Total number of stereo isomers (geometrical + optical)
= 2n
= 26 = 64

11. Answer (02.00)

12. Answer (15.00)
Solution For Q. No. 11 & 12

13. Answer (B)

14. Answer (A)
Solution For Q. No. 13 & 14
II
N is most basic

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Spotlight_(XI)_(2023-24) Day-4_Test_Chemistry

I
N is least basic as it's lone pair participates in resonance.
15. Answer (A)
Ethane-1,2-diol has gauch form as the stable one.
16. Answer (B)
Rotation around C – C bond in cyclopropane is restricted.
17. Answer (11.00)
All are more e– dense.
18. Answer (05.00)
Naphthalene, Pyridine, Aniline, thiophene and Pyrrole are aromatic species.
19. Answer (48.00)
80 0.282
% Br    100
188 0.250
= 48

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