Class:XII (MA) DPP. NO.

-9

Q.1 Which of the following is not a characteristic of chemi-sorption?

(1)Adsorption is irreversible
(2)  H is of the order of 400 kJ
(3)Adsorption is specific
(4)Adsorption increases with increase of surface area

Q.2 According to Freundlich's isotherm :

x m
(1) = kP1/n (2) = kP1/n
m x
x k
(3) xm = kP1/n (4)  1/ n
m P

Q.3 Which one of the following is not a correct statement?

(1) Physical adsorption is reversible in nature.
(2) Physical adsorption involves van der Waal's forces.
(3) Rate of physical adsorption increases with increase of pressure on the adsorbate.
(4) High activation energy is involved.

Q.4 Which of the following statements is more correct?

(1) Acatalyst only accelerates the rate of a chemical reaction
(2) A catalyst can retard the rate of a chemical reaction
(3) A catalyst can control the speed of a reaction
(4) Acatalyst alters the speed of a reaction

Q.5 Which plot is the adsorption isobar for chemi-sorption?

x x
(1) (2)
m m
T T

x x
(3) (4)
m m
T T

Q.6 Rate of physi-sorption increases with :

(1) Decrease in temperature (2) Increase in temperature
(3) Decrease in pressure (4) Decrease in surface area
Q.7 Which of the following is incorrect statement
(1) Sorption is combination of adsorption and absorption
(2) Desorption is the process of removing the adsorbed molecules
(3)Absorption is surface phenomenon
(4) Dyeing of cotton fibres by azo dyes is the example of sorption

Q.8 Which of the following is true in respect of absorption?

(1)  G < 0;  S > 0; H < 0
(2)  G < 0;  S < 0; H < 0
(3)  G > 0;  S > 0; H < 0
(4)  G < 0;  S < 0; H > 0

Q.9 Although, nitrogen does not adsorb on a surface at room temperature, it adsorbs on the surface at 83 K.
Which one of the following statements is correct?
(1)At 83 K, there is formation of monomolecular layer.
(2)At 83 K, there is formation of multimolecular layer.
(3)At 83 K, nitrogen molecules are held by chemical layer.
(4) At 83 K, nitrogen is adsorbed as atoms.

Q.10 According to the adsorption theory of catalysis, the speed of reaction increases because :
(1)Adsorption produces heat which increases the speed of the reaction.
(2)Adsorption lowers the activation energy of the reaction.
(3) The concentration of reactant molecules at the active centers of the catalyst becomes high due to
adsorption.
(4) In the process of adsorption, the activation energy of the molecules becomes large.
Class:XII (MA) DPP. NO.-10

Q.1 Which of the following process does not occur at the interface of phases ?
(1) crystallisation (2) heterrogenous catalysis
(3) homogeneeous catalysis (4) corrosion

Q.2 At the equilibrium position in the process of adsorption ______

(1) H > 0 (2) H = TS (3) H > TS (4) H < TS

Q.3 Which of the following interface cannot be obtained ?

(1) liquid-liquid (2) solid-liquid (3) liquid-gas (4) gas-gas

Q.4 The term 'sorption' stands for __________

(1) absorption (2) adsorption
(3) both absorption and adsorption (4) desorption

Q.5 On the basis of data given below predict which of the following gases shows least adsorption on a
definite amount of charcoal ?
Gas CO 2 SO2 CH4 H2
Critical temp./K 304 630 190 33
(1) CO2 (2) SO2 (3) CH4 (4) H2

Q.6 In which of the following reactions heterogenous catalysis is involved ?

(a) 2SO2 (g) + O2 (g) NO
 (
g)
 2SO3(g)

(b) 2SO2(g) Pt

(g)
 2SO3(g)

(c) N2(g) + 3H2(g) Fe

 (s )
 2NH3(g)
()
(d) CH3COOCH3(l) + H2O(l) HCl
  CH3COOH(aq) + CH3OH(aq)
(1) (b), (c) (2) (b), (c), (d) (3) (a), (b), (c) (4) (d)
Q.7 At high concentration of soap in water, soap behaves as _________
(1) molecular colloid (2) associated colloid
(3) macromolecular colloid (4) lyophilic colloid

Q.8 Which of the following will show Tyndall effect ?

(1)Aqueous solution of soap below critical micelle concentration
(2)Aqueous solution of soap above critical micelle concentration
(3)Aqueous solution of sodium chloride
(4)Aqueous solution of sugar.

Q.9 Method by which lyophobic sol can protected.

(1) By addition of oppositely charged sol.
(2) By addition of an electrolyte
(3) By addition of lyophilic sol.
(4) By boiling

Q.10 Freshly prepared precipitate sometimes gets converted to colloidal solution by ______
(1) coagulation (2) electrolysis
(3) diffusion (4) peptisation
Class:XII (MA) DPP. NO.-11

Q.1 Extent of physisorption of a gas increases with _______

(1) increase in temperature
(2) decrease in temperature
(3) decrease in surface area of adsorbent
(4) decrease in strength of van der Walls forces.

Q.2 Extent of adsorption of adsorbate from solution phase increases with ________
(1) increase in amount of adsorbate in solution
(2) decrease in surface area of adsorbent
(3) increase in temperature of solution
(4) decease in amount of adsorbate in solution

Q.3 Which one of the following is not applicable to the phenomenon of adsorption ?
(1) H > 0 (2) G < 0 (3) S < 0 (4) H < 0

Q.4 Which of the following is not a fabourable condition for physical adsorption ?
(1) high pressure
(2) negative H
(3) higher critical temperature of adsorbate
(4) high temperature

Q.5 Physical adsorption of a gaseous species may change to chemical adsorption with ________
(1) decrease in temperature
(2) increase in temperature
(3) increase in surface area of adsorbent
(4) decrease in surface area of adsorbent

Q.6 In physisorption adsorbent does not show specificity for any particular gas because _______
(1) involved van der Waals forces are universal
(2) gases involved behave like ideal gases
(3) enthalpy of adsorption is low
(4) it is a reversible process.
Q.7 Which of the following is an example of absorption ?
(1) Water on silica gel
(2) Water on calcium chloride
(3) Hydrogen on finely divided nickel
(4) Oxygen on metal surface

Q.8 Which of the following electrolytes will have maximum coagulating value forAgI/Ag+ sol ?
(1) Na2S (2) Na3PO4
(3) Na2SO4 (4) NaCl

Q.9 A colloidal system having soild substance as a dispersed phase and a liquid as a dispersion medium is
classified as _________
(1) solid sol (2) gel
(3) emulsion (4) sol

Q.10 The values of colligative properties of colloidal solution are of small order in comparison to those sown
by true solutions of same concentration because of colloidal particles________
(1) exhibit enormous surface area
(2) remain suspended in the dispersion medium
(3) form lyophilic colloids
(4) are comparatively less in number
Class:XII (MA) DPP. NO.-12

Q.1 Arrange the following diagrams in correct sequence of steps involved in the mechanism of catalysis, in
accordance with modern adsorption theory.

(1) a  b  c  d  e (2) a  c  b  d e

(3) a  c  b  e  d (4) a  b  c  e  d

Q.2 Which of the following process is not responsible for the presence of electric charge on the sol
particles ?
(1) Electron capture by sol particles.
(2)Adsorption of ionic species from solution
(3) Formation of Helmholtz electrical double layer.
(4)Absorption of ionic species from solution.

Q.3 Which of the following curves is in accordance with Freundlich adsorption isotherm ?

(1) (2)

(3) (4)

Q.4 Which of the following process is responsible for the formation of delta at a place where rivers meet the
sea ?
(1) Emulsification (2) Colloid formation (3) Coagulation (4) Peptisation

Q.5 Tyndall effect in colloidal solution is due to :

(1) Reflection of light (2) Refraction of light
(3) Scattering of light by dispersed phase (4) Scattering of light by dispersion medium
Q.6 What will be nature of charge on colloidsal particle. When FeCl3 is add to excess of hot H2O.
(1) Positive (2) Negative
(3) Neutral (4) Some time positive & some time negative

Q.7 When dilute aqueous solution ofAgNO3(excess) is add to KI solution. positively charged sol particles
of AgI are formed due to adsorption of ion.
(1) K+ (2) Ag+ (3) I– (4) NO3–

Q.8 Which of the following method is not employed for the purification of colloids ?
(1) Electrodialysis (2) Dialysis (3) Ultracentrifugation (4) peptisation

Q.9 Which of the following is with highest and lowest flocculation value amongAl+3, Na+, Mg+2
(1) Al+3, Na+ (2) Na+, Al+3
(3) Bu+2 , Al+3 (4) They have same flocculation value.

Q.10 Emulsifier is an agent which

(1)Accelerates the dispersion (2) Stabilises the emulsion
(3) Homogenies the emulsion (4) disociate emulsions