‫ﺷﺒﻴﻪ ﺳﺎﺯﻱ ﺟﺬﺏ ﺳﻄﺤﻲ ﮔﺎﺯﻫﺎﻱ ﻧﺠﻴﺐ ﺩﺭﺣﺎﻟﺖ ﺧﺎﻟﺺ ﻭ ﻣﺨﻠﻮﻁ ﺩﻭﺗﺎﻳﻲ‬

‫ﺑﺮﺭﻭﻱ ﻧﺎﻧﻮﻟﻮﻟﻪ ﻛﺮﺑﻨﻲ‬

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‫ﺫﺑﻴﺢ ﺍﻟﻪ ﻣﻬﺪﻭﻱ ﻓﺮ‪، 1‬ﺯﻫﺮﺍ ﺗﺎﺑﻨﺪﻩ‬
‫‪z_mahdavifar@scu.ac.ir‬‬ ‫‪1‬ﺍﺳﺘﺎﺩﻳﺎﺭ ﺭﺷﺘﻪ ﺷﻴﻤﻲ ﻓﻴﺰﻳﻚ‪،‬ﺩﺍﻧﺸﻜﺪﻩ ﺷﻴﻤﻲ‪،‬ﺩﺍﻧﺸﮕﺎﻩ ﺷﻬﻴﺪ ﭼﻤﺮﺍﻥ ﺍﻫﻮﺍﺯ‬

‫‪z-tabandeh@mscstu.scu.ac.ir‬‬
‫‪2T‬‬ ‫‪2T‬‬ ‫‪2‬ﺩﺍﻧﺸﺠﻮﻱ ﻛﺎﺭﺷﻨﺎﺳﻲ ﺍﺭﺷﺪ ﺷﻴﻤﻲ ﻓﻴﺰﻳﻚ‪،‬ﺩﺍﻧﺸﮕﺎﻩ ﺷﻬﻴﺪ ﭼﻤﺮﺍﻥ ﺍﻫﻮﺍﺯ‬

‫ﭼﻜﻴﺪﻩ‬
‫ﺑﺎ ﺭﺷﺪ ﺭﺍﻳﺎﻧﻪ ﻫﺎ ﺗﺤﻮﻟﻲ ﭼﺸﻤﮕﻴﺮ ﺩﺭ ﺗﻮﺍﻥ ﻣﺤﺎﺳﺒﺎﺗﻲ ﺁﻧﻬﺎ ﺍﻳﺠﺎﺩ ﺷﺪﻩ ﻭ ﺗﻤﺎﻣﻲ ﻋﻠﻮﻡ ﺑﻪ ﻃﻮﺭ ﮔﺴﺘﺮﺩﻩ ﺍﺯ ﺍﻳﻦ ﺍﻧﻘﻼﺏ ﻣﺤﺎﺳﺒﺎﺗﻲ ﺳﻮﺩ‬
‫ﺟﺴﺘﻪﺍﻧﺪ‪ .‬ﺷﺒﻴﻪ ﺳﺎﺯﻱ ﻫﺎﻱ ﺭﺍﻳﺎﻧﻪﺍﻱ ﺑﻪ ﺩﻭ ﺷﺎﺧﻪ ﺩﻳﻨﺎﻣﻴﻚ ﻣﻮﻟﻜﻮﻟﻲ ﻭ ﻣﻮﻧﺖ ﻛﺎﺭﻟﻮ ﺗﻘﺴﻴﻢ ﻣﻲﺷﻮﻧﺪ ﻭ ﺑﻮﺳﻴﻠﻪ ﺁﻧﻬﺎ ﻣﻲﺗﻮﺍﻥ ﭘﺪﻳﺪﻩ‪-‬‬
‫ﻫﺎﻱ ﺷﻴﻤﻴﺎﻳﻲ ﻛﻪ ﺗﺎﻛﻨﻮﻥ ﻣﺸﺎﻫﺪﻩ ﻧﺸﺪﻩﺍﻧﺪ ﻭ ﻳﺎ ﺍﻳﺠﺎﺩ ﺷﺮﺍﻳﻂ ﺁﺯﻣﺎﻳﺸﮕﺎﻫﻲ ﺑﺮﺍﻱ ﺑﺮﺭﺳﻲ ﺁﻧﻬﺎ ﻣﺸﻜﻞ ﺍﺳﺖ ﺭﺍ ﺑﺎ ﺩﻗـﺖ ﻗﺎﺑـﻞ ﻗﺒـﻮﻟﻲ‬
‫ﻣﻄﺎﻟﻌﻪ ﻛﺮﺩ‪.‬ﭘﺘﺎﻧﺴﻴﻞ ﺑﻴﻦ ﻣﻠﻜﻮﻟﻲ ﺭﺍ ﻣﻲﺗﻮﺍﻥ ﺑﻪ ﻛﻤﻚ ﭘﺘﺎﻧﺴﻴﻞ ﺍﺗﻢ ﺑﻪ ﺍﺗﻢ ﺍﺯ ﻳﻚ ﻣﻠﻜﻮﻝ ﺑﻪ ﻣﻠﻜﻮﻟﻲ ﺩﻳﮕﺮ ﺑﺮﺍﻱ ﻫﺮ ﺩﻭ ﺷﺒﻴﻪ ﺳﺎﺯﻱ‬
‫ﺩﻳﻨﺎﻣﻴﻚ ﻣﻮﻟﻜﻮﻟﻲ ﻭ ﻣﻮﻧﺖ ﻛﺎﺭﻟﻮ ﻣﺤﺎﺳﺒﻪ ﻧﻤﻮﺩ‪ .‬ﺩﺭ ﺍﻳﻦ ﻣﻄﺎﻟﻌﻪ ﺍﺯ ﺭﻭﺵ ﺷﺒﻴﻪ ﺳﺎﺯﻱ ﻣﻮﻧﺖ ﻛﺎﺭﻟﻮ ﺑﻪ ﻣﻨﻈﻮﺭ ﺑﻴﺎﻥ ﺟﺬﺏ ﺳﻄﺤﻲ ﺩﻭ‬
‫ﮔﺎﺯ ﻧﺠﻴﺐ ‪ He‬ﻭ ‪ Ar‬ﺑﻪ ﺻﻮﺭﺕ ﺧﺎﻟﺺ ﻭ ﻣﺨﻠﻮﻁ ﺑﺮ ﺭﻭﻱ ﻧﺎﻧﻮﻟﻮﻟﻪ ﺗﻚ ﺩﻳﻮﺍﺭﻩ ﻛﺮﺑﻨﻲ )‪10‬ﻭ‪ (10‬ﺍﺳﺘﻔﺎﺩﻩ ﺷﺪﻩ ﺍﺳﺖ‪.‬ﭘﺘﺎﻧﺴـﻴﻞ ﻣـﻮﺭﺩ‬
‫ﺍﺳﺘﻔﺎﺩﻩ ﺩﺭ ﺍﻳﻦ ﺷﺒﻴﻪ ﺳﺎﺯﻱ ﭘﺘﺎﻧﺴﻴﻞ ﻟﻨﺎﺭﺩ‪-‬ﺟﻮﻧﺰ ﻣﻲﺑﺎﺷﺪ‪ .‬ﺩﺭ ﻓﺮﺍﻳﻨﺪ ﺟﺬﺏ ﻣﺨﻠﻮﻁ ﺩﻭ ﮔﺎﺯ‪ ،‬ﺑﺮ ﺣﺴﺐ ﻧﻮﻉ ﺑﺮﻫﻢ ﻛﻨﺶﻫـﺎ ﻳﻜـﻲ ﺍﺯ‬
‫ﮔﺎﺯﻫﺎ ﺑﻴﺸﺘﺮ ﺟﺬﺏ ﻣﻲﺷﻮﺩ‪ .‬ﻓﺎﻛﺘﻮﺭ ﺍﻧﺘﺨﺎﺏ ﭘﺬﻳﺮﻱ ﻭﺍﺑﺴﺘﻪ ﺑﻪ ﻧﻮﻉ ﺑﺮﻫﻢ ﻛﻨﺶ ﺟﺎﺫﺏ ﻭ ﺟﺬﺏ ﺷﻮﻧﺪﻩ ﻭ ﺷﺮﺍﻳﻂ ﺍﻧﺠﺎﻡ ﻓﺮﺍﻳﻨـﺪ ﻣﺎﻧﻨـﺪ‬
‫ﺩﻣﺎ ﻭ ﻓﺸﺎﺭ ﺍﺳﺖ‪ .‬ﻧﺘﺎﻳﺞ ﺑﻪ ﺩﺳﺖ ﺁﻣﺪﻩ ﺩﺭ ﺩﻣﺎﻫﺎ ﻭ ﻓﺸﺎﺭﻫﺎﻱ ﻣﺨﺘﻠﻒ ﻧﺸﺎﻥ ﻣﻲﺩﻫـﺪ ﻫﻤـﻪ ﺍﻳﺰﻭﺗـﺮﻡ ﻫـﺎﻱ ﺟـﺬﺑﻲ ﺍﺯ ﻣـﺪﻝ ﻻﻧﮕﻤـﻮﺭ‬
‫ﭘﻴﺮﻭﻱ ﻣﻲﻛﻨﻨﺪ ﻭﺍﻳﻦ ﺩﻭ ﮔﺎﺯ ﺭﻓﺘﺎﺭ ﺟﺬﺑﻲ ﻣﺸﺎﺑﻬﻲ ﺩﺍﺭﻧﺪ‪ .‬ﻧﺘﺎﻳﺞ ﻧﺸـﺎﻥ ﻣـﻲﺩﻫـﺪ ﮔﺮﻣـﺎﻱ ﺟـﺬﺏ ﺁﺭﮔـﻮﻥ ﺑﻴﺸـﺘﺮ ﺍﺯ ﻫﻠـﻴﻢ ﺍﺳـﺖ ﻭ‬
‫ﺟﺪﺍﺳﺎﺯﻱ ﺍﻳﻦ ﺩﻭ ﮔﺎﺯ ﺩﺭ ﻓﺸﺎﺭ ﻫﺎﻱ ﭘﺎﻳﻴﻦ ﺑﻬﺘﺮ ﺍﻧﺠﺎﻡ ﻣﻲﺷﻮﺩ‪.‬‬

‫ﻭﺍژﻩ ﻫﺎﻱ ﻛﻠﻴﺪﻱ‪ :‬ﺷﺒﻴﻪ ﺳﺎﺯﻱ ﻣﻮﻧﺖ ﻛﺎﺭﻟﻮ‪ ،‬ﭘﺘﺎﻧﺴﻴﻞ ﻟﻨﺎﺭﺩ‪-‬ﺟﻮﻧﺰ‪ ،‬ﺍﻳﺰﻭﺗﺮﻡ ﺟﺬﺑﻲ‪ ،‬ﻧﺎﻧﻮ ﻟﻮﻟﻪ ﻛﺮﺑﻨﻲ‪ ،‬ﻓﺎﻛﺘﻮﺭ ﺟﺪﺍﺳﺎﺯﻱ‬

‫ﻣﻘﺪﻣﻪ‬
‫ﺑﺎ ﺭﺷﺪ ﺭﺍﻳﺎﻧﻪﻫﺎ ﺗﺤﻮﻟﻲ ﭼﺸﻤﮕﻴﺮ ﺩﺭ ﺗﻮﺍﻥ ﻣﺤﺎﺳﺒﺎﺗﻲ ﺁﻧﻬﺎ ﺍﻳﺠﺎﺩ ﺷﺪﻩ ﻭ ﺗﻤﺎﻣﻲ ﻋﻠﻮﻡ ﺑﻪ ﻃﻮﺭ ﮔﺴﺘﺮﺩﻩ ﺍﺯ ﺍﻳﻦ ﺍﻧﻘﻼﺏ ﻣﺤﺎﺳﺒﺎﺗﻲ ﺳـﻮﺩ‬
‫ﺟﺴﺘﻪﺍﻧﺪ‪ .‬ﺷﻴﻤﻲ ﻣﺤﺎﺳﺒﺎﺗﻲ ﻧﻴﺰ ﺑﺎ ﺑﻬﺮﻩ ﮔﻴﺮﻱ ﺍﺯ ﺗﻮﺍﻥ ﺑﺎﻻﻱ ﺳﺎﻣﺎﻧﻪﻫﺎﻱ ﺭﺍﻳﺎﻧـﻪ ﺍﻱ ﺣـﻞ ﺑﺴـﻴﺎﺭﻱ ﺍﺯ ﻣﺴـﺎﺋﻞ ﺭﺍ ﺩﺭ ﺩﻧﻴـﺎﻱ ﺍﻣـﺮﻭﺯ‬
‫ﺍﻣﻜﺎﻥﭘﺬﻳﺮ ﺳﺎﺧﺘﻪ ﻭ ﺩﺭﻛﺎﻫﺶ ﻫﺰﻳﻨﻪﻫﺎﻱ ﻣﺮﺑﻮﻁ ﺑﻪ ﺁﺯﻣﺎﻳﺶﻫﺎﻱ ﺗﺠﺮﺑﻲ ﻧﻘﺶ ﻣﺆﺛﺮﻱ ﺍﻳﻔﺎ ﻣﻲﻛﻨﺪ‪ .‬ﺍﺯ ﻣﻴﺎﻥ ﺭﻭﺵﻫـﺎﻱ ﻣﺤﺎﺳـﺒﺎﺗﻲ‬
‫ﻣﻲﺗﻮﺍﻥ ﺑﻪ ﺭﻭﺵﻫﺎﻱ ﺷﺒﻴﻪ ﺳﺎﺯﻱ ﻣﻮﻟﻜﻮﻟﻲ ﺍﺷﺎﺭﻩ ﻛﺮﺩ‪ .‬ﺷﺒﻴﻪ ﺳﺎﺯﻱ ﻫﺎﻱ ﺭﺍﻳﺎﻧﻪﺍﻱ ﺑﻪ ﺩﻭ ﺷﺎﺧﻪ ﺩﻳﻨﺎﻣﻴﻚ ﻣﻮﻟﻜﻮﻟﻲ ﻭ ﻣﻮﻧـﺖ ﻛـﺎﺭﻟﻮ‬
‫ﺗﻘﺴﻴﻢ ﻣﻲﺷﻮﻧﺪ ﻭ ﺑﻮﺳﻴﻠﻪ ﺁﻧﻬﺎ ﻣﻲﺗﻮﺍﻥ ﭘﺪﻳﺪﻩﻫﺎﻱ ﺷﻴﻤﻴﺎﻳﻲ ﻛﻪ ﺗﺎﻛﻨﻮﻥ ﻣﺸﺎﻫﺪﻩ ﻧﺸﺪﻩﺍﻧﺪ ﻭ ﻳـﺎ ﺍﻳﺠـﺎﺩ ﺷـﺮﺍﻳﻂ ﺁﺯﻣﺎﻳﺸـﮕﺎﻫﻲ ﺑـﺮﺍﻱ‬
‫ﺑﺮﺭﺳﻲ ﺁﻧﻬﺎ ﻣﺸﻜﻞ ﺍﺳﺖ ﺭﺍ ﺑﺎ ﺩﻗﺖ ﻗﺎﺑﻞ ﻗﺒﻮﻟﻲ ﻣﻄﺎﻟﻌﻪ ﻛﺮﺩ‪.‬‬

‫ﻧﺎﻧﻮ ﻟﻮﻟﻪ ﻫﺎﻱ ﻛﺮﺑﻨﻲ ﺑﻪ ﺩﻟﻴﻞ ﺳﺎﺧﺘﺎﺭ ﺫﺍﺗﻲ ﻭ ﻭﻳﮋﮔﻲ ﻫﺎﻱ ﻣﻨﺤﺼﺮﺑﻔﺮﺩﺷﺎﻥ ﺑﺴﻴﺎﺭ ﻣﻮﺭﺩ ﺗﻮﺟﻪ ﻣﺤﻘﻘﻴﻦ ﻭ ﺗﺤﻘﻴﻘـﺎﺕ ﻋﻠﻤـﻲ ﺑـﻮﺩﻩ ﻭ‬
‫ﺑﺮﺍﻱ ﻛﺎﺭﺑﺮﺩﻫﺎﻱ ﺷﻴﻤﻴﺎﻳﻲ ﻭ ﺑﻴﻮﻟﻮژﻳﻜﻲ ﺑﺴﻴﺎﺭ ﮔﺴﺘﺮﺵ ﻳﺎﻓﺘﻪﺍﻧﺪ‪ .‬ﺍﺯ ﺟﻤﻠﻪ ﺧﺼﻮﺻﻴﺎﺕ ﺑﺎﺭﺯ ﻧﺎﻧﻮﻟﻮﻟﻪ ﻫﺎﻱ ﻛﺮﺑﻨﻲ ﻣﻲ ﺗﻮﺍﻥ ﺑﻪ ﺧﻮﺍﺹ‬

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‫ﻧﻮﺭﻱ‪ ،‬ﺷﻴﻤﻴﺎﻳﻲ‪ ،‬ﻣﻘﺎﻭﻣﺖ ﻣﻜﺎﻧﻴﻜﻲ ﺑﺎﻻ ﻭ ﻫﺪﺍﻳﺖ ﮔﺮﻣﺎﻳﻲ ﺍﺷﺎﺭﻩ ﻛﺮﺩ‪ .‬ﻛﺮﺑﻦ ﻳﻚ ﻋﻨﺼﺮ ﺍﺯ ﮔﺮﻭﻩ ﭼﻬﺎﺭﻡ ﺍﺳﺖ ﺑﻨﺎﺑﺮﺍﻳﻦ ﺗﻮﺍﻧﺎﻳﻲ ﺗﺸﻜﻴﻞ‬
‫ﭘﻴﻮﻧﺪﻫﺎﻱ ﻛﻮﻭﺍﻻﻧﺴﻲ ﺩﻭ ﻣﺮﻛﺰ ﺩﻭ ﺍﻟﻜﺘﺮﻭﻥ ﺭﺍ ﺩﺍﺭﺩ ﻭ ﺍﻧﺪﺍﺯﻩ ﻛﻮﭼﻚ ﺍﺗﻢﻫﺎﻱ ﻛﺮﺑﻦ ﻣﻮﺟﺐ ﻫﻤﭙﻮﺷﺎﻧﻲ ﻣﻮﺛﺮ ﻣﻲﺑﺎﺷﺪ‪ .‬ﻧﺎﻧﻮﻟﻮﻟﻪ‬

‫ﻫﺎﻱ ﻛﺮﺑﻨﻲ ﺗﻚ ﺩﻳﻮﺍﺭﻩ ﻧﺴﺒﺖ ﺑﻪ ﻧﺎﻧﻮﻟﻮﻟﻪﻫﺎﻱ ﻛﺮﺑﻨﻲ ﭼﻨﺪ ﺩﻳﻮﺍﺭﻩ ﺩﺭ ﺯﻣﻴﻨﻪ ﺗﺤﻘﻴﻘﺎﺕ ﺗﺌﻮﺭﻱ ﻭ ﺁﺯﻣﺎﻳﺸﮕﺎﻫﻲ ﺑﻴﺸﺘﺮ ﻣﻮﺭﺩ ﺗﻮﺟﻪ ﻗﺮﺍﺭ‬
‫ﮔﺮﻓﺘﻪﺍﻧﺪ‪ .‬ﺍﻣﺮﻭﺯﻩ ﺍﺯ ﻣﻮﺍﺩ ﻣﺨﺘﻠﻔﻲ ﺑﺮﺍﻱ ﺟﺬﺏ ﮔﺎﺯﻫﺎ ﻭ ﻣﺎﻳﻌﺎﺕ ﺍﺳﺘﻔﺎﺩﻩ ﻣﻲﺷﻮﺩ‪ .‬ﺍﺯ ﭘﺮﻛﺎﺭﺑﺮﺩﺗﺮﻳﻦ ﺁﻧﻬﺎ ﻣﻲﺗﻮﺍﻥ ﺑﻪ ﭼﺎﺭﭼﻮﺏﻫﺎﻱ ﺁﻟـﻲ‬
‫ﻓﻠﺰﻱ)‪ ،(MOFs‬ﻧﺎﻧﻮﻟﻮﻟﻪ ﻫﺎ)‪ (NTs‬ﻭ ﺯﺋﻮﻟﻴﺖ ﻫﺎ ﺍﺷﺎﺭﻩ ﻛﺮﺩ‪.‬‬

‫ﻳﻜﻲ ﺍﺯ ﻛﺎﺭﺑﺮﺩﻫﺎﻱ ﻣﻬﻢ ﻧﺎﻧﻮﻟﻮﻟﻪ ﻫﺎ ﺟﺬﺏ ﮔﺎﺯ ﻫﻴﺪﺭﻭژﻥ ﻣﻲ ﺑﺎﺷﺪ ﻛﻪ ﺩﻧﻴﺎﻱ ﺷﮕﺮﻓﻲ ﺭﺍ ﺑﻪ ﺭﻭﻱ ﺩﺍﻧﺸﻤﻨﺪﺍﻥ ﺑﺮﺍﻱ ﺫﺧﻴﺮﻩ ﺳﺎﺯﻱ ﺍﻳﻦ‬
‫ﮔﺎﺯ ﮔﺸﻮﺩﻩ ﺍﺳﺖ‪ .‬ﺩﺭ ﺳﺎﻝ ‪ 1997‬ﮔﺰﺍﺭﺷﻲ ﻣﺒﻨﻲ ﺑﺮﻇﺮﻓﻴﺖ ﺫﺧﻴﺮﻩ ﺳـﺎﺯﻱ ﮔـﺎﺯ ﻫﻴـﺪﺭﻭژﻥ ﺑـﻪ ﻣﻴـﺰﺍﻥ ‪ %10-5‬ﻭﺯﻧـﻲ ﺯﻣﻴﻨـﻪ ﺳـﺎﺯ‬
‫ﺗﺤﻘﻴﻘﺎﺕ ﻭﺳﻴﻌﻲ ﺷﺪ]‪ .[۱‬ﻋﻼﻭﻩ ﺑﺮ ﻫﻴﺪﺭﻭژﻥ]‪ [۲‬ﺟﺬﺏ ﮔﺎﺯﻫﺎﻱ ﺧﺎﻟﺺ ﻭ ﻣﺨﻠﻮﻁ ﻣﺘﺎﻥ‪ ،‬ﺍﺗﺎﻥ ﻭ ﭘﺮﻭﭘﺎﻥ ﻧﻴﺰ ﺑﺎ ﺭﻭﺵ ﻫـﺎﻱ ﺗﺌـﻮﺭﻱ‬
‫ﺗﺎﺑﻌﻴﺖ ﭼﮕﺎﻟﻲ) ‪ (DFT‬ﻭ ﺷﺒﻴﻪ ﺳﺎﺯﻱ ﺍﻧﺠﺎﻡ ﺷﺪﻩ ﺍﺳﺖ]‪.[۳‬‬
‫ﻣﻚ ﺍﻟﺮﻭﻱ ﻭ ﺑﻮﻳﻞ ﻧﻴﺰ ﺟﺪﺍﺳﺎﺯﻱ ﻣﺨﻠﻮﻁ ﺩﻭﺗﺎﻳﻲ ﮔﺎﺯﻫﺎﻱ ﻣﺘﺎﻥ ﻭ ﻫﻴﺪﺭﻭژﻥ ﺭﺍ ﺭﻭﻱ ﺿﺨﺎﻣﺖ ﻫﺎﻱ ﻣﺨﺘﻠﻒ ﻏﺸﺎﻫﺎﻱ ﻛﺮﺑﻨﻲ ﻣﻄﺎﻟﻌـﻪ‬
‫ﻛﺮﺩﻩﺍﻧﺪ‪ .‬ﻋﻼﻭﻩ ﺑﺮ ﺍﻳﻦ ﻫﺎ ﺟﺬﺏ ﮔﺎﺯﻫﺎﻱ ﻧﺠﻴﺐ ﻧﻴﺰ ﻣﻮﺿـﻮﻉ ﺑﺮﺧـﻲ ﻣﻄﺎﻟﻌـﺎﺕ ﺑـﻮﺩﻩ ﺍﺳـﺖ]‪ .[۴،۵،۶‬ﮔﺎﺯﻫـﺎﻱ ﻧﺠﻴـﺐ ﺩﺭ ﻣﺼـﺎﺭﻑ‬
‫ﺻﻨﻌﺘﻲ ﻣﺎﻧﻨﺪ ﻟﻴﺰﺭ]‪،[۷‬ﺭﻭﺷﻨﺎﻳﻲ]‪ ،[۸‬ﻣﺒﺮﺩ ﺑﺮﻭﺩﺗﻲ ﻭ ﺩﺭ ﭘﺰﺷﻜﻲ ﺑﻪ ﻛﺎﺭ ﻣﻲ ﺭﻭﻧﺪ‪ .‬ﺑﺎ ﻭﺟﻮﺩ ﺍﻳﻨﻜﻪ ﻓﺮﺍﻭﺍﻧﻲ ﺍﻳﻦ ﮔﺎﺯﻫﺎ ﺩﺭ ﻫﻮﺍ ﻧـﺎﭼﻴﺰ ﻭ‬
‫ﻭﺍﻛﻨﺶ ﭘﺬﻳﺮﻱ ﺑﺴﻴﺎﺭ ﻛﻤﻲ ﺩﺍﺭﻧﺪ ﺍﻣﺎ ﺑﺮﺍﻱ ﻣﺒﺎﺣﺚ ﻋﻠﻤﻲ ﭼﺎﻟﺶ ﺑﺮﺍﻧﮕﻴﺰﻧﺪ‪ .‬ﮔﺮﻭﻫﻲ ﺍﺯ ﻣﺤﻘﻘﺎﻥ ﺗﻮﺍﻧﺎﻳﻲ ‪MOF‬ﻫـﺎ ﺑـﺮﺍﻱ ﺟﺪﺍﺳـﺎﺯﻱ‬
‫ﻣﺨﻠﻮﻁ ﮔﺎﺯﻫﺎﻱ ﺯﻧﻮﻥ ﻭ ﻛﺮﻳﭙﺘﻮﻥ ﺭﺍ ﻧﺸﺎﻥ ﺩﺍﺩﻧﺪ‪ .‬ﻫﻤﭽﻨﻴﻦ ﺧﻮﺍﺹ ﺗﺮﻣﻮﺩﻳﻨﺎﻣﻴﻜﻲ ﻭ ﺳﺎﺧﺘﺎﺭﻱ ‪MOF‬ﻫﺎ ﺍﺯ ﺍﻳﺰﻭﺗﺮﻡ ﻫﺎﻱ ﻛﺮﻳﭙﺘـﻮﻥ‬
‫ﻭ ﺯﻧﻮﻥ ﺗﻌﻴﻴﻦ ﺷﺪﻩ ﺍﺳﺖ]‪۱۰‬ﻭ‪ .[۹‬ﻫﺪﻑ ﺍﺯ ﺍﻳﻦ ﻣﻄﺎﻟﻌﻪ ﺑﺮﺭﺳﻲ ﺭﻓﺘـﺎﺭ ﺟـﺬﺑﻲ ﮔﺎﺯﻫـﺎﻱ ﻫﻠـﻴﻢ ﻭ ﺁﺭﮔـﻮﻥ ﺑـﺮ ﺭﻭﻱ ﻧﺎﻧﻮﻟﻮﻟـﻪ ﻛﺮﺑﻨـﻲ‬
‫)‪10‬ﻭ‪ (10‬ﻭ ﺟﺪﺍﺳﺎﺯﻱ ﺍﻳﻦ ﺩﻭ ﮔﺎﺯ ﺑﻪ ﺭﻭﺵ ﺷﺒﻴﻪ ﺳﺎﺯﻱ ﻣﻮﻧﺖ ﻛﺎﺭﻟﻮ ﺑﻮﺩﻩ ﺍﺳﺖ‪.‬‬

‫ﺭﻭﺵ ﻣﺤﺎﺳﺒﺎﺗﻲ‬

‫ﻓﺮﺍﻳﻨﺪ ﺟﺬﺏ ﮔﺎﺯﻫﺎﻱ ﻫﻠﻴﻢ ﻭ ﺁﺭﮔﻮﻥ ﺧﺎﻟﺺ ﻭ ﻣﺨﻠﻮﻁ ﺍﻳﻦ ﺩﻭ ﮔﺎﺯ ﺑﺮ ﺭﻭﻱ ﻧﺎﻧﻮﻟﻮﻟﻪ ﻛﺮﺑﻨﻲ)‪10‬ﻭ‪ (10‬ﺑـﻪ ﺭﻭﺵ ﺷـﺒﻴﻪ ﺳـﺎﺯﻱ ﻣﻮﻧـﺖ‬
‫ﻛﺎﺭﻟﻮ ﻣﻄﺎﻟﻌﻪ ﺷﺪﻩ ﺍﺳﺖ‪ .‬ﺷﺒﻴﻪ ﺳﺎﺯﻱ ﺩﺭ ﺩﻣﺎﻱ ‪ 77K‬ﺩﺭ ﻣﺤﺪﻭﺩﻩ ﻓﺸﺎﺭ ‪ 1-30 MPa‬ﺗﺤﺖ ﺷﺮﺍﻳﻂ ﻣﺘﻨﺎﻭﺏ ﻣﺮﺯﻱ ﺩﺭ ﻳﻚ ﺟﻌﺒـﻪ‬
‫ﺷﺒﻴﻪ ﺳﺎﺯﻱ ﺑﻪ ﺍﺑﻌﺎﺩ‪ 50×50×50 Å 3‬ﺣﺎﻭﻱ ﺗﻨﻬﺎ ﻳﻚ ﻧﺎﻧﻮﻟﻮﻟﻪ ﺍﻧﺠﺎﻡ ﺷﺪﻩ ﻭ ﻧﺎﻧﻮﻟﻮﻟﻪ ﻛﺎﻣﻼ ﺻﻠﺐ ﺩﺭ ﻧﻈـﺮ ﮔﺮﻓﺘـﻪ ﺷـﺪﻩ ﺍﺳـﺖ‪ .‬ﺩﺭ‬
‫‪P‬‬ ‫‪P‬‬

‫ﺷﺒﻴﻪ ﺳﺎﺯﻱ ﻣﺠﻤﻮﻋﻪ ﻛﺎﻧﻮﻧﻴﻜﺎﻝ ﺩﻣﺎ‪ ،‬ﺗﻌﺪﺍﺩ ﺫﺭﺍﺕ ﻭ ﺣﺠﻢ ﺳﻴﺴﺘﻢ ﺩﺭ ﻃﻮﻝ ﺷﺒﻴﻪ ﺳﺎﺯﻱ ﻭ ﺩﺭ ﻫﻤﻪ ﮔﺎﻡ ﻫﺎ ﺛﺎﺑﺖ ﻣﻲ ﺑﺎﺷـﺪ‪ .‬ﺩﺭ ﺍﻳـﻦ‬
‫ﺭﻭﺵ ﺍﺯ ﻧﻤﻮﻧﻪ ﺑﺮﺩﺍﺭﻱ ﻣﺘﺮﻭﭘﻮﻟﻴﺲ ﺟﻬﺖ ﭘﺬﻳﺮﺵ ﭘﻴﻜﺮﺑﻨﺪﻱ ﻫﺎﻱ ﺗﻮﻟﻴﺪ ﺷﺪﻩ ﺗﻮﺳﻂ ﺟﺎﺑﺠﺎﻳﻲ ﺗﺼﺎﺩﻓﻲ ﻣﻮﻟﻜﻮﻝﻫﺎ ﺑﻬﺮﻩ ﮔﺮﻓﺘﻪ ﺷﺪﻩ‬
‫ﺍﺳﺖ ﻭ ‪ 2×710‬ﭘﻴﻜﺮﺑﻨﺪﻱ ﺗﻮﻟﻴﺪ ﻣﻲ ﺷﻮﺩ‪ .‬ﺑﺮﺍﻱ ﺭﺳﻢ ﺍﻳﺰﻭﺗﺮﻡ ﻫﺎﻱ ﺟﺬﺑﻲ ‪ ،‬ﻇﺮﻓﻴﺖ ﺫﺧﻴﺮﻩ ﺳﺎﺯﻱ ﻭﺯﻧﻲ ﺍﺯ ﺭﺍﺑﻄﻪ ﺯﻳﺮ ﻣﺤﺎﺳﺒﻪ ﻣﻲ‪-‬‬ ‫‪P‬‬ ‫‪P‬‬

‫ﺷﻮﺩ‪:‬‬

‫𝑠𝑎𝑔𝑚 𝑠𝑎𝑔𝑁‬
‫= 𝑤𝜌‬
‫𝐶𝑚 𝐶𝑁 ‪𝑁𝑔𝑎𝑠 𝑚𝑔𝑎𝑠 +‬‬

‫ﻛﻪ ﺩﺭ ﺍﻳﻦ ﺭﺍﺑﻄﻪ ‪ N gas‬ﺗﻌﺪﺍﺩ ﺍﺗﻢ ﻫﺎﻱ ﮔﺎﺯ ﺟﺬﺏ ﺷﺪﻩ ﻭ ‪ NC‬ﺗﻌﺪﺍﺩ ﺍﺗﻢ ﻫﺎﻱ ﻧﺎﻧﻮﻟﻮﻟﻪ ﺭﺍ ﻧﺸﺎﻥ ﻣﻲ ﺩﻫﺪ‪.‬‬
‫‪R‬‬ ‫‪R‬‬ ‫‪R‬‬

‫ﺑﺮﻫﻢ ﻛﻨﺶﻫﺎﻱ ﺑﻴﻦ ﻣﻮﻟﻜﻮﻟﻲ ﺑﺎ ﺍﺳﺘﻔﺎﺩﻩ ﺍﺯ ﭘﺘﺎﻧﺴﻴﻞ ﻟﻨﺎﺭﺩ‪-‬ﺟﻮﻧﺰ )‪6‬ﻭ‪ (12‬ﻣﺪﻟﺴﺎﺯﻱ ﺷﺪﻩ ﺍﺳﺖ‪ .‬ﭘﺎﺭﺍﻣﺘﺮﻫﺎﻱ ﺍﻳﻦ ﻣﻌﺎﺩﻟﻪ ﺩﺭ ﺟﺪﻭﻝ‪1‬‬
‫ﺁﻣﺪﻩ ﺍﺳﺖ‪.‬‬

‫‪2‬‬
 ‫ﭘﺎﺭﺍﻣﺘﺮﻫﺎﻱ ﻟﻨﺎﺭﺩ‪-‬ﺟﻮﻧﺰ ﺑﺮﺍﻱ ﺑﺮﻫﻤﻜﻨﺶ ﺑﻴﻦ ﺍﺟﺰﺍﻱ ﺳﻴﺴﺘﻢ ﺍﺯ ﻗﺎﻧﻮﻥ ﻫﺎﻱ ‪ Lorentz-Berthelot‬ﺑﺪﺳﺖ ﻣﻲ ﺁﻳﺪ‪.‬‬
‫𝑗𝜎‪𝜎𝑖 +‬‬
‫= 𝑗𝑖𝜎‬ ‫‪2‬‬
‫‪,‬‬ ‫𝑗𝜀𝑖𝜀�=𝑗𝑖𝜀‬

‫ﺟﺪﻭﻝ‪.1‬ﭘﺎﺭﺍﻣﺘﺮﻫﺎﻱ ﻟﻨﺎﺭﺩ‪-‬ﺟﻮﻧﺰ]‪۱۲‬ﻭ‪[۱۱‬‬

‫‪Species‬‬ ‫)‪ε/k B (Κ‬‬

‫‪R‬‬ ‫‪R‬‬ ‫)‪σ (Å‬‬

‫‪He–He‬‬ ‫‪۱۰٫۲۰‬‬ ‫‪۲٫٥٦‬‬

‫‪C–C‬‬ ‫‪۲۸٫۲۰‬‬ ‫‪۳٫٤‬‬

‫‪Ar–Ar‬‬ ‫‪۱۲۰‬‬ ‫‪۳٫۳۸‬‬

‫ﻫﻤﭽﻨﻴﻦ ﭘﺘﺎﻧﺴﻴﻞ ﻛﻞ ﻧﺎﺷﻲ ﺍﺯ ﺑﺮ ﻫﻢ ﻛﻨﺶ ﺑﻴﻦ ﻣﻮﻟﻜﻮﻝ ﻫﺎﻱ ﮔﺎﺯ ﻭ ﺍﺗﻢ ﻫﺎﻱ ﻧﺎﻧﻮﻟﻮﻟﻪ ﺍﺯ ﺭﺍﺑﻄﻪ ﺯﻳﺮ ﻣﺤﺎﺳﺒﻪ ﻣﻲ ﺷﻮﺩ]‪: [۱۱‬‬
‫‪12‬‬ ‫‪6‬‬
‫𝑁‬ ‫𝜎‬ ‫𝑤𝑓𝜎‬
‫‪R‬‬ ‫‪R‬‬ ‫‪R‬‬
‫𝑓‬
‫‪Ø fw = 4Ɛ fw ∑𝑖=1‬‬ ‫𝑁∑‬ ‫𝐶‬ ‫𝑤𝑓‬
‫� 𝑟 �� ‪𝑗=1‬‬ ‫� � 𝑟�‪−‬‬
‫𝑗𝑖‬ ‫𝑗𝑖‬

‫‪ Nf‬ﺗﻌﺪﺍﺩ ﻛﻞ ﻣﻮﻟﻜﻮﻝ ﻫﺎﻱ ﮔﺎﺯ ﻭ ‪ N c‬ﺗﻌﺪﺍﺩ ﺍﺗﻢ ﻫﺎﻱ ﻛﺮﺑﻦ ﻧﺎﻧﻮ ﻟﻮﻟﻪ ﻭ ‪ r ij‬ﻓﺎﺻﻠﻪ ﻣﺮﻛﺰ ﺗـﺎ ﻣﺮﻛـﺰ ﻣﻮﻟﻜـﻮﻝ ﮔـﺎﺯ ﻭ ﻛـﺮﺑﻦ ﻧﺎﻧﻮﻟﻮﻟـﻪ‬
‫‪R‬‬ ‫‪R‬‬ ‫‪R‬‬ ‫‪R‬‬

‫ﺍﺳﺖ‪.‬ﺯﻳﺮﻭﻧﺪ ‪ fw‬ﻧﻤﺎﻳﺎﻧﮕﺮ ﺑﺮ ﻫﻢ ﻛﻨﺶ ﺑﻴﻦ ﻳﻚ ﻣﻮﻟﻜﻮﻝ ﮔﺎﺯ ﻭ ﺍﺗﻢ ﻛﺮﺑﻦ ﻣﻲ ﺑﺎﺷﺪ‪.‬‬

‫ﻓﺎﻛﺘﻮﺭ ﺟﺪﺍﺳﺎﺯﻱ ﺑﻪ ﺷﻜﻞ ﺯﻳﺮ ﺗﻌﺮﻳﻒ ﻣﻲ ﺷﻮﺩ ﻛﻪ ﻣﻘﺪﺍﺭ ﺍﻳﻦ ﭘﺎﺭﺍﻣﺘﺮ ﻣﺸﺨﺺ ﻣﻲ ﻛﻨﺪ ﺟﺬﺏ ﻛﺪﺍﻡ ﮔﻮﻧﻪ ﺑﻬﺘﺮ ﺻﻮﺭﺕ ﻣﻲ ﮔﻴﺮﺩ‪.‬‬

‫)𝑟𝐴𝑦‪𝑆 = (𝑥𝐻𝑒/𝑥𝐴𝑟)/(𝑦He/‬‬

‫‪ x i‬ﻭ‪ y i‬ﺑﻪ ﺗﺮﺗﻴﺐ ﺗﺮﻛﻴﺐ ﺩﺭﺻﺪ ﺟﺰ ‪ i‬ﺩﺭ ﻓﺎﺯ ﺟﺬﺏ ﺷﺪﻩ ﻭ ﺗﻮﺩﻩ ﺭﺍ ﻧﺸﺎﻥ ﻣـﻲ ﺩﻫـﺪ‪ .‬ﺩﺭ ﻳـﻚ ﻓﺮﺍﻳﻨـﺪ ﺭﻗـﺎﺑﺘﻲ ﻭ ﻣﺨﻠـﻮﻁ ﺩﻭ ﮔـﺎﺯ‬ ‫‪R‬‬ ‫‪R‬‬ ‫‪R‬‬ ‫‪R‬‬

‫‪ s‬ﻫـﻴﭻ ﺭﻗـﺎﺑﺘﻲ‬
‫‪R‬‬ ‫‪R‬‬ ‫‪R‬‬ ‫‪R‬‬

‫‪ij‬‬ ‫ﻫﻨﮕﺎﻣﻲ ﻛﻪ ‪ Sij > 1‬ﮔﻮﻧﻪ ‪ i‬ﺑﻬﺘﺮ ﺟﺬﺏ ﻣﻲ ﺷﻮﺩ ﺩﺭ ﻏﻴﺮ ﺍﻳﻦ ﺻﻮﺭﺕ ﺟﺬﺏ ﮔﻮﻧﻪ ‪ j‬ﺍﺭﺟﺤﻴـﺖ ﺩﺍﺭﺩ‪ .‬ﺍﮔـﺮ ‪=1‬‬

‫ﺑﺮﺍﻱ ﺟﺬﺏ ﻭﺟﻮﺩ ﻧﺪﺍﺭﺩ‪.‬‬

‫ﮔﺮﻣﺎﻱ ﺟﺬﺏ) ‪ Q st (isosteric heat‬ﻧﻴﺰ ﺍﺯ ﺭﺍﺑﻄﻪ ﺯﻳﺮ ﺣﺎﺻﻞ ﻣﻲ ﺷﻮﺩ‪:‬‬

‫‪R‬‬ ‫‪R‬‬

‫𝑚∑ ‪Q ST = - R‬‬
‫‪R‬‬

‫𝑁 𝑖𝑎 ‪𝑖=0‬‬
‫‪i‬‬
‫‪P‬‬

‫ﻛﻪ ‪ N‬ﺗﻌﺪﺍﺩ ﺍﺗﻢ ﻫﺎﻱ ﺟﺬﺏ ﺷﺪﻩ ﻭ ‪ R‬ﺛﺎﺑﺖ ﮔﺎﺯﻫﺎﺳﺖ‪.‬‬

‫‪3‬‬
 ‫ﺑﺤﺚ ﻭ ﻧﺘﺎﻳﺞ‬

‫ﺍﻳﺰﻭﺗﺮﻡ ﻫﺎﻱ ﺟﺬﺑﻲ ﺑﺮﺍﻱ ﺩﻭ ﮔﺎﺯ ﺩﺭ ﺩﻣﺎﻱ ﺛﺎﺑﺖ ‪ 77‬ﻛﻠﻮﻳﻦ ﻭ ﻓﺸﺎﺭﻫﺎﻱ ﻣﺨﺘﻠﻔﻲ ﺑﺪﺳﺖ ﺁﻣﺪﻩ ﺍﺳﺖ‪.‬ﺍﻳﺰﻭﺗﺮﻡ ﺟﺬﺑﻲ ﻧﺸـﺎﻥ ﻣـﻲ ﺩﻫـﺪ‬
‫ﺟﺬﺏ ﮔﺎﺯ ﺁﺭﮔﻮﻥ ﺑﻴﺸﺘﺮ ﺍﺯ ﻫﻠﻴﻢ ﺍﺳﺖ ﻭ ﺑﺎ ﺍﻓﺰﺍﻳﺶ ﻓﺸﺎﺭ ﻣﻘﺎﺩﻳﺮ ﮔﺎﺯﻫﺎﻱ ﺟﺬﺏ ﺷﺪﻩ ﺑﻴﺸﺘﺮ ﻣﻲ ﺷﻮﺩ]ﺷﻜﻞ‪.[1‬‬

‫ﻓﺎﻛﺘﻮﺭ ﺍﻧﺘﺨﺎﺏ ﭘﺬﻳﺮﻱ ﻭﺍﺑﺴﺘﻪ ﺑﻪ ﻧﻮﻉ ﺑﺮﻫﻢ ﻛﻨﺶ ﺟﺎﺫﺏ ﻭ ﺟﺬﺏ ﺷﻮﻧﺪﻩ ﻭ ﺷﺮﺍﻳﻂ ﺍﻧﺠﺎﻡ ﻓﺮﺍﻳﻨﺪ ﻣﺎﻧﻨﺪ ﺩﻣـﺎ ﻭ ﻓﺸـﺎﺭ ﺍﺳـﺖ‪ .‬ﺷـﻜﻞ‪2‬‬
‫ﺍﻧﺘﺨﺎﺏ ﭘﺬﻳﺮﻱ ﺁﺭﮔﻮﻥ ﻧﺴﺒﺖ ﺑﻪ ﻫﻠﻴﻢ ﺩﺭ ﺣﺎﻟﺖ ﻣﺨﻠﻮﻁ ﺭﺍ ﻧﺸﺎﻥ ﻣﻲ ﺩﻫﺪ‪ .‬ﺍﺛﺮ ﻓﺸﺎﺭ ﺑﺮ ﻓﺎﻛﺘﻮﺭ ﺟﺪﺍﺳﺎﺯﻱ ﺩﺭ ﻳﻚ ﺩﻣﺎﻱ ﻣﻌـﻴﻦ ﻧﻴـﺰ‬
‫ﺑﺮﺭﺳﻲ ﺷﺪﻩ ﺍﺳﺖ‪ .‬ﺩﺭ ﻫﺮ ﺩﻭ ﻓﺸﺎﺭﺑﺮﺍﻱ ﺗﺮﻛﻴﺐ ﺩﺭﺻﺪ‪ 0,4‬ﺗﺎ‪ 0,6.‬ﺁﺭﮔﻮﻥ‪،‬ﺟﺪﺍﺳـﺎﺯﻱ ﺭﺥ ﻧﻤـﻲ ﺩﻫـﺪ‪ .‬ﺩﺭ ﻓﺸـﺎﺭ ‪ 10MPa‬ﺑﻴﺸـﺘﺮﻳﻦ‬
‫ﺟﺪﺍﺳﺎﺯﻱ ﺩﺭ ‪ %25‬ﺁﺭﮔﻮﻥ ﺍﻧﺠﺎﻡ ﻣﻲ ﺷﻮﺩ ﻭ ﻛﻤﺘﺮﻳﻦ ﺁﻥ ﻣﺮﺑﻮﻁ ﺑﻪ ‪%61‬ﺁﺭﮔﻮﻥ ﺍﺳﺖ‪ .‬ﺑﻪ ﻃﻮﺭ ﻛﻠﻲ ﻧﺘﺎﻳﺞ ﻧﺸﺎﻥ ﻣﻲ ﺩﻫﺪ ﺟﺪﺍﺳـﺎﺯﻱ‬
‫ﺍﻳﻦ ﺩﻭ ﮔﺎﺯ ﺩﺭ ﻓﺸﺎﺭ ﻛﻤﺘﺮ ﺑﻬﺘﺮ ﺍﻧﺠﺎﻡ ﻣﻲ ﺷﻮﺩ‪.‬‬

‫‪0.7‬‬
‫)‪Gravimetric storage(gC/g gas‬‬

‫‪0.6‬‬
‫‪0.5‬‬
‫‪0.4‬‬ ‫‪Ar‬‬
‫‪He‬‬
‫‪0.3‬‬
‫‪0.2‬‬
‫‪0.1‬‬
‫‪0‬‬
‫‪0‬‬ ‫‪10‬‬ ‫‪20‬‬ ‫‪30‬‬ ‫‪40‬‬
‫)‪P(MPa‬‬

‫ﺷﻜﻞ ‪ :1‬ﺍﻳﺰﻭﺗﺮﻡ ﺟﺬﺑﻲ ﮔﺎﺯﻫﺎﻱ ‪ Ar‬ﻭ‪ He‬ﺩﺭ ﺣﺎﻟﺖ ﺧﺎﻟﺺ ﺩﺭ ﺩﻣﺎﻱ‪77‬ﻛﻠﻮﻳﻦ‬

‫‪1.5‬‬

‫‪1.3‬‬
‫‪p=30 MPa‬‬

‫‪1.1‬‬ ‫‪p=10MPa‬‬
‫‪SAr/He‬‬

‫‪0.9‬‬

‫‪0.7‬‬
‫‪0‬‬ ‫‪0.2‬‬ ‫‪0.4‬‬ ‫‪0.6‬‬ ‫‪0.8‬‬ ‫‪1‬‬

‫‪yAr‬‬
‫ﺷﻜﻞ‪-2‬ﺍﻧﺘﺨﺎﺏ ﭘﺬﻳﺮﻱ ‪ Ar‬ﻧﺴﺒﺖ ﺑﻪ ‪ He‬ﺑﺮﺣﺴﺐ ﺗﺮﻛﻴﺐ ﺩﺭﺻﺪ ﺁﺭﮔﻮﻥ ﺩﺭ ﺩﻣﺎﻱ ‪ 77‬ﻛﻠﻮﻳﻦ‬

‫ﺷﻜﻞ ‪ 3‬ﮔﺮﻣﺎﻱ ﺟﺬﺏ ﺩﻭ ﮔﺎﺯ ﺭﺍ ﺩﺭ ﺣﺎﻟﺖ ﺧﺎﺹ ﻧﺸﺎﻥ ﻣﻲ ﺩﻫﺪ‪.‬ﺑﺎ ﺍﻓﺰﺍﻳﺶ ﻣﻘﺎﺩﻳﺮ ﺟﺬﺏ ﺷﺪﻩ ﮔﺎﺯ‪ Q st ،‬ﺑﻪ ﻃﻮﺭ ﺧﻄﻲ ﻛـﺎﻫﺶ ﻣـﻲ‬
‫‪R‬‬ ‫‪R‬‬

‫ﻳﺎﺑﺪ ﺯﻳﺮﺍ ﻣﻮﻟﻜﻮﻝ ﻫﺎﻱ ﺟﺬﺏ ﺷﺪﻩ ﺍﺿﺎﻓﻲ ﺩﺭ ﻧﻮﺍﺣﻲ ﻛﻢ ﺍﻧﺮژﻱﺗﺮ ﺟﺬﺏ ﻣﻲ ﺷﻮﻧﺪ‪.‬ﻫﻤﭽﻨﻴﻦ ﻣﻘﺎﺩﻳﺮ ‪ Q st‬ﺑﺮﺍﻱ ﺁﺭﮔﻮﻥ ﺑﻴﺸﺘﺮ ﺍﺳﺖ‪.‬‬
‫‪R‬‬ ‫‪R‬‬

‫‪4‬‬
 40
35
30
Qst (J/mol

25
20 He
15 Ar
10
5
0
0 60 120 180 240 300
Amount adsorbed (mg/g)

‫ ﻛﻠﻮﻳﻦ‬77 ‫ ﮔﺮﻣﺎﻱ ﺟﺬﺏ ﻫﻠﻴﻢ ﻭ ﺁﺭﮔﻮﻥ ﺩﺭ ﺩﻣﺎﻱ‬:3‫ﺷﻜﻞ‬

‫ﻧﺘﻴﺠﻪ ﮔﻴﺮﻱ‬

‫ﻧﺘﺎﻳﺞ ﺣﺎﺻﻞ ﺍﺯ ﺷﺒﻴﻪ ﺳﺎﺯﻱ ﻧﺸﺎﻥ ﻣﻲﺩﻫﺪ ﺟﺬﺏ ﮔﺎﺯ ﺁﺭﮔﻮﻥ ﻧﺴﺒﺖ ﺑﻪ ﮔـﺎﺯ ﻫﻠـﻴﻢ ﺑﻴﺸـﺘﺮ ﺍﺳـﺖ ﻭ ﺍﻳﺰﻭﺗـﺮﻡ ﻫـﺎﻱ ﺟـﺬﺑﻲ ﺍﺯ ﻣـﺪﻝ‬
.‫ ﺭﻗﺎﺑﺖ ﺁﺭﮔﻮﻥ ﺑـﺮﺍﻱ ﺟـﺬﺏ ﺑﻴﺸـﺘﺮ ﺍﺳـﺖ‬،‫ﻓﺎﻛﺘﻮﺭ ﺟﺪﺍﺳﺎﺯﻱ ﺣﺎﻛﻲ ﺍﺯ ﺁﻥ ﺍﺳﺖ ﻛﻪ ﺩﺭ ﻣﺨﻠﻮﻁ ﺍﻳﻦ ﮔﺎﺯﻫﺎ‬.‫ﻻﻧﮕﻤﻮﺭ ﺗﺒﻌﻴﺖ ﻣﻲ ﻛﻨﻨﺪ‬
‫ﮔﺮﻣﺎﻱ ﺟـﺬﺏ‬، ‫ﺩﺭ ﻳﻚ ﺷﺮﺍﻳﻂ ﻳﻜﺴﺎﻥ ﺑﺮﺍﻱ ﻫﺮ ﺩﻭ ﮔﺎﺯ‬.‫ﮔﺮﻣﺎﻱ ﺟﺬﺏ ﻧﻴﺰ ﺑﺮ ﺣﺴﺐ ﺗﻌﺪﺍﺩ ﺫﺭﺍﺕ ﮔﺎﺯ ﺟﺬﺏ ﺷﺪﻩ ﻣﺤﺎﺳﺒﻪ ﺷﺪﻩ ﺍﺳﺖ‬
[11] ‫ ﺑﻪ ﻃﻮﺭ ﻛﻠﻲ ﻣﻲ ﺗـﻮﺍﻥ ﮔﻔـﺖ ﻃﺒـﻖ ﻧﺘـﺎﻳﺞ ﺗﺤﻘﻴﻘـﺎﺕ ﮔﺬﺷـﺘﻪ‬.‫ ﻛﺎﻫﺶ ﻣﻲ ﻳﺎﺑﺪ‬Q st ،‫ﺁﺭﮔﻮﻥ ﺑﻴﺸﺘﺮ ﺍﺳﺖ ﻭ ﺑﺎ ﺍﻓﺰﺍﻳﺶ ﻓﺸﺎﺭ‬
R R

.‫( ﺟﺎﺫﺏ ﻣﻨﺎﺳﺒﻲ ﺑﺮﺍﻱ ﺫﺧﻴﺮﻩ ﻭ ﺟﺪﺍﺳﺎﺯﻱ ﮔﺎﺯﻫﺎﻱ ﻧﺠﻴﺐ ﻣﻲ ﺑﺎﺷﺪ‬10‫ﻭ‬10) ‫ﻧﺎﻧﻮﻟﻮﻟﻪ ﻛﺮﺑﻨﻲ ﺗﻚ ﺩﻳﻮﺍﺭﻩ‬

‫ﻣﺮﺍﺟﻊ‬

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