재료물리 화학도

Chap l .Basic

[전통적)
.
fhermodyhamics T
Classical -
:
macroscopic
statistical -
( 통계 열역학] : microscopic
oideal gas
-

V → O

-
no interaction ) ⇒ PV =
MRT

. Och Law
-

열 흐름시 ⇒ 열평형

9
ystem
.

-
o
pen :
열 물질 교환
-
closed :
열 교환
-

isolated :
열시 물질 X

이 s어 laww * infensive
extensive
-

δw = -

pal
Function of state :
pathindependant블
-

Heat work . X

Internal : o
energy
 - do =
sw + sQ

lreversible
om~m changin gas) du =
SQ -

pa
없
Heat
.

capacity
-

Constant V : dUFδQQ
=

ldTd)
@ 0J
co =

v
=
IAT. =
3
-

2
R ( monoatomic )

딛C
-
Constan+ P : aU -
δw =
8Q

sQ dU - Sw par
1 = ]
=
+

20
=
( zT ) dT V
+ )
fardv7
+
par

Cp =

ldraQlp =
( aTauv + (aTrr ~*
없
국 p]

=
co + R
=

=
다
0

. Isothermal expansion