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ARJUNA (JEE) Chemistry

20-06-2021
Practice Test - 01
31. If the atomic mass of sodium is 23, the number 38. Mole fraction of A in H2O is 0.2. The molality
moles in 46 g of sodium is: of A in H2O is :
(A) 1 (B) 2 (A) 13.9 (B) 15.5
(C) 2.3 (D) 4.6 (C) 14.5 (D) 16.8

32. If two moles of an ideal gas at 546 K occupies 39. 5 moles of AB2 weigh 125 × 10–3 kg and 10
a volume of 44.8 liters, the pressure must be: moles of A2B2 weigh 300 × 10–3 kg. The molar
(R = 1/12 L atm k–1 mol–1) mass of A(MA) and molar mass of B(MB) in
(A) 2 atm (B) 3 atm kg mol–1 are
(C) 4 atm (D) 1 atm (A) MA = 10 × 10–3 and MB = 5 × 10–3
(B) MA = 50 × 10–3 and MB = 25 × 10–3
33. Under the same conditions, two gases have he (C) MA = 25 × 10–3 and MB = 50 × 10–3
same number of molecules. They must: (D) MA = 5 × 10–3 and MB = 10 × 10–3
(A) be nobles gases
(B) have equal volume 40. Acetylene, C2H2, reacts with oxygen
according to the unbalanced equation:
(C) have a volume of 22.4 dm.3 each
C2H2(g) + O2(g)  CO2(g) + H2O(g)
(D) have an equal number of atoms
What is the O2/C2H2 ratio when this equation
is correctly balanced?
34. 0.5 moles of H2SO4 is mixed 0.2 mole of
2 3
Ca(OH)2. The maximum number of moles of (A) (B)
CaSO4 formed is: 1 1
H2SO4 + Ca(OH)2  CaSO4 + 2H2O 4 5
(C) (D)
(A) 0.2 (B) 0.5 1 2
(C) 0.4 (D) 1.5
41. A 300 K and 1 atmospheric pressure, 10 mL
35. In the reaction 4A + 2B + 3C  A4B2C3 of a hydrocarbon required 55 mL of O2 for
what will be the number of moles of product complete combustion and 40 mL of CO2 is
formed? Starting from 2 moles of A, 1.2 moles formed. The formula of he hydrocarbon is
of B and 1.44 moles of C. (A) C4H7Cl (B) C4H6
(A) 0.5 (B) 0.6 (C) C4H10 (D) C4H8
(C) 0.48 (D) 4.64
42. Solder is an alloy of tin and lead that is used in
electronic circuits. It has melting point of
36. If 10 g of Ag reacts with 1 g of Sulphur, the
225°C. It is ............. °F.
amount of Ag2S formed will be:
(A) 498 °F (B) –437 °F
2Ag + 1S  Ag2S (C) 437 °F (D) 400 °F
[Atomic weight of Ag = 108, S = 32]
(A) 7.75 g (B) 0.775 g 43. Find volume of C3H8 Which will react with 30
(C) 11 g (D) 10 g L of O2
(A) 3 L (B) 6 L
37. Molarity of H2SO4 is 18 M. Its density is 1.8 (C) 9 L (D) None of these
g/cm3, hence molality is:
(A) 18 (B) 100
(C) 36 (D) 500

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44. For the reaction: 7A + 13 B + 15C → 17P 51. The mole fraction of glucose (C6H12O6) in an
If 15 moles of A, 26 mole of B and 30.5 moles aqueous binary solution is 0.1. The mass
of C are taken initially, then limiting reactant is: percentage of water in it, to the nearest
(A) A (B) B integer, is ……….
(C) C (D) none of these
52. The mass of ammonia in grams produced
when 2.8 kg of dinitrogen quantitatively
45. For the reaction: 2X + 3Y  3Z, the reacts with 1 kg of dihydrogen is ………
combination of 2.00 moles of X with 2.00
1N2 + 3H2  2NH3
moles of Y produces 1.75 moles of Z. What is
[molar mass of N2 = 28g, molar mass of H2 =
the percent yield of this reaction?
2g]
(A) 43.8% (B) 58.3%
(C) 66.7% (D) 87.5% 53. A 100 mL solution was made by adding 1.43
of Na2CO3.xH2O. The normality of the
46. Human lungs can absorb 8 gm O2 per hour by solution is 0.1 N. The value of x is ……… .
respiration. If all oxygen atoms are converted
to carbohydrates (C6H12O6) how long will it 54. The molarity of HNO3 in a sample which has
take to produce 180 gm C6H12O6? density 1.4 g/mL and mass percentage of 63%
(A) 8 hours (B) 12 hours is ……..(Molecular weight of HNO3 = 63)
(C) 10 hours (D) 6 hours
55. If the value of Avogadro’s number is 6.023 ×
47. Two oxides of a metal contain 36.4% and 1023 mol–1 and the value of Boltzmann
53.4% of oxygen by mass respectively. If the constant is 1.380 × 10–23 JK–1, then the number
formula of first oxide is M2O, then that of the of significant figure in the calculated value of
second is the universal gas constant is
(A) M2O3 (B) MO
56. A student performs a titration with different
(C) MO2 (D) M2O5
butters and finds tiitre value of 25.2 mL, 25.25
mL, and 25.0 mL. The number of significant
48. Density of 2.05 M solution of CH3COOH in figure in the average titre value
water is 1.02 g/mL. The molality of same is
solution is: (Molar mass of CH3COOH = 60 g)
(A) 1.14 mol kg–1 (B) 3.28 mol kg–1 57. Average atomic mass of magnesium is 24.3.
(C) 2.28 mol kg –1
(D) 0.44 mol kg–1 This magnesium contains 80 mole % of 24Mg,
20 mole % of 26Mg and 25Mg. The mole % of
25
Mg is ________ .
49. What is equivalent mass of propane (C3H8) in
following reaction
58. A compound AB with molecular mass 60 g
C3H8 + 5O2  3CO2 + 4 H2O
mol–1 is dissolved in a solvent having density
(A) 2.2 g (B) 4.4 g 0.26 g ML–1. Assuming no change in volume
(C) 6.6 g (D) 8.8 g upon dissolution, the molality of 3.9 molar
solution is ________.
50. The crystalline salt Na2SO4.xH2O on heating
loses 55.9% of its weight. The formula of the 59. 29.2% (w/w) HCl stock solution has a density
crystalline salt is of 1.15 g mL–1. The molecular mass of HCl is
(A) Na2SO4.5H2O (B) Na2SO4.7H2O 36.5 g mole–1. The volume in mL of stock
(C) Na2SO4.2H2O (D) Na2SO4.10H2O solution is required to prepare a 460 mL
solution of 0.4 M HCl is _______

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60. Consider the reactions.

Yield  100%
4NH3  5O 2   4NO  6H 2O
(Excess)
Yield  100%
2NO  O2   2NO 2
(Excess)
Yield  100%
3NO  H 2 O   2HNO3  NO
(Excess)

11.2 of NH3 react at S.T.P. with excess of O2

according to the above reaction. The mass of
HNO3 formed (in g) in above reaction is

ANSWERS
31. (B) 41. (B) 51. (47)
32. (A) 42. (C) 52. (3400)
33. (B) 43. (B) 53. (10)
34. (A) 44. (B) 54. (14)
35. (C) 45. (D) 55. (4)
36. (A) 46. (B) 56. (3)
37. (D) 47. (B) 57. (10)
38. (A) 48. (C) 58. (15)
39. (D) 49. (A) 59. (20)
40. (D) 40. (D) 60. (21)

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Hint and Solutions

31. (B) 38. (A)

46
Here A = solute
n 2 H2O = Solvent
23
  1000
32. (A) m  solute
 solvent  M A
PV  nRT
P  44.8  2  0.0821  546 0.2  1000
m  13.9
P = 2 atm 0.8  18
33. (B) 39. (D)
Let atomic mass of A = x
Avogadro’s Law
Let atomic mass of B = y
34. (A)
Molar mass of AB2 = x + 2y
0.2
Limiting reagent is Ca(OH)2 =  0.2 Molar mass of A2B2 = 2x + 2y
1 5( x  2 y )  125  103 ……(i)
 0.2 mole of Ca(OH)2 gives 0.2 mole
10(2 x  2 y )  300  10 3 ……(ii)
of CaSO4
35. (C) On solving above equation (i) and (ii)
1.44 x  M A  5  103 kg
Limiting reagent is C  = Lowest
3 y  M B  10  103 kg
 3 Moles of C gives = 1 mole of 40. (D)
product 5
C2 H 2  O2   2CO2  H 2O
1.44 moles of C gives = 2
1 moles of O2 5
 1.44  0.48  
3 moles of C2 H 2 2  1
36. (A) 41. (B)
10 11
Number of moles of Ag =  0.092 1C4 H 6 ( g )  O2 ( g ) 
 4CO2 ( g )  3H 2O
108 2
11
1 1 ml ml 4 ml
Number of moles of S =  0.03 2
32 11
10 ml 2
× 10 = 55 ml 40 ml
1
Limiting reagent is S =  0.03 42. (C)
32  1 9
As 1 mole of S gives 1 mole of Ag2S ºF  º C  32
5
37. (D) 9
º F   225  32  437 F
Md 5
M
mM B 43. (B)
1
1000 C3 H 8 ( g )  5O2 ( g ) 
 3CO2 ( g )  4 H 2O( )
1.8m
18  1L 5L
98m
1 5L of O2 combine with C3H8 = 1L
1000 30L of O2 combine with C3H8 =
 m = 500 6L

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44. (B) 48. (C)

Limiting reagent = md
No. of moles M
 Lowest 1
mM B
Stoichiometric coefficient 1000
 Correct answer is (B).
1.02 m
2.05 
60 m
45. (D) 1
1000
2
Limiting reagent is y = = Lowest m = 2.28 m
3
 3 moles of y gives mole of z = 3
2 moles of y gives moles of z = 2 49. (A)
(maximum moles of z can be formed)
160 g of O2 react with C3H8 = 44 g
1.75
% age yield =  100  87.5% 44
2 8g of O2 react with C3H8 =  8  2.2 g
160
46. (B)
Apply POAC for oxygen atoms 50. (D)
2 × moles of oxygen atoms in O2 = 6 ×
Molar mass of Na2SO4.xH2O = 142 + 18 x
moles of oxygen in atoms in C6H12O6
8 mass of C6 H12O6 55.9
2  6  (142  18 x)  18 x
32 180 100
Mass of C6H12O6 formed in 1 hour = 15 g  x = 10
15 g of glucose formed = 1 hour
180 g of glucose formed =
1 51. (47)
 180  12 hours
15  B 0.1 WB  18 W
   B
 A 0.9 180  WA 10WA
47. (B)
10 WB
In Ist oxide oxygen = 36.4 parts 
9 WA
 36.4 parts of oxygen has = 1 atom
53.4 parts of oxygen has atoms in 10 WB
 1  1
second oxide 9 WA
1
  53.4  1.46 9  10 WB  WA
36.4  
In Ist oxide metal = 63.6 parts 9 WA
 63.6 parts of metal has = 2 atom 9 WA
 
46.6 parts of metal has atoms in 19 WA  WB
second oxide
Mass % age of water =
2
  46.6  1.46 WA 9
63.6  100   100  47%
M 1.46 O1.46 WA  WB 19

Divide it by HCM = 1.46

 formula MO

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52. (3400) 57. (10)

2800 Let mole %age of 26Mg = 20 – x
Molar of N2 =  100
28 Then mole %age of 25 Mg = x
1000 Average atomic mass =
Moles of H2 =  500
5
100 M1n1  M 2 n2  M 3 n3
L.R. is N2 =  Lowest n1  n2  n3
1
1 mole of N2 gives 2 moles of NH3 24  80  25 x  26(20  x)
24.3 
100 moles of N2 gives 200 moles of NH3 100
1 mole of NH3 has mass = 17g (molar x = 10
mass)
200 moles of NH3 has mass = 17 × 200 = 58. (15)
3400 g Density of solvent = 0.26 g/ml
3.9 molar means 3.9 moles of solute
53. (10) present in 1000 ml of solution
MB = 2 × 23 + 12 + 48 + 18x = 106 + 18x Volume of solvent = volume of solution
106  18 x Mass of solvent = 1000 × 0.26 = 260 g
EB  ( n f  2)
2 3.9  1000
m  15m
1.43  100  2 260
N  0.1
106  18 x  100
x = 10 59. (20)
29.2  1.15  10
M1   9.2M
54. (14) 36.5
63  1.4  10 M 2  0.4 M , V2  460 ml
M  14
63 M 1V1  M 2V2
9.2  V1  0.4  460
55. (4)
R V1  20 ml
K
NA
60. (21)
R  K  NA
11.2
R  6.023  1023  1.384  1023 Number of moles of NH3 =  0.5
22.4
R  8.314 JK 1mol 1 4 2 2
Moles of HNO3 formed =    0.5
Number of significant figures = 4 in R. 4 2 3
1
56. (3)  moles
3
After addition = 25.2 + 25.25 + 25.0 1
= 75.4 (Answer should have 3 Mass of HNO3 =   63 (molar mass)
3
significant figures)
Mass of HNO3 = 21 g
75.4
Average =  25.1
3
 In average value 3 significant figures
should be reported

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