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MSDS Unipoxi Lining Clear
MSDS Unipoxi Lining Clear
1. IDENTIFICATION
A. Product name
- UNIPOXY LINING CLEAR BASE
C. Supplier information
- Company name : KCC Corporation
- Address : 764, Gwahak-ro, Bongdong-eup, Wanju_Gun, Jeollabuk-do
- Emergency telephone
: 82-63-260-7000
number
2. HAZARD IDENTIFICATION
A. GHS Classification
- Acute toxicity (dermal) : Category1
- Skin corrosion/irritation : Category2
- Serious eye damage/irritation : Category2A
- Skin sensitization : Category1
- Germ cell mutagenicity : Category1B
- Carcinogenicity : Category1B
- Acute aquatic toxicity : Category2
- Chronic aquatic toxicity : Category2
○ Signal words
- Danger
○ Hazard statements
- H310 Fatal in contact with skin
- H315 Causes skin irritation
- H317 May cause an allergic skin reaction
- H319 Causes serious eye irritation
- H340 May cause genetic defects
- H350 May cause cancer
- H401 Toxic to aquatic organisms.
- H411 Toxic to aquatic life with long lasting effects
○ Precautionary statements
1) Prevention
- P201 Obtain special instructions before use.
- P202 Do not handle until all safety precautions have been read and understood.
- P261 Avoid breathing gas/mist/vapours/spray.
- P262 Do not get in eyes, on skin, or on clothing.
- P264 Wash hands thoroughly after handling.
- P270 Do not eat, drink or smoke when using this product.
- P272 Contaminated work clothing should not be allowed out of the workplace.
- P273 Avoid release to the environment.
- P280 Wear protective gloves/protective clothing/eye protection/face protection.
- P281 Use personal protective equipment as required.
2) Response
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- P302+P350 IF ON SKIN: Gently wash with plenty of soap and water.
- P302+P352 IF ON SKIN: Wash with plenty of soap and water.
- P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
- P308+P313 If exposed or concerned: Get medical advice/attention.
- P310 Immediately call a POISON CENTER or doctor/physician.
- P321 Specific treatment
- P322 Specific measures
- P332+P313 If skin irritation occurs: Get medical advice/attention.
- P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
- P337+P313 If eye irritation persists: Get medical advice/attention.
- P361 Remove/Take off immediately all contaminated clothing.
- P362 Take off contaminated clothing and wash before reuse.
- P363 Wash contaminated clothing before reuse.
- P391 Collect spillage.
3) Storage
- P405 Store locked up.
4) Disposal
- P501 Dispose of contents/container in accordance with local/regional/national/international regulation
3. COMPOSITION/INFORMATION ON INGREDIENTS
2,2'-[(1-Methylethylidene)bis(4,1-
2,2-Bis(4'-glycidyloxyphenyl)propane phenyleneoxymethylene)]bisoxira 1675-54-3 67 ~ 74
ne
B. Skin contact
- Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
- Wash contaminated clothing thoroughly before re-using.
- Get medical attention immediately.
- Go to the hospital immediately if symptoms(flare, irritate) occur.
- Prevent the spread of the skin.
- Remove contaminated clothing, shoes and isolate.
- Wash thoroughly after handling.
- Wear gloves when washing the patient, and please avoid contact with contaminated clothing.
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C. Inhalation contact
- When exposed to large amounts of steam and mist, move to fresh air.
- Take specific treatment if needed.
- Get medical attention immediately.
- If breathing is stopped or irregular, give artificial respiration and supply oxygen.
D. Ingestion contact
- Please be advised by doctor whether induction of vomit is demanded or not.
- Rinse your mouth with water immediately.
- Get medical attention immediately.
E. Delayed and immediate effects and also chronic effects from short and long term exposure
- Not available
F. Notes to physician
- Notify medical personnel of contaminated situations and have them take appropriate protective measures.
- If exposed or concerned, get medical attention/advice.
5. FIREFIGHTING MEASURES
A. Suitable (Unsuitable) extinguishing media
- Dry chemical, carbon dioxide, regular foam extinguishing agent, spray
- Avoid use of water jet for extinguishing
B. Environmental precautions
- Prevent runoff and contact with waterways, drains or sewers.
- If large amounts have been spilled, inform the relevant authorities.
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- Spilled material should be treated as a potential risk of waste collected.
B. Engineering controls
- Business owner is recommended to maintain below recommended exposure limits for the working place with general exhaust of
gas/vapour/mist/fume.
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- Wear appropriate clothing.
○ Others
- Not available
A. Appearance
- Appearance Liquid(Viscous liquid)
- Color CLEAR
B. Odor Solvent odor
C. Odor threshold Not available
D. pH Not available
E. Melting point/Freezing point Not available
F. Initial Boiling Point/Boiling Ranges Not available
G. Flash point 90 ℃
H. Evaporation rate Not available
I. Flammability(solid, gas) Not available
J. Upper/Lower Flammability or explosive limits Not available
K. Vapour pressure Not available
L. Solubility Not available
M. Vapour density Not available
N. Specific gravity(Relative density) Not available
O. Partition coefficient of n-octanol/water Not available
P. Autoignition temperature Not available
Q. Decomposition temperature Not available
R. Viscosity Not available
S. Molecular weight Not available
C. Conditions to avoid
- Avoid contact with incompatible materials and condition.
- Avoid : Accumulation of electrostatic charges, Heating, Flames and hot surfaces
D. Incompatible materials
- Not available
B. Delayed and immediate effects and also chronic effects from short and long term exposure
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○ Acute toxicity
* Oral
- Product (ATEmix) : >5000mg/kg
- [2,2-Bis(4'-glycidyloxyphenyl)propane] : LD50 11,300 ㎎/㎏ rat (HSDB)
- [Neodecanoic acid 2,3-epoxypropyl ester] : LD50 > 10 ㎎/㎏ Rat
- [Dodecylphenol, branched] : LD50 2100 ㎎/㎏ (ECHA)
- [2-Propenoic acid 2-ethyl-2-[[(1-oxo-2-propenyl)oxy]methyl]-1,3-propanediyl ester] : LD50 = 5000 ㎎/㎏ Rat (RTECS)
- [Solvent naphtha (petroleum), light arom.] : LD50 = 8400 ㎎/㎏ Rat (RTECS)
- [4-Heptanone, 2,6-dimethyl-] : LD50 >2000 ㎎/㎏ Rat (Guideline 401, GLP, ECHA)
- [Benzyl alcohol] : LD50 1610 ㎎/㎏ Rat (OECD SIDS)
- [Secret] : LD50 = 4250 ㎎/㎏ Rat
- [Secret] : LD50 = 8532 ㎎/㎏ Rat (IUCLID)
- [Secret] : LD50=3523 mg/kg Rat (EU Method B1) (ECHA)
- [Secret] : LD50 536 ㎎/㎏ Mouse (NLM)
- [Secret] : LD50 = 3500 ㎎/㎏ Rat (ECHA, HSDB)
- [Secret] : LD50 1414 ㎎/㎏ Guinea pig (OECD TG 401, GLP)
- [Secret] : LD50 5580 ㎎/㎏ Rat (EU Method B.1) (ECHA)
* Dermal
- Product (ATEmix) : 5mg/kg < ATEmix <= 50mg/kg
- [2,2-Bis(4'-glycidyloxyphenyl)propane] : LD50 >23,200 ㎎/㎏ Rabbit (IARC, NITE)
- [Neodecanoic acid 2,3-epoxypropyl ester] : LD50 = 4 ㎎/㎏ Rat
- [2-Propenoic acid 2-ethyl-2-[[(1-oxo-2-propenyl)oxy]methyl]-1,3-propanediyl ester] : LD50 = 5170 ㎎/㎏ Rabbit (RTECS)
- [Solvent naphtha (petroleum), light arom.] : LD50 > 2000 ㎎/㎏ Rabbit (IUCLID)
- [4-Heptanone, 2,6-dimethyl-] : LD50 >2000 ㎎/㎏ Rat (OECD Guideline 402 ,GLP, ECHA)
- [Benzyl alcohol] : LD50 2000 ㎎/㎏ Rabbit (SIDS, NITE)
- [Secret] : LD50 > 5000 ㎎/㎏ Rabbit (IUCLID)
- [Secret] : LD50 ≥1,700mg/kg Rabbit (NIER)
- [Secret] : LD50 1600 ㎎/㎏ Mouse (NLM)
- [Secret] : LD50 = 15400 ㎎/㎏ Rabbit (ECHA, ChemIDPlus)
- [Secret] : LD50 >2000 ㎎/㎏ Rat (ECHA)
- [Secret] : LD50 >5000 ㎎/㎏ Rabbit (ECHA)
* Inhalation
- Product (ATEmix) : Not available
- [Neodecanoic acid 2,3-epoxypropyl ester] : Steam LC50 > 0.25 ㎎/ℓ 4 hr Rat
- [Solvent naphtha (petroleum), light arom.] : LC50 > 5.61 mg/L 4 hr Rat (ECHA), Mist LC50= 3400 ppm 4hr Rat (IUCLID)
- [4-Heptanone, 2,6-dimethyl-] : Vapour LC50 > 14.5 mg/L 4 hr (OECD Guideline 403, ECHA)
- [Benzyl alcohol] : LC50 = 6.25 ㎎/ℓ 4 hr (1000ppm/8hr) Rat (HSDB)
- [Secret] : Steam LC50 = 28.8 mg/L/4 hr Rat (KOSHA)
- [Secret] : Vapor LC50 = 10 ~ 20 mg/L/4hr (NIER)
- [Secret] : Vapor LC50 17.8 mg/L 4 hr Rat (conversion value of 4000 ppm) (ECHA, HSDB)
- [Secret] : Vapor LC50 >7.4 ㎎/ℓ 7 hr Rat (ECHA)
- [Secret] : LC50 >20 ㎎/ℓ Rat (OECD TG 403) (ECHA)
○ Skin corrosion/irritation
- Causes skin irritation
○ Serious eye damage/irritation
- Causes serious eye irritation
○ Respiratory sensitization
- Not available
○ Skin sensitization
- May cause an allergic skin reaction
○ Carcinogenicity
* IARC
- [Secret1] : Group 3
- [2-Propenoic acid 2-ethyl-2-[[(1-oxo-2-propenyl)oxy]methyl]-1,3-propanediyl ester1] : Group 2B
- [Secret2] : Group 2B
- [Secret3] : Group 3
- [2,2-Bis(4'-glycidyloxyphenyl)propane3] : Group 3
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* OSHA
- Not available
* ACGIH
- [Secret1] : A3
- [Secret2] : A3
- [Secret3] : A4
- [Secret4] : A4
* NTP
- Not available
* EU CLP
- [Solvent naphtha (petroleum), light arom.0] : Carc.1B
○ Germ cell mutagenicity
- May cause genetic defects
○ Reproductive toxicity
- Not available
○ STOT-single exposure
- Not available
○ STOT-repeated exposure
- Not available
○ Aspiration hazard
- Not available
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- [Benzyl alcohol] : EC50 770mg/L 72hr (NITE: Ministry of the Environment, 1997)
- [Secret] : EC50 = 11.038 ㎎/ℓ 96 hr (Estimate)
- [Secret] : EC50 0.212 ㎎/ℓ 96 hr (Estimate)
- [Secret] : EC50 1000 ㎎/ℓ 72 hr Selenastrum capricornutum (SIDS)
- [Secret] : ErC50 4.06 ㎎/ℓ 73 hr (OECD TG201, GLP) (ECHA)
- [Secret] : EC50 3.6 ㎎/ℓ 96 hr (EPA 1985, GLP)
- [Secret] : EC50 = 500 ㎎/ℓ 72 hr (IUCLID)
- [Secret] : EC50 911 ㎎/ℓ 72 hr Selenastrum capricornutum(OECD TG 201)
C. Bioaccumulative potential
○ Bioaccumulative potential
- [2,2-Bis(4'-glycidyloxyphenyl)propane] : Log BCF 1.11 ± 0.75, BCF 31 (OASIS CATABOL QSAR estimate, ECHA )
- [Neodecanoic acid 2,3-epoxypropyl ester] : BCF 148.8 (Estimate)
- [Dodecylphenol, branched] : BCF = 6266 (Estimate)
- [4-Heptanone, 2,6-dimethyl-] : BCF 130 (ECHA)
- [Secret] : BCF 470.5 (Estimate)
- [Secret] : BCF25.9 (ECHA)
- [Secret] : BCF 1
- [Secret] : BCF = 0.3493 (Estimate)
○ Biodegradation
- [2,2-Bis(4'-glycidyloxyphenyl)propane] : 0 (%) 28 day (NITE)
- [Neodecanoic acid 2,3-epoxypropyl ester] : 7 ~ 8 (%) 28 day (OECD TG 301D) (IUCLID)
- [4-Heptanone, 2,6-dimethyl-] : 88 % 20 day (ECHA)
- [Benzyl alcohol] : Biodegradability = 94 (%) 28 day (Aerobic, Activated Sludge)
- [Secret] : Biodegradability 90 (%) 5 day (IUCLID)
- [Secret] : Biodegradability > 60 (%) 28 day (OECD Screening Information Data Set)
- [Secret] : 90 % 28 day (OECD TG301F, GLP)(ECHA)
- [Secret] : 70-80% 28 day (ISO 14593 CO2, GLP)
- [Secret] : 90.4 % 28 day (OECD TG 301G)
- [Secret] : 80 % 20 day (Readily biodegradable) (ECHA)
D. Mobility in soil
- [Secret] : log Kow = 3.12 (measured) (ortho), 3.2 (measured) (meta), 3.15 (measurements) (p) (5)
- [Secret] : log koc= 2.41, measured (ECHA)
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13. DISPOSAL CONSIDERATIONS
A. Disposal methods
- Stabilization and minimization treatment by incineration or similar method can be applied, if more than two kinds of designated wastes are in
mixture state and it is impractical to separate them
- Oil water separation technology shall be applied as pre-waste treatment if it is applicable
- It shall be treated by incineration
C. Hazard Class
-9
E. Marine pollutant
- Applicable
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- Not applicable
* CERCLA Section 103 (40CFR302.4)
- [Secret] : 45.3599 kg 100 lb
- [Secret] : 453.599 kg 1000 lb
* EPCRA Section 302 (40CFR355.30)
- Not applicable
* EPCRA Section 304 (40CFR355.40)
- Not applicable
* EPCRA Section 313 (40CFR372.65)
- [Secret] : Applicable
○ Rotterdam Convention listed ingredients
- Not applicable
○ Stockholm Convention listed ingredients
- Not applicable
○ Montreal Protocol listed ingredients
- Not applicable
B. Issue date
- 2014-01-17
D. Other
- This SDS is prepared according to the Globally Harmonized System (GHS).
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