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68

sep
2007
Technical note

Sulfate-resisting Concrete
Sulfate-resisting
concrete
INTRODUCTION Sulfate exposure conditions in Australia
This Technical Note discusses the mechanisms of Sulfates may occur naturally in soil and
external sulfate attack and the physio-chemical groundwater, industrial effluents and wastes
effects on concrete. It reports the outcome of a from chemical and mining industries, as well as
research project conducted by Cement Concrete in sea water. Acid sulfate soils are associated with
& Aggregates Australia (CCAA). In this project the naturally occurring sediments and soils containing
performance of ten Australian concrete mixes, iron sulfides usually found in mangroves, salt marsh
proportioned using five sulfate-resisting cements vegetation or tidal areas and low lying parts of
(Type SR) complying with AS 3972 Portland and coastal floodplains, rivers and creeks.
blended cements was evaluated in both neutral and Some cases of aggressive sulfate soil and
acidic sulfate conditions The results were examined groundwater conditions have been reported in
in relation to the long-term concrete exposure Australia. In certain sections of the Parramatta Rail
data from the US Portland Cement Association Link in the Lane Cove Valley in Sydney, aggressive
(PCA) and the 40-year non‑accelerated exposure sulfate and carbon dioxide in groundwater were
programme at the US Bureau of Reclamation found; concretes with and without protective
(USBR). Current specifications for sulfate-resisting membrane were therefore used to satisfy the
concrete in relevant Australian Standards and some 100 years design life. The concrete at the base
Road Authorities’ specifications are reviewed in of water cooling towers have been found to
the context of CCAA research findings which are be exposed to high sulfate levels in the closed
applicable to concrete structures in sulfate or acid circuit cooling systems. In the case of cooling
sulfate soil conditions. towers at Bayswater Power Station in NSW, the
concrete was found to show no sign of attack
when inspected after 10 years of service. In the
M5 East Motorway project at Cooks River Crossing
near Kingsford Smith airport in Sydney, sulfate- the pH of the solution and the microstructure
resisting concrete was used for the piles and of the hardened cement matrix. Some cements
diaphragm wall constructed in areas where the are more susceptible to magnesium sulfate
groundwater was found to have very high sulfate than sodium sulfate, the key mechanism is
contents, possibly caused by effluents from the replacement of calcium in calcium silicate
the industrial areas around the Cooks River. hydrates that form much of the cement matrix.
According to the NSW Acid Sulfate Soils This leads to a loss of the binding properties.
Management Advisory Committee2, acid sulfate Formation of brucite (Mg(OH)2) and magnesium
soils are soils containing highly acidic soil horizons silicate hydrates is an indication of the attack.
or layers resulting from the aeration of soil The presence of chloride in soil and
materials that are rich in iron sulfides. The oxidation groundwater may be beneficial since there is
produces hydrogen ions in excess of the sediment’s considerable evidence, from seawater studies5,6,
capacity to neutralise the acidity, resulting in that the presence of chloride generally reduces
soils of pH of 4 or less. The field pH of these expansion due to sulfate attack. The risk of
soils in their undisturbed state is pH 4 or more corrosion of embedded metals in buried concrete
and may be neutral or slightly alkaline. Organic in non-aggressive soil is generally lower than
acids are common in coastal ecosystems and can in externally exposed concrete. However, high
produce acid water and sediment. The pH of these chloride concentrations in the ground may
sediments is usually around 4.5–5.5. As they do not increase the risk of corrosion since chloride
have the ability to generate additional acid when ions may permeate the concrete, leading
exposed to air, they do not exhibit the same kinds to a depassivation of the metal surface.
of environmental risks that are associated with acid Above the soil or water table level in the soil
sulfate sediments. profile where the concrete surface is exposed
In New South Wales, acid sulfate soil conditions to a wetting and drying condition, the concrete
have been reported by the Roads and Traffic will also be subjected to a physical sulfate
Authority3 in the Pacific Highway upgrading attack. Folliard and Sandberg7 reported that the
programme, eg at the Chinderah Bypass which physio-chemical process is more prevalent in
involved the dredging and disposal of potential the field, in which concrete is physically, rather
acid sulfate soil from a site near a major bridge than chemically attacked by sodium sulfate. The
over the Tweed River at Barneys Point. Other only reactions involved are within the sodium
locations include the floodplains of many rivers sulfate-water system; the phase changes from
including Clarence River, Clyde River, Hawkesbury a solution to a solid, or from an anhydrous solid,
River, Hunter River, Macleay River, Manning River, thenardite (Na2SO4), to its hydrated form, mirabilite
Myall River, Nambucca River, Richmond River (Na2SO4 .10H2O). The amount of deterioration
and Shoalhaven River. In Queensland, acid sulfate is a function of the potential crystallisation
soils have also been found in the coastal regions pressures or the volume increase associated with
including sulphide-bearing source rock and sodic a given mechanism. Any of the mechanisms can
soils which cover 45% of Queensland4. This has potentially produce pressures that are an order
led Queensland Main Roads to draw designers’ of magnitude greater than the tensile strengths
attention to detailed analysis of the chemistry of the of the concrete. Further, the same pressures can
soil and groundwater, and the design of concrete to be reached by any one of several crystallisation
withstand these potentially harsh conditions. mechanisms by simply varying the temperature
and concentration of the sulfate solution in the
Mechanisms of Sulfate attack system. The volume increase could cause severe
The deterioration of concrete exposed to sulfate is deterioration of the concrete but may be partially
the result of the penetration of aggressive agents accommodated in air-entrained concrete.
into the concrete and their chemical reaction
with the cement matrix. The three main reactions Physical and chemical resistance of
involved are: concrete
■ Ettringite formation – conversion of hydrated Both the physical resistance of concrete to the
calcium aluminate to calcium sulphoaluminate, penetration and capillary-induced migration of
■ Gypsum formation – conversion of the calcium aggressive agents and the chemical resistance
hydroxide to calcium sulfate, and of the concrete to the deleterious reactions
■ Decalcification – decomposition of the hydrated described above are important attributes of sulfate-
calcium silicates. resisting concrete. Thus factors influencing the
These chemical reactions can lead to expansion permeability and surface porosity of the concrete
and cracking of concrete, and/or the loss of and the chemical resistance of cement are prime
strength and elastic properties of concrete. The performance parameters of concrete exposed to
form and extent of damage to concrete will depend sulfate attack.
on the sulfate concentration, the type of cations The physical resistance of concrete is
(eg sodium or magnesium) in the sulfate solution, traditionally achieved by specifying mix design

Page 2 Sulfate Resisting Concrete


CONCRETE 28-DAY COMPRESSIVE STRENGTH (MPa)
W/C = 0.4 W/C = 0.5
parameters such as maximum water–cement ratio
80
and minimum cement content, while the chemical
resistance is by the use of sulfate-resisting cement. 70
This is the approach adopted in codes and guideline
60
such as ACI 3188 and BRE Special Digest 19 and
directly or indirectly in relevant Australian Standards. 50
Recent research has focused on performance- 40
based specification for sulfate-resisting concrete.
A specification based on water permeability was 30
proposed by Sirivivatnanon and Khatri (1999)10 . More 20
recently, a rapid electrochemical test procedure
similar to ASTM C 1202 Indication of Concrete’s 10
Ability to Resist Chloride Ion Penetration which was 0
1 2 3 4 5
proposed by Tumidajski and Turc (1995)11 has been
CEMENTS
used to assess the ability of concrete to resist sulfate
penetration. Long-term concrete performance tests Figure 1 28-day compressive strength of the concretes
are being evaluated by CCAA to substantiate the each at W/C of 0.4 and 0.5
validity of the proposed approaches.
The role of concrete quality on the resistance to
both the chemical and physical attack by sulfates retention of 100 mm x 200 mm duplicate cylinders
have been studied by researchers at the PCA. It throughout the exposure period of three years.
involved long-term exposure of concrete prisms The 28 day compressive strength of the concrete
in the laboratory and in the field. Findings have varied widely from 45.5–75.5 MPa for W/C of 0.4
been reported by Verbeck (1967)12 and Starks to 32.5–59.0 MPa for W/C of 0.5, reflecting the
(2002)13. Interestingly, it was found that a continuous influence of different SR cements. Results are
immersion in sulfate solution was a relatively shown in Figure 1.
mild condition compared with cyclic wetting and
drying. The physical resistance of the concrete to Performance of Buried Concrete
the physio-chemical sulfate attack was achieved From previous CSIRO and PCA studies10,13 of
by limiting the maximum water–cement ratio and long‑term expansion of concrete submerged in
minimum cement content of the concrete, and the sodium sulfate solution, an expansion performance
application of a sealer to the surface of concrete. limit of 120 microstrain per year within the first
three years of exposure has been found to indicate
Australian Research on Sulfate-resisting long-term volume stability of the concrete. After
Concrete three years of exposure, all ten concretes from
In 2002, CCAA initiated a research project to the CCAA research project performed well both
develop a performance–based specification for in terms of expansion and strength retention. As
sulfate-resisting concrete. The research was shown in Figures 2 and 3, all the concretes were
undertaken and completed by CSIRO in 2006. In stable in both neutral and acidic sulfate solutions
this research project, ten concrete mixes were with increases in expansion rate well below the
proportioned using five sulfate-resisting cements, performance limit of 120 microstrain per year, and
Type SR, complying with AS 3972, each at two with strength retentions well above 90% of the
water–cement ratios (W/C) of 0.4 and 0.5. The 28-day compressive strength. The results suggest
concrete was proportioned with a fixed dosage of that all concretes of 0.4 and 0.5 water–cement
water–reducing admixture and a variable dosage of ratio, irrespective of the strength, will provide good
superplasticiser to produce concrete with a slump resistance to sulfate attack in the long-term and
of 120 ± 20 mm. The cement contents were 415 and could be classified as sulfate-resisting concretes.
335 kg/m3 for the mixes with W/C of 0.4 and 0.5 In Figures 4 and 5, it can be observed that the
respectively. The concrete specimens were moist compressive strength of the concrete increased
cured for three days and kept in the laboratory well above the 28 day strength in the first 1–2 years
until testing at 28 days. (Hence there was a limited of immersion, followed by a gradual reduction in
depth of carbonation at the surface of the concrete strengths. After three-year exposure in both neutral
at the commencement of sulfate exposure.) and acidic sodium sulfate solutions, the strengths
Compressive strength and water permeability remained at or above the 28-day strength level. This
of the concretes were determined at 28 days. clearly showed the integrity of the concrete and its
At 28 days, the concrete specimens were mechanical resistance to sulfate attack.
exposed by full immersion in 5% (50,000 ppm) The expansion performance limit was derived
sodium sulfate solutions maintained at pH from a long-term study by the PCA of concretes
of 7 ± 0.5 and 3.5 ± 0.5. The performance of the exposed to accelerated field and laboratory-
concrete was measured in terms of expansion simulated sulphate environments reported by
of 75 x 75 x 285 mm duplicate prisms and strength Stark13. In Sacramento, California concrete prisms

Sulfate Resisting Concrete Page 3


CEMENTS: 1 2 3 4 5 CEMENTS: 1 2 3 4 5
400 400

300 300

200 200
EXPANSION (Microstrains)

EXPANSION (Microstrains)
100 100
pH = 7 W/C = 0.5 pH = 3.5 W/C = 0.5

0 0
0 200 400 600 800 1000 0 200 400 600 800 1000
IMMERSION TIME (Days) IMMERSION TIME (Days)

400 400

300 300

200 200
EXPANSION (Microstrains)

EXPANSION (Microstrains)

100 100
pH = 7 W/C = 0.4 pH = 3.5 W/C = 0.4

0 0
0 200 400 600 800 1000 0 200 400 600 800 1000
IMMERSION TIME (Days) IMMERSION TIME (Days)

Figure 2 Expansion of concrete prisms in 5% Na2SO4 Figure 3 Expansion of concrete prisms in 5% Na2SO4
solution at pH 7 (CCAA research project) solution at pH 3.5 (CCAA research project)

from 50 concrete mixtures were partially buried exposure did not exhibit rapid increase in the rate
in sodium sulfate-rich soils, maintained at about of expansion in subsequent years nor did their
6.5% or 65,000 ppm sodium sulfate concentration, maximum expansion reach 3000 microstrain –
and exposed to cyclic immersion and atmospheric an elastic strain limit for most concrete. This PCA
drying condition since 1989. The performance of study concluded that sulfate resistance of concrete
the prisms was rated visually from 1.0 to 5.0 with a was mainly governed by water–cement ratios at
rating of 1.0 indicating excellent performance with W/C of 0.4 and below, whereas cement composition
virtually no evidence of deterioration, while a rating would influence the performance of concrete with
of 5.0 represented major loss of paste matrix and intermediate W/C of 0.4 to 0.55.
widespread exposure and loss of coarse aggregate The US Bureau of Reclamation (USBR)
particles. It was found that the main deterioration non‑accelerated sulfate testing programme,
mechanism of concrete in this wetting and drying on concrete cylinders partially submerged in
condition was due to the physio-chemical process of 2.1% or 21,000 ppm sodium sulfate solution at
sulfate attack. ambient temperature, showed concrete with
A second set of companion concrete prisms W/C ratio of 0.45 and lower to be intact even
were immersed in a 6.5% or 65,000 ppm sodium after 40-year exposure period14. The Bureau
sulfate solution in PCA’s Construction Technology defined failure when expansion reached 0.5% or
Laboratories (CTL) in Skokie, Illinois and their 5000 microstrain. The results also showed the
expansion monitored for over 12 years. All the importance of permeability and the importance
concrete prisms were reported to perform very well of cement composition for concrete with W/C
after a 12–year exposure period. More importantly, exceeding 0.45. USBR results confirm the validity
all concrete with low expansion rate (within of current service life performance specification.
120 microstain) per year in the first three years of

Page 4 Sulfate Resisting Concrete


CEMENTS: 1 2 3 4 5 CEMENTS: 1 2 3 4 5
100 100

80 80

60 60
COMPRESSIVE STRENGTH (MPa)

COMPRESSIVE STRENGTH (MPa)


40 40

pH = 7 W/C = 0.5 pH = 3.5 W/C = 0.5


20 20

0 0
0 300 600 900 1200 0 300 600 900 1200
IMMERSION TIME (Days) IMMERSION TIME (Days)

100 100

80 80

60 60
COMPRESSIVE STRENGTH (MPa)

COMPRESSIVE STRENGTH (MPa)

40 40

pH = 7 W/C = 0.4 pH = 3.5 W/C = 0.4


20 20

0 0
0 300 600 900 1200 0 300 600 900 1200
IMMERSION TIME (Days) IMMERSION TIME (Days)

Figure 4 Strength retention of concretes in 5% Figure 5 Strength retention of concretes in 5%


Na2SO4 solution at pH 7 (CCAA research project) Na2SO4 solution at pH 3.5 (CCAA research project)

Performance of Partly Buried Concrete deterioration in the outdoor exposure was due
While most buried concrete elements such as largely to cyclic crystallisation of NaSO4 salts after
piles and footings are likely to be kept moist sufficient evaporation of moisture from the outdoor
throughout their service life, parts of some of exposure as postulated by Folliard and Sandberg7.
them (eg the top of footings and pile caps) may be This is probably the reason for the effectiveness
exposed to periodic wetting and drying conditions. of a sealer, such as silicon and linseed oil, in
The PCA study confirmed that the exposure to limiting the capillary-induced migration of sulfate,
alternate immersion and atmospheric drying in and thus improving the performance of concrete
the sodium sulfate-rich soil was a more severe including concrete with higher W/C of 0.49–0.52.
exposure condition than continuous immersion With all ten Australian concrete mixes
in the same solution. Attention must therefore performing exceedingly well under full immersion in
be given to the sulfate resistance of concrete sodium sulfate solutions at both neutral and acidic
under such exposure conditions. Stark13 found a conditions, and a cement content of 415 kg/m3
consistently improved trend in the rating of the in the 0.4 W/C series, it is likely that the five low
surface deterioration of concrete with increased water–cement ratio concretes will also perform very
cement content irrespective of the type of cement. well in the severe wetting and drying condition. With
In the PCA’s 17 concrete mixtures with a cement appropriate surface protection, the 0.5 W/C series
content of 390 kg/m3, most concretes had a rating of concrete with a cement content of 335 kg/m3
between 1.4 and 3.8 after 12–years exposure would also be expected to perform well in the
in the sulfate‑rich soil ground in Sacramento. more aggressive wetting and drying condition.
This is considered to be a good performance of
the concrete under such an aggressive sulfate
environment. Stark found that the observed severe

Sulfate Resisting Concrete Page 5


Table 1 Strength and cover requirements for sulfate soils
(Summarised from Tables 4.8.1 and 4.10.3.2 in the revised AS 3600)

SO4
Exposure Characteristic Minimum cover
In groundwater (mg/L) In soil (%) classification strength (MPa) (mm)

<1000 <0.5 A2 25 50
1000–3000 0.5–1 B1 32 501
3000–10,000 1–2 B2 40 501,2
>10,000 >2 C1 and C2 ≥50 651,2,3

Notes:
1 It is recommended that cement be Type SR.
2 Additional protective coating is recommended.
3 The cover may be reduced to 50 mm if protective coating or barriers are used.

Table 2 Additional requirements (from Table 8 of QDMR MSR11.70)

Exposure Minimum cementitious Maximum water–cementitious Strength grade


classification content (kg/m3) ratio (MPa)

B1 320 0.56 32
B2 390 0.46 40
C 450 0.40 50

As can be noted, the findings from CCAA research project also support the above specifications.

Specifying sulfate-resisting concrete conditions in term of its permeability. In severe and


Sulfate-resisting concrete has traditionally been very severe conditions, where sulfate levels exceed
specified prescriptively by the type of cement and 2000 ppm in groundwater or 1% in soil, AS 3735
mix proportion limits in terms of maximum water– Supplement18 recommends a minimum cement
cement ratio and minimum cement content. In content of 320 kg/m3 and a maximum water–cement
highly acidic and permeable soils where pH is below ratio of 0.5 and the use of Type SR cement.
3.5, additional protective measures are required to The findings from CCAA research, described in
isolate the concrete from direct contact with the the previous section, supported the specification
aggressive ground condition. ACI 3188 and BRE SD19 of sulfate-resisting concrete by strength grade
are examples of these specifications. BRE SD1 and cover (AS 2159 and AS 3600), and in particular,
is particularly progressive in recommending confirmed the expected performance of the sulfate-
specifications for sulfate-resisting concrete for resisting concrete in the moderate (B2) and severe
intended working life of 50 years for building works to very severe (C1 and C2) exposure classifications
and 100 years for civil engineering structures. shown in Table 1.
It should be noted that the Australian Standard
Australian Standards for bridge design AS 510019 provides no specific
In the revision of the Australian Standard for guidance on specifying concrete for 100 years
concrete structures AS 360015 (expected to be design life in sulfate conditions.
published by the end of 2007), specifications for
concrete in sulfate soils with a magnesium content Other Specifications
of less that 1000 mg/L have been introduced. For Road authorities, such as the RTA in New South
each exposure classification, concrete is specified Wales and the Queensland Department of Main
in terms of concrete grade and minimum concrete Roads, are specifying sulfate-resisting concrete
cover, see Table 1. The current Australian Standards based on exposure classifications in Austroads
for piling, AS 215916 and for concrete structures Bridge Design Code (superseded by AS 5100),
for retaining liquids, AS 373517, recommend but with additional limits on maximum W/C and
the specification of certain concrete grades and minimum cement content. Queensland Department
corresponding covers for a design life 40–60 years of Main Roads refers to MRS11.70 with the
in a range of exposure classifications. The exposure additional requirements shown in Table 2.
classification is defined by the magnitude of sulfate
in the soil or in groundwater, pH level and the soil

Page 6 Sulfate Resisting Concrete


Thermocouple + 60 V 0V Sulfate-resisting concrete can be achieved using
and gas apeture Inlet a sufficient quantity of a sulfate-resisting cement
(Type SR complying with AS 3972) and a low water–
cement ratio to obtain a concrete with low water
permeability. For fully buried concrete structures, a
sulfate-resisting concrete can be achieved from an
SR cement at a cement content of 330 kg/m3 and a
0.3N NaOH Test 8.8% Na2SO4
specimen water–cement ratio of 0.5. For partially buried
structures exposed to a wetting and drying condition,
the same sulfate-resisting concrete can be used but
Metal mesh Machined
perspex with additional protective measure such as the
chamber application of an appropriate sealer to the surface of
the exposed concrete. Alternatively, a sulfate-
resisting concrete can be achieved from Type SR
Figure 6 An accelerated test set-up for the rapid cement at a cement content of 415 kg/m3 and a
sulfate permeability determination water–cement ratio of 0.4. The specifications
required in the revision of AS 3600 based on
minimum compressive strength and Type SR cement
Performance-based Specifications is shown to produce adequate sulfate-resisting
Sulfate-resisting concrete has traditionally been concrete for the exposure condition indicated.
specified prescriptively by the maximum
water‑cement ratio and a specific type of SR cement. W/C = 0.4 W/C = 0.5
This is to ensure good physical resistance of the 2.0
concrete to limit the penetrating sulfate ions, and CONCRETE WATER PERMEABILITY (10 –12 m/s)
1.8
good chemical resistance of the cement matrix to
1.6
the deleterious sulfate reactions. A performance
specification based on water permeability of the 1.4
concrete has been proposed by Sirivivatnanon 1.2
and Khatri 10. As part of CCAA research, a further 1.0
attempt has been made to develop a performance- 0.8
based specification for sulfate-resisting concrete 0.6
based on the physical resistance of the concrete
0.4
(eg water permeability, rapid sulfate permeability)
0.2
and the chemical resistance of the cement (sulfate
0
expansion). A six‑hour accelerated test method for a 1 2 3 4 5
rapid sulfate permeability determination was CEMENTS
developed and is shown in Figure 6.
The influence of water permeability and rapid Figure 7 Water permeability of the concretes
sulfate permeability on the long-term sulfate at W/C of 0.4 and 0.5
resistance of concrete has been studied with initial
results shown in Figures 7 and 8 respectively. Based
on these limited data, preliminary performance- W/C = 0.4 W/C = 0.5
based specifications for sulfate-resisting concrete 2000
have been proposed using Type SR cement 1800
RAPID SULFATE PERMEABILITY (Coulomb)

complying with AS 3972:


1600
■ Concrete should have a coefficient of water
1400
permeability no greater than 1.8 x 10-12 m/s, or
■ Concrete should have a rapid sulfate 1200
permeability less than 1750 coulombs. 1000
Further research is currently underway to 800
broaden and confirm the proposed performance- 600
based specifications for concrete exposed to sulfates.
400
200
Conclusions
0
Sulfate resistance of the concrete is a function of 1 2 3 4 5
its physical and chemical resistance to penetrating CEMENTS
sulfate ions. Good physical resistance of the
concrete is directly related to the water-cement Figure 8 Rapid sulfate permeability of the
ratio and the cement content. Good chemical concretes at W/C of 0.4 and 0.5
resistance is related to the resistance of the cement
matrix to the deleterious sulfate reactions.

Sulfate Resisting Concrete Page 7


68
sep
References
1 Sulphate Attack on Concrete. Fly Ash Technical
CCAA OFFICES
SYDNEY OFFICE:

2007
Notes No.2, Ash Development Association of Level 6, 504 Pacific Highway
St Leonards NSW Australia 2065
Australia, 1995. POSTAL ADDRESS:
2 Acid Sulfate Soils Assessment Guidelines, Locked Bag 2010
St Leonards NSW 1590
NSW Acid Sulfate Soils Management Advisory
TELEPHONE: (61 2) 9437 9711
Committee, 1998. FACSIMILE: (61 2) 9437 9470
3 Selim H, Forster, G and Chirgwin G, ‘Concrete BRISBANE OFFICE:
Structures in Acid Sulfate Soils’, Proceedings Level 14, IBM Building
of Austroads Bridging the Millennia Conference, 348 Edward Street
Brisbane QLD 4000
edited by G.J. Chirgwin, Vol. 2, Sydney, 1997, TELEPHONE: (61 7) 3831 3288
pp 393–409. FACSIMILE: (61 7) 3839 6005

4 Carse A ’The design of concrete road structures for MELBOURNE OFFICE:


aggressive environments’, Proceedings of Concrete 2nd Floor, 1 Hobson Street
South Yarra VIC 3141
Institute of Australia 22nd Biennial Conference, TELEPHONE: (61 3) 9825 0200
Melbourne, 2005. FACSIMILE: (61 3) 9825 0222

5 Lea F M Chemistry of Cement and Concrete. 4th PERTH OFFICE:


edition, Elsevier, London, 2004. 45 Ventnor Avenue
West Perth WA 6005
6 Biczok I Concrete Corrosion: Concrete Protection. TELEPHONE: (61 8) 9389 4452
8th edition, Akademiai Kiado, Budapest, 1980. FACSIMILE: (61 8) 9389 4451

7 Folliard K J and Sandberg P ‘Mechanisms of ADELAIDE OFFICE:


Concrete Deterioration by Sodium Sulfate Greenhill Executive Suites
213 Greenhill Road
Crystallization’, American Concrete Institute, Eastwood SA 5063
SP145, Durability of Concrete, Third International POSTAL ADDRESS:
PO Box 229
Conference, Nice, France, pp 933–945. Fullarton SA 5063
8 Building Code Requirements for Reinforced TELEPHONE: (61 8) 8274 3758
FACSIMILE: (61 8) 8373 7210
Concrete, ACI 318–05, American Concrete Institute.
EXTRACTIVE INDUSTRIES OFFICE
9 Building Research Establishment. Concrete in PO Box 243
aggressive ground, BRE Special Digest 1:2005. Henley Beach SA 5022
10 Sirivivatnanon V and Khatri R P ‘Performance TELEPHONE: (61 8) 8353 8151
FACSIMILE: (61 8) 8353 8151
Based Specification for Sulphate Resisting
TASMANIAN OFFICE:
Concrete,’ Proceedings of International Conference
EXTRACTIVE INDUSTRIES OFFICE
on a Vision for the Next Millennium, edited by R N PO Box 246
Swamy, Sheffield, U.K., June, 1999, pp 1097–1106. Sheffield TAS 7306
TELEPHONE: (61 3) 6491 2529
11 Tumidajski P J and Turc I, A Rapid Test for Sulfate FACSIMILE: (61 3) 6491 2529
Ingress into Concrete, Cement and Concrete
WEBSITE: www.concrete.net.au
Research, Vol. 25, No. 5, pp 924–928, 1995.
EMAIL: info@ccaa.com.au
12 Verbeck G J ‘Field and Laboratory Studies of the
Sulphate Resistance of Concrete’, Proceeding of a Layout: Helen Rix Design

symposium in honour of Thorbergur Thorvaldson, Disclaimer: Cement Concrete & Aggregates


Australia is a not for profit organisation sponsored
Candana, 1967, 113–124. by the cement concrete and aggregate industries
in Australia to provide information on the many
13 Stark D C ‘Performance of Concrete in Sulfate uses of cement and concrete. This publication
Environments, RD129, Portland Cement is produced by CCAA for that purpose. Since
the information provided is intended for general
Association, (USA), 2002 guidance only and in no way replaces the services
14 Monteiro P J M and Kurtis K E, ‘Time to failure for of professional consultants on particular projects, no
legal liability can be accepted by CCAA for its use.
concrete exposed to severe sulfate attack’, Cement
CCAA respects your privacy. Your details have
and Concrete Research, Vol. 33, No. 7, pp 987–993, been collected to provide you with information on
2003. our activities, publications and services. From time
to time your details may be made available to third
15 AS 3600 Concrete Structures, Standards Australia, party organisations who comply with the Privacy
Act such as affiliated associations, sponsors of
Sydney, (revision to be published). events and other reputable organisations whose
16 AS 2159 Piling – Design and installation, Standards services we think you may find of interest. If you do
not wish to receive information from CCAA or wish
Australia, Sydney, 1995. to be taken off the database please write to the
17 AS 3735 Concrete structures for retaining liquids, Privacy Officer, CCAA, Locked Bag 2010,
St Leonards, NSW, 1590
Standards Australia, Sydney 2001.
18 AS 3735 Concrete structures for retaining liquids
Supplement – Commentary, Standards Australia,
Sydney, 2001.
19 AS 5100 Australian Standard for Bridge Design,
Standards Australia, Sydney, 2004.

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